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By Rob Scott

Making a difference with Zinc & Health Two billion people do not get enough zinc in their diets. Every year 450,000 children die from complications arising from zinc deficiency Our Zinc Alliance For Child Health partnership with CIDA and Micronutrient Initiative, our involvement with UNICEF through the IZA and our partnership with BASF are gaining wide recognition. Sustainability at Teck ? Integrating into our Core Business Strategy Our strategy Long term goals Our approach Managing risks and finding opportunities Our progress Early reports Moving Forward Metrics and indicators

May 1, 2013

By Julian Boldy

"A review of lI5 significant volcanogenic massive sulphide discoveries in the Canadian Precambrian during the past 65 years reveals that only 7% resulted from surface exploration methods aimed at depths below the effective reach of current geotechnical systems. This has been due to the relative ease of shallow discovery, resulting in the harvesting of ore deposits within 100 m of surface. This surficial layer has been more or less effectively supersaturated by routine exploration. In view of the fact that a mining district's metal content is not likely to be confined to a surficial layer, the time has come to explore the vertical dimension, prospecting for ore at depths in excess of 150 m in productive districts.Essential to this task is an understanding of the Precambrian volcanogenic ore deposit model. The deposits generally have .a tendency to be associated with the terminal phases of felsic volcanism, and to be located along certain time-stratigraphic horizons, marked by the products of volcanic exhalation. The significant massive sulphide deposits are discrete entities, ranging from the top 5% of deposits greater than 45 million tonnes in size, with a surface area of 0.30 km2, to median-sized deposits greater than 1.2 million tonnes in size with a surface area of 0.02 km2. These significant economic ore deposits range in value from $5.5 billion for the top 5% of deposits to $125 million for median-sized deposits. In terms of their frequency of occurrence, the former group has a 4% distribution and the median-sized deposits have a 15% distribution.An historical review of many of the principal Precambrian mining districts, such as Noranda and Flin Flon, shows that major tonnages are usually discovered during the initial phase of application of each new geotechnical search system, until carried to its ultimate limit of effective depth penetration. With the exception of the Noranda district, the mean depth of ore discovery in the other districts is still generally confined to within 50 m of surface.Targeting deep ore is difficult. One effective prospecting method is the detection of fracture-controlled mercury leakage haloes in outcrop (or core) above and peripheral to blind deposits. This technique has proved to be a useful pathfinder, and focuses attention on deposits buried at depths in excess of 700 m in some instances. Down-hole EM systems also promise to be effective in locating deposits previously bypassed by drilling. In addition, trend surface analysis programs of trace element geochemistry should be used as an aid to targeting ore by directing exploratory drilling along the plane of ore-hosting stratigraphy.By definition, mining districts have a proven ""favourability"" for the occurrence of ore. Discovery probabilities in these districts will be considerably enhanced if future search efforts are concentrated below a depth of 150 m, and more use is made of ""deep"" ore search systems coupled with sound geological reasoning. Deep drilling programs to a depth of800 m should initially be designed to search for the top 25% of deposits greater than 3.3 million tonnes in size, with a surface area of0.05 kmt. :a value of$310 million and a 12% frequency of occurrence; This can be accomplished for an over-all cost approximating $40,000 per drill hole. If the search depth is limited to 400 m, the over-all cost of each drill hole is $20,000, equivalent to expenditures routinely allocated to grassroots exploration drilling in the remote greenstone belts of the Precambrian. Depending on a company's objective, prospecting for deep ore offers a stimulating challange - though risky, it has its rewards."

