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By S. Yalcin, S. Chang, M. Oliazadeh

"Present day ferrochrome demand is on the rise, as more steel products require this material as an alloying element. It is projected that the stainless steel demands will grow by about 6% per year to 2020; as such, the supply and demand for ferrochrome appears promising. Chromite is the only economical source of chromium, which is commonly upgraded by gravity techniques and used to produce ferrochrome. The gravity separation methods are not able to treat particles finer than 0.1 mm efficiently. Therefore, in processing chromite ore, a large quantity of fine tailings; some 25% of the mineral values have been reported as lost in slimes during processing. The chromite content of these tailings is typically 10-20% Cr2O3 and accumulates into a large stockpile/pond. A chromite concentrator project in Canada, considers a cut-off grade of 20% Cr2O3. This indicates further processing might be required to recover chromite from low-grade stockpile when the high-grade deposits are depleted. Low-grade ores normally indicates disseminated chromite ores with low liberation and consequently fine comminution. This paper reviews the techniques for treating chromite from fine material and provides some examples of successful operations in fine chromite recovery. Beneficiation techniques for fine particles include gravity separation, magnetic separation, and flotation. Several case studies are presented here that used one of the aforementioned methods or a combination of them.INTRODUCTIONChromium is one of the essential element and important material for production of ferrochrome alloys and special steel. Chromium occurs as chromium spinel, a complex mineral with chemical composition of (Fe, Mg) O (Cr, Al, Fe)2 . Chromite ore is exclusively found in ultramafic igneous rocks. Major associated gangue minerals are talc, quartz, serpentine and iron oxides.Chromite is a heavy mineral, with a specific gravity in the range of 4-5, relative to associated gangue minerals in a chromite ore, which makes gravity concentration a suitable process. This is generally true for coarse particles, ranging from 1 mm to 100 mm. Typically, the ore is prepared by crushing (and grinding if necessary) to a suitable size and the material is sized for the appropriate beneficiation techniques. It is common to use heavy medium separation (e.g. dense media drums, dense media cyclones, or Dyna Whirlpool) to treat coarse size and intermediate size particles (1 – 100 mm). Intermediate and fine particles (20 – 0.1 mm) could be treated by jigs. Spirals, shaking table, sluices, and Reichert cones can upgrade fine particles. Figure 1 shows a typical chromite beneficiation process flowsheet. As can be seen, it consists of three major sections: feed preparation (crushing, screening), de-sliming, and concentration. Beneficiation recoveries range from 80 to 85%, although the ratio of upgrading is only 2 to 3."

Jan 1, 2013

By M. Coleman, M. E. Reed

The control of feed delivery quality to the flash furnace remains an unsolved problem. Many operations around the world still have limited control of feed quality to their flash furnace. Schenck Process and WorleyParsons continue to work towards the ‘holy grail’ of simple quality feed delivering both radial feed distribution and pulseless feed delivery. Ten years ago they joined forces to offer a system based on then Clyde Process RotoFeed system which could deliver ground level installation, online mixing of materials, pulseless feeding direct to the burner, with good radial distribution. Unfortunately, this proved to be too large a step for the Flash Smelting community and met with resistance from the process owners. Since then the community has developed a range of options some of which have been implemented over this period. Despite these improvements there are still areas of concern including safety issues associated with concentrate leaks and spills, uncontrolled variations in feed rate including massive flooding events, intermittent distribution improvement and set up of the burner continues to be trial and error and hard to repeat the success in each burner campaign. These continue to impact flash furnace performance globally on a daily basis. Following the community reticence to pursue the complete solution a number of interim steps are now available to pave the way to the ultimate feed system. The mixing of material has been installed and is delivering line blended materials on a daily basis. This paper will investigate the developments over the last 10 years and discuss the pros and cons of this incremental step process for overall furnace control. INTRODUCTION Schenck Process and WorleyParsons have continued to interact and observe changes in the flash smelting industry and to consider application of the Clyde RotoFeed now incorporated in the Schenck Process ProStreamTM range for delivery of feed directly to the concentrate or matte burner. Schenck Process pneumatic injection from the Clyde Process range, ProStreamTM, utilises two types of volumetric feeders to accurately control the feed of material into an injection pipeline. These are referred to as the RotoFeed and RotoScrew technologies and the choice of feeder type is dependent on the characteristics of the material to be handled. The RotoFeed is generally used for finer, granular and powdered materials which cannot be accurately handled with a screw such as pulverised coal and copper concentrate, whilst the RotoScrew is particularly suited to coarser lump materials, particularly abrasive of cohesive materials like zinc powder, electronic scrap and metal ashes. Both units can operate at high pressures and many systems work at 3 to 10 bar with the occasional system working at 20 or 30bar for carbon to gasifiers. For the Flash furnace the ProStreamTM units can be used to deliver each of the furnace feed materials into a single line, mixing the materials homogeneously and live to the burner.

