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By Éric Côté

Introduction The 425 Main Ore Zone ? Block of ore partially mined in the late sixties; ? Area was sealed off for over 30 years due to SO2 emissions from oxidizing fill material; 425 Project goal ? Bring the zone back into production without jeopardizing the mine; ? Minimize risks associated to SO2;

Feb 1, 2008

By M. Dupuis, V. Bojarevics

It is well known that horizontal current density in the metal pad contributes greatly to the generation of MHD driven bath-metal interface wave. It is possible to compute very accurately the metal pad current density using a very detailed finite element model [1], but a MHD model must be compatible to this level of mesh refinement and to recalculate the current distribution at each time step, including the full busbar supply system. The accuracy of the instability prediction of the cell depends on the accuracy of the metal pad current density calculation. This study presents the comparison of the metal pad current density calculation of the detailed finite element model and the MHD-Valdis model for different metal pad heights and ledge thickness. It also presents the corresponding cell MHD stability predictions.

Jan 1, 2006

By A. Sadough vanini A. Kami

In this paper, effects of different ageing treatments on the mechanical properties, microstructure and formability of 7075 aluminum alloy have been studied. Forming limit diagrams of the alloy have been obtained for four ageing conditions including T6, OA1, OA2 and O. For this purpose, combination of uniaxial tensile tests and the Erichsen cupping tests with different sizes and shapes of sheet specimens have been performed after each ageing treatment. The highest formability and the lowest formability have been observed at samples with O and T6 ageing treatments, respectively. Also, investigation of precipitated microstructures showed that the size of precipitation particles has a significant effect on the formability of the alloy. Formability improves with coarsening of precipitation particles.

Oct 1, 2011

By H. Dundar, C. Dzomeku

An extensive testwork was performed around the HPGR plant at GoldFields Ghana Limited Tarkwa Gold Mine. The HPGR was used to prepare the feed for heap leaching. The circuit was configured in such a way that the edge material from the HPGR discharge was recycled for further crushing while the product from the centre reported to the heap leach section. The set-up of the Polysius HPGR provided an opportunity to study the effect of different design and operating variables. This paper will discuss the results from the tests performed to assess the effect of rolls’ speed and applied pressure on the capacity and the grinding efficiency of the HPGR. Applying different pressure values appeared to have an influence on the amount of edge material recycled.

Jan 1, 2012

By N. Morrison, I. Holl, R. Welyhorsky, A. Hempstock

ABSTRACT: The Victor diamond mine is located in the James Bay lowlands, 90 km west of the First Nations village of Attawapiskat. The project was the first of its kind in northern Ontario. The process plant was designed to produce a 95 to 98% by weight diamond concentrate through three stages of comminution, dense medium separation, and proprietary X-ray technology for final recovery. The plant was commissioned over a period of six months, commencing prior to substantial completion of construction. Through effective planning of the commissioning phase, the Victor mine start-up was safely completed nine months ahead of schedule.

Jan 1, 2011

By R. Knapp, R. Firlotte

"Les Terrains Auriferes (LIA) Property, formerly the Malartic Goldfield (Goldfield) mine, ceased its remaining milling operations in the fall of 1994. During the early years of mining, the mill processed a non-sulfide ore with substantial carbonate mineralization.In 1977 after an extended shutdown period, ore from a nearby property, Bousquet, was processed at the mill. That ore contained larger quantities of sulfides, and unlike the old tailings, had acid generating potential.Upon closure of the L TA mill, the closure options considered for the L TA site were to cover with:1. a thin cover of 0.5 metres of borrow material (sand and gravel) to achieve basic erosion protection/stabilization; collect acidic seepage and treat with lime.2. a 2 metres of non-acid producing tailings; final surface to be vegetated.3. an engineered oxygen barrier consisting of a multi-layer cover; final surface to be vegetated.The paper presents the technological and economical methodologies that were used to select the closure alternative, describe the associated construction challenges that were faced with the implementation of the multi-layer cover concept and presents preliminary results on the cover's performance.In addition to being the first full scale demonstration of this type of multi-layer engineered oxygen barrier cover technology, this project had the advantage of using non acid producing mine tailings as part of the reclamation solution."

Jan 1, 1997

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By Louise Laverdure

The Canadian mining sector has to be innovative and invest in the development of sustainable mining technologies to maintain its international leadership. Natural Resources Canada (NRCan) collaborated with the Canada Mining Innovation Council (CMIC) to define the Green Mining Initiative (GMI) and in order to focus its R&D activities on industry and other stakeholders? needs. The GMI was launched in 2009 to spur innovation in the mining sector and further enhance its environmental performance. The initiative, led by CANMET- Mining and Mineral Sciences Laboratories (MMSL), takes a holistic approach looking at the entire mining life cycle, from design to closure and beyond, through four innovation and research pillars: ? Footprint Reduction, ? Innovation in Waste Management, ? Mine Closure and Rehabilitation, and ? Ecosystem Risk Management. The Canada Mining Innovation Council has also been creating a new initiative on Sustainable Mining, which will bring further focus to environmental aspects of mining, and engaging wide range of research providers to develop research programs complementary to GMI goals.

