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By Scott Honan, Tassos Grammatikopoulos, Mike Johnson, Kelton Smith, Niels Verbaan, Ernesto Bourricaudy, Eric Larochelle, Rick Sixberry

"NioCorp is developing the niobium/scandium/titanium Elk Creek carbonatite resource deposit. The carbonatite phase contains significant niobium (0.71% Nb2O5), titanium (2.68% TiO2) and scandium (72 g/t) and is composed predominantly of calcite, dolomite and ankerite. Niobium is mostly (80%) contained in the pyrochlore and the balance in various Fe-Nb-Ti oxides, which also host most of the titanium. Scandium is distributed homogeneously throughout the ore mineral assemblage. The process flowsheet recovers separate niobium, titanium and scandium products. Scandium is extracted from whole ore hydrochloric acid leach solutions through solvent extraction, and is further refined through a re-leach and precipitation process. Scandium leach residues are treated with sulphuric acid to recover separate niobium and titanium precipitates. Both hydrochloric acid and sulphuric acid reagents are recycled within the flowsheet. This paper will discuss key bench and pilot test results (focusing on the scandium flowsheet) and will present a conceptual flowsheet developed by the project team for NioCorp at SGS Minerals.INTRODUCTION NioCorp is developing North America's only niobium/scandium/titanium project. The Elk Creek project is located near Elk Creek, Nebraska, and is the highest grade niobium project in North America and the largest prospective producer of scandium in the world. These elements are unique and valuable superalloy materials that are strategic and critical to many industries and national defense technologies. The project includes the Elk Creek Carbonatite (the Carbonatite) that intruded older Precambrian granitic and low to medium grade metamorphic basement rocks. Both the carbonatite and Precambrian rocks are interpreted to be unconformably overlain by approximately 200 meters (m) of Paleozoic marine sedimentary rocks of Pennsylvanian age. As a result of this thick cover, there is no surface outcrop within the Project area of the carbonatite, which was identified and targeted through magnetic surveys and confirmed through subsequent drilling. The available magnetic data indicate dominant northeast, west-northwest striking lineaments, and secondary northwest and north oriented features that mimic the position of regional faults parallel and/or perpendicular to the Nemaha Uplift."

Jan 1, 2017

Post--Crunch Financial Management -An Overview A. The Industry and the Capital Markets B. .The SME -De-risking the Current and New Assets Followed by: C. The Lender?s Perspective on Re-financing?Jeff Stufsky, BNPParibas, NYCD D. .The Agency/Export Credit Lender Perspective?Doug Macaulay, EDC, Ottawa E. The Foreign Political Insurance Perspective?Pierre Vieillescazes, Carrick-Bend, Washington, DC ?Four Fundamental Metal Models No Longer Prevail. ?Mining is in new ?waters?: so be prepared (next page). ?Capital markets are uncertain-so be your own financier first ?If tight capital may remain, prepare to triage based on cash-flow production (not oz, lbs, tonnes, etc) ?Know your banker/financier(and it should know mining) ?In the past, it was ?know your borrower? ?The climbing team can fall if one climber carries too much ?Constantly re-assess the risk matrix (and j/v?s), and ?De-risk/diversify both the asset and the capital base

May 1, 2010

By T. G. Joseph

The strain softening relationship developed in part 1 is now applied to coal. Having determined the post-failure stress-strain curve for coal specimens, this information can then be used in a finite element program, such as Phase 2, to examine the post failure characteristics of coal pillars. Using example data, the strength of coal pillars of different width/height ratios are estimated and compared with well-known empirical pillar size-strength relationships. In addition, the post-failure stress-strain behaviour of a coal pillar is compared with an empirical relationship reported in the literature.

