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By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By Evans B. Mayo

ABSTRACT Orange Footwall 'sill' is locally concordant locally discordant, with the structure of its sedimentary walls. The sediments were folded in two directions. Folds, following both these directions, are preserved in the concordant portion of the 'sill'. It seems, therefore, that the porphyry has replaced the sediments, thus preserving within itself their structure. During replacement, the nascent porphyry may have been much weaker than its walls. Accordingly, under directed pressure, the porphyry could have flowed locally, disarranging the replaced structures within it and developing a flow structure discordant with the folds in the sediments. Some such action may account for the discordant parts of the 'sill'. INTRODUCTION The senior author has seen certain granitoid massifs that have an internal structure vastly different from, and discordant with, the structures in their wall rocks. It seems that? such massifs have moved independently of their surroundings. Yet, a structure section elsewhere in the same mountain range may reveal granitic rocks with internal structures that appear to continue the structure of the invaded rocks. In such a case, it is at least thinkable that the granite has replaced the older sediments or volcanic rocks. In February, 1950, the writers mapped, on 15 level of the Nickel Plate mine, near Hedley, B.C., a diorite or gabbro porphyry 'sill' that, in one cross-cut (1503), appeared to be quite concordant with the wall-rock structures, whereas in another cross-cut ( 1500) about 100 feet to the south, the same porphyry was discordant (see Figure 1).

Jan 1, 1951

By J. E. Armstrong

"Pinchi Lake and Bralorne Takla mercury mines; Canada's only producing mercury mines during the past war (1939-1945); occur within the Pinchi Lake mercury belt. This belt is in central British Columbia; and is approximately 150 miles long extending from southeast of Fort St. James northwest to the headwaters of Omineca river.During the field season of 1937 cinnabar was discovered by J. G. Gray of the Geological Survey in Permian limestone on the north shore of Pinchi lake, where the main showings of the Pinchi Lake mercury mine were later developed. Following the publication of Gray's report claims were staked in the spring of 1938, and later that year were optioned to the Consolidated Mining and Smelting Company, and in June 1940 a reduction plant with a rated capacity of SO tons a day was brought into operation. In 1943 the plant had a capacity of more than 1,000 tons a day. The grade of ore treated was reported to average S to 10 pounds of mercury a ton, and production during the years 1940 to 1944 exceeded 4,000,000 pounds. The Bralorne Takla mercury mine, which is 90 miles northwest of the Pinchi Lake mercury mine, was brought into production in November 1943 with completion of a 50-ton mill. During the next 10 months more than 100,000 pounds of mercury were recovered, and the grade of the ore was reported to average 15 to 20 pounds of mercury a ton. During the war, production from these two properties was far in excess of Canadian requirements, and Canada was able to supply the United Kingdom and United States with part of their need.s. Both properties ceased operations during 1944, and, due to an excessive supply of mercury, have not yet reopened. The Pinchi Lake mercury belt lies along a northwest-trending major fault zone called the Pinchi fault zone (Fig. 1). This zone is approximately 150 miles long and varies in width from 200 to 1,000 feet . It forms the northeastern edge of a northwest trending fault belt up to 10 miles or more wide in places. In general the northeastern margin of the Pinchi fault zone represents the contact between closely folded, stratified Permian rock:s on the southwest and Mesozoic formations and Omineca intrusions on the northeast. It seems probable that the fault zone marks the site of major thrust faulting from the southwest and that the Permian rocks moved up with respect to the Mesozoic formations. Intense faulting occurs in the Permian rocks within the fault zone. There the more important faults trend north and northwest, dip steeply west and southwest, and may join a major low-angle thrust fault at depth."

