Search Documents

By Derek J. Cyr

Climate has an immense impact on the properties of Athabasca oil sands and the ease or difficulty with which it is excavated and extracted. During the winter months, exposed oil sands surfaces freeze. When hydraulic and electric shovels used in the various operations in the Fort McMurray area excavate the benches, large frozen lumps are created. These lumps are either destined for a lump dump where increased costs are incurred due to rehandle, or they are sent to the primary crushers where they can cause significant downtimes by jamming the crusher. The crusher down time can sometimes be in the order of hours of lost production. Studies on data from two consecutive winters at Syncrude Canada?s North Mine show a high correlation between climate and the generation of frozen oil sands lumps. Temperature, ground cover, traffic, bench exposure time, oil sands grade and moisture content all contribute to this problem. A 1D frost penetration model was used to predict the depth of frost expected in oil sands and the corresponding likelihood of frozen oil sands lumps. To combat the challenge of frozen lump generation, a number of proactive and reactive measures can be taken: artificial snow, shallow ponds, scheduling, blasting or ripping.

May 1, 2004

By R. A. Rabnett, G. Paget, Patrick Walsh

"Tumbler Ridge, Canada's newest resource community, has been developed differently than have been other resource communities.Since its conceptualization, emphasis has been placed on the establishment of a traditional municipal government at early a stage as possible.Planning f or the community goes back to 1977. By then, extensive study by provincial agencies had shown a new resource town would be required to exploit north east coal. The Ministry of Municipal Affairs, in conjunction with a consultant named R.A. Rabnett began the extensive Tumbler Ridge conceptual plan.The results of the conceptual plan are evident in the organizational and planning goals of Tumbler Ridge. In every aspect from the election of officials to some financial matters, the town functions as a normal municipality. With the resource companies of the North East Coal Development within its municipal boundaries. Tumbler Ridge has been able to debenture its capital projects against its municipal tax base.The town's ability to function as a normal municipality is enhanced by its control over Crown land it has purchased from the province. This gives it further control over the development of the community and helps in establishing agreements with the resource companies and the provincial government to ensure that housing and service needs are met. While resource company representatives sit on certain municipal committees, their roles are advisory in nature.The community continues to move toward full municipal status and will have a fully elected Council by 1986.BackgroundPlanning for the development of northeast British Columbia coal resources began in 1976 under the aegis of the provincial Cabinet Committee on Coal Development. A series of subcommittees were established including a Townsite/Community Development subcommittee. The Ministry of Municipal Affairs chaired this subcommittee and continued as the lead agency for the provincial settlement planning effort over the period 1976 to 1981."

Jan 1, 1983

By K. Yoo

Chalcopyrite is the most abundant copper sulfide mineral, which is normally processed using pyrometallurgical methods (i.e., smelting) to produce copper metal. Smelting has several major disadvantages, such as high gas-handling costs, high capital costs, saturation of sulfuric acid market, and inability to treat low-grade concentrates and to recover some by-products, such as zinc, nickel and cobalt. The development of hydrometallurgical processes for chalcopyrite is desirable to overcome the problems of smelting. Because chalcopyrite is refractory, the leaching rate for chalcopyrite is very low. Therefore, increasing the leaching rate has been extensively investigated, both in sulfate and chloride media, as well as in the presence of bacteria. Chloride leaching processes have shown relatively high leaching rates. The mechanism of the chloride leaching process has been investigated, but the behavior of chalcopyrite leaching in chloride solution is not clear. Therefore, the effect of the solution redox potential on the leaching rate of chalcopyrite in chloride solution was investigated. In the present study, leaching experiments were carried out using 0.1 M chloride solutions and the results indicate that high leaching rates of chalcopyrite can be achieved at relatively low solution redox potentials.

Jan 1, 2007

By C. W. Langenberg, D. E. Macdonald, R. S. Strobl

"The successful marketing of Alberta coals will increasingly depend, to a large degree, on an extensive coal quality information base. This information, at present, is generally based on a deliverable, cleaned coaland is confined to existing mine sites. Coal quality information is not as well understood for raw in situ coal outside of mine sites and even less is known about the geological factors that control it.If new uses and markets for Alberta coal are to be developed, such as gasification, coprocessing, and exploiting high rank coals for combustion, it will be imperative that the coal quality parameters important for these utilizations be known. These parameters need to be known for existing deliverable coals and, just as important, for as yet unexploited in situ coal. Factors such as the Cl, No, K, Co, P and trace element contents should be addressed to meet the requirements of these new utilizations.The geological characterization and explanation of what factors control these coal quality parameters is part of research being done at the Alberta Geological Survey. In-seam vertical profiling has been undertaken within the plains and foothills/mountains coals to determine exactly where coal quality variations occur and why. In the Ardley coal zone at the Highvale Mine it has been found, for example, that the ash content of the mined coal is made up of discrete partings and of microsized particles associated with inertinite macerals. The in-seam characterization of coal seams will lead to a better understanding of in situ coal quality variations, leading to new uses and markets for Alberta coal."