May 1, 2011

Bahuerachi Project Characteristics Why it?s nicer at Bahuerachi Mexico is a mining country Low political, regulatory and trade risk Low social/permitting risk Proximity to infrastructure Road Power grid (8 km) Rail line (25 km) High grade zones (skarns), CRD and near surface oxide component are sweet spots to the overall system. Size of low grade system points to potential long mine life?and numerous new targets developing. Timelines-2006? 90 to 100 combined RC and core holes to go! MAIN ZONE Drilling ? Goat ?Finish Mid April ? Main Zone, going North, depth of testing dependent, estimated for May ? North Lobe-May ? Commission independent resource estimate by May 06 for results of first pass drilling to date ?tonnesand grades ?Main Zone Milestone. ? Continue infill or expanded drilling to July (minimum) ? 1stpass RC scheduled until September OTHER Targets ? Begin drill testing North Skarn target Mid-April, minimum 5 drill holes, 1,000 meters. Ongoing expansion of target with surface work (mapping) ? Road to Colome(Skarnin north of Main Zone) as part of porphyry program ? Tule(southern) porphyry and skarn system-soils and mapping OUTSTANDING events Metallurgical report on floating and leaching tests (Sulphide/oxides).

May 1, 2006

By Fan Delian, Ye Jie, Lui Tiebing

The lower and the upper parts of the Doushantuo Fonnation, Hubei Province, China, contain silicate-type K-rich beds (illite and feldspar), and intraclastic phosphorites, as well as Ag-V and V deposits in a "Black Shale Series". The K-rich beds fonned in an anoxic basin whereas the phosphorites fonned in a more oxic and higher energy depositional environment. The Black Shale Series occurs in the lower and upper parts of the Doushantuo Fonnation; that in the upper part consists of black illite shale and dark gray dolostone, and contains Se-rich Ag and V deposits. These deposits are of more industrial significance than the previously discovered Ni-Mo polyelement sulfide deposits which occur in the Lower Cambrian Black Shales Series of South China. Studies of lithotype, sedimentary sequence, and geochemistry of the Doushantuo Fonnation have led to more attention being focused on the uppennost Black Shale Series and its Ag-V and V deposits. There are three ore types: black, Ag-V-rich, illite shale; black, V-rich, illite shale; and dark gray, Ag-Vrich, fmely crystalline dolostone. The first two ore types contain 3070 to 5% Corg and the last, 1.25%. The Ag-bearing minerals are naumannite, argyrodite, aguilarite, acanthite, and native silver that occur as inclusions in pyrite associated with barite. Vanadium substitutes for AI in illite and is also related to organic-matter contents. Because (1) the pre-Sinian Kongling Group contains one to three times greater than the Clark Ag value; (2) black, illite shale has a negative Ce anomaly; and (3) there are large occurrences of black, K-rich, tuffaceous, fme siltstone, the sources of Ag are thought to include subaerial and submarine volcanic materials. It is proposed that Ag, V, and Se were absorbed by clay particles and organic matter during syngenetic deposition in an anoxic environment; Ag subsequently was reconcentrated into sulfides and selenides, whereas V was incorporated structurally into illite during early and late diagenesis. These types of Black Shale Series-hosted Ag-V and V deposits are, therefore, considered to be sedimentary-diagenetic in origin.

Jan 1, 1992

By Anna Maria Venezia

Bimetallic Au-Pd catalysts supported on amorphous silica-alumina (ASA) with vary amount of alumina (0, 8, 14, 28 and 100%) were prepared by the simultaneous reduction of palladium and gold precursors by ethanol in the presence of the polyvinylpyrrolidone (PVP). X-ray diffraction and X-ray photoelectron spectroscopy analyses indicated formation of alloyed Au-Pd particles. Ammonia temperature programmed desorption measurements were performed to monitor the acid strength and the amount of acid sites on the catalysts after their reduction with 10%H2/Ar at 573 K for 1h. The effect of the support acidity on the catalytic activity was investigated in the simultaneous hydrogenation (HYD) of toluene (T) and naphthalene (NP) in the presence of dibenzothiophene (DBT). Coke formation was also determined. Under the selected conditions (P = 5.0 MPa, T = 523 K, WHSV = 41.2 h-1), all the catalysts were resistant to poisoning with 113 ppm of S (as DBT). The hydrogenation activity of toluene and the HDS activity of DBT were found to correlate with the concentration of the medium strength acid sites. The enhancement of the HYD activity and the S- tolerance was related to modifications of the electronic properties of the metal atom upon interaction with the Brönsted acid sites and upon intermetallic interaction.

