Search Documents

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By P. -A. Bosse, J. Robitaille, P. Blatter

The LaRonde ore is a Cu-Zn-Pb ore with gold (3-4 g/t) and silver (60-100 g/t). The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation. Subsequent to a recent mill expansion, excessive gold was reporting to zinc concentrate with a concurrent decrease in gold to copper concentrate. Owing to the higher return obtained from the metal, the mill endeavors to recover additional gold and silver to the copper concentrate and minimize the placement of precious metals to the zinc concentrate. A gold deportment study showed that the gold occurs mainly as küstelite, with a moderate amount of electrum and a minor amount of native gold. It also showed that various sulfur-based Au-and/or Ag-bearing coatings on liberated küstelite and electrum were the major mineralogical factors that caused gold and silver to report to zinc concentrate. By frequency, such coatings were observed on 70-80% of total liberated gold particles reporting to the zinc concentrate. Based on the gold deportment and the chemistry of the coatings, the collector chemistry was reviewed and a new collector was added into the circuit which resulted in a significant increase in gold and silver recovery to the copper concentrate. The information obtained from the mineralogy confirmed and guided other process optimization. In this paper, the authors will describe the process mineralogy of the LaRonde ores, and in particular, the mineralogical evidence diagnosing the problem. Reference will also be made to the rationale behind how the problem was solved, the results achieved, and future steps in optimization.

Jan 1, 2005

By H. J. Ni, M. Y. Huang, S. W. Chen

The effects of several fluxes on purification, microstructures and properties of A00 aluminium have been studied. The experimental results and analyses indicate that many cracks and large porosities exist in the surface film above the melt purified by C2Cl6 and that the film is floe and mostly composed of AhO3 and pure aluminum, which carries many carbon particles and AlCh not fully volatilized. And then over 50% of the all-melting residue is pure aluminum, which is one of the major reasons for high melting loss. Moreover, because of a mass of gas bubbles and a state of seethe, there exist many inclusions which size is under l0µm in the microstructure of A00 aluminum purified with C2Cl6 or fluxes containing C2Cl6- With this purifying method, the aluminum crystal grains are extended along the radius that was observed firstly and the average crystal size of A00 aluminum are about 100µm~150µm. In addition, small size inclusions have little affected on tensile strength and micro inclusions under l0µm have little affected on elongation.

Jan 1, 2006

By Y. Wang

In this paper, the tribological and electrochemical corrosion properties of Al2O3/polymer nanocomposite coatings were studied using a micro-hardness test, a single-pass scratch test, an abrasive-wear test, and finally an electrochemical technique such as potentiodynamic polarization measurement, The coatings containing Al2O3 nanoparticles showed improvement in scratch and abrasive resistance compared with polymer coatings; this improvement is attributed to the dispersion hardening of Al2O3 nanoparticles in polymer coatings, Corrosion test results showed that the embedded Al2O3 nanoparticles in the polymer matrix do not sacrifice the corrosion resistance of the polymer itself.

Jan 1, 2005

By T. Junne, L. Eltrop, S. Moreno-Leiva, J. Haas, W. Kracht

The energy systems of the future will be highly renewable. The flexibility that is consequently required can be provided with many options, the main ones being energy storage, transmission reinforcement, and demand side management. The role of the latter is explored for the copper industry, using the scheduling of maintenance services as an example of Solar-Paced Design - the coupling of energy demand with solar resource availability. We used a linear energy optimization model to define the minimum-cost configuration for a fully renewable energy system of a copper concentration plant under different scenarios for the scheduling of maintenance services. For the case we studied, (total) costs were 4% lower when the maintenance was scheduled in winter. We expect that exploring the potential of such Solar-Paced Design in the copper industry will allow new potentials for a more cost-effective full renewable energy supply of this critical industry. INTRODUCTION The mitigation of climate change requires a worldwide transformation of the energy system by the significant expansion of renewable energies and the electrification of various sectors and processes (Teske et al., 2015)(International Energy Agency IEA, 2018). Moreover, considering the decreasing costs of renewable energy technologies and the intensive use required to deliver the goals in the Paris Agreement, we can expect to have highly renewable energy systems in the near future. However, to rebuild and expand our energy systems, we need certain materials, including copper. Also, energy systems based on renewables are more copper-intensive than conventional ones (Kleijn, van der Voet, Kramer, van Oers, & van der Giesen, 2011). The mineral industry, in turn, needs clean energy to achieve a better environmental performance (e.g. solar energy for copper production (Moreno-Leiva et al., 2017)) and to avoid negative secondary effects induced by the strong expansion of clean technologies. But there is something else the minerals industry can offer in this bi-directional relation with energy systems.

