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By Jean Vavrek

What is CIM?s role on a planet-wide scale? That question has been coming back to the forefront of many discussions regularly in the months since we came on board as Executive Director and Vice-President International. CIM, by its name and by the nature of its history and make up, has mainly been a Canadian entity. It has been created by an act of Canadian Parliament and it is set up to work within the Canadian federal and provincial framework.

Feb 1, 2004

By E. Esponosa-Gomez, J. A. Finch, A. R. Laplante

"Water quality plays an important role in oxide flotation. The effects on selective flotation of fine (1-16 um) pyrochlore of two types of water used at the Niobec concentrator, potable and plant recycle, were assessed. Several pyrochlore collectors and silicate depressants were tested. Water effects were different for each mineral-reagents) combination. In general plant recycle water decreased selectivity and increased reagent consumption. Interpretation of results is given in terms of electrokinetic effects, hydrolysis of cations, and mineral-collector interactions. Two techniques of treatment for plant recycle water, cation precipitation and zeolite adsorption were assessed. The former was found to be more effective under the tested conditions but recycle water continued to give poorer selectivity than the potable.INTRODUCTIONWater quality plays an important role in selective flotation. Specific effects have been reported by many workers (1-6) and in general the better the water quality the more selective is flotation. Water composition depends on origin and the minerals being processed. For example pulp containing salt-type minerals (calcite, apatite, dolomite) will contain more Ca and Mg cations than that from a sulphide deposit. Another source of water contamination is the flotation reagents added to the pulp, particularly if water recycling is practiced."

Jan 1, 1986

By G. C. McKerrow

"Mr. G.C. McKerrow, Assistant Manager of Noranda Mines and formerly Smelter Superintendent attended the meeting to answer questions as to why smelters imposed penalties for too much zinc in a copper concentrate or too much copper in a zinc concentrate, etc.D.W. Bridges -Mattagami Lake MinesWhat limits do you set on zinc and lead in a copper concentrate?G.C. McKerrow - At Noranda, we allow 5% zinc free and charge 25 cents for every unit above that. For lead, it is 1% free and 25 cents per unit above that. Lead is a much more harmful impurity than zinc because it tends to recycle more in the smelter circuit and creates a greater health hazard in the plant.E. Thornton - Sullivan GroupWHat harm does fluorine do in the smelting process?G.C. McKerrow - Fluorine usually does not occur in harmful concentrations in non-ferrous smelters. Fluorides are present in exhaust gases in the aluminum and phosphate industries. If these fumes escape into the atmosphere, they may settle out on forage grasses in concentrations that are harmful to livestock.Thorton - Sullivan GroupI have asked this question other places and have been told that it is hard on brick linings and causes gold and silver to be lost up the stack.G.C. McKerrow - Almost any volatile constituent in a smelter charge will aid in carrying other metal values. To this extent it may be harmful.E. Thornton - Sullivan GroupMr. Tait mentioned before a smelter where they have a copper-tin ore and they pay for copper, tin, bismuth and silver but object strongly to indium in the concentrate. Why would this be?G.G. McKerrow - 1 can't see why indium would be a serious impurity. It does tend to concentrate in flu dusts and if you get enough of it you can recover it and sell it but I have never heard of anyone putting a penalty on it.Question - I once ran into a small copper mine in Peru that had cadmium in the copper concentrate but no zinc. The copper smelter charged a penalty for the cadmium. Why would this be?"