Jan 1, 1993

By A. Vien, B. C. Flintoff, R. P. Edwards

"A major thrust in industrial automation over the past few years has been the exploration and incorporation of higher level (supervisory and optimizing) control strategies aimed at more fully exploiting the existing control system infrastructure. There is little doubt that this is worthwhile pursuit, however, one must not lose sight of the maintenance and development requirements of the basic control system. Statistics on loop performance indicate that this too is an area of considerable potential. In this paper the authors look at some of the less elegant, but arguably equally important issues in mineral processing plant control. The focus is on controller structures, loop tuning, sampling, filtering, and some of the other principal components of the regulatory control foundations. In many cases significant improvements in control performance can be achieved by getting back to the basics.IntroductionEvery modem concentrator has a state-of-the-art computer control system in place. Several of these are contemplating installing, or have installed, advanced control systems, such as expert systems, but the foundation of their control system remains the PI controller. Although the authors are not aware of any survey or published information for the mineral processing industry, it is reasonable to assume that it would be similar to the pulp and paper industry. ""The average [pulp] mill has some 2000 control loops of which 97% use PI control. This means that PID, dead time compensation, adaptive controllers, specialized algorithms, ... , constitute only 3% of the installed base."" (Bialkowski [1992]).Bialkowski [1992] also stated that ""If you have been keeping score, only 20% of the loops surveyed actually decrease variability in automatic over manual mode of operation, in the short term."" He attributed the problems to: poor tuning (30% of all loops), control valve problems (30% of all loops) and process problems (20% of all loops). There appear to be a serious need to go back to basics and review the existing control system."

Jan 1, 1998

By Simon D. Handelsman

?Artisanalmining ?Application of human energy (e.g. pick & shovel) directly to produce minerals ?majority no technical skills and lack adequate working tools ?Small-scale mining ?Application of modern technology for limited scale mineral production Significance of ArtisanalMining ?15 million people in artisanaland small scale gold mining ?55 developing countries ?Use of mercury damages health of 100 million people

May 1, 2006

By Kjell Winther

"Hydralift Scanmec introduced early in the eighties a new and different mill design for very large grinding mills. The design described has actually no size limitation upwards and is so far suggested with motor power up to 40 MW. The mill is furnished with gearless ring motor drive transmission. It is totally fabricated, without heavy castings. The first installation, an 8, 1 MW ball mill dia. 6,5 m x 9,65 m length, has been in continous operation in 13 years without problems. Total grinding costs has been reduced with 3 0% compared to traditional smaller mills. Reductions has been achieved in maintenance cost, power consumption, liner wear and grinding media consumption.So far 3 ball mills of the described design are delivered and in operation, one grinding Iron ore and two grinding Nickel ore.IntroductionThe design of mills for mineral ore dressing has basically been unchanged since grinding in mills started some I 00 years ago, in spite of the fact that mills have grown larger and larger. This has resulted in structural and mechanical problems, causing expensive failures and loss of production.Hydralift Scanmec engineers were designing mills for more than 20 years according to the old «rules». As they experienced interest for an increase in the mill size at the time when reports about failing mills were published, they started analyzing the different mill parts to find new solutions. One goal was to only use elements from proven technology in the new design. Two key items were ring motor (wrap around motor)(Isch et al. 1977, Meintrup and Klein 1982, Ranze 1983) and large diameter pad bearings (wrap around bearings)(Fuller 1984), both acknowledged from other industries."

