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By Sanat Talmaki

Construction and mining worksites pose unique challenges to workers and equipment operators due to their dynamic and unstructured nature. Narrow haul roads, crowded work spaces and presence of workers and equipment in close proximity, combined with large blind spots and overall poor visibility afforded to operators lead to collisions and run-over-type accidents between equipment, workers, and other entities that may be present on the jobsite. Operations that involve machine-infrastructure interaction, particularly in the case of concealed infrastructure such as excavation and drilling lead to unintended strikes between the equipment?s end-effect or and the infrastructure. Such accident-prone scenarios can be avoided by providing operators with real-time feedback and warnings using 3D visualization and proximity monitoring of the entities present in the equipment?s vicinity. Thus the jobsite in the real world is abstracted and represented in a 3D virtual world. However, this requires the ability to create a seamless link between real-world sensors present on the equipment and/or the jobsite and the virtual environment. This paper describes a non-restrictive acquisition allocation framework that allows position and orientation sensor streams from construction and mining job sites to be used for updating 3D virtual scenes in real-time for providing vital collision avoidance warnings to equipment operators.

Aug 1, 2013

By D. Royston

In SAG mills fed with a variety of ore types, hard packing between the shell lifters can come and go depending on rock type and rock size distribution and the presence of a binder. Packing can appear in all sizes of SAG mills, and can be tenacious. High ball impact forces (depending on ball size) in larger mills may compact and encourage packing. Packing can have a negative impact on milling performance and a change in shell liner design may be required to remove it. However shell liner design changes need to be managed with care to ensure liner reliability. In smaller mills control of packing can extend shell plate wear-life and may help to maintain milling performance in fixed-speed mills through the liner wear-cycle.

Jan 1, 2012

By Paul J. Beck

The impact of mining development on the environment can be minimized through comp careful construction and accurate monitoring. Key to meeting these objectives is t information at all stages of design, development, operation and decommissioning. This paper will describe cost-effective means of gathering and managing reliable fiel groundwater flow and surface water regime within and surrounding the mine site, as localized contaminant plumes associated with mine operations, and monitoring ground quality. Recent research has led to the development of inexpensive, easy to install syst sampling/monitoring from different zones within a single borehole. Advances in elect developed small diameter probes and pumps for measuring water levels and taking wat continuous monitoring stations in remote areas can be colldeacttaeldo gaguetrosm aatnidc adlolwyn luosaidnegd from a central facility using telemetry systems powered by direct, battery or solar radio frequency, landline or cellular telephones, and satellite. Two case studies will illustrate the use of datalolgagregres sacnadl et eblaesmient rwyi dien mao nitoring sc and the use of multilevel samplers for managing a contaminant plume.

May 1, 2004

By A. J. Petrina

"At Craigmont Mines Limited, Merritt, B.C., tests were begun in March, 1965 to evaluate the use of shotcrete as a method of ground support m development headings; previously, ail drifts had. required support, which was accomplished mainly by timber and occasionally by the use of rockbolts. The tests demonstrated conclusively the effectiveness of shotcrete for supporting Craigmont's ground. Gradually, the use of timber for ground support was virtually eliminated in favour of shotcrete. This paper describes the equipment used, the operation of the equipment, pertinent cast data and opera ting details. Also discussed are other uses developed for the shot-creting equipment, the use of reinforcing bar rockbolts, and a method used at Craigmont for lining long vertical ore passes with steel plate and concrete as part of the raising cycle."

Jan 1, 1968

By C. A. Rowland

"Plant owners and operators, plant designers and grinding mill manufacturers are giving much attention to the design and manufacture of autogenous and semi-autogenous grinding mills, particularly the mills that have large diameters and draw power up to 10,000 hp and greater. Reliable designs giving long operating lives are required in today 's ore processing plants.This paper reviews bench-scale and pilot-plant testing to determine first if the ore is suitable .to be ground by these methods and then reviews the data obtained from pilot-plant testing that is used to select the mills and the grinding circuit. The paper then discusses the use of the pilot-plant results to design the mills. The most important pilot-plant data used for mill design are power and the amount of ball charge to be used. The mill size selected is a combination of these factors. Pilot-plant data not only establish power requirements, but can be used in the selection of the type of drive, variable speed or fixed speed, and the operating procedure to be followed. This leads into the mill control circuit to be used. The total charge in the mill, the type of drive and mill discharge arrangements are needed in the calculation of stresses and bearing loads. Conclusions reached from pilot-plant work are used to obtain data for process design, and autogenous and semiautogenous mill design should be part of any test program incorporating either or both of these grinding methods."