May 1, 2002

By D. F. Sangster

"Eight volcanogenic massive sulphide districts in Canada and Japan, ranging in age from Archean to Miocene, were selected for analysis. The study revealed that: {I) each district has an average diameter of 32 km; (2) the districts contain 4 to 20 deposits each, with an average of /2 deposits; (3) the average total base metal content per district is 4.6 million tonnes, with a coefficient of variation of32%; (4) ranked in order of size, the largest deposit in each district contains, on average, 67% of the total metal and the second largest about 13 %. The remaining deposits range downward in decreasing proportions. Empirical observations such as these may be used f or evaluating the undiscovered potential of new districts as well as contributing to a better understanding of the distribution and genesis of this important class of base metal deposits. Previous WorkThe characteristic geological features o f volcanogenic massive sulphide deposits have been described by numerous authors over the past fifteen years and it is now widely accepted that these deposits comprise a major ""deposit-type."" In addition to these geological parameters, however, it is now becoming apparent that volcanogenic massive sulphide deposits show several distinctive grade-tonnage relationships. For example, Singer et al. (1975) demonstrated a slight negative correlation between copper grade and ore tonnage in their sampling of 146 volcanogenic deposits. In a study of 110 Canadian Precambrian deposits of this type, Boldy (1977) showed that the size of the modal deposit is 0.39 million tons, that of the median deposit is 1.40 million tons and the arithmetic average is 6.85 million tons. Moreover, Boldy's data show that the average grade of combined base metals (Cu + Zn + Pb) for each of the se three deposit-sizes is, respectively, 6.25%, 5.35% and 6.47%. Because the lead content of Canadian Precambrian volcanogeni c deposits is most frequently less than 1%, the total metal grade is effectively Cu + Zn . From Figure 2 in Bold y (1977), it can be seen that 83% of the deposits fall in the range of 0.l to 10 million tons ."

Jan 1, 1980

By Z. -G. Ren, J. -S. Qian, Y. -G. Yang

The waste slags from chemical and metallurgical plants contain approximately wt 1% water soluble Cr6+. This hexavalent chromium is very harmful to human health, and the treatment of the slags has concerned metallurgists for many years. A sintering method was developed to treat the waste slag. In this process, sinter was made from a mixture of the waste slag containing hexavalent chromium, iron concentrate and coke breezes. During sintering, hexavalent chromium was reduced to trivalent chromium. The latter is known as a non-harmful material and can be used as chromium resource for the production of ferrochromium or chromium-containing cast iron. After sintering the hexavalent chromium in the sinter could be reduced to less than 0.0008%. It was found that the waste slag with fine particles was favourable to the Cr6+ removal. An increase of carbon content in the sintering mixture could increase the rate of Cr6+ removal and the strength of the sinter produced. The rate of Cr6+ removal increased with increasing basicity of the sintering materials with basicity less than B=1.8, above which it decreased with increasing basicity. Blast furnace was found to operate smoothly when using the sinter made from the waste slag containing chromium. However the productivity of sintering machine was slightly low compared to the sintering operation using ordinary raw materials.

Jan 1, 2004

By Hamid Mahmoudabadi

In the present paper, the performance of four approaches based on neural networks and geostatistical method for grade estimation are compared and analyzed their performance to find a proper method. Four methods, Multi Layer Perceptron neural network (MLP), Radial Basis Function (RBF), General Regression Neural Network (GRNN) and Ordinary Kriging (OK) are selected for ore grade estimation of variable Fe in an iron deposit located in Iran. For each method, two diagnostic statistics are calculated: Mean square error (MSE) and correlation coefficient. The results show the superiority of the General Regression Neural Network.

Oct 1, 2009

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

By V. Schenk

Dust exposure resulting from the exploitation and winning of natural resources below ground has presented a serious health problem since the beginning of mining. The boom phase of the German hard coal mining industry after World War II with at times up to 500,000 employees saw an increase of dust exposure of miners below ground as the mechanization of road heading and mining increased significantly. More and more miners were diagnosed with coal-workers-pneumoconiosis (CWP), a chronic and irreversible lung disease resulting in a significant impairment of pulmonary function. This realization led to a reduction of CWP in the German hard coal mining industry in the 1960s. The successful fight against CWP began with the introduction of technical dust prevention measures. By infusing the coal seam with water before mining, sprinkling and spraying of heading and mining machines as well as canopies with water, aspiration in places with high amounts of dust and the suppression of dust with chemical substances it is possible to significantly reduce the miners? dust exposure. All operating points below ground are checked and measured regularly with regard to dust exposure. Through the combination of these values together with the individual shift data a relatively precise profile of individual dust exposure can be obtained. This profile allows the targeted work assignment when certain predetermined limits have been reached, moving the miner to a work place with less dust exposure and thus reducing the chronic dust exposure. The state of health of the individual is known because since about 60 years ago extensive occupational health checks have been carried out regularly at least every two years which means that work restrictions can be imposed depending on the findings. Since the beginning of the 1980s more value has been attached to not only situational but also behavioral prevention. Given the comprehensive provision of protective masks, having a protective effect as well as the required comfort when being worn, each miner has the opportunity to protect his respiratory organs depending on the specific dust exposure. Through a combination of all these measures the German hard coal mining industry has succeeded in beating the classic coal miner?s disease CWP. For mines in the Ruhr valley this means that a miner who started work after 1978 will no longer develop CWP.