Jan 1, 1995

By Karim El-Ouassiti, Marc Minville, Stéphane Chabot, Claude Bazin, Valérie Ouellet

"Alumina is the main source of aluminium and it is extracted almost exclusively from bauxite ores found in the Southern hemisphere. Clays are abundant minerals that contain from 15 to 40% w/w of alumina from which it can be extracted by various processes. This paper reviews the processes used for the extraction of alumina from clays and discusses results obtained with a clay sample from the Murdochville area in the Quebec Province. The application of a conventional process to this clay did not yield an acceptable recovery although smelter grade alumina was produced. A modification to the process allows increasing alumina recovery from 85% to more than 92%. The application of the improved flow sheet to other alumina carriers failed to yield comparable recovery, showing that an optimum processing path for the recovery of alumina should be found for individual clay materials.INTRODUCTIONMost of the aluminium smelters are fed with alumina extracted from bauxite found in the Southern hemisphere. Bauxite is processed by the Bayer process that uses a caustic leach of the ore. In the middle of the century, the US Bureau of mines, motivated by the fear of an alumina delivery disruption, conducted several research projects aiming at producing alumina from non bauxitic ores. These projects led to the development of various acid leaching processes (Habashi, 1993). The sulphuric and hydrochloric acid leaching processes were brought to pilot plant evaluation (Bengtson, 1979), while nitric and other leach liquors were tested in the laboratory (Phillips and Wills, 1982; Habashi, 1983). Although clays are abundant and inexpensive minerals, the studied processes remained uncompetitive with the alumina extraction from bauxite (Hudson, 1987 page 42; Peters et al., 1962) for which reserves are estimated to support alumina production for the next 50 years (Oye et al., 1999). On the other hand, the local extraction of alumina from clays could significantly reduce the transportation costs of alumina to smelters and provide an alternative source of alumina supply from the Southern hemisphere countries. Also, the extraction of secondary products for some types of clay (Nasyrov et al., 1999) containing significant amounts of potassium and sodium could provide an additional return that may improve the economics of alumina production from clays."

Jan 1, 2005

By Bruce Jago, Joe Zhou, Chris Martin

"From the perspective of metallurgical processing, gold ores can be classified into free-milling and refractory ores. Their extractive metallurgy are largely driven by mineralogical factors such as: gold particle size, association with other minerals, coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of refractory gold minerals and locking of submicroscopic gold in sulfide mineral structure etc. Gold process mineralogy helps address issues and problems related to gold ore processing. It provides useful information on process selection, flowsheet development, recovery improvement and reagent consumption optimization. By combining classic mineralogical techniques, modern instrumental analysis and diagnostic metallurgy, the mineralogist is able to balance the various types of gold occurrence in an ore. This paper will provide a broad review of gold process mineralogy and the techniques available, and use case studies to describe how they can be used together, to provide the complete picture of gold process mineralogy in an ore. Examples will be used where applicable.INTRODUCTIONSince the early 1980’s, a great deal of work has been done in the characterization of gold ores, particularly refractory ores (Gasparrini, 1983; Wang, 1984; Hausen, 1985; Haines, 1986; Henley, 1989; Chryssoulis et al., 1990; Wang et al., 1992, 1994; Kojonen, 1999; Simon et al., 1999; Hong et al., 2000; Pals et al, 2003). Process mineralogy has come into its own as a respected inter-discipline in the fields of mineralogy and metallurgy – a subject that occupies an important place in both research and industry. As the free-milling gold ores are being depleted and more refractory ores are being discovered and processed, gold process mineralogy receives more and more attention from both the mineralogist and metallurgist as it helps to solve various problems encountered during gold ore processing. Steadily rising gold prices are also stimulating the need for gold process mineralogy due to the increasing demand for and production of the yellow metal. At SGS Lakefield Research, gold process mineralogy studies are conducted routinely on all types of gold ores and mill products to assist in a wide variety of metallurgical projects. This paper will briefly discuss the gold ore types and gold mineralogy, review the common mineralogical factors affecting gold extractive metallurgy and the techniques available to gold process mineralogy, introduce the procedure employed at SGS Lakefield Researc"

Jan 1, 2004

By R. R. Rogers

Introduction The subject of cathodic protection is not new. In 1824 Sir Humphry Davy, in publishing the results of his investigations for the British navy, pointed out that copper could be protected from sea-water corrosion by connecting it electrically with zinc or iron. Since that time much work has been clone in this field, particularly in the protection of metals from the action of sea water, neutral brines, and treated and untreated waters. Special mention should be made of the successful protection of underground pipe-lines which formerly were badly corroded by the water in the ground. So far, magnesium alloy and zinc anodes have been the most popular. However, fairly recent work has indicated that aluminium anodes will give good service under certain conditions. The principle of cathodic protection has been applied extensively in coating steel articles with zinc and in cladding aluminium alloy sheet with pure aluminium. A valuable discussion of the fundamentals and applications of cathodic protection recently was presented in the Corrosion Handbook. A useful list of references was included in the article.