Oct 1, 2003

By A. Boucher, D. Marcotte

"Abstract- The accepted practice for the estimation of thin (2D) vein deposits recommends the use of the grade x thickness service variable (i.e., the accumulation). Grade estimates are obtained indirectly by the estimated accumulation/estimated thickness ratio. This practice stems from the varying support (thickness) problem and the resulting non-additive nature of the grade variable. We compare the actual performance of the direct grade estimation approach used by some practitioners to that of the indirect approach using accumulation. Our simulated and real data indicate that the direct approach is more accurate for point grade estimation where the grade-thickness correlation coefficient is positive (and vice-versa). Moreover, the relative gain of the direct method increases with the (positive) correlation coefficient. This finding contradicts common thinking that the indirect approach should be the preferred method where grade-thickness correlation is strongly positive. Also, for a given positive grade-thickness correlation, the relative gain of the direct method increases with the coefficient of variation of the grade and thickness. Résumé - L’estimation de veines minces (2D) minéralisées est normalement réalisée à l’aide de la variable auxiliaire épaisseur x teneur (i.e., accumulation). Les estimés des teneurs sont alors obtenus indirectement du rapport accumulation estimée/épaisseur estimée. Cette pratique découle du problème du support variable pour la teneur, l’épaisseur de la veine, qui fait que la teneur est alors une variable non-additive. Nous comparons les performances de l’estimation directe de la teneur, utilisée par certains praticiens, à celle de l’approche indirecte. Pour l’estimation ponctuelle des teneurs, nos données simulées et réelles indiquent une meilleure justesse de l’approche directe quand la corrélation teneur-épaisseur est positive (et vice-versa). De plus, le gain relatif de la méthode directe s’accroît avec la valeur de cette corrélation (positive). Ce résultat contredit l’opinion répandue que l’approche indirecte devrait être utilisée en présence de forte corrélation positive de la teneur et de l’épaisseur. Nous montrons également que pour une corrélation positive teneur-épaisseur donnée, le gain de l’approche directe augmente avec les coefficients de variation de l’épaisseur et de la teneur."

Jan 1, 2001

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By M. Kalin

Tailings deposits are frequently the source of ground water contamination due to the transport of contaminated tailings pore-water. If amendments to tailings covers could be made to facilitate a precipitation reaction and halt or reduce the generation of acid in pyritic tailings, the quality of pore-water quality would be improved which would in turn reduce the production of contaminants. The effects of phosphate wastes, added to base-metal mine tailings in Newfoundland, Canada, were tested. Laboratory and field experiments determined the effects of different mixing ratios of phosphate wastes to tailings volume (1:4, 1:8, 1:12 and 1:20, dry weight) for a total period of 3.2 years. The addition of phosphate at ratios of 1:4 to 1:12 substantially increased the pore water pH, and reduced both acidity and Zn concentrations. These results suggest that addition of phosphate wastes to tailings covers can reduce acidity generation and improve tailings pore-water quality.

Jan 1, 2004

By P. Walford, C. Mealin, D. Good

"The geology of the Ore Fault Ni-Cu deposit has been reinterpreted in the light of recent studies of the geology of the Neoarchean Bird River Sill Complex and the occurrence of economic Ni-Cu and Zn-Cu-Ag mineralization. The Ni-Cu sulfides are hosted by the lower of two parallel NNW-trending and moderately W-dipping mafic-ultramafic intrusions related to the Bird River Sill Complex. The bod¬ies intruded a bimodal volcanic suite consisting of weakly deformed mafic flows and felsic pyroclastic rocks. The mafic volcanic rocks are geochemically related to the MORB-type rocks of the Lamprey Falls Formation, and the felsic volcanic rocks are related to arc-type rocks of the Peterson Creek Formation. The original pyroxene- and olivine-dominated mineralogy of the sills has been replaced by variable ser¬pentine-amphibole-talc-carbonate assemblages.The Ni-Cu sulfide assemblage exhibits textures and geochemical signatures typical of orthomagmatic sulfide mineralization. The sulfide minerals are associated with cumulate layers of magnetic ferrochromite that range in thickness from a few to tens of centimeters. A later event of Zn-Cu-Ag sulfide mineralization associated with quartz veining and garnet-chlorite alteration along a fault that strikes north, dips vertically, and cuts all rock types. The mineralized fault is cut by the NE-trending Peterson Creek shear zone. Where the Ni-Cu and Zn-Cu-Ag mineralized zones intersect, remnant magmatic features such as amphibolite or cumulate ferrochromite bands occur within quartz veins or local chlorite alteration. The mixed zones contain a very unusual polymetallic assemblage of Ni, Cu, Zn, Ag, and platinum group elements (PGE)."