Jan 1, 1981

By Brian Rausch

Agenda ?? Refresher: Victor Project Execution ?? Operations Capability roadmap: ? Operations staffing starter group: design participation ? Operations staffing build up for production start-up ? Training and commissioning integration ? Turning OPSCAP ramp-up into a project ?? Go Live! The Results

May 1, 2009

By T. Hidayat, D. Shishin, V. Prostakova, M. Shevchenko

The chemical compositions of copper feed streams are becoming increasingly complex following the growing demand for metals and corresponding shortages of primary sources. The optimisation of process conditions requires an accurate description of phase equilibria and thermodynamics. Integrated experimental and thermodynamic modelling research program on the characterisation of the complex, multi-component, multi-phase gas-slag-matte-speiss-metal-solids Cu2O-PbO-ZnO-Al2O3- CaO-MgO-FeO-Fe2O3-SiO2-S-(As-Bi-Ni-Sb-Sn-Ag-Au) system is being carried out to support companies undertaking the pyrometallurgical primary production and recycling of copper. The experiments involve high temperature equilibration in controlled gas atmospheres, rapid quenching and direct measurement of equilibrium phase compositions with quantitative microanalytical techniques, including electron probe X- ray microanalysis and Laser Ablation ICP-MS. The thermodynamic modelling is undertaken using FactSage computer package with advanced thermodynamic solution models. The continuing development of research methodologies has resulted in significant advances in research outcomes. Implementation of the results of these fundamental studies involves an ongoing collaboration of researchers and industry technologists. An overview of recent progress in research, implementation and applications in industrial practice are given in the paper. INTRODUCTION Rapidly developing technologies increase the demand for various metals in number and volumes. Modern technological devices such as mobile phones, computers, other electronic devices, have dozens of metals—all those metals have to be a) produced and b) recycled. The fast transition in mobility from fossil energy delivered through combustion to renewable energy first stored in bakeries and delivered through electric engines introduce a significant change in the metal demand in terms of both type and volume of metals. Pyrometallurgy is playing a key role in supporting these changes in our industrialised society.

Jan 1, 2019

By Michael Moats, Adirek Janwong

The use of cylinder electrowinning cells, such as emew® technology, for the recovery of silver from primary and secondary sources has been growing. In this study, common operating parameters used in silver electrowinning were evaluated for recycling applications. Silver powders were produced from an industrial solution in a laboratory scale emew® cell. A design of experiments was employed to evaluate the effects of HNO3 concentration, iron concentration, current density and solution flow rate on current efficiency, particle size, bulk density, and crystallographic orientation. Current efficiency was affected by each parameter with increasing HNO3 concentration having a strong negative effect, increasing iron concentration and current density having moderate negative effects and increasing flow rate having a positive effect over the ranges examined. Finer particles were produced with increasing current density and decreasing flow rate. Bulk density increased when HNO3 concentration increased. The crystallographic orientation of all powders was dominated by the (111) plane. Increasing flow rate decreased the relative intensity of (200) direction. Based on these observations, silver electrowinning in cylindrical cells can operate at high current efficiency and produce larger powders at low HNO3 concentration, low iron concentration, low current density and high flow rate.

Jan 1, 2014

By Samuel O. Akande

"Gold occurs as native metal, in electrum, and in a telluride mineral in quartz carbonate veinlets of three vein systems at the Ross Mine, northern Ontario. The 14 Vein System is made up predominantly of concordant veinlets within layered ankeritic dolomite stratabound by, and conformable with, andesite tuff Individual veinlets contain pyrite, sphalerite, galena, chalcopyrite, tennantite, pearceite, proustite, native gold and electrum in a matrix of quartz, dolomite, ankerite and calcite. The 2B Vein System is made up of both concordant and discordant veinlets within andesite tuffs. The veinlets contain pyrite, chalcopyrite, sphalerite, bornite, tennantite and free gold in quartz, calcite and dolomite. The 18 Vein System is comprised of stockwork veinlets in and around intrusive syenite which has both sharp and gradational contacts with enclosing andesite tuff The veinlets contain pyrite, chalcopyrite, bornite, chalcocite, native gold and calaverite. Sulphide and silicate minerals in veinlets and wall rocks are stable assemblages for the regional metamorphism of greenschist rank. ,The 14 Vein System is interpreted as a metalliferous siliceous carbonate chemical sediment, the components of which were leached from the underlying volcanic rocks by convecting sea water and subsequently deposited on the sea floor between the extrusion of flows and pyroclastic rocks. Subsequent regional metamorphism and intrusions remobilized and redistributed the syngenetic stratabound material into dilatant fractures in adjacent tuff, as in the 2B and the 18 vein systems."

