Search Documents

By P. K. Chatterjee

"The operations of a large-scale open-cut mine are simulated to produce a user-oriented interactive digital model. SIMULA is chosen as the programming language and a sophisticated data base system is designed to consider the complex information network of large mines. The main features of the program are the mine planning and mine evaluation modules. These modules are responsible for the computation of truck-shovel performance and other equipment details in a mine. Stochastic methods are employed to generate event times. The use of a Data Base Management System and the data base provide an efficient method of information storage and retrieval. Truck allocation techniques have been examined in detail and comparisons between random dispatching and conventional methods are made. The model is intended for mine operators and engineers and the program is well structured and very readable. It is hoped that these features will make the model readily acceptable.IntroductionThe Department of Mining and Metallurgical Engineering at the University of Queensland has been conducting research into computer simulation methods in mining since 1972. The research has been mainly applied to actual operations, with both open-cut and underground mining being equally emphasized. The results of the research to date have not only strengthened the methodology of the approach to complex mining problems, but have also increased confidence in the use of modelling and computer simulation technique s in mining.The model described in this paper translates a complex LHD situation into a user-oriented interactive digital model using SIMULA. The present methods of evaluating truck dispatching and trolley assist are tedious and laborious. This model provide s the engineer with readily acceptable means of rapidly assessing the relative merits of these techniques in a large-scale open-pit operation. Poor utilization figures in many current operations (for example, 40% for trucks, 70% for shovels) are of serious concern to mine officials and computer-controlled dynamic truck dispatching systems have been considered by some of these mines to improve equipment utilization ."

Jan 1, 1981

By Free. Michael L.

Crushing ore prior to heap leaching enhances mineral liberation and creates fine particles that may require agglomeration to avoid permeability problems during leaching. Conventional modeling is relatively successful in describing general fluid flow and extraction in heaps. However, most models do not adequately account for the effects of mineral liberation and exposure or the effects of agglomeration, curing, and loading on heap leach performance. This paper will discuss methods to account for mineral liberation and exposure as a function of comminution. It will also discuss methods for incorporating liberation, exposure, and mineral locking as well as curing and fluid flow in heap leach modeling. It will also provide information regarding agglomeration and the effect of loading in heap leach modeling.

Jan 1, 2014

By M. Roy, Y. Roux, R. McIvor

"La Compagnie Minière Québec Cartier at Port Cartier. Quebec, utilizes six parallel wet grinding open circuit ball mills to grind iron ore concentrate for the pellet making process. In an attempt to improve grinding efficiency, a mix of 605 25 mm (1 in.) and 405 38 mm (1 ½ in.) grinding balls was charged to mill D while the opposite mix was used in all the other mills. Because media costs were higher for mill D, it was necessary to find out if the smaller balls provided a net economic benefit. Therefore, a test program was undertaken to determine the relative efficiency of the charge in mill D compared to the other grinding mills. Mill F was chosen for comparative efficiency measurements.The first problem was to choose a suitable definition of grinding efficiency. In management's view, previous attempts to quantify milling performance using population balance modelling were ineffective because they were unable to relate breakage rate functions to grinding circuit economical in any meaningful way. Work index analysis was also not favoured because of a number of complicating effects, including the fineness of the feed and product streams and open circuit grinding.It was decided to adopt a recent innovative approach which had been successfully applied to closed-circuit ball milling. For ""functional performance analysis of ball milling"" (McIvor et al., 1990; McIvor et al., 1991), a size criterion is first chosen to define ""fines·' and ~'coarse particles"". In this case 45 microns (325 mesh) was chosen to distinguish fines from coarse material. The relative grinding efficiency of each ball mill environment would then be ~e cumulative grinding (disappearance) rate of coarse (plus 45 nucrons) material per kilowatt hour of energy applied to the coarse material in the mill, divided by the grindability (measured in the laboratory) of the coarse material in the mill feed.Because the disappearance rate of coarse particles is also the production rate of fines, the following equation can be written for the efficiency of the mill environment, Effe, as defined above:"