Jan 1, 1971

By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015

By George Hope, Brigitte Lacouture

"The Red Dog mine has increased mill throughput most years since start-up. Although flotation equipment has been added over the last 10 years, the Red Dog metallurgical performance has been restricted by a lack of adequate flotation capacity. Two reduced tonnage trials conducted in 1997 as well as numerous SAG relines have consistently indicated the potential to significantly increase both zinc concentrate recovery and grade with additional flotation capacity. Later in 1999, a new circuit was designed with increased flotation capacity while simplifying the current circuit, providing for three stages of dilution cleaning, and creating a retreat section. The purpose of the retreat section is to target the more complex particles and allow the chemical environment to be fine tuned for improved iron depression. In total, 21 Outokumpu OK50 (50 m3) mechanical flotation cells and four 3.66 mØ column cells were added to the current flotation circuit. The VIP (value improvement program) mill optimization project is also addressing thickening, water treatment, and power generation issues and has a total budget of US$105 M. Start-up of equipment was phased in to minimize the impact on current operations and the project was completed by the end of 2001. IntroductionRed Dog Operations started production in November 1989. The mine is located above the Arctic Circle in northwest Alaska. It is linked by an 80 km road to a port-site facility where the concentrate is stored. Concentrate is shipped to markets throughout the world during the one hundred days of open seas. As of January 2002, the Red Dog main pit had 38.4 Mt of reserves grading 19.2% Zn, 5.3% Pb, and 102 g/t Ag. Additional reserves and resources contribute an additional 72 Mt at 15.6% Zn, 4.2% Pb, and 78 g/t Ag. Red Dog is a Mississippian to Permian, black shale-hosted, zinc-lead-silver deposit located in the DeLong Mountains, western Brooks Range, Alaska. All the rocks associated with the mineralizing event are considered to be part of the exhalite rock package. Silicification was a dominant component of the mineralizing event and the host shale has been silicified and locally resembles a chert. The major sulphides in decreasing order of abundance are sphalerite, pyrite, marcasite and galena. Most of the deposit’s silver occurs within the crystal structure of the galena. The dominant ore mineral, sphalerite, is very fine grained to amorphous and is commonly intergrown with silica. Ore textures are massive, fragmental, chaotic, veined and rarely show classic sulphide sedimentary layering. The upper portion of the orebody has been physically and chemically weathered. Oxidation has altered the sulphides to sulphates. The zinc and iron sulphates are very soluble and are readily depleted from the weathered cap, while the lead sulphate is residual and is, therefore, enriched."

Jan 1, 2003

By Jorge Blanco, Joaquin Gotor, Enrique Delgado, Carlos Frias

Since 2009 Cobre las Cruces (CLC) has successfully operated a sustainable mining business near Seville, Spain, applying the most advanced hydrometallurgical technologies to process secondary copper sulphide ores through atmospheric leaching in ferric sulphate media and using oxygen sparging in a cascade of ten reactors. In comparison to conventional copper smelters, the CLC hydrometallurgical process does not generate SO2 gas, airborne emissions or slags. The copper ore is ground and sent directly to atmospheric leaching reactors; flotation is not required, and consequently, copper extraction is maximized at 93-95%, while producing 72,000 t/y copper cathodes of the highest purity (99.999 wt.% Cu, Grade A). Reserves for the CLC deposit were estimated at 16 million tonnes of ore averaging over 6 wt.% Cu and containing principally a chalcocite mineralization. Other copper bearing species include digenite, covellite, chalcopyrite, bornite and enargite. Pyrite represents over 70 wt.% of the ore. In the CLC leaching process, chalcocite reacts with ferric sulphate at approximately 90 ºC and copper is released into solution while ferric ions are reduced to ferrous ions. The ferric sulphate leachant is regenerated continuously by oxygen injection and consumes sulphuric acid. It is remarked that pyrite plays a crucial role to yield high copper leaching rates. When pyrite is oxidized, a small proportion of iron is co-leached and some sulphuric acid is generated. The CLC leaching technology has been designed to allow a certain level of pyrite oxidation, which is positive in many ways: (i) to maintain a Fe/Cu ratio in solution; (ii) to facilitate Fe(II) oxidation; (iii) to produce a high redox potential; and (iv) to counterbalance a bleed solution that removes some iron. Moreover, galvanic interaction between pyrite (cathode) and chalcocite (anode) can substantially increase atmospheric leaching kinetics and efficiency (copper recovery).

Jan 1, 2016

By B. D. H. Knights, N. B. du Preez

The recovery of the economy of the Democratic Republic of Congo has allowed for the rapid increase in production of copper from this region, while the increased price of cobalt continues to support the recovery of that country’s economy. This has enabled the modernization of the process technology used, particularly the change from direct electrowinning of copper to solvent extraction-electrowinning. With this change has come a variety of technical challenges in optimizing the recovery of cobalt from these sources. In this paper, we discuss aspects of the flowsheets for the production of cobalt from the ores of the DRC and Zambia, highlighting the technological improvements that have been made. Following this description of the practice, we assess the challenges of further improving the recovery and purity of cobalt from these sources. INTRODUCTION The African Copperbelt (Figure 1) is by far the biggest producer and holds the greatest reserves of cobalt (Sheed, 2015). However, the ores of this great mining region are extracted primarily for their copper content, and cobalt is a by-product. The ratio of copper-to-cobalt is between 6 and 20 to 1, with the ores from the DRC richer in cobalt than those from Zambia. The overall supply of cobalt, shown in Figure 2, is increasing due to an increase in demand for its use as a battery material. Cobalt is used in superalloys, hard metals, pigments, catalysts magnets, tyre adhesives, lithium-ion rechargeable batteries, and wear-resistant coatings, amongst others. Although these generic categories persist, Figure 3 shows how the relative usage of cobalt is changing due to the uptake of electric vehicles in China and Europe. Cobalt is a key element in lithium-ion batteries, and because it is widely anticipated that electric vehicles will be legislatively encouraged, it is anticipated that the demand for cobalt will rise. This anticipated increase in demand resulted in an increase in the price for cobalt, to which suppliers responded over-eagerly, and the price has dropped dramatically in the first few months of 2019, as shown in Figure 4. However, there is a clear cycle of price peaks in cobalt’s history.

