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By Margaret Anne Stephenson

While the concepts of Aboriginal title share a similar jurisprudence in both Australia and Canada resource development regimes on Aboriginal title lands differ significantly. In Australia, the process is the right to negotiate with mining proponents. In Canada, the process is the duty to consult with government regarding mining projects. This paper compares and assesses the processes for ?consultation and negotiation? with Indigenous peoples when development actions (particularly in the context of mining resource development) impact Indigenous property rights and how agreement making can be progressed. This paper will question whether the resource development processes afford Indigenous people?s property rights full respect when mining developments on Indigenous lands are proposed.

Aug 1, 2013

"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

By The Honourable George Prudham

"I AM PLEASED indeed to be present with you here today and to be taking part in the proceedings of your convention. You have been greeted and welcomed to the Province by Premier Manning who is also provincial Minister of Mines and Minerals, and to this City by Mayor Hawrelak. As Minister of Mines and Technical Surveys in the federal government and as Member of Parliament for Edmonton West, I have been asked to share the honour of extending greetings and a cordial welcome to all.It is a happy coincidence that this representative national gathering, indicative of the growing strength and significance of a great basic Canadian industry, is taking place in the Macdonald Hotel, the new addition of which marks another important step forward in the progress of this City and district.This happens to be the third national convention of the C.I.M. that I •have had the pleasure of attending and I trust that I am not presumptuous in expressing the hope that I will have the opportunity of attending many more conventions of the Institute in my present capacity.Dr. Kidd has bestowed on me a high honour by asking me to be Co-Chairman of this Inaugural Session of the Convention and thus to share with him the responsibility of presiding over the proceedings of this afternoon."

Jan 1, 1953

By David Forrester

"At the 95th CIM Annual General Meeting in Calgary, 1993, a paper entitled “Progress on Futuristic Mining Technologies” was presented(Matthews and Sarin), in which they outlined the goal of continuous excavation of hard rock and some of the technologies being developed to achieve it. The subject continues to be featured in periodic reviews and articles in the literature, (Gertsch, 1994; E&MJ, 1995). Matthews and Sarin note the considerable success of the development and application of continuous mining technologies in the soft rock under-ground mining industry, especially those in coal and potash, with major benefit to overall production, productivity and economic viability. It is the belief that similar achievements can be realised in the underground hard rock mining which continues to drive the development of hardrock continuous mining technology.This overview has been prepared specifically for this issue of the CIM Bulletin. It attempts to tie together current advancements in continuous mining in soft rock (where remote control and automation are already well established) with the background and status of development in hard rock continuous mining. Following a brief review of key factors and machine types, soft rock aspects are discussed, then a more detailed review is given of hard rock technology, with particular reference to Canada’s HRDK Mining Research Ltd. and their key role.The mining industry has long been at the forefront of technology development, for example, the application of the early steam engine to reach reserves at greater depth for dewatering mines in the industrial revolution. By necessity, the individual characteristics of seams and orebodies dictate the mining method, continually presenting mining engineers with new challenges. One of these is the extraction process itself and the goal of replacement of the drill-blast-muck cycle by continuous excavation. Very soft rocks have always been mineable using some form of cutting, even with primative tools. However, as the challenge has been taken up, technologies have evolved to steadily increase the hardness of rock that can be mechanically excavated. It may surprise some readers that at least three machines have successfully cut and loaded rock with an unconfined compressive strength (UCS) of 250 Mpa to 300 MPa (36 000 to 43 500 psi) in field trials (Table 1)."

Jan 1, 1996

"Far from being eclipsed by petroleum and natural gas, Canadian coal continues to command wide (and apparently growing) interest.Major R & D investigations are currently heavily oriented toward coal beneficiation (e.g., cleaning and utilization of fines) and toward a broad range of studies on metallurgical coals and cokes. However, active work is also being carried out in the areas of coal geology, mining, transportation and combustion; and, in some laboratories, increasing stress has been laid on developing a number of new, essentially non-fuel uses for coal and coal products.This review summarizes the work of Canadian coal research agencies during 1966 and indicates some of the more important advances made by them."