Aug 1, 2013

By Trung Nguyen

Midwest is a unique uranium deposit with exceptionally high arsenic content. The ore body is located 17km west of the McClean Lake operation. The McClean Lake mill will be modified to process Midwest ore and handle solid wastes coming from the Midwest water treatment plant. This paper describes the modifications required of the McClean Lake mill, process challenges associated with treatment of the arsenic, and the possibility of recovering nickel and cobalt as a by-product. It also reviews the complexity in the design of the Midwest water treatment facility which incorporates reverse osmosis technology with conventional physical-chemical water treatment.

Aug 1, 2010

"During the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material from a selection of various drilling products or a sample from a mining test. It can be also a sample from an existing plant in order to investigate process enhancement. This sample can represent several tonnes of material which are analysed and split for use in various tests.In the current case, a composite sample of gold ore is dedicated to a Gravity Recoverable Gold (GRG) test. The properties of interest are the head grade of gold, the size distribution of the material, and the gold assay per size class. The sample is mixed and a sub-sample is taken to measure the feed properties: the size distribution and the gold assay per size class. The remaining material of the sample is subject to the first stage of concentration using the laboratory Knelson concentrator. The concentrate is analysed in its entirety, while a sample of tailings is taken for the same analysis. The remaining part of tailings is subject to grinding to feed the second and third stages of concentration. Similar sampling is performed at each stage.The concentration performances are analysed in light of these measurements. But what is the accuracy of the measurements of the properties? Pierre Gy’s theory of sampling, associated with a heterogeneity model built using the GRG test results, will answer this question. The current paper presents, through a real example, the calculation of the errors of the measurements of size distributions and gold assays performed during the GRG test. The uncertainties of the concentration performances and liberation size estimate are then calculated and their impact on the results interpretation is analysed.INTRODUCTIONDuring the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material from a selection of various drilling products or a sample from a mining test. It can be also a sample from an existing plant in order to investigate process enhancement. This sample can represent several tonnes of material which are analysed and split for use in various tests. In order to take into account the ore variability in terms of gold deportment, it is recommended to perform variability studies (Dominy, Murphy, & Gray, 2011, Dominy, 2013) using samples representing various horizons or years of production. But for a given ore type, it can be necessary to perform many tests with different operating conditions (Brochot, 2012a). In that case, the variability of the samples is not due to the heterogeneity of distribution of the deposit, but only on the heterogeneity of constitution of the primary sample. The level of confidence associated with the estimated performance parameters is directly linked to the overall error (including sampling error) of the measurements performed during the tests."

Jan 1, 2016

By M. Yao, D. Thibodeau

"Selective mining, such as post pillar cut and fill, is used in large, flat, irregularly shaped ore bodies where ground stability is to be maintained. This selective mining is used to open the stope to the full lateral extent of the ore body in order to minimize the dilution and maximise the recovery. For increased mining depth, design of the post pillar becomes more challenging since those pillars will eventually fail as mining progresses upwards. The post pillar should be designed such that failure does not occur at the early mining stage, such as at the first cut. After mining progresses upwards, the post pillars are expected to fail but be confined by backfill. In order to maximise ore recovery, both drift width and post pillar size must be designed adequately with a consideration of all geomechanic parameters. This paper will describe the process used to design post-pillar cut and fill for one of the ore bodies in Vale’s Copper Cliff Mine using a combination of both empirical deterministic and numerical modelling techniques. By utilizing both empirical deterministic and numerical modelling techniques drift width and post pillar size can be effectively designed. Current post pillar cut and fill design in the existing Vale operations are used to validate the design for Copper Cliff Mine. INTRODUCTIONCopper Cliff Mine is located within the Copper Cliff Offset in the limits of City of Greater Sudbury, Ontario, Canada, as shown in Figure 1. The Copper Cliff Offset extends about eight kilometres south from the Sudbury Igneous Complex into the footwall rocks. Until 2008, the current Copper Cliff Mine was operated as two separate mines i.e. North Mine and South Mine. However, as part of restructuring of Vale Ontario Operations, the North and South Mines were merged in 2009 to form the “Copper Cliff Mine”."