Jan 1, 1949

By Chris Harris, Kamal Adham

The use of HCl acid is gaining momentum among hydrometallurgical processes. However, the issue of environmentally efficient and economically viable ways to regenerate HCl acid (from various metal chloride intermediate products) remains a technology and operational challenge. The authors provide a state-of-technology review based on Hatch’s years of testing, design and commissioning experience with high-temperature units (fluid bed and spray roasters), plus the recent efforts in the area of low-temperature HCl regeneration.

Jan 1, 2014

By E. L. Chanturiya

The research and characterisation for compositional, physicochemical, structural, electrical and flotation properties of various pyrite samples for a copper-zinc sulfide ore was carried out. Various methods were used during the research, such as optical microscopy, X-ray diffraction, electron probe micro-analysis (EPMA), phase emission analysis, routine chemical analysis, auger electron spectroscopy (AES), scanning electron microscopy (SEM), back-scattered electron images (BSE), potentiometry, and instrumental neutron-activation analysis, flotation. Analysis of obtained results established the interrelation between impurity structures and concentration of electric charge carriers in minerals, Butyl xanthate sorption and flotation yield of pyrite. The research concluded that pyrite samples differ by morphology, micro defects of structure, concentration of donor and acceptor impurities (Co, As, Sb, etc.) and conductivity parameters (thermo-electrical force, specific resistance and concentration of charge carriers The peculiarity of pentagon-dodecahedral pyrite is the high concentration of electric charge carriers (electrons) and the more negative surface potential (by 25–75 mV) in comparison to cubic pyrite. The surface of cubic varieties is more active, therefore it is oxidized in alkaline lime medium much faster, than the surface of pentagon-dodecahedral varieties. This phenomenon is caused by high reaction ability, irregular jointing and defects of cubic pyrite. This promotes the increase of calcium ion sorption on its surface and the decrease of Butyl xanthate sorption. According to this, an increase in alkalinity (lime medium) from a pH of 10.0–11.5 leads to an increase of gold content reporting to the tail of bulk flotation. Gold content is increased from 0.58 g/t (?? 9.5) to 1.9 g/t (?? 11.6), which represents an increase in gold recovery of 24.68 to 79%, respectively.

Jan 1, 2016

By E. Gallestey, D. Groenveld, F. Kolb, M. Rozou

"Recent copper price evolution pushes modern mining industry even harder to achieve highest production with maximum efficiency. Operations are bound by numerous contractual and environmental conditions that bring a high degree of complexity to both the operators controlling the process and the plant managers assessing the circuit’s potential and setting the production goals.Advanced process control (APC) for grinding is one important tool to operate this most energy intense area in an optimal way, finding the optimal trade-offs between highest throughput, energy efficiency and product quality based on variable ore properties, production targets and management priorities.ABB’s state of the art control and optimization software platform enables user to design a controller based on model predictive control (MPC). The paper and the presentation show the technology used and the results achieved through an APC controller installed in a pilot project in Aitik (Boliden SA), Sweden. Furthermore, possibilities to interconnect grinding with other areas as stockpile management and flotation with various interconnected APC controllers will be shown. Finally, an example of the return on investment and the payback times based on the increased throughput and better product quality will be presented.INTRODUCTIONDepending on the ore characteristics and the targeted plant capacity, the design of the grinding circuit may vary significantly. Typically, the circuit consists of several mills (rod, ball, SAG, AG) in series and/or parallel with a number of classifiers and sumps at appropriate locations (see Figure 1).The main goal of the grinding section is to reduce the ore particle size to a level that enables efficient separation between gangue and precious metals in the subsiding processing step. The trade-off between quality and quantity has to be made. At the same time, it is also crucial to execute this process at the lowest possible energy and grinding media consumption."

Jan 1, 2015

By A. M. Simons

Cyanide destruction by Caro’s acid is one process commonly employed by gold operations to meet regulatory requirements and/or the International Cyanide Management Code compliance for weak acid dissociable (WAD) cyanide in cyanidation tails or waste water from such operations. Typically smallscale bench tests to evaluate and assess the suitability of the Caro’s acid destruction process are conducted. Additionally, the experimental procedure used during these preliminary investigations may also differ from that implemented at the full-scale. This paper presents the results from a fundamental investigation of the Caro’s acid process to establish a more detailed understanding of the impact that the experimental procedure has on the destruction of cyanide. In particular, it was found that the control of pH was important to avoid copper(I) cyanide precipitation at low pH and maximise WAD cyanide destruction. Residual peroxide in the preparation of Caro’s acid has the potential for subsequent cyanide destruction and could be exploited.