Jan 1, 1967

By Limao Zhang

This paper presents a novel model to assess the risk of adjacent buildings in tunnelling environments based on Extended Cloud Model (ECM). ECM is an organic integration of Extension Theory (ET) and Cloud Model (CM), where ET is appropriately employed to flexibly expand the variable range from [0, 1] to (-8, +8), and CM is used to overcome the randomness and fuzziness during the gradation of evaluation factors. The risk level of a specific adjacent building is assessed by the correlation with the cloud models. A confidence indicator ? is proposed to illustrate the rationality and reliability of evaluating results. Ten buildings adjacent to Wuhan Metro Line Two (WMLT) are randomly chosen among hundreds of adjacent buildings for a case study. Results have proved to be consistent with the actual situation. Compared with other traditional evaluation methods, ECM has been verified to be a more competitive solution with high calculation accuracy, wide adaptability, as well as simplified computer programming. There are no stringent requirements on the quantity of training data during the modelling process, and the original data can be directly entered into ECM without a normalization procedure, avoiding the potential information loss. ECM can be offered as a decision support tool for the risk assessment in urban tunnelling construction and worth popularizing in other similar complicated projects.

Aug 1, 2013

By Guy Demers

"This paper defines the responsibilities and functions of the Maintenance Department, and its organization, physical and human assets, highlighting the unique operating problems. Due to the self-sufficient aspect of the Asbestos Hill Deception Bay project, the Maintenance Department cover-s fields that are numerous and very dissimilar: production, mobile, processing, service, power generation, fire protection, heating, water and sewage disposal equipment. Added to this, buildings, plant and camps, wharves and communications equipment all demand versatility, adaptability and expertise from maintenance personnel. Good maintenance practices are a necessity in this environment and are more critical than at southern locations; that is, high-quality replacement material, complete and well-controlled preventive maintenance, major repairs on a component-replacement basis, updated inventory, efficient training and permanent contacts with suppliers, combined with an equipment improvement program, updated specifications on lubricants, hoses, seals, filters, etc., are mandatory. The seasonal aspect of the operations applies a great deal of pressure on the maintenance team, as the production months do not permit major repairs. Short- and medium range planning and accurate evaluation of equipment conditions highly influence production efficiency. Maintenance control, planning and scheduling do not follow the accepted standard routines, as personnel turnover normally does not permit an accumulation of knowledge of the equipment history and condition by the •individual tradesman."

Jan 1, 1976

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By P. V. Golde, R. A. Poole, G. R. Baiden

"The results being presented in this paper are those obtained during 1996 on a drilling automation project at Stobie mine. This project has successfully demonstrated that the remote operation of multiple drills (by a single driller) from surface using Tamrock Data Solo 1000 Sixty drillrigs is technically feasible and can potentially bring significant rewards in terms of productivity and work environment improvements, as well as labour and maintenance savings. BackgroundThe ObjectiveThis paper is an update of a previous report on remote drilling research at Stobie mine. Enabled by the communications system installed at the mine, the ability to remotely control underground equipment from surface has been demonstrated (Poole et al., 1996). This paper discusses the needs and process required to carry this concept to consolidate the operation of multiple machines under a single operator.The TeamThe team assembled to develop and implement the automation and the communi-cations extensions needed to allow the multiple machines’ operation from the surface by one operator included the following:INCO Mines Research supplied the project management and original project initiative. The primary purpose was to prove the advantages of savings associated with the driller not being required to travel to the underground drill location coupled with the savings associated with one-man, multiple-machine techniques.Tamrock EJC supplied the Data Solo 1000 Sixty drills and the Tamrock specific machine-based custom software. The drills were produced in Finland with no provision for remote operation of the drill from other than the umbilical attached local console.Automated Mining Systems supplied the modifications to the drill communications equipment to allow the machine communications to become broadband compatible. As well, Automated Mining Systems also supplied the hardware necessary to be able to remotely control the portable video camera, as well as the data logging equipment.Stobie Mine personnel were made available to test the function and then integrate the concept of remote control drilling into the Stobie operations."

Jan 1, 1997

By A. M. L. Cushing, S. Kelebek

Presently, adsorption is one of the effective methods of removing toxic contaminants from waste waters. The contaminants from metal mining industrial operations include an effluent water containing various types of heavy metal species at concentrations beyond the maximum allowable limits, which are 0.5 ppm and 0.3 ppm for nickel and copper species, respectively. Adsorption behavior of copper ions pre-chelated with diethylenetriamine (DETA) and triethylenetetramine (TETA) onto natural bentonite and peat has been investigated. Both natural bentonite and peat was found to be capable of removing these copper-polyamine complexes from aqueous solutions relevant to process water effluents. However, the adsorption capacity of bentonite was significantly higher than that of peat. Two models were used to study the adsorption kinetics: a pseudo-first-order rate expression and a pseudo-second-order rate expression. For both adsorbents, the data conformed best to the pseudo-second-order rate expression. Representation of the experimental data through adsorption models was also investigated. Out of the four cases considered, namely, Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms, it was found that for both bentonite and peat, the copper polyamine adsorption data conformed best to the Dubinin-Radushkevich adsorption model. The Langmuir model also represents the bentonite-copper polyamine adsorption system reasonably well as the second best case, suggesting that the amount adsorbed on bentonite might be a monolayer with strong affinity.