Jan 1, 2019

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, Z. S. Abisheva

"Phosphorus slag is the most heavy-tonnage waste of yellow phosphorus production, which is stored in the dump fields for many years creating ecological problems in the regions. Despite of the actions taken to utilize the slags, most of them remain in the slag disposal area. One of the relevant and priority directions is rare-earth metals production (REMs), presence of which in the phosphorus slags allows considering the latter as an acceptable raw material source. Phosphorus slags contain about 30–40 wt% of silicon dioxide, therefore they can serve as a source of production of precipitated silicon dioxide highly required in different industries.The purpose of this work is the most complete REMs recovery in the solution while leaching and subsequent processing of siliceous cake. The work shows results of researches on establishment of the chemical and phase compositions of phosphorus slags, determination of the forms of presence therein of REMs compounds, processes of phosphorus slag leaching by nitric acid and processing of produced siliceous cake by NaOH solution.Based on the data of the instrumental and chemical methods of phosphorus slag analysis, it was established that it consists of pseudowollastonite a-CaSiO3 for 90–92%. It was found out that REMs are present in it in the form of carbonate apatite Ca10(PO4)6CO3 or rare earth apatite, and La2S3 compound inclusions.Optimum parameters of phosphorus slag leaching process were selected: HNO3 concentration 7- 7.5 mol/L; L/S ratio = 2.6–3 mL/g; temperature – 50–80o?; duration – 1 h; pulp stirring – 500 rpm. Recovery of SREMs, CaO, Al2O3 and Fe2O3 into the solution were achieved at 98.0, 99.1, 99.0 and 18.8%, respectively. Presence of 10 elements of the rare earths group in the phosphorus slag was established. It was found out that recovery of almost all REMs is within ~92–99%, except for Sc and Lu – ~39% and ~28%, respectively.For the purpose of optimization of siliceous cake leaching by NaOH solution, influence of some physical and chemical parameters was studied: N?O? concentration, L/S ratio, temperature, and duration. Results of the experimental data will serve as a basis for development of the technology of complex processing of the technological waste of phosphorus industry with production of REMs concentrate and precipitated silicon dioxide."

Jan 1, 2016

By Gerhard W. Heinrich, Gerald V. Schroeder, Daniel A. Murphy, Daniel F. Suarez, Jamie B. Beauchamp

"Washwater 'Finger' sprays were installed and tested in the copper/nickel separation circuit at Strathcona Mill to improve flotation capacities and related metallurgical performances. The new spray design features submerged sideways introduction of wash water into the flotation froth through nozzles at the end of vertical pipes which are suspended from a header above the froth. This maximizes the effective cross sectional area of flotation vessels while maintaining effective froth cleaning and a desirably high density of the concentrate slurry. The plant tests gave increases of copper concentrate production rates of 17% to 20% for conventional cells and 16% to 20% in column flotation at target grades of 29% to 30% copper and of less than 0.5% nickel. Basic considerations and concepts of tests and evaluation procedures are described.IntroductionMeeting flotation concentrate grade targets at maximum production rates and recoveries is a challenge all too familiar to operators of base metal ore concentrators. Frothwashing is an option to improve grade/recovery performance by minimizing entrainment of impurities into the concentrate, which is commonly known since the sixties (Kaya & Laplante, 1989). It has been recommended for the flotation of sulphides and industrial minerals alike (Kaya & Laplante, 1989; Miller, 1969; Heinrich, 1989) and has found its ultimate application in flotation columns (Finch & Dobby, 1990). The washwater addition in a flotation column is most evenly distributed over the column's cross-sectional area thus ensuring almost complete displacement of feed water from the froth by a countercurrent washwater flow -provided, a positive bias is maintained. Therefore, flotation columns are ideal for cleaning flotation. However, there is usually less room for boosting the concentrate production capacity by increasing airflow or slurry level then with conventional cells because of the smaller cross-sectional area available."

Jan 1, 1994

By Michel Masse

1. A battery-powered wireless mesh network for dynamic diesel machinery tracking and operating status monitoring. 2. A real-time ventilation model and fan speed optimizer. 3. An OPC server for information interchange. 4. OPC linkage to existing control infrastructure. 5. A Human Machine Interface (HMI) providing data archiving, trending and reporting. 6. Live MS-Excel to interrogate the simulation, controls and optimizer. 7. The battery-powered network mesh also provides SCADA functionality to route optimized setpointsto the fans and automated regulators not linked to PLCs.