Jan 1, 1982

By S. Flewelling, M. Scobie, G. R. Baiden

"SynopsisA feasibility study to develop a research program, the Mine Automation Plan (MAP), was recently completed. This was undertaken by a team comprised of Inco Ltd., Falconbridge Limited, the Canadian Centre for Automation and Robotics in Mining (CCARM) and the Centre for Resource Studies (CRS). The study was sponsored by PRECARN Associates, which is a consortium of thirty-six Canadian companies focussed on research and development in artificial intelligence and robotics. PRECARN Associates was formed in 1987 when a number of research proposals were funded in the fields of process control systems, robotics systems and intelligent engineering systems. In July 1991, PRECARN accepted the next round of proposals for research. The MAP project was one of the successful proposals, being awarded $100,000 for the development of a feasibility study defining a long-term R&D plan for underground hardrock mining automation.The development of the feasibility study started by addressing the fundamental structure of the mining process, and its relationship to the metallurgical process, over-all infrastructure support and management systems (Fig. I).Mining may be considered as comprising five subprocesses: (I) delineation; (2) development; (3) production; (4) backfilling; and (5) infrastructure support services. Within these subprocesses many applications for artificial intelligence and robotics exist. The mining process is dependent upon the interaction between the physical mining process and information. For example, the delineation process is dependent on geomechanical, geochemical and geophysical techniques to develop a model of the orebody based upon access to such data. This same relationship between the physical and information models holds true through the development, production, backfill and infrastructure support systems.The foundation for the MAP study has been the recent development by Inco Ltd. of an underground communications system (Fig. 2). The system has the ability to supply high bandwidth communications, over voice, data and video to mobile and stationary locations within the mining operation. It is seen to be the future backbone of a comprehensive, automated information system which should permit the application of the concept of Computer Integrated Manufacturing (CIM) to underground mining. CIM, through the automated flow of information, has been successful in integrating the engineering, production and various support groups in manufacturing."

Jan 1, 1994

By J. Y. Kim, Kenneth Stowe, Stephen Chryssoulis

"A series of flotation tests was carried out on Brunswick Mining ore with various pH modifiers (soda ash, lime, KOH) and added ions (ferric, nitrate, sulphate) in the copper lead rougher circuit. The main objective was to identify downstream effects on sphalerite activation and subsequent zinc rougher flotation. Some significant differences in zinc flotation were obtained. Most notably, soda ash and nitrate ions had a positive impact and ferric ions a pronounced negative effect on selectivity.Selected products from the flotation tests were deslimed at 400 mesh, washed with methanol, air dried, placed in teflon vials purged with nitrogen and stored at -15 degrees C. Numerous liberated sphalerite and pyrite particles were selected under a stereoscope and placed in rows on indium foil. The surface compositions of the particles were analyzed with an innovative laser probe (LIMS). The very small analysis area of the LIMS enables the surfaces of individual grains to be characterized. In addition, the rapid analysis time allows a statistically significant number of grains to be analyzed quickly.Surface lead appears to play a major role in zinc activation/flotation. Possible mechanisms are proposed to explain the variations in metallurgical performance at the different test conditions.IntroductionAlthough the bulk composition of mineral grains is an important consideration for the mineral processor it is ultimately surface composition and topography (edges and dislocations preferred sites for reactions) that control reactivity in flotation and cyanidation (passivation, encapsulation and preg-robbing). Determination of the surface properties of particles from process streams poses a particular challenge for the surface chemist for a variety of reasons, including:"