Jan 1, 2015

By A. J. Giroux

"The use of Ishikawa cause and effect diagrams in an analysis of requirements for improving safety and productivity at Falconbridge's Strathcona Mill is presented. The analysis lead to numerous small improvements being made with the cumulative effect being a significant improvement in both areas.INTRODUCTIONMill management in the 90's involves the major requirements to improve both safety and productivity in the workplace. These objectives, once seen as unrelated or even mutually exclusive, are now accepted as being complementary. Managers, trained either on the job (coming up through the ranks) or in an engineering discipline followed by first and second line supervisory experience are now turning to methods developed in consumer product manufacturing to ensure that all the components are in place to ensure the ore processing facilities are safe and efficient.This paper shows how management at Falconbridge' s Strathcona Mill used the Ishikawa ""fishbone"" diagram ( 1) , a method further developed by Deming(2), to put into place a comprehensive safety and productivity process. The Ishikawa/Deming concept is that no one element or program will itself continually improve a process or service. It is only by examining and then improving all the elements that are involved in the process or service that continuous improvement is obtained. The process was built on the Deming principle of worker ownership where management is the facilitator for putting into place the mechanisms whereby workers can themselves improve the operation. The process is illustrated mainly by examples of the changes made in the hope that these may be of direct help to other operations."

Jan 1, 1993

By B. W. Clyburn

"Coals from the Corporation's Lingan and No. 26 mines are classified as high-volatile A bituminous, with a very low inherent ash and containing all essential properties to provide metallurgical coal, with the exception of a high sulphur content. Only through proper cleaning at low specific gravity can the pyritic sulphur fraction of the coal be liberated to an extent where final sulphur meets coking standards. This first section of the paper deals with the operation of a Dutch State Mines heavy-media cyclone circuit to achieve an actual separation in the region of 1.30 specific gravity. A discussion of the parameter of control which must be applied along with an appraisal of the results obtained is included in the paper.Introduction Very high fluidity and unusually low ash are the outstanding characteristics of coal from Devco's mines in the Harbour seam of the Sydney coal field. However, sulphur content, mainly pyritic, ranges from 1 to 2.50Jo. To obtain the low and consistent sulphur level required in metallurgical coking coals, preparation at low specific gravity is required. Metallurgical coke is used as the fuel in an iron blast furnace. Its sulphur content largely determines the quantity of slag required to remove it and therefore influences furnace productivity and unit costs. Typical data on the various coal properties of importance in the production of coke are included in Table 1."

Jan 1, 1985

By C. Kuehmann, B. Tufts

QuesTek Innovations has applied its Materials by Design® methodology to computationally design a new ultra high-strength corrosion resistant steel. Ferriurn® S53 eliminates the need for toxic cadmium coatings currently used on conventional steels in landing gear systems. S53 has the strength of 300M steel, and corrosion resistance similar to 15-5PH stainless steel. S53's corrosion resistance improves stress corrosion cracking resistance and reduces susceptibility to hydrogen embrittlement, improving component reliability and providing an opportunity for extended overhaul and repair intervals. Ultimate tensile stress is 1965 to 2000MPa. S53 was designed to be mechanically equivalent to 300M, with the key addition of intrinsic corrosion resistance. Alloy design, microstructural characterization, and mechanical properties are discussed herein.