Jan 1, 1994

By V. J. Hucka, J. H. Tu

"A computer model has been developed for evaluating the performance of truck and shovel operations in an open-pit mine. The data required for describing the haulage network are simplified and shift startup and ending procedures specific to any given mine can be incorporated into the model readily . The model uses a FORTRAN-based simulation language SLAM and can be tailored to the conditions and practices of a particular mine.The model is used to analyze truck and shovel operations, evaluate different haulage layouts in the planning stage, or compare the expected performance of alternative truck dispatching systems.Stochastic simulation is used to model the random variation in time required f or the individual activities. This gives a more realistic representation of the processes under study. Simulation runs show good agreement with actual performance. The model is especially useful for examining alternatives in equipment acquisition , haulroad design, truck-shovel allocation and dispatching methods. The results of such simulations provide a sound basis f or making major management decisions.IntroductionTruck haul age is widely used in open-pit mining operations. It is also the largest cost item in the operating costs of an openpit mine, in some cases accounting for an estimated 50% of operating costs(1) , Truck replacements, which are necessary from time to time, involve large amounts of cap ital. Increasing depth of mining and consequent increase in stripping ratios require additional capital investment in the truck-shovel fleet. The sharp rise in energy costs over the last decade has also contibuted significantly to an increase in truck fleet operating costs . All these factors have led mine operators to search for ways to improve the effectiveness of the truck-shovel fleet, in order to lower costs and maintain a profitable operation in the face of declining markets and increasing world wide competition.Control of truck haulage in an open-pit mine is usually done in one of two ways."

Jan 1, 1985

By Bob Butler

Brunswick Mine has been involved in a comprehensive research program investigating site specific aspects of thiosalt management to eliminate its adverse environmental effects. Minimum annual reagent cost estimates for thiosalt treatment using hydrogen peroxide and sodium hypochlorite are $400K and $1.5 million respectively. Also, minimum costs for the use of bicarbonate to buffer the pH depression associated with thiosalt oxidation in the receiving environment is in the order of $400K annually. A design of experiment (DOE) research program identified that natural UV radiation, temperature, DO and water chemistry are key factors influencing the natural oxidation rate of thiosalts within Brunswick?s water management system. A DOE surface response model was used to describe the thiosalt oxidation kinetics, which were then used to develop a predictive oxidation model for thiosalt and pH control of the mill?s reclaim water system.

Nov 1, 2002

By C. Overton, R. W. Nice

"With todays economic trials and tribulations we have all become deeply engaged in costs and cost cutting in our field of mineral processing. Grinding is one of the most expensive unit operations. The cost of grinding media is the most expensive item in grinding costs. Therefore, it is only reasonable to attack the cost-cutting area by trying to reduce the consumption of media. This introduces the field of autogenous or rock-on-rock grinding.Rock-on-rock grinding is not new to us. It has been known for many decades;The South Africans used pebble grinding in the '20's for gold.Mr. B. Crocker was prompted for the same reasons to introduce pebble grinding at Lakeshore Mines in Kirkland Lake during the last war.The Buffalo Anchorite used beach pebbles in grinding prior to the war.Autogenous and semi-autogenous grinding is used quite successfully in the iron ore field. Base metals have their examples in Australia at Caba, in Africa at Komato and in Sweden at Aitik.Recently three mills in British Columbia and one in Arizona started with autogenous mills in their circuits. One was originally conceived to utilize a modified autogenous grind with a crusher in the circuit. All except the same mill had contingency plans for converting to semi-autogenous. All four mills have since converted to the semi-autogenous mode. These are Island Copper, Lornex, and Similkameen in B.C. and Pima Mining in Arizona."