Jan 1, 1994

By R. Kamguem

The surface of a mechanical part plays an important role in determining performance in service. The presence of scratches left by the cutting or tearing of the material on the surface of the workpiece supports the concentration of stress and strain. This article presents the experimental study for high speed milling of the aluminum alloy 7075-T6, using cutting tools different by the nose radius and coatings (TiCN, TiAIN, TiCN + A12O3 + TiN). A multi levels factorial design of experiment (DOE) and statistical analysis was used. The roughness parameters investigated are Ra, Ra, Rv, Rc, Rsm, and Rk. The results show that the feed rate, the types of coatings and the geometry of the cutting tools have the most significant impact on the surface roughness profil. Surface finish charts according to feeds and cutting speeds were established for each tool tested.

Jan 1, 2011

By William A. Price

The objective of this paper is to outline the approaches used in British Columbia to address the challenges posed by metal leaching and acid rock drainage (ML/ARD). Challenges include the large financial costs, the need for site-specific assessments, the large information requirements, the need for mitigation measures to be designed and financed in a manner that permits long-term performance, the lack of long-term operating experience, the ongoing changes in many important processes, the need for pro-active detection and resolution of concerns, difficulties in predicting the potential for ARD or significant metal leaching, the need for new tools, and the multidisciplinary, highly specialized nature of the work. Consequently, mines must be planned, operated and closed in a manner that permits regular review, detailed monitoring and adaptive management. Proper consideration of the challenges involved, including a plan of how all outstanding concerns will be addressed, studies to address areas of significant uncertainty and caution in the absence of the required understanding, should ensure environmentally safe practices in the future.

Nov 1, 2002

"The Detour Lake Mine is located in northeastern, Ontario, approximately 300 kilometres northest of Timmins and 185 kilometres by road northeast of Cochrane. The mill processes a free milling gold ore using both gravity circuit and leaching with a state-of-the-art carbon-in-pulp circuit. The grinding circuit is a conventional SABC circuit with a tonnage of 55,000 mtpd at 95 microns with the addition of pre-crushing upstream of the SAG mill.The present paper will describe the methodology used to successfully prove that gold of the Detour Lake Mine ore is mostly concentrated into the fine size fraction of the blasted rocks. It will describe the various options possible to create value from this ore property.IntroductionThe purpose of this test work was to determine the grade of the pebbles and consider if there was value into discarding the pebbles and replacing the material by fresh feed.1. Pebble samplingThe pebbles were sampled and assayed for grade every day for 3 months. After 3 months of sampling, the results showed that the pebbles only carried 28% of the fresh feed grade. This phenomenon can possibly be explained by the fact the gold is located into area of fracture in the rocks.January-March 2014 – Pebble assay average• Line #1 = 0.222 g. Au/t• Line#2 = 0.275 g. Au/t• Head grade = 0.88 g. Au/t2. Crushing and grinding circuit surveysWith the above information, a grinding circuit survey was planned. The purpose of the survey was to build a JKSIMMET model of the grinding circuit for mill optimization but also to understand the deportment of gold into various size fractions that may explain why there is so little gold in the pebbles. All streams and size fractions was analysed for particle size analysis and for gold.Since Detour has dual grinding lines, both circuits were sample at the end of May. Two supplemental survey of the secondary crushers were also done and a survey of the gyratory crusher."