Jan 1, 2014

By V. J. Sopuck, O. P. Lavin, Ian Nichol

"A major challenge of contemporary exploration geochemistry is the development of procedures that can locate blind mineralization or mineralization that sub-crops below a cover of transported overburden, the composition of which bears no relation to the underlying mineralization. Over the past few years, the possible existence of diagnostic geochemical features in the country rock associated with volcanogenic massive sulphide deposits has attracted increasing attention both on the local mine scale and on the regional scale. In the present investigation, the nature of the geochemistry of a number of Archean greenstone belts of the Canadian Shield is examined to determine the feasibility of distinguishing productive from non-productive areas of copper-zinc mineralization. The results indicate that productive areas are distinguishable from non-productive areas providing consideration is given to the effects of igneous differentiation on rock compositionIntroductionArchean massive sulphide deposits are an important source of copper and zinc, and to a lesser extent silver and gold, particularly in Canada. As in the case of most other forms of mineralization, there is a continual need to develop new techniques that will improve the chances of success in the search for these deposits. The majority of Archean areas in the northern latitudes are overlain by a variable cover of glacial overburden. Considerable progress has been made in the development of new geochemical exploration techniques for use in glaciated terrain, based on the detection of anomalous dispersion in the glacial overburden. In certain situations, however, as in the search for blind deposits or in areas covered by glaciolacustrine deposits, overburden geochemistry offers little hope for success. In the case of massive sulphide deposits, one possible solution may lie in the detection of anomalous geochemical signatures in the bedrock. Recognizing this possibility, attention has been directed to the investigation of the nature of lithogeochemical dispersion associated with massive sulphide deposits on both regional and local scales, to establish the potential of lithogeochemistry as an aid in the search for these deposits."

Jan 1, 1980

By G. P. Contractor

Many factors affect the forge ability of steels. One of the major factors is chemical composition.' This article discusses the individual effects of alloying elements and the effect of the resultant modification of microstructure onforgeability. INTRODUCTION T HE use of alloy steels is expanding considerably and the fabrication procedures for such alloys are becoming more complex. An attempt is made in this article to describe the effect of alloying elements on the hot-workability of steels. Most of the data reported here are taken from the studies of Ihrig, Clark and others (Refs. 1-4). Chemical composition is not the only controlling factor. Grain size and surface condition of the material, forging temperature, and speed of deformation are also important. Certain conclusions can be drawn regarding the effect of various alloying elements on the hot-work-ability of forging stock. The results of hot-twist tests are considered useful in this connection as the number of twists to failure has been taken as the level of forgeability at a particular temperature. The peak in the "Number of Twists -Tem--

Jan 1, 1962

By D. B. Dreisinger, D. G. Dixon, G. Nazari

"The kinetics of chalcopyrite leaching in acidic ferric/ferrous sulfate media under atmospheric conditions in the presence of pyrite has been investigated. It has been found that pyrite samples from different sources affect the rate of chalcopyrite leaching differently. A strong correlation between the amount of silver associated with the pyrite and its effectiveness has been noted. In this study, improvement of the catalytic properties of pyrite such that all pyrite samples accelerate the rate of copper extraction regardless of their sources is demonstrated, and a detailed discussion of the mechanisms involved in the process of chalcopyrite leaching in the presence of silverenhanced pyrite is presented. INTRODUCTIONIt is well known that chalcopyrite resists leaching in sulfate media. It has been proved that pyrite facilitates the leaching of chalcopyrite (Berry et al., 1978; Dixon et al., 2008; Mehta and Murr, 1983; Muñoz et al., 2008; Nowak et al., 1984, Tshilombo, 2004). Considering the catalytic effects of pyrite on accelerating the kinetics of chalcopyrite leaching, Dixon and Tshilombo (2005) have developed a new process, known as Galvanox™, which has several advantages over other hydrometallurgical processes. Galvanox™ runs under atmospheric conditions, so it requires only low-cost leaching tanks. The sulfur yield at this temperature is high (>95%) which leads to low oxygen consumption and low sulfuric acid generation. The operating temperature is below the melting point of sulfur which eliminates the use of surfactants. This process also does not require fine grinding. Reaction 1 shows the overall leaching reaction in the Galvanox™ process.CuFeS2 + O2 + 2 H2SO4 = CuSO4 + FeSO4 + 2 S0 + 2 H2O (1)Complete copper recovery from the Galvanox™ process can be achieved at a considerably higher rate than other atmospheric ferric sulfate leaching processes (Dixon et al., 2008). Recycling pyrite and recovering copper from tailings with the Galvanox™ process have also been evaluated in continuous pilot leaching campaigns (Dixon et al., 2007)."