Jan 1, 1975

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By N. Plint, D. Philips, J. Sweet, B. Durant

A pilot scale AG milling campaign was conducted at the AngloAmerican Platinum pilot plant in South Africa. Different blends of hard: soft (silicate: chromite) and coarse: fine particles in the AG mill fresh feed were tested. The effects of multi-component feed on the pilot scale autogenous grinding are presented in this paper, and can be used as a guideline for multi-component feed blends for AG mil

Jan 1, 2012

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By Dean McDonald

The Committee Bay Greenstone Belt extends over 300km and is one of the largest unexplored greenstone belts in North America with excellent gold and diamond potential. Committee Bay Resources Limited holds over 550,000 acres of land with prospective geology in the Committee Bay area southwest of Melville Peninsula, Nunavut. Committee Bay is a typical Archean greenstone belt comparable to the Yellowknife, Red Lake, Kirkland Lake and other prolific gold belts. Drilling during 2003 at Committee Bay resulted in: 1) the discovery of high-grade gold-bearing quartz veins with silicification and sulphidation at Three Bluffs, and 2) the continuation of high-grade gold mineralization in the hinge area of the iron formation at Inuk. Gold mineralization at Three Bluffs is identified in iron formation and adjacent sediments and has been traced by drilling for over 700m. The Three Bluffs iron formation is open to depth and along strike where is has been traced on surface for over 6km. In January 2004 Committee Bay and joint venture partner Gold Field?s announced a $7.1 million exploration program for the Committee Bay project in 2004. A total of 8,000m in exploration drilling has been approved for the expansion of the Three Bluffs to the resource stage and drilling of at least five new target areas. Additional mapping, sampling and geophysics will be used to identify new gold targets along the very prospective Committee Bay belt.

May 1, 2004

By Pierre Bénard

To achieve penetration on the energy market, hydrogen must overcome obstacles in the areas of storage, safety and infrastructure. One of the most important is the onboard storage of hydrogen for transportation applications, where large performance gaps exist between the current state of the technology and user expectations. In order to develop and demonstrate viable hydrogen storage technologies for cars, a set of gravimetric and volumetric system targets have been proposed by the US Department of Energy, based on achieving a driving range of 500 km for a hydrogen powered vehicle. A factor of 2 to 3 improvement in both hydrogen storage capacity and energy density is needed along with several other performance goals. Another key issue is safety. Although some of the safety issues can be arguably assigned to misperceptions, hydrogen has specific properties that have to be addressed, particularly in confined geometries where the risk of hydrogen detonations becomes an issue.

May 1, 2007

By C. Bazin, D. Hodouin, M. Ounpuu

Sensors are now available in mineral processing circuits to monitor pulp flowrate and density, as well as ore characteristics and other process variables. The amount of information provided by these instruments is considerable but in many cases poorly exploited. This paper gives the results of the application of time series analysis techniques to signals generated by the sensors installed on an industrial Pb dezincing flotation circuit in New-Brunswick. Autocorrelation and cross correlation functions appear to be interesting tools for a preliminary circuit analysis, however the calibration of single input single output discrete transfer functions using collected sensors signals leads to conflicting results. For this reason a phenomenological approach, based on the kinetic and transport properties of the flotation process, is also considered. It has several advantages over the empirical transfer function modelling but also limitations in its applicability to industrial processes. A combination of the transfer function and kinetic modelling approches appears to be a promising avenue for better process modelling and control.

Jan 1, 1985

By J. D. Gillaspie, D. T. White

"Sulphuric acid atmospheric leaching of nickel saprolite / garnierite ores was proposed in the early twentieth century, prior to the development of the pressure acid leaching process for limonite ores. Sulphuric acid leaching with alkali addition for iron precipitation as jarosite has been considered periodically since the early 1970s, shortly after the development of the jarosite process for iron control in zinc refining. In the late 1990’s a series of flowsheets were proposed and tested involving simultaneous atmospheric leaching, iron precipitation and acid regeneration. These were considered particularly suited to sequential leaching of limonite and saprolite ores. A number of laterite sulphuric acid leaching processes utilising this chemistry have been put into commercial operation. Similar sequential leaching flow sheets involving precipitation of iron as goethite were also developed and piloted. This paper will firstly describe some of the important historical developments of both the jarosite and goethite processes. It will then provide descriptions of the commercialised processes involving alkali jarosite/alunite precipitation, with special emphasis on the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution.INTRODUCTION This paper is a summary and extension of previous works with which the authors have been involved, on the subject of sulphuric acid leaching of nickel laterites (Adams, et al., 2004), (Liu H. , Gillaspie, Lewis, Neudorf, & Barnett, 2004), (White, Miller, & Napier, 2006), (White, 2009), (White & Gillaspie, 2013), (White & Gillaspie, 2015). Some of the historical developments of both the jarosite and goethite leaching-precipitation processes will be described, followed by a description of the commercialised sequential nickel laterite leaching processes, involving alkali jarosite/alunite precipitation and acid regeneration, with a comparison to the equivalent goethite based processes. These will include Jarosite Atmospheric Leaching (JAL), Goethite Atmospheric Leaching (GAL) and combined Pressure Acid Leaching – Atmospheric Leaching, termed EPAL®. There will also be an explanation of the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution."