Jan 1, 2016

By J. T. Fyles, C. G. Hewlett

"THE REEVES MACDONALD mine is in the Sa Imo-Pend d'Oreille mining area of southeastern British Columbia. It is on the Nelway-Waneta road 4 miles west of the border-crossing point of Nelway. The Reeves orebody from which all production has come is one of several mineralized zones in easterly-striking limestones occurring between the Pend d'Oreille and the lower part of Salmo River.The property was originally located as two groups of claims by R. M, Reeves and J. H. McDonald. The two groups were consolidated in 1925. and extensive development work was done from then until 1930 and again in 1937, but no ore was shipped. The mine was reopened in 1947 and, between 1949 and 1953, 1,057,804 tons of ore was mined. Concentrates recovered contained 85,626 ounces of silver, 19,394,092 pounds of lead, 72,076,495 pounds of zinc, and 455,051 pounds of cadmium. Low metal prices forced the mine to close in 1953, but operations were resumed in November, 1955.The orebodies at the Reeves MacDonald mine are steeply plunging lead and zinc sulphide replacement deposits in a banded limestone named the Reeves limestone. The orebodies contain pyrite, honey-coloured sphalerite, and galena, and are surrounded by a dolomitized zone. In the Reeves orebody, where the relationships are known, the dolomite has the same general shape as the orebody. Four zones of sulphides are known on the property (see Figure 1). Three of these, the Reeves, B. L., and O'Donnell, are believed to be faulted segments of one mineralized zone. The fourth, the Point ore zone, exposed on the north bank of the Pend d'Oreille River, is not developed and its structural position is not known, but it appears to be a separate deposit."

Jan 1, 1949

By M. Doggett

All 231 Canadian primary gold mines that produced from 1946 to 2004 were analyzed with respect to their production and economic characteristics. Trend analysis revealed that the average annual capacity of Canadian gold mines, as measured by ore processed or gold produced, has increased over time. Conversely, the average grade of gold mines has decreased over time. The distribution of gold output is highly uneven: for example, the 22 giant mines producing more than 100 t (metric tonnes) of gold account for 62% of total output. Small mines producing less than 10 t Au account for 54% of total mines, but less than 4% of total gold. Each historical mine in the database was evaluated on the basis of a set of economic and technical assumptions to determine if it would be economic to develop today. Based on the net present value using an 8% discount rate, only 103 of the 231 mines were determined to be economic. About 80% of the uneconomic mines had less than 10 t of contained gold, and 63% had less than 5 t. It is concluded that these small mines would not be viable today due to a combination of real capital cost increases, and more stringent permitting and environmental regulations. The implication is that future gold supply in Canada will hinge on the discovery and development of a new generation of larger mines. Given that only one giant mine has been discovered in the past 20 years, it seems likely that gold output will decrease in the future.

Jan 1, 2007

By S. Y. Mostowy, P. W. M. Shibley

"When Texas Gulf Sulphur Company discovered the Kidd Creek ore body in 1964, a crash program began almost immediately for the design and construction of a modern concentrator. It was necessary to mill two distinct ore types; one containing copper and zinc, the other lead, silver and zinc minerals. The final concentrator design was to handle 9,000 tons of ore daily in three circuits. One circuit was to treat copper-zinc and another lead-zinc ore exclusively on a permanent basis. A central circuit was designed with adequate flexibility to treat either of the above ore types in accordance with planned mining schedules. Ecstall Mining Limited, a wholly owned subsidiary, now operates the mine and concentrator complexes for Texas Gulf. The mine is located 15 miles north of Timmins and the concentrator 15 miles to the north-east along Highway 101. The ore is hauled from the mine to the concentrator over a 17-mile railroad. Initial milling operations began in November, 1966.1 - ABSTRACTThis paper deals with bulk reagent handling at the Kidd Creek concentrator. The reagent section at Kidd Creek has operated excellently since milling began in 1966. The bulk handling techniques are satisfactory. They have contributed substantially to good working conditions, economical practices and metallurgical efficiencies. The bulk handling features described should be considered in existing and proposed concentrators."

Jan 1, 1970

By Denghong Wang

Abstract- The Ashele Cu-Zn deposit is a recently discovered volcanogenic massive sulfide deposit in Xinjiang, China, hosted by Lower to Middle Devonian submarine bimodal volcanic rocks. The primary ores of this polygenetic deposit are represented by massive syn-depositional pyrite, chalcopyrite, and sphalerite, and were formed by submarine exhalation. Hydrothermal alteration consists of strong sericitization, chloritization, silicification, and carbonatization of the metavolcanic rocks beneath the massive orebodies. Depletion of Na2O is an obvious chemical change in the hydrothermal halo. Geological and geochemical evidence suggest that the Ashele Cu-Zn massive sulfide deposit was formed by submarine exhalation related to bimodal volcanic rocks, trapped in a rifting basin, then deformed by shearing, and thermally metamorphosed by the intrusion of dacitic porphyry. Sulfur and lead isotopic studies indicate that metals such as copper and zinc may have originated from spilites, but that volatile components, especially sulfur, were derived directly from submarine volcanic magmas.