Jan 1, 1954

By Patrice Nadeau, Yuejun Zhang, Dan Chen, Liming Huang, Claude Gagnon

"The traditional Denver flotation cell is generally suitable to process material ranging approximately from 5 µm to 300 µm. For floating over 300 µm material, its efficiency is significantly getting lower mainly due to the difficulty to suspend coarse particles uniformly, which decreases the chances of particles to attach to bubbles and increases the chances of detachment.RTFT (Rio Tinto Fer et Titane) owns one of the world’s largest hemo-ilmenite deposits. Considering the whole processing technology, the ore is only crushed to -1180 µm. The crushed ore contains about 0.32% S and most of the sulfur is removed by rotary kilns in the ore preparation plant. In order to achieve a similar S reduction, without emitting SO2 into the air, an alternative technology by flotation was pursued.Laboratory and pilot scale-up tests showed that traditional Denver flotation cell could perfectly remove the sulfur from the material sizing 0-300 µm. For the coarser particle sizes, two different models of equipment were tested to improve flotation efficiency: HF (HydroFloat Separator) from Eriez and CLF from BGRIMM (Beijing General Research Institute of Mining and Metallurgy), China. The D6” HF, which is a device that combines flotation and gravity separation, demonstrated its ability to recover those very coarse particles. As compared to the Denver flotation cell, the modified 25 L CLF coarse particle flotation cell achieved better results at higher pulp solids percentage and with a shorter flowsheet."

Jan 1, 2016

By John H. McKillop

Industrial minerals production in Newfoundland in--creased in gross value by a total of 175 per cent during the ten-year period from 1954 to 1964. The Province accounts for all of ?Canada's fluorspar production and contains one of the most important fluorspar districts in North America. It is also the only producer of pyrophyllite in Canada, and quite recently has become an important producer of asbestos fibre. Limestone, gypsum, brick shale, sand and gravel also ?Contribute appreciably to the expanding industrial minerals phase of the Province's rapidly growing mining industry. Geological diversity characterizes Newfoundland's industrial minerals: Pyrophyllite deposits were formed by contact metamorphism of predominantly volcanic Proterozoic rocks. Fluorspar deposits are fissure-filling veins having the characteristics of typical epithermal deposits. Chrysotile asbestos production comes from one of the Island's serpentinized ultrabasic belts. Limestone is produced at three localities; two of them in the extensive carbonate rocks of the west coast. Gypsum production comes from a thick evaporite (gypsum and anhydrite) sequence in the Carboniferous rocks of the St. George's Bay area. Introduction

Jan 1, 1965

By M. E. Wilson, A. C. Lee

"The property owned by Senator-Rouyn Mines, Limited, is in Rouyn township about 17'2 miles southwest of the town of Rouyn. It adjoins the Chadbourne claims of Noranda Mines, Limited, on the south and the Bagamac property on the ·west. It includes seven claims-block 44, blocks 80 to 83 and blocks 96 and 97; the mine is wholly in blocks 44 and 82.Late in 1936 gold was discovered in an outcrop of rusty weathering carbonate rock near the north end of block 44, and the following year the present Company was organized to proceed with the development of the property. During 1937-38, 17,000 feet of diamond drill core were bored to determine the extent of the ore deposit at depth. From October 15th, 1940, to April 15th, 1941, the ore was hauled to the mill at the Arntfield mine for treatment. The mill on the Senator-Rouyn property started on April 25th, 1941, and has been in practically continuous operation since than time. To the end of 1946, 574,874 tons of ore, from which gold having a value of $3,836,450 was recovered, were treated in the mill.GEOLOGYThe rocks exposed at the Senator-Rouyn mine, except in the southern part of the property, are almost wholly quartz diorite, part of an irregular mass that extends west from the town of Rouyn along the north shore of Noranda lake and thence southwest across the Senator-Rouyn claims. In the northern part of the propertyt inclusions of rhyolite occur here and there in the diorite. In the southern part the predominant rock is dacite and in the east-central part of block 44 claim andesite. Dykes of andesite, quartz syenite, and later diabase also occur on the property.The andesite of the Abitibi volcanics is not exposed on the property, but has been intersected in three diamond drill holes, one on the eastern boundary of block 44 and two farther west within the block. This andesite is probably the western end of a band of pillowed andesite well exposed in the Larose claim to the east."