Jan 1, 2019

By Y. A. Topkaya

In this research work, a process was described for the recovery of copper and zinc in copper converter flue dust from the Black Sea Copper Works' Samsun Smelter Plant. After characterization of a representative flue dust sample, the process included roasting of the flue dust and then leaching in dilute sulfuric acid solution. Roasting time and temperature were studied to determine the optimum roasting conditions. Sulphuric acid concentration, duration, temperature of leaching and solid to liquid ratio were the parameters studied in the bench scale laboratory leaching experiments.

Jan 1, 2007

A Joint Venture between Hope Bay Gold Corporation and Miramar Mining Corporation recently acquired the Hope Bay project in Nunavut, which represents the first discovery of a major new Archean greenstone gold belt in Canada since the discovery of Hemlo in 1982 and the Yellowknife belt in 1938. Located some 685 km North of Yellowknife, the Hope Bay Belt is geologically comparable to the other major gold producing regions of Canada. The initial discovery of gold mineralization in 1992 led BHP to acquire virtually all of the Hope Bay belt. Over the subsequent 6 years, BHP expended C$85 million on exploration, including 180,000 meters of drilling, 2.3km of underground workings and a 27,000 tonne bulk sample, as well as extensive environmental and economic studies. Hope Bay Gold and Miramar acquired the Hope Bay property in December 1999 for a cost of C$27 million, considerably less than the C$85 million spent by BHP in exploring the property. They both hold 50% of the project, and share expenses equally. Hope Bay Gold is the manager of all exploration phases and Miramar will manage feasibility, construction and operations. The Hope Bay Joint Venture controls 1,117 sq. km., covering virtually the entire 80 km long Hope Bay and adjacent Elu greenstone belts. We believe that Hope Bay is one of the best-undeveloped gold projects in Canada. Work to date has defined a global resource in excess of three million ounces of gold in three principal deposits, each of which is open to extension along strike and to depth. A C$17 million work program for year 2000 focused on advancing a significant portion of the gold resource to a measured and indicated category. This will provide the basis for initiation of a feasibility study in 2001. The 2000 drill program was one of the largest undertaken in Canada last year, and is a clear indication of our confidence that Hope Bay will develop into a major gold producing district. The majority of the potential mineable areas known to date lie within 350m of surface and would be accessed through a combination of open pit and declines. Currently, development of a 1,800 to 2,000 tpd gold mine producing in excess of 300,000 ounces of gold per year at cash costs below $US200 per ounce is envisioned. In addition, the exploration potential on the 80 km gold belt at Hope Bay is clearly tremendous.

May 1, 2001

By M. M. C Jiménez, D. C. Buzzi, D. C. R. Espinosa, J. A. S Ténorio, G. F. R Oliveira

In this work the extractive and selective capacities of solvent extraction synergistic systems to recover nickel and cobalt were evaluated. The liquor used was from the high pressure acid leaching process (HPAL). Initially the industrial liquor, processed from lateritic ores, was analyzed to identify the concentrations of the metals. Experiments of synergistic solvent extraction were performed later. The extraction liquid-liquid was carried out with a mixture of Cyanex 272 (CY) and Ionquest 290 (IQ) extractants. The process was executed with the temperature of 65 ºC, pH of 5.2 and the ratio aqueousorganic 2:1. Systems of 80% kerosene and CY 20%, CY 16% - IQ 4%, CY 12% - IQ 8%, CY 8% - IQ 16%, CY 4% - IQ 16%, IQ 20% were studied during 20 minutes. The results of this paper showed that the mixture of these two extractants doesn’t improve significantly the recovery of nickel and cobalt from liquor.

Jan 1, 2014

To determine the optimal circuit configuration for gravity gold recovery consideration should be given to a range of factors in addition to the efficiency of the gravity circuit, including capital costs, ease of operation and impact on comminution. The most common gravity gold circuits utilise a centrifugal concentrator treating a portion of the hydrocyclone underflow. This paper will examine this option and alternative circuit configurations to illustrate the effect of various gravity circuit feed and tailings configurations on the equipment sizing, capital costs, operating costs, water balance, comminution efficiency and gravity gold recovery. The optimum circuit configuration can provide reduced capital and operating costs, maximise gravity gold recovery and improve comminution efficiency.