Jan 1, 2012

By Stephen L. Chryssoulis, Daniela Venter, Stamen Dimov

"Comparative surface analysis of floated and rejected free gold grains from a number of full scale benefication plants and from pilot plant testwork, has shown silver (the most common impurity in gold) and sulphur invariably in greater concentration on floated gold grains, implying that they assisted gold flotation (gold activators). Collector loading measurements on individual gold grains from concentrates of staged rougher flotation tests on a cyclone U/F product of a pyritic gold ore, revealed first progressively lower concentrations of the collector monomer on gold from each follow-up concentrate and secondly a direct proportionality between the surface concentration of silver and the collector monomer. These two observations leave no doubt that silver activates gold and that collector monomers play a significant, previously not fully recognized role in gold flotation.INTRODUCTIONGold to some degree is naturally floatable in industrial systems, which means that it can be recovered without collector addition (Marsden and House, 1992). This is due to the adsorption of hydrocarbons and deposition of sulphur, which are dependent on the metallic properties of gold, particularly its high electrical conductivity, which allows surface electrochemical reactions to occur catalytically and selectively. Cyclic voltammetry has shown that gold can be rendered hydrophobic by deposition of a surface layer of sulphur (Sº) from S2- and HS- solutions (Walker et al., 1984). Twenty monolayers of sulphur were required to produce a hydrophobic gold surface.However, no sulphide flotation plant relies solely on the natural floatability of gold for its recovery. Gold hydrophobicity is enhanced by the addition of flotation collectors such as xanthates (X), dithiophosphates (DTP), dithiophosphinates (DTPI), mercaptobenzothiolates (MBC) etc., as used in sulphide mineral flotation (Dekok, 1973: Adams et al., 1986). The mechanism invoked in enhancing the hydrophobicity of pure gold with the aforementioned four groups of collectors is similar to that of pyrite, whereby collector anions are oxidized at the gold surface to form dimers (Groot, 1987; Marsden and House, 1992; Basilio et al., 1992) As an example, xanthate ions are oxidized at the gold surface to form the neutral dimer dixanthogen (X2):"

Jan 1, 2003

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?' eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? ' phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?' eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

"In response to mine head grades declining and orebodies becoming more complex, Glencore Technology has developed an alternative method for recovering economic minerals once leached into solution, rather than relying on conventional flowsheet options. The method involves the precipitation and separation of base metals from solution with limestone or lime. The final grade of these precipitate is not usually high enough to attract favourable terms of sale due to dilution from gypsum and sulphate salts. A set of operating conditions have been developed to allow the separation of the base metal precipitate from gypsum by exploiting the difference in particle size. A high-grade oxide product can be easily separated from the gypsum stream at very low cost. This process was originally developed by Glencore for zinc and copper systems. This paper reports on the successful application to nickel and cobalt, and this process has significant advantages over the incumbent precipitation process utilising magnesia.INTRODUCTION During evaluation of transitional and oxide zinc ore deposits during the 1990’s, Noranda Inc. (now Glencore) developed a sulphate based ore leach process to extract zinc into solution. For flowsheet development, conventional schemes dictated that once the zinc was dissolved in an acidified solution it was recovered by means of purification or solvent extraction followed by electrowinning and casting to produce zinc ingots. The deposits Noranda evaluated were high grade but had a relatively short mine life (10 years) and economic analysis showed that the projects couldn’t sustain the investment of a full zinc refinery. Compounding this problem was the lack of power supply infrastructure and the high power cost in the region. Noranda then evaluated alternative means of recovering zinc from solution. Laboratory testwork showed that a high-grade zinc precipitate (+50 wt% Zn) could be produced as an oxide, carbonate or sulphide by contacting acidified zinc sulphate solution with a number of reagents including soda ash, sodium hydroxide, and sodium hydrogen sulphide. Economic evaluation showed that the cost of the reagents are prohibitive, especially when the final product is still a metal intermediate (ZnO, ZnCO3 or ZnS). Noranda then continued to focus on fine zinc oxide precipitation for supply into the automotive tyre industry as this product would attract favourable terms of sale as a premium on Special High Grade (SHG) zinc."

Jan 1, 2017