Jan 1, 1954

By Theo. Koulomzine

"The property of Consolidated Central Cadillac Mines, Limited, consists of 1,103 acres formerly held by Central Cadillac Mines, Limited, and Wood Cadillac Mines, Limited. Both mines have been partly developed to depths of 565 and 1,000 feet respectively, and from 1939 to 1943 they produced gold, with small amounts of silver and tungsten, having a total value of $2,208,528 from 377,489 tons of ore. The average grade of the ore was $5.85 a ton . Less than 10 per cent of the ore hoisted was discarded by sorting. New development work, carried out since the former Wood property has been purchased by Central Cadillac, has shown that the tonnage indicated by mine workings and diamond drilling exceeds 2,000 tons per vertical foot.The property lies between the claims of Kewagama Gold Mines, Limited, and Pandora Cadillac Gold Mines, Limited, and straddles the Cadillac 'break' for a length of nearly 1 ½ miles. The main workings are 1 3/4 miles east of the well-known O'Brien gold mine.GEOLOGYOutcrops are very scarce, with none at all of the most important horizons, so that the general geology shown in Fig. 1 is deduced mostly from underground workings and diamond drilling. Fig. 2 is a vertical cross-section and Fig. 3 a longitudinal section through the ore zone.The ore lies within a belt of Blake River volcanics which is approximately 600 feet wide and is flanked on the north and south, respectively, by Cadillac and Kewagama sediments. All the formations have a nearly vertical attitude. The Blake River belt consists essentially of well sheared volcanic tulfs, but associated with these in the northern part are a number of bands of iron formation and the central part, to a width of 100 feet, is occupied by talc schists, making the Cadillac fault proper. Intruding the volcanics south of the Cadillac shear zone are dykes of two types- finegrained aplite or quartz albitite, and porphyry; both consist essentially of albite and quartz and are distinguishable only by the grain size. They have the general east-west trend of the formations they intrude."

Jan 1, 1954

By Martin Irving

Adding Value to Canadian Diamonds - A Changing Diamond Industry - Diamond Mining - Diamond Manufacturing - Diamond Jewellery Markets - NWT Diamonds Changing Diamond Industry - De Beers ? privatization - Oppenheimers (45%), Anglo-American (45%), Botswana (10%) ? going retail - LVMH joint venture - New Players ? jurisdictions - Canada ? companies - BHP-Billiton - Aber Diamonds

May 1, 2002

By G. Itoh, S. Fukasawa

The Al-Zn-Mg alloys have been known to be susceptible to stress corrosion cracking (SCC), which is based on intergranular cracking arisen from hydrogen embrittlement (HE). The mechanism of HE has not been fully understood yet. In order to elucidate the mechanism of HE, we need to investigate the behavior of hydrogen in the alloys. In this paper, behavior of hydrogen in an Al-5.8%Zn-2.4Mg alloy was investigated by means of hydrogen microprint technique, a method to visualize location of hydrogen emission from specimen surface as silver particles. One side of the tensile test pieces was electrolytically polished and then covered with photographic emulsion. Hydrogen was pre-introduced into the test pieces from opposite side by cathodic electrolytic charging for 30min. Then, the test pieces were stretched with continuing the charging. After that, the specimen was fixed, rinsed, dried and observed with a scanning electron microscope. As a result, silver particles were observed on some grain boundaries.