Jan 1, 2009

By O. M. Arafat, J. A. Finch

"The Functional Performance Equation calculated from a plant grinding survey defines two distinct ball mill circuit efficiencies and how they relate to total production rate through the target grind size. The survey data are also used to calculate a complete ball mill size distribution model, represented by the energy specific grinding rates, not just through the target grind size, but through all the size classes. Cyclone separation performance is represented by individual size recoveries to underflow. When these two unit operation performances are entered into the circuit modelling program (Streamline™), along with the circuit feed rate and size distribution, all the circuit survey size distributions and mass flows are perfectly regenerated by the program. The many issues associated with the historical Epstein (breakage-selection) models are eliminated. Once the circuit program is populated, pump and cyclone performance changes can be evaluated using a step-by-step procedure in order to maximize Classification System Efficiency. Mill water use and media sizing opportunities are also diagnosed in order to maximize Mill Grinding Efficiency at the size of interest. An example is provided. This circuit analysis and modelling system, and related training, is provided through a web-based application.IntroductionSince its development (McIvor, 1988), the Functional Performance Equation for ball milling has facilitated new understanding of industrial circuit cause and effect relationships, leading to significant strides in operational performance. Success stories of this refreshing approach to plant circuit performance improvement are now too numerous to list. Finch and McIvor (circa 1986) also discovered that the Functional Performance “Mill Grinding Rate” at the size of interest was the same cumulative grinding rate that is calculated from mill feed and discharge size distributions using a first-order rate equation. By calculating these cumulative grinding rates for all screen sizes, a complete ball mill model is generated (as used by Finch and Ramirez, 1981). Others in industry, Hinde and Kalala (2009), for example, have noted the same. Lacking the complexity needed to maintain their interest, most researchers have ignored this model, broadly opting instead for Epstein’s (1948) characterization of grinding as a chemical reaction, combining “selection rate” and “breakage size distribution” functions. The much simpler ball mill model presented here has previously been incorporated into a proprietary circuit modeling program (McIvor, 2005) and used for plant improvement work (for example, see McIvor and Finch, 2007, and McIvor, 2014). Now, by combining this extremely business-friendly ball mill model with optimization criteria from Functional Performance Analysis, a circuit modeling system (including the needed supplementary steps to assure successful plant implementation of circuit design changes) is at the disposal of every plant metallurgist, grinding equipment/material provider, and circuit designer."

Jan 1, 2017

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract-Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O sig- nature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

CFD (Computational Fluid Dynamic) models have been developed and validated for a pulsed column with disk-doughnut internals, as used for solvent extraction. First a single phase model was developed to simulate the turbulent oscillating flow around the internals of the column. This model was successfully validated using detailed PIV measurements of velocity taken at eight different phases through the pulse cycle. Second, the CFD model was extended to allow for a continuous aqueous phase and a dispersed organic phase (kerosene) flowing counter-currently. The model was a two-fluid model that accounts for droplet breakup and coalescence, and solves for droplet size distribution using a population balance model incorporated into the CFX4 package. PDIA (Particle Droplet Image Analysis) measurements were taken on a pilot scale solvent extraction pulsed column to determine droplet size distribution for calibration and validation of the CFD model. The measurements were made under pulsing intensities ranging from 10 mm/s to 32.5 mm/s.

Jan 1, 2007

By D. B. Johnson

Acidic, metal-rich waters generated at working metal mines and abandoned mine sites are generally considered to be major pollutants of the environment. However, the metals they contain often have significant value of their own, or as sources of useful mineral products. We have developed novel bioreactor systems that facilitate the selective recovery of various transition metals (e.g. copper, zinc and iron) as defined minerals that can be recovered and recycled. The bioreactors use novel species of acidophilic bacteria. Ferrous iron is oxidised by Ferrovum myxofaciens, a specialist bacterium that forms large amounts of exopolymers and grows as filamentous streamers in flowing mine waters, and the ferric iron generated is precipitated as the mineral schwertmannite, a small proportion of which is used to remove any arsenic present in mine water. Copper and zinc are precipitated as sulphides using H2S generated by consortia of acidophilic and acid-tolerant sulphate-reducing bacteria in a continuous flow, on-line low pH bioreactor. Transition metal sulfides can be segregated by precipitating them, either on-line or off-line, at different pH values. The modular units that have been developed can be configured to treat mine waters of different chemistries. A hypothetical acidic (pH 2.5) mine water stream containing 500 mg/L iron, 100 mg/L of copper and zinc, 50 mg/L of aluminum and manganese, 2 mg/L of arsenate, and discharged at a rate of 10 L/s, is used as an example of the potential application of the mineral-generating bioreactors. The environmental benefits and economic implications of considering mine waters as resources rather than wastes are discussed.

Aug 1, 2013