Jan 1, 1981

By A. Philipp, A. S. Middleton, G. A. Harron, A. B. Durham

"Basal till sampling techniques were used to search for gold mineralization in the Timmins, Ontario area. During 1978 and 1979, approximately 90 overburden sampling drill holes were completed in Murphy and Hoyle Townships to test specific geophysically defined target areas. A conventional tricone dual tube drill system, and a unique retractable tricone/rock coring system were used to various advantages.First pass till sampling at 800 to 1200 ft intervals perpendicular to ice transport direction yielded anomalous gold values in till and carbonatized quartz pyrite-rich bedrock chips, and lateritic soil. Subsequent induced polarization-resistivity surveys defined the areal extent of a pyritic carbonate alteration zone. A second pass till sampling/limited rock coring program evaluated the gold mineralization potential of the alteration zone. Diamond drilling has substantiated the till and bedrock gold anomalies. Further evaluation of this mineralization is currently in progress. IntroductionThis paper describes an integrated geochemical/geophysical gold mineralization discovery case history in Hoyle Township. This discovery is on a property jointly owned (I983) by Canamax Resources Inc. and Du Pont of Canada Exploration Limited. Exploration of the property began in 1978 by Rosario Resources Canada Ltd. and in 1979 a joint venture agreement was signed with Du Pont of Canada Exploration Limited. Rosario Resources Canada Ltd. was taken over by Amax Minerals Exploration in 1981, which became Canamax Resources Inc. in 1982.The work described in this paper deals with a gold mineralization discovery located three-quarters of a mile northwest of the gold deposit currently being readied for underground exploration and development. Further drilling is required to investigate the economic potential of the gold mineralization herein described."

Jan 1, 1987

Operating and Social Considerations from a Contractor?s Perspective

May 1, 2013

By J. D. Bliss, G. J. Orris, W. O. Menzie

"Analysis of gold placer data from gold placers throughout the world suggests that gold grades and volumes cannot be used to distinguish between most types of gold placers. Only the alluvial plain and fan placers are significantly different among the types of gold placers considered. Gold grades and volumes change when working gold placers go from small-volume methods to large-volume methods. The small-volume methods are either of the surface or subsurface (drift mining) type. The odds that a gold placer will be dominantly worked using small volume methods at the surface are about 5:3. Once small volume mining has occurred, the odds against subsequent large-volume mining are about 4:1. If a placer deposit is suitable for large-volume mining, and the amount of gold produced from small-volume mining was reported, an estimate of the remaining gold (log10kg) can be made using the following equation:The relationship shown by this equation suggests that very large gold placers have over half their total gold content in the rich gravels appropriate for small-volume mining. These relationships in conjunction with other data and computer simulation can be used to estimate placer gold resources for an area targeted for mineral resource assessment. IntroductionGold placers have been an important source of gold throughout man's history and may have been one of the first sources-dating back to around 6000 B.C. (Gregory, 1980). From the primitive basket to the modern floating dredge, a variety of methods have been used to work gold placers. Placers are found in a wide spectrum of geologic and climatic settings. They have been classified by using a mixed set of criteria including age (Recent, Tertiary), climate (desert), fluvial position (modern channel, bench, alluvial fan), environment of deposition (eluvial, alluvial, residual, beach), type of transport (stream, wind, glacier), and whether the placer is buried or at the surface (Boyle, 1979; Wells, 1969). Several mining methods have usually been used to extract gold from anyone placer."