Feb 1, 2008

By L. C. Kitchener, K. Vollenwyoer

"This paper describes the development of an automated, 70-ton capacity, underground electric trolley truck at Inco Ltd. The purpose of the project is to provide a high capacity and high productivity haulage system to suit continuous loader applications in existing mining horizons where conveyor belt application is not immediately practical. IntroductionWith the start o f a program by Inco in mid-1983 to develop a continuous loader for bulk mining of our hardrock orebodies, the need for a rapid ore transportation system was recognized to match the increased extraction rates planned. Two methods were investigated, truck haulage and conveyor belt. As a result, a conveyor belt system has since been designed and installed with a continuous loader at Stobie Mine and an electric truck has been designed, fabricated and assembled, with shop testing underway. This paper deal s with the latter project. BackgroundMany existing mining horizons which could utilize continuous loaders do not have the straight runs required for conveyor belts. In these situations, truck haulage would be the only alternative of the other transportation methods that would be practical. In order to match the high productivity potential of the continuous loader, however, a more efficient trucking system is required than would be available with conventional diesel powered trucks or with electric truck designs commercially available, or under development. A higher capacity truck and an automated operation is necessary so that the application of additional units to suit increasing haulage distances matches loader output without reducing over-all productivity because of the need for additional operators.A first effort to work with a major electrical manufacturer was unsuccessful and resulted in a project delay of almost one year. In November 1984, an investigation into the concept was reinstigated with UTDC, and an agreement to start design was reached in April 1985."

Jan 1, 1988

By Gabka T., R. E. Gregorczyk

Work to improve employees' behavior in Głogów Copper Smelter began in 2009. It has been noted that over 90% of accidents at work are attributable to human reasons. At that time, a series of external workshops was contracted based on exercises conducted by a psychologist trainer with supervisors. Having trained about 300 employees, an observation of employee behavior at workstations was started as part of the control of risk reduction measures. As a result of the above actions, the number of accidents was reduced by half between 2009 and 2017. Currently, internal workshops for communication improvement for behavioral auditors are conducted by the employees of the Smelter. Named: "I observe, react and communicate" and aimed at further mastering the elements of the safety culture in Głogów Copper Smelter. INTRODUCTION KGHM Polska Miedz is an integrated mining and smelting copper producer based in Poland and operates on the international metal market. KGHM, with annual production of over 500 thousand tonnes of copper, holds a middle position in the world ranking of copper producers. At the same time, in Europe it is the largest producer of copper from its own ore deposits, possessing its own integrated production structure, from underground mining operations to final, top-quality product. It is also worth mentioning that KGHM Polska Miedź is one of the largest Polish exporters and, apart from copper, is a significant primary silver producer in the world. The mission of our company, consistent with its strategy, is to produce copper and silver in a safe mode for workers and the environment, with reduced environmental impact. Therefore, "Głogów" Copper Smelter operations are continuously focused on the creation of safe working conditions, and minimizing the negative effects on the environment. The company meets the requirements of an Integrated Management System comprised of the following: Quality Management System ISO 9001:2008 Environment Management System ISO 14001:2004 OHS Management System according to the requirements of BS OHSAS 18001:2007 Being a proud socially responsible company, we are aware that part of an efficient OHS system is to recognize, monitor, prevent, educate and motivate, thus continuously improve working conditions for 2500 employees of Głogów Copper Smelter &Refinery. We clearly communicate that a low accident rate is beneficial for both, staff and the company, and is of utmost importance as a part of our health policy.

Jan 1, 2019

By M. Kalin

"Ecological Engineering and Biological Polishing technology is a decommissioning approach for inactive coal, uranium and base metal operations. To improve acid mine drainage water some fundamental aspects of wetland ecology and sediment microbiology are combined, to provide conditions to allow for biomineralization of the contaminants.This paper summarizes the first records of microbial alkalinity generation in acid mine drainage through the utilisation of the ARUM process. The process requires that the seepage is at pH 4.5 where sulphate reducers utilize sulphate to produce hydrogen sulphide, which in turn precipitates with metals. The pH increase is brought about by alkalinity generating microbes.The ARUM process has been successful in increasing the pH from 2.5 to 7.0. Flow through reactors operated in the laboratory continuously for more than 60 days have removed Ni from 13 mg/L to < 0.01 mg/L. Design parameters are being developed for low flow rates of 5 L/min in a test system receiving seepage from a tailings.1.0 INTRODUCTIONAcid mine drainage associated with mining wastes poses a significant environmental problem. Conventional means to treat acid mine drainage (AMD) use chemical treatment system. Ecological Engineering technology uses natural biological means to curtail and ameliorate AMD during mine operations and at the time of decommissioning. The premise underlying Ecological Engineering technology is that AMD is the result of a natural process enhanced by mining activities. Therefore, in nature, a process providing a natural balance to AMD has to exist, which, when assisted through appropriate means, can counteract the detrimental effects of AMD on the environment. This process is microbial alkalinity generation which is known to occur in wetlands, lake and ocean sediments (Baas Becling et al, 1960)."