Jan 1, 2015

By Vincent Doyon

For several years, the GDD SSW EM Probe is being used in nickel?s mines in Canada and Brazil to define ore limits, reduce dilution and predict nickel grades. It is used with success to test most if not all percussion blast holes at all Falconbridge Mines in Sudbury and Raglan and all Inco?s Thompson mines. However, after testing the SSW Probe in other metal mines, we realized that EM conductivity does not define ore limits by testing blast holes for copper, zinc or gold. For non-conductive ores, no instrumentation is yet available on the market to reduce dilution, by outlining quickly and inexpensively the real shape of an orebody. To that effect, Instrumentation GDD Inc has developed a new revolutionary photonic probe that will make the reduction of dilution possible by probing blast holes. Once surveyed with the probe, a computer draws graphs of the ore grade as a function of depth for each blast hole. A contribution by Canada Economic Development made possible the development of this new technology. Canmet and Soredem also cautioned this technology developed by Instrumentation GDD Inc. This new photonic probe will allow: 1) to better understand the shape of the orebody 2) to raise the grade of the ore fed to the mill 3) a more complete extraction of the ore 4) to raise the competitiveness of mines

Oct 1, 2004

By A. J. Smethurst, S. B. Hearn, S. Boskovic

"The problem of crud in solvent extraction is well known and can be a major handicap and operational issue. Colloidal silica can cause a number of problems including interfering with flocculation, initiating crud formation in solvent extraction (SX), decreasing SX extraction kinetics and increasing SX phase disengagement times. Flocculation can be utilized to remove some of the troublesome particulates but colloidal silica does not flocculate well and presents a different problem requiring innovative chemistry to solve. Coagulants can assist by facilitating the removal of this colloidal silica by promoting the agglomeration of the particles to a size which can be more readily settled or flocculated in solid/liquid separations. This is achieved when the coagulants bind to the surfaces, displacing water and destabilizing the colloids, whereupon they bind to each other which facilitate their amenability to conventional flocculation.INTRODUCTIONSilicate minerals are abundant in the upper layers of the Earth’s crust, and there are few mineral deposits without significant levels of gangue silicates. Silicate minerals include the pure silicas, such as quartz and other silicate containing minerals such as clays, chlorites, feldspars, as well a vast number of less common silicates.During the acid leaching of ores, two types of fine silica particles are released in solution from the dissolution of the host mineral. The first consists of partly depleted silicates, and the second is colloidal silica, which forms in solution. It is this second type which has the potential to cause crud formation as well as poor solution clarities, slow filter rates and excessive flocculant usage (Figure1)."

Jan 1, 2016

By Jessica Egan, Daniel Hodouin, Mohammed Reza Khalezi, Steve Bellec, Claude Bazin, Carl Duchesne

"A model for gold leaching was developed and implemented into a simulator. The simulator uses a description of the ore that is based on the mineral composition and precious metal content. The model accounts for the distribution of minerals and precious metals through the size intervals. An ore texture model based on precious metals and minerals grain sizes within the ore is used to predict the exposed surface of the species in the various size intervals. A model is proposed to predict the rate of dissolution of any species dissolution using the exposed surface, particle size, cyanide and oxygen concentrations, temperature, pH and agitation. The flow of slurry through a leaching tank is modelled using a parallel arrangement of perfect mixers to simulate a bypass and a Cholette-Cloutier mixer model. The simulator can be used for circuit optimization but was developed to provide an environment for learning the basic concepts of process analysis methods. Examples are given to illustrate the application of the simulator for planning tracer tests and sampling campaigns.INTRODUCTIONThe constant pressure to improve the operation of processes that are already close to optimum imposes to plant engineers to be aware of the available process analysis tools and to be able to use them to assess process operation and make a diagnosis to possible problems. Some of these tools are:•,Sampling the streams of a process;•,Data reconciliation;•,Analysis of mixing in reactors;•,Estimation of rate parameters;•,Optimal tuning and flow sheet modification;•,Automatic control and real time optimization.Although some of these tools are part of the curriculum of many university engineering programs, the students are not exposed to actual process analysis problems. In addition the complexity of the ore dressing processes compounded with unavoidable measurement errors and plant disturbances can discourage many motivated engineers. These factors often lead to an incomplete valorization of the collected data and a poor return on the investment associated with the sampling, testing and analysis of the samples.Simulators are readily available for process optimization (Yalcin and Shang, 2006) by allowing:•,The simulation of various flow sheet configurations;•,The simulation of a change of operating conditions;•,The simulation of various control strategies;•,The training of plant operators.However few simulators have been developed with the objective of providing an environment for training plant engineers and technicians to the use of tools for process analysis and optimisation."