Jan 1, 1987

By I. Jackman

"Gold is present in different forms and associations in different ores. Flotation is used to recover gold and minerals associated with gold, but the applicability and type of flotation vary. The purpose of flotation in a gold recovery plant is largely dependent on the mineralogical association of the gold, and environmental and economic considerations. In this paper, the role of flotation in the recovery of gold is reviewed. The paper will describe examples of gold recovery by flotation including flotation of native gold, gold associated with sulphides including specifically copper sulphides, gold associated with tellurides, gold ores containing carbonaceous material and gold contained in tailings.INTRODUCTIONFlotation is widely used in the recovery of gold. However, the objectives and the mode of application are quite variable dependent on the type of ore, the gold association(s), other metal values, marketing considerations and environmental requirements. In this paper, a range of different applications of flotation incorporated in the recovery of gold are discussed. The reasons for each particular application are outlined and metallurgical results are presented.The mineralogy of the ore and the gold associations are fundamental influences on gold recovery. The use of flotation to concentrate gold is dictated by the mineralogy of the ore and gold. The fundamental factors are mineral/gold size, liberation size, association of the gold and type of gangue minerals or other valuable minerals. Gold can exhibit a range of sizes in a host from relatively large size (+50 µ) to refractory size (1 µ and sub-micron size). Similarly, the gold can occur in a number of phases in the same host. For example, the gold was present as petzite (AgAu telluride), calaverite (AuTe2) and native gold in a gold telluride ore and each of these minerals was associated with the pyrite host.Understanding the gold mineralogy and association is important in establishing the correct process route. The gold mineralogy is established by good mineralogy, use of diagnostic tools such as diagnostic leaching and assay by size fraction analyses and basic metallurgical testwork."

Jan 1, 1995

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By C. R. Edwards, J. R. Smith

"INTRODUCTIONThe purpose of this paper is to give an overview of the ALSANDS PROJECT, with emphasis on the approach taken in the design of the Primary Extraction and Froth Treatment Plants.The Alsands Consortium (Table 1) is a Joint Venture of 9 companies formed in 1978, with its prime objective to obtain governmental approval and concomitant suitable commercial terms to build and operate a third oil sands mining and upgrading facility in the Athabasca Oil Sands Deposit.Alsands Energy Limited is the Consortium Manager.The Alsands Project will provide about 10 percent of Canada's forecast crude oil production by 1990, which will be 20,700 cubic metres per day (130,000 barrels/day) of synthetic crude oil plus 1,100 cubic metres per day (7,000 barrels/day) of liquid petroleum gases. To construct Alsands the time required by construction labour, field non-manual and engineering support personnel as well as those trades involved in project-related urban development will total approximately 100,000,000 manhours or 50,000 man years. During regular operations, 4,800 people will be employed by Alsands.Approximately $13 billion will be spent to design, construct and start up the plant by the scheduled 1988 completion date."

Jan 1, 1982

By N. Nemeth

A brief summary of available filtration research is given. Its usefulness and shortcomings to practical application are examined and suggestions for new avenues of research outlined.

Jan 1, 1967

By O. Mejia

"As study was undertaken to investigate the relationship between mill liner wear and grinding energy efficiency and to assess the opportunity to control mill speed to improve energy performance as mill liner wears. The study involved analysis of plant operating data and liner wear profiles over time. The operating work index was found to be an effective tool to identify the decrease of grinding efficiency along the liner service. The plant data show that the mill grinding efficiency as determined by monitoring the operating work index, and throughput decreases as liner wears. However, efficiency and throughput can be maintained by either changing the liner more frequently or by increasing the mill speed. Two scenarios for increasing mill throughput were analyzed. The first one involves changing the liner before the efficiency drops and the second one requires increasing the mill speed from 75% to 79%. Both scenarios show financial benefits that can be used in mill operations.INTRODUCTION The analysis of the mill power draw is used in this study as a key parameter for comparing mill liner profile and its effect on mill performance. Current technology and simulation software used in the mining industry do not factor in the impact of liner wear profiles in grinding efficiency and mill throughput (Toor, 2013). To address this gap, this study provides an analysis of key factors affecting mill throughput and grinding efficiency: mill speed, ball loading, and liner profiles. Several years of plant mill operating data, published research papers, and MillTraj® simulation results are used to demonstrate that face angles impact grinding efficiency and throughput and that mill speed can be used to overcome this problem. Moreover, the liner profile wear analyses clarify a mismatch between actual and estimated power draw calculations."