Jan 1, 2016

By James Kear, Romain Prioul, Robert G. Jeffrey, Andrew P. Bunger, Dimitry Chuprakov

"Unconventional gas and geothermal reservoirs are typically naturally fractured and therefore the challenging problem of hydraulic fracture (HF) growth through naturally fractured rocks is an important issue especially for the development of accurate predictive HF models. This paper presents results from laboratory experiments in which HFs have been created in both sandstone and crystalline (gabbronorite) rock specimens such that they impinge either orthogonally or at an oblique angle on an unbonded, machined frictional interface. Depending on the conditions of each experiment, the fractures either cross or are blunted at the interface. The growth behavior was ascertained for these experiments based on a synthesis of the injection pressure record, active ultrasound monitoring, and direct post-experiment inspection of fractured specimens. From these experiments we observe: 1) A contrast between direct crossing and crossing with an offset for orthogonal and oblique intersection, respectively, 2) Apparent independence of crossing/blunting behavior on the friction coefficient for orthogonal intersection, 3) Dependence of the stresses required to promote crossing on the intersection angle between the HF and NF, 4) Existence of cases in which the hydraulic fracture crosses but then essentially ceases propagation such that all fluid is diverted to the interface. INTRODUCTIONHydraulic fracturing is a vital technology used to increase the productivity of oil, gas, and geothermal wells. Predicting hydraulic fracture (HF) growth is, in turn, critical to design of hydraulic fractures that grow to the desired length, accept the desired amount of proppant, and remain contained in the reservoir without unwanted height growth into surrounding layers (e.g. Economides and Nolte, 2000). The importance of HF modeling has prompted 6 decades of research during which simulators have become more efficient, more accurate, and have addressed a growing range of complexities (see review of e.g. Adachi et al., 2007).One of these complexities is the interaction between HFs and mechanical discontinuities such as natural fractures (NFs). Efforts in this area have been mainly driven by development of unconventional (i.e. low permeability) oil and gas resources because essentially all viable low permeability reservoirs, including shale gas/oil reservoirs, are naturally fractured to some degree (King, 2010). One of the most important questions for developing effective HF stimulation strategies in these reservoirs is whether the hydraulic fracture(s) is/are expected to be single-stranded or whether interaction with the NFs will lead to network-like growth. The basic building block for numerical simulators that can address this question (such as Kresse et al., 2013 and Weng et al., 2014) is whether an HF that intersects an NF will cross the NF or whether its growth will be captured by the NF so that additional fluid injection pressurizes the NF but does not generate ongoing growth of a new HF. These scenarios, including subcategories such as crossing with an offset, have been recognized for several decades (Daneshy, 1974; Warpinski and Teufel, 1987, and as recently reviewed and expanded by Chuprakov et al., 2013)."

Jan 1, 2015

By Sammy Bansah, Komla Dzigbodi-Adjimah

Abstract-Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized ("Banka") drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi- Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration programs for use in similar settings.

Jan 1, 1995

By Sammy Bansah, Komla Dzigbodi-Adjimah

Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized (“Banka”) drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi-Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration pro-grams for use in similar settings.