Jan 1, 1999

By Jarek Jakubec

The new euphoria in diamond exploration brings with it a need to understand the challenges that new projects can face in different stages of the development and risks that the commercial outcomes from the new projects fall short of expectations. In many cases, the problems are related to a poor understanding of the technical risks and a failure to adequately address them during the course of investigation. Failure to evaluate all disciplines to the same level of certainty could lead to a situation where the important issues are only identified late in the project development, resulting in costly delays and financial difficulties. The diamond projects located in Canadian Arctic, with its challenging environmental, geographical, social, political and geological contexts are especially sensitive to the high variability of the outcome. This presentation highlights some of the technical aspects that could be the leading sources of risk in diamond projects and could ultimately result in inappropriate mine designs, reducing the economic outcome.

May 1, 2006

By W. Yang, R. Rajasingam, B. Tadesse, K. Mohanarangam

Copper electrowinning is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. Acid mist is produced by these oxygen bubbles bursting at the electrolyte free surface. It is an undesired by-product of the Electrowinning process which unchecked could result in mist generation higher than the recommended time-weight-average exposure limit. Various approaches to alleviate the problem have been adopted by companies, all with varying degrees of success. All of these have been attempts to treat the symptom acid mist rather than the inherent problem, often proving expensive and, in some cases, ineffectual. In this paper, a new method was developed for acid mist quantification based on ‘total acid mist’ capture above the EW cell under well controlled conditions. With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables including current density, flow rate, temperature, etc. independently and their effect on bubble size, bubble velocity, gas hold-up as well as acid mist generation and its droplet size. Results show that total acid mist capture increases with an increase in current density but remains more or less constant between 300–500 A m-2. Total acid mist also shows an increase with increasing electrolyte temperature. These findings are substantiated with the aid of bubble size and gas hold-up measurements with the transparent EW cell.

Jan 1, 2019

By Makarinskym F. M.

"This paper describes mechanical and operating modifications that were and are being made to current on-line flotation cells at Falconbridge Nickel Mines concentrators. Improved metallurgical performance and metal recoveries of some 3·4% over the past ten years are the end result of the modifications made. The paper acknowledges the contribution of operating, technical and maintenance personnel and the Company ""suggestion plan"" program. 1. INTRODUCTIONFalconbrirdge Nickel Mines Limited, incorporated in 1928 is a major product of nickel, copper,coba1t and other metals and minerals. The Canadian Nickel Division operating facilities in the Sudbury Area currently includes seven mines, two concentrators, and a smelter.For many years at all concentrators, improv0mcnts in metal recoveries have been continually under investigation. One area was to improve the flotation cell performance. This paper will deal with mechanical and operating modifications to the cells at the Strathcona and Falconhridge Ni-Cu sulphide concentrators, at the Sudbury Operations.One of the prime means to mineral beneficiation processing has been, and will continue to be, the basic froth flotation cell. The efficient operation of a flotation cell is the key to satisfactory metal selectivity and recovery. The essence of good design is simplicity. Changes to cell design can contribute to a significant improvement in metal recovery.Over the past 10 years, modifications to the flotation cells have contributed to an improvement of some 3-4” in mineral recovery. Providi11g tl1c initiative for improvements include operating, maintenance and technical personnel, as well as the employee suggestions submitted th1·ough the Suggestion Plan Program."