Jan 1, 2008

By Marc Symbaluk

Core Programs Current ? Aboriginal Involvement Program ? Adaptive Forest Management / Forest History Program ? Grizzly Bear Research Program ? Natural Disturbance Program ? Foothills Growth and Yield Association ? Foothills Stream Crossing Program ? Fish and Watershed Program ? Caribou Landscape Management Association ? Social Science Program ? Local Level Indicators Program ? Communications and Extension Program ? Geographic Information Systems Program ? Mountain Pine Beetle Ecology Program In Development ? Climate Change Program ? Forest Community Program ? Water, Quantity and Quality Program (Water for Life) ? Circumboreal Initiative ? Yellowhead Ecosystem Management Group

May 1, 2008

By J. Oliveira, A. R. Barnes, R. Pandher

Sub-stoichiometric roasting of arsenic-bearing copper ores is a well established practice. However, ores containing calcium commonly prove challenging where very low arsenic levels are desired, but the reasons for this phenomenon have largely been speculative. In the course of treating arsenicbearing copper ores by partial roasting in fluid bed reactors, XPS encountered one of these Ca-bearing ores which proved a challenge to roast to acceptably low levels of arsenic. Mineralogical examination of the calcines using a combination of XRD (X-ray diffraction), QEMSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) and EPMA (Electron Probe Micro-Analysis) helped to identify the arsenic bearing species and assisted in developing a workable theory on the sequence of reactions occurring during the roast. With the assistance of thermo-chemical modelling, this allowed adjustment of the roasting conditions to minimise the amount of arsenic retention in the calcine in spite of the presence of calcium in the ore and advance the roasting program to a commercially acceptable solution.

Jan 1, 2014

By Trygve Høy

"Important stratabound lead-zinc deposits in southeastern B. C. occur in rocks that range in age from Proterozoic Helikian to Middle Cambrian. The Sullivan deposit, and similar but smaller deposits in the Sullivan area are the only important deposits that occur in clastic rocks with little carbonate content. The highly deformed and metamorphosed Shuswap deposits, of probable Hadrynian to Helikian age, are in mixed marble, calc-silicate gneiss and pelitic schist assemblages, rocks transitional between clastics and carbonates. Deposits in younger rocks, such as the Kootenay Arc deposits in the Lower Cambrian Badshot-Reeves Formation and the Monarch -Kicking Horse deposits in Middle Cambrian dolomite, are hosted by platformal carbonate rocks.An important regional control for the distribution of deposits appears to be a northeast-trending tectonic zone that crosses the Rocky Mountains and the Purcell Mountains just south of the Sullivan area, and projects southwestward toward the Salmo camp at the southern end of the Kootenay Arc. Pronounced northeast-trending gravity and magnetic anomalies, basic volcanism of Hadrynian age (the Irene volcanics west of Creston) and a preferred alignment of Mesozoic granitic rocks indicates that the zone coincides with deep crustal structures. Within the zone are dramatic and abrupt thickness and facies changes in Hadrynian Windermere rocks and lower Paleozoic rocks, and on the east side of the Rocky Mountain Trench in Helikian Purcell Supergroup rocks, indicating that block-faulting was active intermittently within the zone from Helikian through to lower Paleozoic time. Right-lateral and reverse movements occurred on northeast-trending tear faults within the zone in Mesozoic time."