Jan 1, 1995

By E. Busse, J. E. Burgener, J. G. Eacott, M. C. Robinson, P. E. Burgener

"This paper presents a preliminary assessment of the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from electric arc furnace baghouse dust at a mini-steelplant. Recent studies and literature are referenced briefly as they pertain to the formation and characterization of dust, toxicity considerations and alternative dust treatment and disposal options.Laboratory testwork results, published data, pilot plant experience and anticipated influences resulting from recycling residues are used for the purpose of developing a conceptual design for a caustic leach - electrowinning plant to treat 15,000 tonnes/year of dust at a one million tonnes /year capacity steelplant in Canada.Target economic studies, comprising preliminary estimates of capital and operating costs, revenues and rate of return are presented. Economic and commercial considerations concerning the relative merits of dust treatment at a centralized facility compared with an on-site plant are discussed.IntroductionThe treatment or disposal of mini-steelplant electric arc furnace (EAF) baghouse dust has been given increasing attention in recent years for two principal reasons. Firstly, the dust is now classed as a hazardous waste material under V.S. EPA regulations which prohibit its disposal in dumps other than controlled landfill sites. Secondly, the dust contains certain metal values, notably zinc and lead, which may be economically recoverable, depending on the costs associated with disposal resulting from enforcement of the EPA regulations. Other metallurgical dusts and waste materials, from both ferrous and non-ferrous operations, may require the same considerations as EAF baghouse dust.Several studies have been carried out to examine various aspects of dust treatment but few commercial plants are in operation. Technology employed uses pyrometallurgical techniques. Commercial-scale hydrometallurgical plants are not known to exist although small-scale plants are frequently more economically attractive than their pyrometallurgical counterparts which generally require economies of scale to be viable.The concentration of mini-steelplants in northeast V.S.A. and southeast Canada merits study to determine whether or not dust treatment for metals recovery is a commercially feasible alternative to disposal.This paper examines the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from EAF baghouse dust at an on-site ministeel plant processing carbon steel scrap and discusses economic and commercial considerations pertaining to dust treatment at a larger, centralized facility."

Jan 1, 1984

By Ferri P. Hassani, Riadh Bouzaïene

"Selected methods of pressure loss predictions in horizontal slurry flow in pipelines are presented. For a given combination of flow velocity, solids concentration and particle size, the slurry and its flow conditions are described, and an appropriate method of pressure loss prediction is outlined. The wide range of conditions treated in this paper may be found in practice in areas varying from the hydraulic transport of low concentration slurries to dense-phase conveying of paste backfill in underground mines.IntroductionThe hydraulic conveying of solid particles in pipelines is a major component of the mining and mineral processing industry. Whether the objective is to transport ore to the processing plant or to make use of mill tailing as backfill material; the need for well designed, economical hydraulic conveying systems is recognized.The contribution of this paper is part of an on-going research program at McGill University involved in optimizing and developing techniques for total mine waste disposal. One of the main concerns in the conveying of solid-liquid mixtures is the prior knowledge of the pumping power input required. This energy requirement is directly proportional to the pressure losses incurred in the pipeline system. Understanding the sources of such pressure losses and predicting their magnitudes should enable the system designer to make informed decisions regarding the optimum mode of hydraulic transportation commensurate with the over-all requirements of the operation.This paper is an attempt to classify pressure loss prediction methods encountered in the literature for solid-liquid mixtures. In spite of the large number of publications spanning thirty years of research in the field of slurry transportation, it is sometimes difficult to correctly identify the appropriate methods applicable to a given situation. This is partly due to the inherent complexity of the mechanics of slurry flow and the ensuing uncertainty about the nature of the flow regime under investigation.Our approach is to use three fundamental parameters, namely: flow velocity, solids concentration and particle size (for solid particles with a given density) to characterize the slurry and the flow conditions, and to match them with an adequate pressure loss prediction method. For each combination of flow velocity, solids concentration and particle size, a description of the most likely prevalent flow conditions and some known methods of dealing with them will be presented. Qualitative definitions of ""high"" and ""low"" magnitudes of the aforementioned parameters will be given as a general guide to the classification scheme presented in this paper."