Jan 1, 2006

By Joël P. T. Kapusta

Back in 1995, Air Liquide and Union Minière presented a joint paper at the Copper 95 – Cobre 95 Conference in Santiago, Chile, describing the first full scale plant trials of shrouded sonic injection in a Hoboken converter at the Hoboken smelter in Belgium. Almost a quarter of a century later, the technology known as ALSI, or Air Liquide Shrouded Injection, has been tested or commercially implemented in several copper and nickel smelters. Despite these successes, the copper industry did not adopt it widely in the same manner the steel industry adopted the Savard-Lee tuyere in the 1970s and beyond, not even in the way the lead industry adopted it with the Queneau-Schuhmann-Lurgi, or QSL, process. The development and implementation of bottom-blowing smelting and converting technologies in China in the last ten years, however, changed the industry’s perception that high- and ultra-high oxygen injection in copper smelting and converting was indeed possible under specific process conditions. In this paper, I retrace the key learnings of my journey with sonic injection over the twenty five years from my humble beginnings in my early years with Air Liquide, through plant trials and technology implementation in the late 1990s and into the first decade of the new millennium, and ultimately, to the most conclusive proof that the sonic injection design methodology I established is valid, and the calculation tools I developed are accurate. I conclude by sharing my thoughts about whether the deployment of the Savard and Lee legacy within the nonferrous industry was just a pipe dream or whether it will become a reality. INTRODUCTION In the context of lower quality ores and changing economic markets, copper smelters need to continuously innovate and improve to remain competitive and respect their corporate social responsibility engagements. One avenue towards this business, social, and environmental goal is to increase process intensity while lowering fossil fuel consumption to lower greenhouse gas emissions and reducing process off-gas volumes to better capture As and SO2–laden emissions. I believe high oxygen sonic injection for submerged tuyere copper bath smelting and converting is one technology that can help smelters achieve that goal of higher business, social, and environmental performance. Twenty five years ago, when I discovered that the Savard-Lee tuyere had revolutionized the steel industry (Savard & Lee, 1966; Knuppel, Brotzmann, Fassbieder, Savard, & Lee, 1972), I had a dream — or was it a vision? — that within the first decade of the new millennium, modern copper smelters operating submerged tuyere bath smelting and converting vessels will have implemented high oxygen sonic injection and will be reaping the financial and environmental benefits that the steel industry enjoyed in the 1970s. As we approach the end of the second decade of the new millennium, I have to admit that my dream has been all but shattered as the majority of copper bath smelting and converting vessels today continue to operate under bubbling regime conditions. This mode of operation is archaic, still requires tuyere punching and blows at inherently low enrichment levels, particularly in converting, producing large volumes of process off-gases. Under such operating conditions, regulations and emission quotas for As, SO2, and particulate matter oblige smelters to use not just primary or secondary hoods, but sometimes even tertiary hoods. I vividly recall being told, fifteen or twenty years ago when visiting smelters to promote the application of the Savard-Lee tuyere in nonferrous processes, that implementing sonic injection was not economically viable due to the high cost of compressing air and oxygen. Some of the smelters I visited back then have since mandated their engineering partners to design and build secondary or even tertiary hoods. I cannot fathom how secondary and particularly tertiary hoods, with all of their auxiliary equipment and added ducting, could be more economically viable than purchasing and installing a few compressors, expanding the pipeline network for compressed air and oxygen, and installing a new control valve train to feed sonic tuyeres. Besides, adding hoods does not address the problem of As and SO2-laden fugitive emissions at its source but merely provides a costly mitigation for it by capturing larger volumes of process off-gases rather than reducing these large volumes in the first place. Moreover, hooding does not reduce energy consumption nor does it increase process intensity, two aspects that I believe are critical for smelters to remain competitive and sustainable in a deeply changing market environment.

Jan 1, 2019

By D. E. Keeley

Introduction Gunite is a mixture of sand and cement applied to any surface by being shot by compressed air through a nozzle, where it is wetted just before leaving the orifice. The mixture is transported through a hose from a machine called a 'cement-gun'(l). Guniting of rock surfaces has been standard practice at the Mcintyre Porcupine Mines, Limited, for several years. Where used on walls and backs of cross-cuts; shaft stations, and other rock openings, as an air seal, gunite has eliminated the necessity of constant scaling to keep rock from falling from these places, and, under worse conditions, it has been used in place of timber supports. This has been of definite help in reducing costs, promoting safety, and minimizing fire hazards. During the past year guniting has been quite extensively used here in the rock head-works of the new internal shaft, No. 12, sunk from the 3,875-foot level. Gunite is at present being applied to the stations of that shaft well below a mile from the surface. This paper describes the method of guniting as carried out at the McIntyre, and illustrates how, by the adoption of this process, mining problems connected with scaling and loose ground have been completely solved. It is hoped that the information presented may stimulate discussion and assist in the use of gunite in this and other mines. The guniting method of applying cement was first developed by Carl E. Akeley (2), Curator of the Field Museum, Chicago, in 1907, and was exhibited in New York at the Cement Show in 1910. The museum was located in one of the old World's Fair buildings, built of roughcast and in bad repair. Mr. Akeley, who was a man of inventive nature, set about devising means of applying cement to repair the walls. The cement-gun was the result. Mr. Akeley was a taxidermist of note, a sculptor, and also the inventor of the Akeley camera. In his work, he was in the habit of using fast setting materials to build up foundations for statues, etc.