Jan 1, 2019

By L. Tang

A seismic monitoring system was installed in 2005 at Dongguashan Copper Mine, the deepest metal mine in China. Based on the seismic events monitored in situ, the possibility of rockburst prediction and prevention is investigated in this paper. The characteristics of space-timeintensity of mining-induced seismicity and the seismic response to mining are studied in detail using the seismic data in Dongguashan Mine. A conceptual model and a criterion of assessment of hazard seismic nucleation are proposed for Dongguashan Mine. In this model, the mine seismic stiffness method is adopted for rockburst prediction within the framework of the unstable failure theory. To analyze rock failure cases in Donggauashan Mine, the rate of the ratio of stiffness of rock in nucleation area to its surrounding area is proposed as a criterion for rockburst prediction.

May 1, 2009

By Richard W. Lawrence, Richard Poulin

"Numerous processes co-exist for metal extraction and for metal removal from effluents of mining operations. Each process enjoys an economic advantage, including environmental cost and benefit, if utilized in a specific situation. This applies equally to biohydrometallurgical processes. This paper will analyze four types of biohydrometallurgical processes for their economic and environmental attributes: biooxidation of refractory gold, extraction of copper from sulfide, metal removal from effluents by active sulfate reduction, and metal removal by the use of wetlands. By examining the economic and environmental advantages of these processes, generalizations can formalized and it becomes possible to define niches of application where biohydrometallurgy can be considered. Our analysis shows that biohydrometallurgy can be efficient at small scale, be more environmentally friendly than conventional technologies and is relatively easier to operate. The higher financial risk associated with unproven technologies at the commercial scale is being eliminated as biotechnology-based plants are put into production.IntroductionBiotechnology can be described as the rational exploitation of the activities of living cells or parts thereof, requiring an integrated multidisciplinary approach between biological and technical disciplines. Microbiology, biochemistry, botany, molecular biology, chemistry and engineering all contribute to practical applications in the extraction, manufacturing and service industries, and in environmental management. Considerable commercial success of biotechnology has been achieved in several sectors, including health care, agriculture, forestry and aquaculture.Over the past 40 years, industry, research organizations, government laboratories, and universities in a large number of countries have participated in investigating the utilization of biotechnology applications in mining. Today, several technologies are used commercially in well understood and engineered systems which can be grouped under the term biohydrometallurgy. Many more technologies have been demonstrated at laboratory or pilot plant scale. Although initial developments and commercial applications were aimed at metal extraction, the dramatic increase in environmental awareness, the practice of sound environmental management demanded by more stringent regulations over the past decade, and the need for low cost treatment in perpetuity, has led to serious investigation of biotechnology for environmental control. In addition, increasing power costs, lowering of ore grades, and decreasing commodity price in real dollar terms require the use of highly efficient and competitive extractive technologies."

Jan 1, 1998

By David H. Searle

This paper will discuss the common trends existing in various Canadian jurisdictions for the closure and reclamation of mines. Included will be a discussion of the requirement to post security as well as its form and how security is calculated and refunded. Reclamation can no longer be left to the end of mine life. Progressive reclamation must occur throughout mine life and must be part of the mine plan from the beginning.

May 1, 2006

By T. R. Bieler

"Hot forming and superplasticity in powder metallurgy aluminum alloys and composites is reviewed. The effects of alloy composition, particulate composition, size, and size distribution is summarized. The role of climb distance for recovery is described in connection with the size of strengthening phases. In materials with fine strengthening phases on the order of one micron or less, high strain rate superplastic deformation processes are likely. However, the quality of superplastic deformation depends on the prior processing history, and these effects are reviewed. Very few data describing the effects of hot forming history on post-forming properties exist, but some results emerging in the literature are compared.IntroductionHot deformation in aluminum based materials is done for several technological purposes, such as thermomechanical processing to alter mechanical properties of simple forms, and/or final shaping operations to produce a complex shaped part by means of extrusion, forging, or superplastic forming. In the interest of improving the mechanical properties of aluminum based materials, two microstructural design strategies are commonly used, dispersion strengthening, and composite strengthening. The introduction of fine, stable dispersions is commonly done for high temperature strength, and the dispersions are typically ceramic particles in the range of 10 nm to 1000 nm in volume fractions around 5 vol.% (Higashi et al., 1990; 1991a; 1991b; 1992; Bieler and Mukherjee, 1990; Otsuka et al., 1987; Bieler et al., 1991; Oliver and Nix, 1982). Alternatively, composite strengthening strategies using 10-40 v% of 3 µm to 40 µm ceramic particles provide high modulus and high strength aluminum based materials (Midling and Grong, 1995; Lloyd, 1994; Subramanian et al., 1995)."