Jan 1, 1982

By H. A. Bilgin, G. G. U. Aldas

"Ground vibration is the natural result of the blasting process. Many empirical formulae and methodologies including analysis of travel path effects have been developed. The scaled distance, which is the most popular approach for the calculation of the attenuation of particle velocity in the ground, has led to significant advances in the prediction of particle velocity when both explosive charge and distance vary. However, this approach does not consider the effect of ground anisotropy and existence of structural geological features on ground vibration. Therefore, in this study, the effects of these rock mass properties on types, amplitudes, and frequencies of ground vibration waves at four surface mines are examined. The results, which were implemented at Kangal coal mine, Bastas quarry and Kíbrís quarry, provided guidance for the extensive study at Orhaneli surface coal mine.As a result of the study, the authors came to the conclusion that vibration amplitudes change depending on the ground on which sensors were deployed and the conditions depending on whether measurements were done near major structural geological features. It was determined that the vibration amplitudes, measured at equal distances from the source but in different directions, change because of the propagation velocity anisotropy. Besides the change of wave type due to the kind of ground at the measurement location, it was determined that vibration anomolies were due to structural features."

Jan 1, 2004

By K Byrne, W. Hawker

The average grade of copper concentrate is steadily declining, forcing the industry to turn to lower grade and metallurgically challenging orebodies. When faced with a low grade, challenging ore, mining companies are often forced to choose between high recovery at low grade or low recovery at high grade. Hydrometallurgical processing of copper concentrates using metathesis reactions, which replace iron with copper in copper-iron sulphide minerals and increase the copper to sulphur ratio in copper sulphide minerals, provide an opportunity to upgrade copper concentrates and potentially allow high copper recovery for a high grade concentrate. Factors such as concentrate mineralogy, reaction time and temperature, and the concentrations of copper, chloride and acid in solution are reported to affect the reaction extent and mineral phases formed by metathesis. In this paper, a copper concentrate has been studied over a wide range of conditions to investigate the influence of these key parameters on the extent of copper metathesis reactions and product phases formed. Solution and solid phases are assayed with the main mineral phases identified by Quantitative X-Ray Diffraction. INTRODUCTION The minerals present in copper deposits determine the prospective processing options either: pyrometallurgical or hydrometallurgical. For copper oxide ores, copper is typically present as oxides, carbonate, chlorides, silicates and sulphates. These minerals are readily solubilised in acid and are usually treated through hydrometallurgical processes. The typical process route for copper oxides is to leach copper into aqueous solution, purify and upgrade the solution phase through solvent extraction and then recover copper as metal by electrowinning (Davenport, King, Schlesinger, & Biswas, 2002). Copper sulphide deposits may contain a multitude of copper bearing minerals, including chalcopyrite, bornite, enargite, covellite, digenite and chalcocite. The copper ore grade and treatment options are affected by the mineral type and distribution. Sulphide ores are typically treated through comminution and mineral flotation to form concentrates, followed by pyrometallurgical smelting. Hydrometallurgy can also be used to process sulphides depending on the mineralogy and impurity levels (Davenport et al., 2002). The trend of decreasing copper grade with increasing impurity levels are common across the mining industry and pose future challenges to copper processing. This trend has prompted research into hydrometallurgical options for upgrading copper concentrates. One promising hydrometallurgical option is using metathesis reactions. Metathesis reactions, sometimes also called double replacement or displacement reactions, are chemical processes involving the exchange of bonds between two chemical compounds or species. In this case, the metathesis reactions involve copper in solution exchanging with cations in the solid sulphide concentrate. The driving force for copper sulphide metathesis is the relative affinity of the exchanging cation elements for sulphide. Based on sulphide precipitation diagrams, the expected order of affinity for sulphide should be Hg2+ > Ag+ > Cu+ > Cu2+ > Bi3+ > Cd2+ > Pb2+ > Sn2+ > Zn2+ > Co2+ > Ni2+ > Fe2+ > Mn2+ (Monhemius, 1977). Hence, copper metathesis reactions are capable of increasing copper content and removing impurities such as iron, nickel, zinc and lead from copper concentrates.

Jan 1, 2019