Jan 1, 2015

By B. T. Lu, J. L. Luo, J. F. Lu

The present paper investigates the chemo-mechanical effect in slurry-erosion corrosion process of carbon steel to understand the synergistic mechanism due to interaction of chemical and mechanical factors. The erosion-corrosion tests were conducted with A1045 steel in slurries comprising tap water and silica sand. Various heat treatments were adopted to achieve different hardness in the test material. The chemo-mechanical effect is evaluated in line with the correlation between the degradation of hardness in the surface layer and anodic current density. During the erosion-corrosion tests, various anodic currents were applied to find the relation between the anodic dissolution rate and erosion rate. The experimental results indicate that the hardness decreased with increasing anodic dissolution. Based on the fact that pure mechanical erosion rate increased with decreasing hardness, this result suggests that the corrosion-induced degradation of mechanical property is a mechanism of corrosion-enhanced erosion. This theoretical prediction is verified by erosion-corrosion experimental results.

Jan 1, 2004

By M. Leroux, J. A. Finch

"Sizing below 38 µm (400 mesh) is an increasing requirement in mill testing laboratories. The Cyclosizer is gaining wide acceptance in this role. A recent alternative is to use electro-formed sieves (micro-sieves), which are available with openings down to 5 µm. The advantage of micro-sieving is a cut size which is independent of mineral density, easier retention of the fi nest fraction and reduced purchase cost. A simple method of microsieving using an ultrasonic bath, which performs readily to 10 µm, is described.A systematic study of Cyclosizing and micro-sieving is reported for three samples; silica, copper oxide and a lead concentrate. Micro-sieving gave comparable results. Comparison with a standard sizing method, the Sedigraph 5000D, revealed misplaced material in each fraction by both methods. The range for micro-sieving was from 20% to 60% depending on the sieve and material; for the Cyclosizer it was a consistent 40-50% for all cones and all materials. The Cyclosizer can be sensitive to feed mass and particle size for dense materials. It is recommended that for minerals of specific gravity greater than 5, no more than 35 g of -38 µm be used.The disadvantage of micro-sieving is that it requires continuous operator attention and sieving time depends on sample mass. To fractionate 35 g-as used on the Cyclosizer and considered at reasonable mass for mill testing purposes-through 25-, 15- and 10-µm sieves requires about 80 minutes.IntroductionParticle size has a pronounced influence on mineral separation processes. Consequently, the measurement of particle size plays an important part in mill testing. By far the most common method is by screening. This, however, is usually limited to 38 µm (400 mesh) or occasionally 25 µm (500 mesh). Increasingly, mineral products are becoming finer than this limit and consequently finer sizing methods are required."

Jan 1, 1982

By K. Soucek, J. Ptácek, A. Hastíková, R. Kukutsch, P. Konícek, P. Waclawik

"Cable bolts are used frequently as a secondary support system (with steel arch support) in difficult stress-strain conditions of deep coal mines. The load transfer mechanism of cable bolts depends on several factors, such as the strength, deformation and geometric properties of the bolts, resin and the surrounding rock mass so-called cable-resin-rock system (CRR system). The bonding length and bolt/borehole diameter ratio strongly influence the final bearing capacity of the CRR system.The study presents the behaviour of CRR system during a pull-out test which is usually used in the carboniferous rock mass in the Czech part of the Upper Silesian Coal Basin. A series of 28 pull out tests were performed on 3-m-long cable bolts, with various combinations of borehole diameters and bonding lengths, to understand this behaviour. Boreholes were drilled into a solid rock mass consisting of fine-grained sandstone to guarantee similar conditions during the pull-out tests. Video inspection and measurement of borehole diameters were performed to determine their quality and real diameters. Three characteristics were observed from pull-out test results: ultimate pull-out load; displacement of the end of bolt and system stiffness. Numerical modelling by FEM (Finite Element Method) was used to determine the stiffness of the CRR system for variable bolt/borehole ratios and bonding lengths each under constant load. A linear elasto-plastic model and a mohr-coulomb model were used for cable and resin-rock respectively. The results of the experiment may contribute significantly to improving of the methodology of cable bolts installation as well as the design of used cable bolts."