Jan 1, 2019

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By D. Cronin, A. Plumtree, A. Hosseini

"Crack in corrosion (CIC) linepipe defects are hybrid defects not directly addressed by existing assessment methods. To investigate the collapse pressure of these defects, CIC defects were formed in 508 mm (20 in) diameter, 5.7 mm thick API X52 linepipe. These defects were 200mm long and varied in depth from 3.0 to 3.8 mm. The respective failure pressures decreased from 14.3 MPa for the plain pipe to 7.9 and 6.2 MPa respectively. A standard FAD method was applied to evaluate these defects as equivalent length and depth cracks, predicting the rupture pressure conservatively by 18% on average. However, when assessed as equivalent cracks with a reduced wall thickness corresponding to the corrosion depth, the predicted collapse pressures were more accurate, approximately 14% conservative on average.INTRODUCTIONPipelines are a safe and efficient method for transporting high volumes of oil and gas. However, aging pipelines may experience defects, such as cracks or corrosion. Present approaches include detection, assessment and repair of defects before they may become critical to the integrity of the line. There are different codes and standards for assessing pipeline defects, depending on the type of defect, with API 579 (API, 2000) being the most common code for the assessment of cracks in oil and gas pipelines . Corrosion is commonly assessed using RSTRENG (Kiefner & Vieth, 1989). Other methods such as the Finite Element method and the CPS method (Cronin & Pick, 2002) may be used for crack and corrosion, respectively.At present, there is no specific method or procedure for assessing crack in corrosion (CIC) defects, and as a consequence there is a need to provide an assessment and evaluation of the integrity of these defects in order to determine the requirements for defect repair or hydro line testing. Hence, the goal of this study was to provide guidance for the assessment of CIC defects for linepipe.CRACK IN CORROSION DEFECTS (CIC)Significant amounts of corrosion and cracking are not generally found together (Hosseini, 2010). However, a new hybrid defect including cracking within corrosion (CIC) has been identified in operating pipelines. In this case, cracking coincident with corrosion (schematic shown in Figure 1) provides the motivation for the current study."

Jan 1, 2012

By A. F. Robertson

FOR several years, the rock-burst question has been given serious consideration by the operating staff at Wright-Hargreaves mine and, as a result of observations and experiences, several different methods of mining have been developed which are now in use in various parts of the mine. These are described in the following pages. It should be emphasized, how-ever, that these methods, and the views expressed in this paper, are based solely on conditions at Wright-Hargreaves mine. Such conditions may or may not be similar to those obtaining in other mines in the Kirkland Lake area, where ore occurrences, veins, wall-rock, faulting, intrusives, etc., may be entirely different. Size and shape of ore-bodies, composition of the ore-bodies and their surrounding rocks, locations of intrusives and sedimentary rocks, and direction, dip, and strength of faults, all introduce problems that are peculiar to each individual mine. Ground failure' in coal and metal mines is not at all unusual. A variety of systems of mining have been developed to delay movement of large or small blocks of ground, or, in some instances, to take advantage of the fact that ground movement, due to mining operations, is unavoidable. Ground failure may be either slow collapse or it may take place with explosive violence. It is principally with the latter condition that we are concerned in the mines of the Kirkland Lake district.