Jan 1, 2011

By Alireza Sarafi, Alijan Aftabi

"A hydrocyclic system used for mineral separation at the laboratory scale results in the separation of more than 90% of micas. The system functions only by water and might offer advantages where other methods of mica separation are not available. INTRODUCTIONVarious methods for the separation of micas, wollastonite, and garnet, e.g., screening, flotation, magnetic separation, and heavy liquids, are well known (e.g., Spence, 1929; Bates,I960; Gillson et al., 1960; Benjamin, 1971; Connor and Kolhnar, 1991; Collings and Andrews, 1991). However, where these methods are not available, the separation of micas by a hydrocyclic system developed by Sarafi and Aftabi (1991) may prove to be economic. This note is a brief description of the hydrocyclic system. Minerals and MethodFor testing the recovery of mica and other minerals from different rocks (garnet-mica schist, skarn, and pegmatite), standard minerals were tested first, and then rock samples. Pure mineral standards were prepared from coarse-grained samples of pegmatite, mica schist and skarn; the grain size of the minerals separated was more than I cm. The Hydrocyclic System and Mineral SeparationThe hydrocyclic system is shown schematically in Figure 1. In the first step in mineral separation, mineral and rock samples were crushed, milled, and then sieved to minus 250 plus 125 microns. Approximately 10 gm to 25 gm of the sample were inserted in decanter Dt • The motor pwnps, M1 and M2, were then turned on and the water valve rl was opened. At this time, water was flowing turbulently (30 em3/sec. to 50 em3/sec.) and minerals were separated according to their crystallographic nature, density and!or habit. The fInal separation was done by exit valves r2, r3 and r4, while the motor pwnps were still operating. After each experiment, the rt , r2' r3 and r4 valves were closed and the motor pumps were turned off. Following this, minerals in each decanter and the mter were collected, dried and weighed. The whole time of the experiment was optimized to be about 10 minutes, but varied from 3 to 15 minutes for micas and garnets. respectively."

Jan 1, 1994

By Ben Burger

This paper describes the design, the first three years of operation and optimization of a large, single stage SAG mill at Minera Yanacocha?s Gold Mill facility located in northern Peru. The Gold Mill was commissioned in March 2008 with a 32? x 32? EGL, 16.5MW single stage SAG mill, to process 5 million tonnes per annum high grade oxide Au/Ag ore. Operational control, feed size distribution, grinding media, mill liner, grate and pulp lifter optimisation have allowed the mill to operate 15-30% above design throughput rates, but with a product P80 coarser than design. As part of the optimization, full grinding circuit surveys were conducted. Historical operating data and survey data were analyzed and used to evaluate possible circuit changes and determine alternative operating strategies. A number of changes were implemented which allowed the SAG mill to operate similarly to a large ball mill and achieve finer mill product that was closer to design. This paper summarizes life to date data analysis and improvements made by Minera Yanacocha as well as the grinding circuit optimisation study conducted by Metso Process Technology and Innovation.

Jan 1, 2012

By A. E. Wraith, R. Harris, J. Qiu, R. Parra

Small pilot scale experiments have shown that it is possible to almost fully eliminate the minor elements (ME), namely As, Sb, Bi and Pb contained in smelter dusts by vacuum calcination of mixtures of the dust with sulphidizing agents such as dirty copper concentrate or elemental sulphur at 900 °C and 80 +/- 30 Pa for 90 minutes. The products of this calcination are a residue comprising a purified mixture of copper containing compounds along with the gangue constituents and a high sulphur condensate comprising a mixture of the minor element compounds. In particular, the Cu:ME ratios of the concentrate and dust were increased from 250 and 50, from 28 and 12 and from 36 and 8 to roughly 3000, 3000 and 100 for the calcine, for Bi, As and Sb, respectively. It has also been calculated that (i) the copper content of the vacuum calcine may be recovered by feeding it into a Peirce-Smith converter during its slag blow, and (ii) the resulting recycling could increase the minor element treatment capacity of a smelter by 100 % while also reducing the blister As content by a factor of three. The experimental results are briefly discussed and a treated dust recycling option is examined. Example operating conditions are presented and available commercial technology for the vacuum calcination of the mixtures is reviewed.