Jan 1, 2015

By W. H. Hastings

Introductory In the amount of her coal reserves, Saskatchewan ranks third among the provinces of the Dominion, with a total, as estimated by D. B. Dowling, of 59,812,000,000 tons. All the coal so far discovered in the Province is lignite, and it would appear unlikely that bituminous or higher grade coals exist. General Occurrence of the Coal The location of the coal-bearing formations in Saskatchewan is shown on the accompanying map. It will be seen that the areas lie principally in the southern part of the Province. The more darkly shaded areas indicate locations where development is taking place, or where coal-seams are known to occur, either through outcrops in valley-sides or through having been encountered during boring operations. The coal-seams are not necessarily continuous throughout the shaded areas, but in all pans of these there are coal possibilities. It is quite possible that small outliers of the coal-bearing formations may occur further north in the Province, but, generally speaking, coal is not likely to be found outside the shaded areas.

Jan 1, 1929

By A. Dreimans

Tracing of 'float' against the latest ice-flow directions ha!' led to or assisted in discoveries of several mineral deposits in Canada at lP.ast since 1891, e.g., fluorite and corundum in eastern ?Ontario, Steeprock and Josephine iron ore in western Ontario, Malartic, Fisher-Quebec, and Lamaque gold ore, and Vendome zinc ore, in western Quebec, Sullivan zinc and lead sulphides in British Columbia, Orvan Brook or New Calumet sulphide deposit in New Brunswick, Lynn Lake nickel sulphide de-posit in Manitoba, etc. Pebbles or ore boulders whose source has not yet been found include diamonds in the Great Lakes region and ?sulphides in several localities in Ontario and Quebec. Complexity of transport of ore boulders, including non-glacial transport, may be the explanation. Tracing of ore boulders requires knowledge of the Pleistocene history of each particular area (ice flow directions, their ?changes during glacial oscillations, existence of pre-glacial lakes with ice-rafted boulders, later interference by streams, lakes, mass movements). Important also is distinction of till from similar non-glacial deposits and knowledge of the bed-rock geology. Quantitative methods, e.g., pebble counts, maybe applied while tracing magnetite, hematite, or goethite. Fragments of sulphide ores are less abundant in indicator trains, and quantitative methods are less suit-able for tracing them. Heavy-miner-al investigations may give good results for minerals resistant to weathering. Geochemical methods are of value only in the vicinity of ore deposits.

Jan 1, 1958

By Réal Marcotte

L'industrie minière représente un apport économique important pour le Québec ; cette production est très diversifiée et répartie dans plusieurs régions. Hormis les forges du St- Maurice au XVIIe siècle, l'industrie minière québécoise commence en 1862 dans la Beauce avec l'exploitation de placers aurifères dans les affluents de la rivière Chaudière; à la même époque, on met en production les mines de cuivre Eustis, Albert et Capelton, près de Sherbrooke1; à partir de 1881, les mines d'amiante et de chromite au voisinage d'Asbestos et de Thetford commencent à voir le jour. Dans les années ?20, l'extraction de métaux précieux et usuels débute en Abitibi- Témiscamingue; durant les années '50, le fer et l'ilménite de la Côte Nord, ainsi que le cuivre de Murdochville et Chibougamau, commencèrent à être mis en valeur. Plus récemment, soit durant les années '80, le sel des Iles-de-la-Madeleine et le graphite des Hautes Laurentides s'ajoutèrent aux produits que nous commercialisons. Finalement, soit en 1998, le Québec devenait un important producteur de nickel avec le démarrage de la mine Raglan, au Nunavik. L'exploitation d'une mine peut nécessiter l'extraction de grandes quantités de roches stériles, particulièrement lorsque la production se fait à partir d'une fosse à ciel ouvert. De plus, étant donné que les minéraux et les métaux mis en marché ne constituent qu'une fraction du minerai extrait, il faut le concentrer : on se retrouve alors avec des proportions plus ou moins importantes de résidus finement broyés. Ces deux types de rejets totalisent bon an mal an environ 100 millions de tonnes. Lorsque cela est possible, ceux-ci sont, soit valorisés comme matériaux de construction ou retournés dans leur lieu d'origine afin de soutenir les murs des excavations. Toutefois, une bonne partie est accumulée en surface dans des aires aménagées spécifiquement à cette fin ; comme le montre la figure 1, la superficie utilisée à cette fin a progressé parallèlement aux booms miniers que nous venons de mentionner pour atteindre actuellement environ 15,600 hectares, dont environ la moitié sont situés sur des aires encore en activité.