Jan 1, 1997

By D. D. Hogarth

"IntroductionThe Hull iron range, comprising the Forsyth, Scott , Baldwin and Lawless properties (Fig. I), is in Gatineau Park, on the outskirt s o f the city of Hull , and about 6 miles (10 kilometres) northwest of the Federal Parliament Buildings.The deposits have been known many years and described numerous times, although the history has been treated lightly in former publications. Total ore shipments have been calculated at 122,700 long tons, of which over 80% were mined before 1900 and 74% in two brief periods: 1870-74 and 1880-82. It is surprising that the period 1870-74 has been overlooked by most authors and 1880-82 ignored altogether. More surprising, the essential data for these two periods are contained in manuscripts of the Robert Bell collection, which must have been available to officers of the Geological Survey o f Canada.The period 1801-1874 ha s already been covered by the writer in ""Pioneer mines”, but much information has come to light since publication. The present paper is therefore based o n new data and a fresh appraisal. However, little additional data were found for the early history (1801-1854) or for the legal cases involving A.H. Baldwin, and these parts were mainly summarized from the relevant sections of the above-mentioned publication.GeologyThe ore deposits are all situated somewhat below the middle of a graphitic, calcitic marble horizon, here folded into a northeast-plunging synform. The Forsyth, Scott and Baldwin deposits are on the south limb of the synform; the Lawless is on the north limb. The marble is underlain by three non-carbonate groups: biotite gneiss with interlayered quartzite (top), granite gneiss and skarn (middle), and biotite-garnet gneiss (bottom). Below these groups is a lower horizon of graphitic, calcitic marble. The whole sequence is Precambrian and has been subjected to high-grade (Grenvillian) metamorphism, but, in the north, is cut by an unmetamorphosed Cambro-Ordovician diabase dyke. For further information, the reader is referred to the summary by Baird."

Jan 1, 1983

By V. K. Karra

"A simplistic algorithm jar simulating the rod or ball mill Bond grindability test applied to ores and minerals is presented. A performance comparison between the present algorithm and a previously published algorithm by Kapurot, modified in this work jar a fair evaluation, is also given. A worked example is furnished jar leading the reader through the various calculations.IntroductionThe Bond grindability test is widely used for the prediction of the power requirement of an industrial grinding mill. The procedures for conducting this test in either a ball or a rod mill are available(1). In the case of a ball mill, batch grind abilities have been correlated to Bond grindabilities to help monitor day-today variations in ore grindability for the purpose of plant control( 2,3). Of special interest is the algorithm presented by Kapur(3) for the simulation of the Bond test. In practice, the test lasts from 6 to 14 cycles (4 to 10 hours). With this algorithm, one can predict the Bond grind ability using information available from only the first two cycles.Sometimes the prepared feed for the grindability test contains too much fines compared to the total product desired at the mesh of grind under consideration. In such a case, the operator separates the fines from the test feed and adds to the remaining coarse fraction an equal amount of fresh feed. This combined feed then forms the feed to the first cycle of the test. In the present work, Kapur's algorithm is modified to include this special case. A new and relatively simpler algorithm is also presented. Statistical equations relating work index to pertinent variables are also given."