Jan 1, 1992

By M. P. Amsden

"Ecstall Mining Limited, a subsidiary of Texas Gulf Incorporated operates the Kidd Creek Mine, a 10,000 tons per day base metal producer, near Timmins, Ontario. Two different ore types are mined and milled: copper-zinc and silver-lead-zinc. At the highly automated Ecstall Concentrator the ores are processed by selective flotation in threes individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous on-stream x-ray analysis. Recently this system was further automated by adding computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery 0.8%, zinc recovery 1.6%, and reduced reagent costs by 12%. Although not anticipated, copper and zinc concentrate grades were improved modestly as well.INTRODUCTIONSEcstall Mining Limited, a wholly owned subsidiary of the Texas Gulf Incorporated operates the Kidd Creek Mine, one of the world's major base metal producers, near the old gold mining centre of Timmins, Ontario. Discovered in 1964, the property was brought into production in November, 1966. Originally designed for 9,000 tons per day, the operation now treats 10,000 tons per day of two different ore types mined from a single open pit. In the near future, open pit ore will be supplemented by ore from an underground operation now being readied for productionAt the Ecstall Concentrator the ores are processed by selective flotation in three individual circuits. The whole plant is highly automated and control is coordinated from a central control room. The treatment process follows conventional practices although fine grinding is required for optimum flotation recoveries. Normally, two circuits treat copper-zinc ore at a combined rate of 6,500 tons per day while the third circuit treats 3,500 tons per day of silver-lead-zinc ore. Special production averages 2,400 tons per day."

Jan 1, 1973

By K Byrne, W. Hawker

The average grade of copper concentrate is steadily declining, forcing the industry to turn to lower grade and metallurgically challenging orebodies. When faced with a low grade, challenging ore, mining companies are often forced to choose between high recovery at low grade or low recovery at high grade. Hydrometallurgical processing of copper concentrates using metathesis reactions, which replace iron with copper in copper-iron sulphide minerals and increase the copper to sulphur ratio in copper sulphide minerals, provide an opportunity to upgrade copper concentrates and potentially allow high copper recovery for a high grade concentrate. Factors such as concentrate mineralogy, reaction time and temperature, and the concentrations of copper, chloride and acid in solution are reported to affect the reaction extent and mineral phases formed by metathesis. In this paper, a copper concentrate has been studied over a wide range of conditions to investigate the influence of these key parameters on the extent of copper metathesis reactions and product phases formed. Solution and solid phases are assayed with the main mineral phases identified by Quantitative X-Ray Diffraction. INTRODUCTION The minerals present in copper deposits determine the prospective processing options either: pyrometallurgical or hydrometallurgical. For copper oxide ores, copper is typically present as oxides, carbonate, chlorides, silicates and sulphates. These minerals are readily solubilised in acid and are usually treated through hydrometallurgical processes. The typical process route for copper oxides is to leach copper into aqueous solution, purify and upgrade the solution phase through solvent extraction and then recover copper as metal by electrowinning (Davenport, King, Schlesinger, & Biswas, 2002). Copper sulphide deposits may contain a multitude of copper bearing minerals, including chalcopyrite, bornite, enargite, covellite, digenite and chalcocite. The copper ore grade and treatment options are affected by the mineral type and distribution. Sulphide ores are typically treated through comminution and mineral flotation to form concentrates, followed by pyrometallurgical smelting. Hydrometallurgy can also be used to process sulphides depending on the mineralogy and impurity levels (Davenport et al., 2002). The trend of decreasing copper grade with increasing impurity levels are common across the mining industry and pose future challenges to copper processing. This trend has prompted research into hydrometallurgical options for upgrading copper concentrates. One promising hydrometallurgical option is using metathesis reactions. Metathesis reactions, sometimes also called double replacement or displacement reactions, are chemical processes involving the exchange of bonds between two chemical compounds or species. In this case, the metathesis reactions involve copper in solution exchanging with cations in the solid sulphide concentrate. The driving force for copper sulphide metathesis is the relative affinity of the exchanging cation elements for sulphide. Based on sulphide precipitation diagrams, the expected order of affinity for sulphide should be Hg2+ > Ag+ > Cu+ > Cu2+ > Bi3+ > Cd2+ > Pb2+ > Sn2+ > Zn2+ > Co2+ > Ni2+ > Fe2+ > Mn2+ (Monhemius, 1977). Hence, copper metathesis reactions are capable of increasing copper content and removing impurities such as iron, nickel, zinc and lead from copper concentrates.

Jan 1, 2019