Nov 1, 2002

By D. W. I. Griffiths, J. C. Bélanger

"La Division Matagami de Minéraux Noranda inc. a profité de la construction de sa nouvelle mine (Isle-Dieu) pour continuer sa modernisation.L'utilisation d'automates programmables (PLC) s'est intensifiée pour contrôler et automatiser de plus en plus d'équipement dans ses minessouterraines, au concentrateur, dans les atelierset bureaux.Tous les PLC comrnuniquent entre eux et les IBM PC sont utilisespour exterioriser l'information et faire Ie lien entre Ie personnel et les automates. Le système Central IBM 36 emmagasine les donnees traitees par lesPLC (a travers les PC). Ces donnees sont transmisesau programme d'entretien de chaque equipement et compile les heures, cycles, tonnes, etc., fait imprimer automatiquement les feuilles d'entretien préventif ', etc.Les principales realisations adate et en progrès pour la mine Isle-Dieu sont:• automation complète du système de remblayage du concentrateur ala mine Isle-Dieu situee a2 km de la mine principale;• automation du fonctionnnement des ventilateurs qui comprendra la position des portes de ventilation, Ie chauffage, Ie débit, etc.;• automation des pompes, surveillance des sous stat ions électriques, concentration des gas (CO, SO2) à chaque niveau en tout temps et du propane à l'entree d'air frais;• tonnage et cycles par Ie treuil; et• contrôle d'autres équipernents à differénts niveaux. D'autres travaux furent egalement effectues par les employes, tels que:• la conversion d'un Scooptram ST5A de diesel à électrique;• I'installation complete de systèmes de depoussierage a I'eau (scrubber) pour le concassage secondaire;• I'installation d'un marteau hydraulique avant les concasseurs coniques;• la rénovation des cellules de flottation ; et• l'installation d'un système de gardiennage par caméra. D'autres projets seront effectués ou étudiés:• automation d'un Scooptram"";• automation d'un marteau hydraulique;• récupération de Scooptrarn; téléguidé:• gestion de l'énergie, contrôle de la demande, surveillance et contrôle de l'équipernent de machines fixes(compresseurs, boulloires, pompes à vide, génératrices, débits et pression d'air, eau pour diagnostiquer les problémes, analyser les coûts;• concasseur portatif pour fabriquer de la pierre concassée pour utiliser dans les chemins sous-terre, et• utilisation de micro-ondes pour transmettre les images captées par camera."