Jan 1, 1981

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

The hydrometallurgical treatment of copper ores and concentrates continues to be an active field of innovation. The direct extraction of copper from ores containing chalcopyrite is an important development to provide an alternative to flotation-smelting and refining. Jetti Resources (with the University of British Columbia) and the JX Nippon Group have developed process options for chalcopyrite heap leaching. Biological heap leaching developments for chalcopyrite are also continuing in parallel. These direct leaching technologies are also very attractive for arsenical ores. The atmospheric leaching of copper concentrates is an attractive option along with autoclave processing. The Galvanox™ Process is the focus of commercialization by InCoR Galvanox Holdings under exclusive license by the University of British Columbia. The Galvanox™ Process can be used to treat chalcopyrite or enargite containing concentrates to high copper extraction with simultaneous precipitation of arsenic as atmospheric scorodite. FLSmidth has continued development of the Rapid Oxidative Leach (ROL) and associated technologies for chalcopyrite leaching. The Glencore Albion Copper Process using ultra fine grinding of copper concentrates and atmospheric leaching has found application in central Africa. The pressure leaching of copper concentrates continues to be attractive for rapid, complete oxidation of sulfide minerals with high copper extraction and arsenic stabilization of iron-arsenate minerals and precipitates. The Ecometales PLCC project is designed to use high temperature total pressure oxidation for treatment of an arsenical copper concentrate with use of existing copper SX-EW facilities for copper cathode production. The excess acid from the autoclave process will be used to make up the acid demand for associated copper ore heap and dump leaching operations. INTRODUCTION The recovery of copper from ores is dominated by the flotation of copper concentrates followed by smelting—converting and electrorefining. This process has been enabled by the development of froth flotation and progressively made more efficient by advances in smelting and converting technologies.

Jan 1, 2019

By P. W. Waggitt

ABSTRACT From approximately 1986 until 2000, uranium production was at a historic low. In 2003, uranium mineral exploration surged, despite the global financial crisis; however, the shortage and aging of qualified and experienced operators and regulators might soon become a constraint to this upsurge. This is true for all types of engineers, geologists, other scientists, tradespeople, and technicians. The situation raises questions about how the global mining industry in general and the uranium sector in particular will cope with future staffing needs. In this paper, the author examines the current situation and describes how some organizations are seeking possible solutions.

Jan 1, 2014

By Z. D. Hora

Sev_eral dozen si lica occurrences have been reported from various parts of Brit ish Columbia. Some represent hydrothermal veins or parts of pegmatite bodies; other are recrystall ized sandstones. Several vein type deposits were mined for smelter flux and as a source of white chips for stucco dash and simi lar products. Some quartzites were studied as potential sources of high-grade silica for ferrosilicon and silicon metal production. The province's only production of silica for ferrosilicon has come from a pegmatitic quartz plug near Oliver in southern British Columbia. Its reserves are now practically depleted.

Jan 1, 1984

By Philip A. Dirige

This paper presents the variability of responses of paste backfill specimens that have been prepared with varying binding agent and binder combinations, when subjected to uniaxial compressive strength testing. A testing program conducted for an underground operating mine to produce cost efficient paste fill recipes using four different binding agents, in various ratios and combinations, is presented to illustrate the responses. These binding agents are Normal Portland Cement Type-10 (NPC T-10), oxidation or sulphide attack resistant binder (Binder A), replacement binder B (Binder B), and replacement binder C (Binder C). The paste fill recipes were prepared at 2, 3.5 and 5% binder content at varying binder combinations, at fixed size and tested in a Material Testing System (MTS) under constant strain rate conditions following cure times of 7, 14, 28, 56, 90, 112, 180 and 240 days. The results of tests suggested that the strength data clearly shows a trend of increasing strength with increasing binder content but not necessarily cure time. It is noted that all the blends achieved dramatic increases in strength up to 28 days of cure and then either increased or decreased moderately beyond 28 days curing, depending on the binder content and binder combination. The moderate decrease is apparent for the 2% paste fill blends and in some binder combinations of the 3.5 and 5% blends, which indicated lackluster performance beyond 28 days curing. This lackluster strength performance indicated that the binder content and combination may not be sufficient for the paste fill to achieve complete hydration and acquire adequate strength performance beyond 28 days. This study indicated that economic paste fill recipes can be designed with confidence using affordable alternative binders. However, it is noted that these alternate binders cannot be used as stand alone binders but should be used in combination with NPC to facilitate hydration of the paste fill.

May 1, 2006

By Laura Mottola

This paper outlines a framework for ensuring the success of the implementation phase that follows research and development of new mining technologies and systems. It is based upon recent and past lessons learned that have demonstrated the critical challenges to effective technology transfer, which frequently receive inadequate attention within the culture of the mining business. The paper focuses on mining automation implementation challenges and then outlines a Roadmap which is proposed as an integrated framework to deal with the key aspects of people, process and technology. This framework is built upon: assembly of a Strategic Team to develop a Roadmap; fully understanding the business requirements of the technology initiative; defining Key Performance Indicators in a Balanced Score Card; performing a Stakeholder Analysis to identify the affected groups; and finally developing a master Project Plan to execute the Roadmap.

Oct 1, 2009

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014