Jan 1, 1982

By M. E. Moraes Castanho de Almeida, A. Ribeiro Cotri

Recovery of cobalt to produce high grade cobalt sulfate from cobalt concentrate by leaching and solvent extraction was investigated. The PLS typically contains Co 10g/l, Mg 2g/l, Fe < 10ppm, Mn < 200ppm, insolubles <100ppm and is extracted with 20wt% Cyanex??272. The typical strip solution contains Co 60g/l, Mg 0.03g/l, and was sent to the current process for the production of cobalt sulfate heptahydrate. The cobalt yield of the plant with two extraction steps was 92%, with three steps was 97% and with four steps 99%. The extraction stage used the concept of "scrubbing" in a countercurrent system. In the first stage of extraction pH was 4.8, and in the last stage of extraction pH 5.5 to promote the exchange of magnesium in the organic with cobalt contained in the PLS. Following the extraction, when using two scrubbing stages, Co/Mg selectivity between of 2,000-3,000 was obtained, and with three scrubbing stages, selectivity was greater than 6,000. The desired selectivity was reached when using a scrubbing configuration with O/A ratio of 10:1. The typical cobalt sulfate heptahydrate had the following composition: Co 20wt%, Mg < 0.01wt%, Fe < 5ppm, Mn < 0.01wt%, Cu < 0.01wt%, Zn < 0.01wt%.

Jan 1, 2014

By Laurence D. Burke

The electrocatalytic behaviour of gold in aqueous media is surprisingly complex and a novel view of gold electrode surfaces is proposed to explain the observed electrochemical responses. The metal surface is considered as a chemically (or redox) modified electrode, with equilibrated, low energy, surface gold atoms functioning as a relatively inert support and low coverage, high energy, protruding gold atoms (or minute clusters of same) functioning as electrocatalytic redox mediators. The protruding atoms are viewed as surface active sites and the complex electrocatalytic behaviour is attributed to the basic instability of the mediators, the diversity (and poor control) of same, and the acid/base (or hydrolysis) behaviour of the oxidized states of the mediators. It is assumed that major advances in the application of gold in the heterogeneous catalysis of gas phase reactions will be accompanied by similar advances in the use of gold in the electrocatalysis area; however, this will require considerable work of both a practical and theoretical nature.

Oct 1, 2003

By J. Brent Hiskey

At present, approximately 80 % of the worlds mine production of copper is achieved by smelting and electrorefining. The principle aim of copper electrorefining is to satisfy the large demand for extremely pure copper. It is remarkable that high quality copper cathodes with the required purity (99.99+% Cu, ASTM B115-10) and structural characteristics (i.e. deposit density and morphological texture) are produced from impure copper anodes dissolved in electrolytes containing a variety of impurities. This is accomplished with the proper control of operating parameters such as: current density; temperature; copper and sulfuric acid concentration; agitation; substrate preparation; and the application of electrolyte additives. The basic elements of the electrolysis of copper have not changed significantly over the past 150 years since the early developments of James Elkington. Importantly, our fundamental understanding of the underlying electrochemistry has advanced considerably. This is especially true regarding our knowledge of the mechanistic role of additives during the electrocrystallization of copper. This is a very complex subject and modern electrochemical techniques and the development of surface characterization and imaging instruments has helped immensely in our ultimate understanding of how additives control the deposit structure and morphology. The purpose of this paper is to review the historical development and application of electrolyte additives in copper electrorefining and to examine our current knowledge regarding their use. INTRODUCTION The first transatlantic telegraph cable was completed in August 1858. Regrettably, this cable failed shortly after the initial connections. After several more failed attempts, improvements in materials and copper quality resulted in successful communication between Europe and America on July 28, 1866. In many ways this hallmark event demonstrated the need for high purity copper. The first copper refinery in the world was commissioned in May 1869 in Pembrey, South Wales by partners Josiah Mason and James Balleney Elkington. (Historical Note). The 1865 and 1868 British patents issued to James Balleney Elkington were the foundation for the first commercial production of high purity electrolytic copper (Elkington, 1865, 1869, 1870). This important achievement was made possible primarily by the invention of the dynamo which was based on the fundamental operating principles advanced by Michael Faraday. A symbiotic relationship between copper refining and the dynamo was henceforth established. The dynamo provided electric current for electrolytic refining of copper and the electrorefining tankhouse provided pure copper which was required for the generation and transmission of electricity.

Jan 1, 2019