Jan 1, 1990

By M. A. Stogran-Baker, S. Cole

"Fluorspar mining occurred in the St. Lawrence area from the 1930s until the mid 1980s. In 2013, CFI discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods. A new mill was designed to produce 200,000 tonnes per year of high quality, acid-grade fluorspar concentrate. The simple mill flowsheet includes crushing, dense medium separation (DMS), grinding, sulphide flotation, pulp thickening, fluorite flotation, thickening, and concentrate filtration. The type of flotation cell used is being installed for the first time in North America. Site clearing commenced in the spring of 2016, followed by mill building erection completed by the fall of the same year. Civil and mechanical installation as well as site-wide construction was completed by the end of September 2017. Commissioning commenced, and at the time of paper submission mill production is on track to ramp up to full capacity by the beginning of 2018. This paper will focus on the use of fluorine NMR analysis applied to fluorite and the development of on-stream analysis, flotation cell selection and the decision to install the new cells, and the water control program designed to maintain process control with the least possible environmental impact.HISTORY St. Lawrence is located on the south-eastern coast of the Burin Peninsula in Newfoundland and Labrador. The first occurrence of fluorspar in the St. Lawrence area was recorded in 1843 by British geologist J.B. Jukes (DNR 2010). Fluorspar was likely extracted in small quantities prior, however commercial fluorspar mining did not commence until 1933 at the Black Duck Mine. The Black Duck Mine operation processed ore by washing and screening – acid-grade was hand-picked from the oversize, the undersize was sold as a lower grade product. The Black Duck Mine was closed in 1941 (Wilson 2010). The American Fluorspar Limited (New Fluor) commenced operations on the Director vein in 1936, and was bought by Alcan in 1942 (Cooper 2012). Alcan also developed the Iron Springs as well as the Tarefare deposits. The Black Duck Mine mill had closed, and a new mill was built. This new mill crushed the ore prior to dense medium separation, the sinks of which were sent to Quebec for use in Alcan’s aluminum smelter (CFI 2016). Alcan shut down it’s mining operations in 1977 due to the dropping price of fluorspar as well as labour disputes. In 1986, the British-based Minworth Limited began producing ore from underground at Blue Beach North and Blue Beach South, as well as from open pits at Tarefare and Director veins (Cooper 2012). A new mill was built by Minworth in order to process the ore using flotation to produce an acid-grade concentrate. The low price of fluorspar caused Minworth to shut down operations in 1990. Whilst exploration has been ongoing, no mining had occurred in the area since 1990."

Jan 1, 2018

By I. S. Laitinen

Outokumpu Technology has recently introduced new technology in both copper electrorefining and electrowinning. This technology includes, among other things, a new permanent cathode (Outokumpu Permanent Cathode) and new busbar technology (Outokumpu Double Contact System). The new technology has already been tested in commercial scale cells. To get a better understanding of the busbar system a multiphysical simulation model of the electrowinning and electrorefining cells was developed. A mathematical model of electrical conduction and heat transfer in a copper electrolysis cell was developed from partial differential equations. The model was expanded to a cell group including seven electrolysis cells connected electrically in series. The model was solved numerically using the finite element method (FEM). Using the model, different intercell busbar systems were simulated. Typical electrical disturbances, like loose contacts between cathodes and the main busbar and short circuits between electrodes, were included in the simulation. The results of the simulation runs with conclusions are presented in this paper.

Jan 1, 2007

By M Reza Afshar

In this work a mathematical model was developed to study the effect of electromagnetic force on the magnesium melt containing nonmetallic inclusion in an electrical isolated channel. The electromagnetic force exerted on the inclusion induced by DC current field was calculated. A three dimensional turbulent flow equations were solved numerically to compute the velocity field within the channel. On the basis of computed velocity and magnetic fields, the trajectories of inclusions were calculated using the equations of motion for inclusions. Parametric studies were carried out to evaluate the effect of various parameters such as current density, channel diameter and particle density on the removal efficiency of inclusions from magnesium melts.

Jan 1, 2004

By Jae-Chun Lee, Rajiv Ranjan Srivastava, Min-seuk Kim, Byung-Su Kim

Recycling of spent hydrotreating catalysts (HTC) can potentially contribute towards the sustainable extraction of metal values. Treating such materials by hydrometallurgical methods to separate metals from the leach liquor of either acid/alkali media is a major step. In the present study, separation of molybdenum from HCl leach liquor of spent NiMo type HTC has been investigated by applying solvent extraction using Cyanex-923. For this, the chloride solution containing 973 mg/L Mo, 254 mg/L Ni and 1634 mg/L Al was taken as the aqueous feed. The parameters including contact time, concentration of the extractant, acid and chloride, and phase ratio were varied to investigate their effect on the extraction efficiency. The McCabe-Thiele plot suggests that > 99% Mo-loading using a 2-stage extraction process. From the molybdenum depleted solution, nickel was selectively extracted by Cyanex-301 leaving Al in the raffinate.

Jan 1, 2014