Jan 1, 2007

By Washington Luiz Mafra

Every year the conventional direct reduction processes ? Midrex and HYL III ? increased their market share in the world steel production, even though they are only economically feasible in countries where natural gas is available at competitive prices. In this context, the new Midrex projects are based on large reactors (Megamod - 1.5 to 1.8 Mt/y of DRI), reduction temperatures of the metallic burden up to 850oC, with bustle gas temperatures between 960oC e 1050oC. Thus, the requirements of metallic burden performance, as well as the evaluating methods, usually based on ISO standards, need to be reviewed. It is well known that the standards usually applied to quality evaluation do not reflect the performance of metallic burden inside the reactors. This paper describes the different methods of evaluating the disintegration under reduction of DR pellets based on ISO 11257 standard. This is the most important method used by pellet producers and customers for evaluating DR feedstocks. The different methodologies tested to evaluate the disintegration under reduction had varying results, evidencing the relevance of the method and the quality of the pellet. Nevertheless, validating the method in an industrial reactor is still fundamental.

May 1, 2007

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process,particularly the operation of the jarosite circuit is reviewed ,specifying process improvements to treat high iron calcines.INTRODUCTIONThe purpose of the leaching process is to recover the metals, mainly zinc,through a series of extraction stages with sulphuric acid solutions, which progressively increase the zinc recovery. After the series of acidification stages,the solution, which is rich in iron, is sent to the jarosite circuit to separate the zinc from the iron (Garcia & Valdez, 1996).The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper, after this solution is sent to the tankhouse to feed the electrolytic cells."

Jan 1, 2016

By Jianwen Yang, Yucai Zhou, Yanhong Dong, Daixiong Chen

"The study of combined depressants for flotation separation of lead from copper has been carried out to solve the copper-lead separation problem. Test results show that the depressant of CMC (Carboxyl Methyl Cellulose) or sodium sulfite plays an important role on the selective depression of galena flotation. When the two reagents above are combined, the selective depression effect on galena is further enhanced. When the mass ratio of CMC to sodium sulfite is 1:4, galena was best depressed, with the lowest lead content in the copper concentrateClosed-circuit tests indicate that under a certain pH value of the slurry, with the best ratio of CMC to sodium sulfite as depressants, the copper concentrate with the grade of 28.23% copper and 4.12% lead is obtained, and the copper recovery is 84.87%; the lead concentrate with 68.12% lead and 0.86% copper is obtained, and the lead recovery reaches to 92.20%. An efficient separation of copper and lead is achieved with the combined depressants. INTRODUCTIONComplex copper-lead-zinc sulfide ore is abundant in China. With the rapid increase of mineral consumption, it has become one of the important sources to produce copper-lead-zinc metals. However, it is difficult to achieve effective separation of copper and lead, due to the complicated ore properties, such as fine dissemination, low copper grade, complex symbiotic relationship and similar floatability of copper and lead.Poisonous reagents of bichromate and cyanide are often used as depressants for copper lead separation. They have good separation efficiency, but pose serious pollution issues. As the environmental protection is becoming more and more important, it is a trend to replace traditional toxic reagents with new nontoxic efficient chemicals. Organic depressant FCLS studied by Liu has strong selectivity against galena, and does not depress chalcopyrite. A new type of galena depressant of CLS-01 discovered by Jin-lin Yang shows good results in the separation a mixed copper and lead concentrate. In addition, dextrin, chitosan and some other natural organic compounds (Drzymala, 2003; Huang, 2012; Qin, 2013) have also been studied to separate copper and lead."

Jan 1, 2016

By Brad E. Melanson

Because mine haul trucks consume considerable quantities of fuel, they are ideal candidates for the adoption of cleaner and cheaper fuels like natural gas. Impressive fuel cost savings will be realized in regions where liquefied natural gas (LNG) has cost advantage to diesel fuel, while also providing significant reductions of air contaminants and greenhouse gases. High Pressure Direct Injection (HPDI) of natural gas utilizes the diesel cycle combustion process and therefore retains the diesel engine?s high performance and efficiency characteristics. HPDI has been demonstrated in on-road Class 8 trucks since 2001 accumulating almost 10 million kilometres to date. The supply of LNG fuel will be an essential parallel aspect in the introduction of HPDI to mining. LNG can be transported to site as diesel is today, or may be produced on or near mine operations that have access to methane sources or pipelines.