Jan 1, 1939

By J. Schmidt

The development of set of laboratory experiments, intended to help undergraduate students meet Canadian Engineering Accreditation Board requirements for Engineering Design outcomes, is described.The laboratory, which is part of a third year level course in hydrometallurgy, is aimed at advancing the ability of students to generate and use experimental results to design an industrial copper leach/SX/EW plant. Emphasis is placed on the students demonstrating the ability to use of their engineering knowledge in weighing the pros and cons of the various process options that they test in converging to a final flowsheet. INTRODUCTION Over the past number of years the Canadian Engineering Accreditation Board, CEAB, has dramatically shifted the way that they evaluate undergraduate programs. In the past, the focus was on measuring of the quantity and quality of material the students were intended to learn as well as the methods and resources used to deliver that material. Now, rather than principally evaluating the inputs of programs, the focus is more on measuring the quality of the outputs from the programs, i.e. the quality of graduating students. In this regard, the CEAB has developed a list of twelve attributes that learners must develop in the course of their studies. Engineering programs must, not only demonstrate that their curriculums provide opportunities to develop these attributes, but must measure student proficiency in each of these attributes as they progress toward graduation. One particular graduate attribute that Laurentian University’s Bharti School of Engineering has encouraged its faculty members to develop content for is “design”. Engineering Canada (2018) defines this attribute as “an ability to design solutions for complex, open-ended engineering problems and to design systems, components or processes that meet specified needs with appropriate attention to health and safety risks, applicable standards, and economic, environmental, cultural and societal considerations”. The previous laboratory component for the hydrometallurgy course was a collection of unconnected experiments covering leaching, solvent extraction, ion exchange, and electrowinning. Like in other undergraduate courses, students would perform stand-alone experiments, make the specified measurements, do the specified analyses of the results, and report the findings, all as strictly detailed in the lab manual. The vision for the new lab was to create an experience that would more closely mimic an industrial research program whereby students would start with a given feed material and would progress through a series of connected experiments. Emphasis is placed on the student demonstrating competency in, not only, generating and analyzing experimental data, but also in using the data along with their engineering knowledge to design and evaluate the pros and cons various plant configuration options. Principally, students are asked to weigh cost, safety, and environmental concerns in converging to their final flowsheet. In designed the leach circuit, students must weigh the costs/benefits of varying leach temperature. Higher leach temperatures will yield faster and more complete copper dissolution, which will allow for the specification of relatively smaller leaching circuits, saving capital costs. However, hotter acid solutions are more dangerous to handle and require increasing amounts of energy to heat the slurry, increasing operating costs. In solid/liquid separation, students must weigh the pros and cons of the addition of a flocculent to assist settling. The flocculant will allow for the design of a thickener circuit that employs units with a relatively smaller area, but will result in a thickener underflow with a lower pulp density, which may necessitate a larger number of thickeners. In addition, the environmental concerns of producing a tailings product that contains an organic contaminant should be addressed. In solvent extraction, students must specify the number of stages of loading and stripping, as well as organic and aqueous flowrates to produce suitable raffinate and rich electrolyte streams. Finally, in electrowinning, students will compare the costs/benefits and risks of the use of precious metal coated titanium dimensionally stable anodes (DSAs) versus conventional Pb based anodes.

Jan 1, 2019

By M. Solomon

Abstract -Giant, sediment-hosted lead-zinc deposits in northern Australia formed during development of Mid-Proterozoic extensional basins that overlie Lower Proterozoic basement. The basement in the Mount Isa area, exposed by folding and faulting, contains fractionated, high-heat-producing granites. These granites generate heat at a rate of about 6 ?Wm-3, probably sufficient to form giant lead-zinc deposits either by (a) driving episodic convection of saline basement and basin fluids for periods of 105 to 106 years at temperatures of about 230°C, or (b) heating basin fluids moving under the influence of topographic relief or fault movement. The presence or absence of such granites may form a vital component of the genetic model. Ore-forming fluid flow was probably initiated by continent-scale, extensional basin fracturing.

Jan 1, 1992

By W. J. Jenner

"Introduction The Saskatchewan Power Corporation is a provincial crown corporation which operates under a mandate to supply all customers within Saskatchewan with electricity and natural gas. The Saskatchewan Power Corporation operates two coal mines within the province of Saskatchewan. The Souris Valley Mine is located a few miles south of the city of Estevan and produces approximately 300 000 Mg of lignite per year. The lignite is shipped about four kilometres by truck and burned at the 882 MW Boundary Dam Power Station, also owned by the Saskatchewan Power Corporation. The Poplar River Mine is located just south-west of the town of Coronach, Saskatchewan which is some 190 kilo metres west of Estevan. This mine produces approximately 1 675 000 Mg of lignite per year. The lignite is shipped seven miles by rail to the Saskatchewan Power Corporation's Poplar River Power Station. The Poplar River Mine is the sole sup plier of fuel to the Poplar River Power Station, which generates some 300 MW of electrical power. A second 300 MW unit is due to be commissioned at the Poplar River Power Station in mid-1983 and the Poplar River Mine will have doubled its capacity to approximately 3 350 000 Mg per year by that time: Souris Valley Mine Geology The Souris Valley Mine extracts lignite from the Estevan seam of the Ravenscrag Formation. This formation is of Tertiary age and was deposited during the Paleocene Epoch. The Ravenscrag Formation outcrops throughout southern Saskatachewan and all coal mined in the province occurs in this formation. Ravenscrag sediments are deltaic in origin and are composed of a series of fine sands, silts, clay and lignite deposits."

Jan 1, 1985

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015