Jan 1, 1934

By Pedram Sahba

In today?s emerging economy, pooling resources is a growing trend to reduce overall system costs. Two important resources of every maintenance department are repair shops and spare parts. In this work, we consider a system consisting of mine drills at multiple areas in a mine. In each area, a number of identical drills are operational. When a failure occurs, the defective component should be repaired in a designated repair shop. The failed component can be replaced immediately if a spare part is available. Otherwise, the drill is down until a component is repaired and put back into service. In this paper, the effect of pooling resources is examined, and the conditions under which it is beneficial to pool the resources are investigated. In addition, determining the optimal number of stand-by units, equipment or spare parts, in each case is of interest.

May 1, 2013

By S. W. Asihene, K. Osseo-Asare

The thermodynamic data necessary for the quantitative treatment of Metal-NH3- H2O systems at elevated temperatures are lacking in the literature. As a result discussions of the chemical basis of high temperature processes, such as leaching and hydrogen reduction, have tended to rely on low temperature thermodynamic data. In this paper a critical review is presented of the available high temperature data for metal ammine formation in aqueous systems, and methods are suggested to enable extrapolation of elevated temperature stability constants from low temperature thermodynamic data. Predictions of the Van't Hoff Lsobar, the simple cation Correspondence Principle (whereby metal ammine complexes are treated as simple cations) and Helgeson's Electrostatic-Nonelectrostatic Model are compared with the available high temperature stability constants for nickel ammines. Up to 80 °C all three estimation methods yield results which are in agreement with experimental data. However, serious deviations occur at higher temperatures; the various models overestimate the stability constants in the order Van't Hoff Isobar > electrostatic-nonelectrostatic model > simple cation Correspondence Principle. Using the experimental nickel data as a basis, a method is presented which permits reasonable estimates to be made of the stability constants of metal ammine complexes for temperatures above 80 °C.

Jan 1, 2004

By B. Crane, S. Schwartz

"IntroductionThe Cape Breton Development Corporation (CBDC) located in Cape Breton, Nova Scotia, in eastern Canada, was established in 1967. Its mandate at that time was to facilitate a phased downsizing of the coal industry and developing viable replacement industries. The oil crisis in the early 1970s changed CBDC’s mandate and focus was modified to increase coal production to support Nova Scotia Power Commission’s “off oil” policy for their power generators. In the late 1980s the mandate to develop viable replacement industries was eliminated and CBDC became primarily a coal mining company. CBDC presently operates two underground coal mines, Phalen Colliery and Prince Colliery, using a retreat longwall method of mining. Both mines operate beneath the Atlantic Ocean. CBDC also operates associated infrastructure — central workshops, a railroad, coal preparation plant, and international pier. The Need For Substantial ChangeOver the last few years, CBDC has been facing some challenging issues, including improving labour management relations and achieving financial self-sufficiency and profitability. Recent achievements with regard to human resource issues, especially in the areas of collective bargaining, absenteeism, and attendance, show noticeable improvements. All participants should be commended for successfully concluding the collective bargaining process with all four CBDC unions, CUPE; CAW; IAM&AW; and UMWA. However, although these changes are encouraging, even critical in the short term, they are not sufficient to ensure the long-term viability of the company. Market ForcesShort- and long-term financial realities are drawing the need for further substantive changes. The corporation has a mandate to achieve financial self-sufficiency by the year 1999. This goal can only be achieved through a combination of cost reductions and productivity gains, specifically, a reduction in the workforce of 658 and an increase in production of 800 000 tonnes annually. This increase in productivity requires CBDC to re-think the way it does things.In the longer term, CBDC faces even greater challenges. The energy market is becoming more competitive. The electrical utilities across Canada are anticipating deregulation and are positioning themselves for the resultant competition. As primary fuel supplier to Nova Scotia Power Inc. (NSPI), the corporation will have to become ever more competitive to stay in business."

Jan 1, 1997

By T E. Tibbetts

This paper deals with coal sampling in general and with mechanical coal sampling in particular. The necessity of obtaining representative samples is emphasized. Other sections of the paper are devoted to the design and selection of automatic samplers, with a consideration of the three main types, and the testing, operation and maintenance of these samplers. The cost of the installation of an automated sampling system must be related to the value of the material to be sampled, to the volume of coal involved, and to the savings in labour and economy which can be achieved. Introduction T HE Committee?:; on Coal Sampling of the Coal Study Subsection, Thermal Power Section (Eastern Zone), Canadian Electrical Association, was established in November, 1963, to "study the various problem areas of coal sampling." The first undertaking of the Committee was to at-tempt to survey the problem areas of coal sampling through an evaluation of coal sampling difficulties as experienced at both the plant design and operational levels within the electric utilities represented on the Committee. The results of this enquiry indicated that satisfactory answers to almost any conceivable

Jan 1, 1965

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a' very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948