May 1, 2006

By W. Zheng

Pipelines can develop stress corrosion cracks in either intergranular or transgranular form. Since the mid-1980s, numerous colonies of transgranular cracks have been found across Canada and many other countries in the world. While the intergranular form of cracking has been well studied in the past 40 years, the mechanisms governing SCC in near-neutral pH environment, i.e., the transgranular form of the cracking, are yet to be understood in greater depth. Over the past ten years or so, a large number of research publications have been available on this subject and this paper summarize our latest progress in understanding the mechanistic aspect of the problem. Better understanding of the role of mill scale surface and the steel metallurgy in crack initiation has been indicated in the recent literature. However, the initiation of SCC in the lab research still relies on loading conditions that are far more aggressive than those encountered in the field. Most crack growth studies in the past are also performed under very aggressive mechanical conditions, which could have prevented the observation of environment effects. However, more recent research at lower K or Delta K ranges seems to suggest a strong role of the environment. Naturally, modeling of growth should reflect the effect of the environment, steel metallurgy, and the changing mechanical properties of the pipe steel with time. For a specific steel in a given environment, the crack growth rates tended to increase with the strain rate, indicated either by the nominal applied loading frequency or by the calculated crack tip opening rate. Future research needs to address the issue of concurrent growth of multiple interacting cracks. More attention should also be given to concurrent initiation of multiple cracks in a colony, as failure is usually caused by a coalesced crack not by an individual crack. The effect of soil environment should not be limited to the chemistry of soil solution; other factors such as cathodic processes, the variation of environment with time and physical conditions of coatings should also be considered as part of the study.

Jan 1, 2005

By A. R. Naji Meidani, A. Cameron, A. Richardson, M. Isac, R. I. L. Guthrie

The supersonic core of shrouded jets remain coherent over longer distances vs conventional supersonic jets. This phenomenon should allow for greater penetration of oxygen into slag/steel reactor systems. As such, they hold the promise for faster slag/metal mixing in BOF type metallurgical reactor systems, possibly creating greater surface area/volume ratios of reacting phases, and thereby faster kinetics, as compared to conventional supersonic jet systems. In order to assess the potential of shrouded supersonic jets versus their conventional counterparts, an experimental investigation of impinging shrouded supersonic jets into a water model of a simplified BOF system was carried out in the MMPC's water modelling laboratory. The experimental results for three different designs of a shrouded supersonic jet nozzle have been compared in terms of greater penetration depths and reduced mixing times. Based on a novel dimensional analysis, the depth of penetration of a gas jet into a liquid bath is shown to depend on the nozzle-bath distance, the liquid's Froude, Reynolds and Weber numbers, reflecting the ratios of gravity, viscous and surface tension forces to the jet's inertial, or momentum, forces. Good agreement between the mathematical model and experiment was obtained in terms of predicted and observed depths of penetration. Further efforts have been made to study jet penetration into liquid metals. The effects of mean liquid density of slag/metal mixtures and a wide range of gas flow rates on the penetration depth were investigated theoretically. The results show that the penetration depth can be increased with increasing gas flow rate and decreased bath density.

Jan 1, 2004

By A. I. A. Salama, M. W. Mikhail

"A comprehensive software package has been developed at the Western Research Centre to meet many of the coal preparation requirements in the Canadian coal industry. This package performs three main functions: (1) data handling and manipulation; (2) data analysis, including the generation of washability data, performance evaluation and prediction, density and size modelling, evaluation of density and size partition characteristics, and attrition curves; and (3) graphics output.The software described in this paper is potentially a valuable tool for coal preparation plant engineers and operators for evaluating process performance and adjusting plant density separator cutpoints. Moreover, the analytical laboratory technician could find this package very useful in manipulating and presenting laboratory results."

Jan 1, 1997

By S. Borle

The microstructural features produced in friction stir welded AZ31, AZ80 and AZ91 alloys are examined when different welding parameters are applied. The microstructures primarily consist of a-Mg grains with a-Mg + Mg17A112 colonies, however melted films of Mg17A112 are produced in AZ91 alloy when high rotation speeds are applied. When the rotation speeds are slow, or the travel speeds are fast the Mg17A112 were incorporated into the stir zone, however they do not exhibit an elongated lamellar morphology associated with melted films. In the case of AZ80, the extruded base material contains a smaller fraction of Mg17A112 and few of these phases are observed in the stir zones. The results are explained based on the dissolution rate and melting temperatures of Mg17A112 controlling the overall morophology and fraction of phases in the stir zone.

Jan 1, 2011