Jan 1, 1991

By J. W. Reynolds

"The use of approved fire-resistant hydraulic fluids in equipment operating underground was made mandatory in British Columbia by amendment to the Provincial Mines Regulation Act effective January 1, 1975. This paper covers the action taken to achieve this, in the largest underground metal mine in British Columbia. Some evaluation of costs and effects based on experience to date is included.BackgroundAn amendment to the Mines Regulation Act of the Province of British Columbia was passed in July 1974 as follow s: "" Rule 111 (b) Hydraulic Fluids. After the first day of January 1975, all hydraulic fluids used in equipment operating underground shall be of a fire-resistant type accept able to the chief inspector.""Unquestionably, its intent was justified as a safety improvement measure. The list of fires in mines involving machinery where hydraulic fluid was a factor in the fires is long and sobering. In British Columbia, in a 22-month period from 1972 to 1974, there were six fires in metal mines resulting in extensive equipment damage and injury to four workmen. Nevertheless, no provision was made for research or development of systems modifications compatible with conditions encountered in B.C. and, as late as June 1977, the Mining Association of British Columbia continued to argue that fire suppression systems should be considered sufficient until a universal suitable hydraulic fluid could be developed. The sole concession was to issue permits for continued use of mineral oil in equipment bought prior to 1975 in order to allow producing operations to continue. The burden of developing the necessary technology was laid on the industry.The Sullivan Mine at Kimberley, the largest and longest established underground mine in the province, and Cominco&apos;s most important source of ore s for its smelter at Trail, B.C., was at the outset of a conversion from conventional to trackless mechanized mining methods in pillar recovery operation s. Introduction of fire-resistant hydraulic fluid s had to be done in a period of change, in many instances on equipment for which no data existed, and called for research which had to be done while retraining the work force.The introductory phase is complete. All equipment is on FRF, the requirements of Rule 111(b) are being satisfied, and a number of research and development programs continue."

Jan 1, 1980

By T. R. Yu, D. B. Counter

"In an effort to increase productivity, the use of fly ash as a binder for consolidated backfill was studied. From laboratory and underground tests f or its cementitious properties and environmental effects, it was found that a portion of Portland cement could be replaced by the same amount of type ""C"" fly ash to produce an acceptable consolidated rockfill product for use at Kidd Creek.The environmental concerns in terms of dust control and emanation of radon gas were unfounded from measurements. The dust count was comparable to the use of Portland cement only, or with ground blast furnace slag, and the radiation readings were low, averaging one-seventh the regulation level.Since May 1984, a total of over 100 000tonnes of fly ash has been consumed as a binder blended with Portland cement, producing over four million tonnes of consolidated rockfill. To date, the fill in the stopes has performed very satisfactorily, while yielding considerable cost savings.IntroductionThe Kidd Creek minesite, located 27 km north of the city centre of Timmins, Ontario, produces 4.5 million tonnes of base metal sulphide ore annually. The mining method for both No. I and No .2 mines is mainly sub-level blasthole stoping with delayed backfilling.No. 1 mine was developed with a shaft to a depth of 930 m in 1973 to recover the ore between the floor of the open pit at the 216 m horizon, and the 792 m horizon. Stopes are normally 18 m wide, 22 m to 65 m long, with heights varying from 90 m to 135 m. Vertical rib pillars between stopes are typically 24 m wide and sill pillars are 30 m thick.Pillar recovery is implemented after the consolidated rockfill placed in the mined stopes has cured for a period of at least three months. This allows a maximum recovery of the ore with a minimum of dilution, while also maintaining safe working conditions.No. 2 mine was developed from a second shaft, sunk to a depth of 1530 m in 1978, for the recovery of ore beneath the No. I mine. Sub-level stoping in No .2 mine is similar to No.1 mine in methodology, yet differs in sequencing, as no rib pillars are left."

Jan 1, 1988

By A. Himsley

"There is an ever-increasing demand these days for efficient methods of removing metals from solutions especially for selectively recovering a particular metal from a mixture of metals in solution.Up until the mid l 930's the only methods widely practiced for such separations involved precipitation techniques or electrolysis. Both these methods have limitations and indeed can only be used for certain metals.It is only within the last 40 years or so when synthetic ion exchange materials became available that chemists in industry and universities have been able to apply ion exchange techniques to a wide variety of separations that not only would be impossible by precipitation methods but which are now achieved with much greater efficiency.Ion Exchange TechniquesIon exchange is a unit process that can be applied using either liquid ion exchangers or solid resin particles. Liquid ion exchange - or solvent extraction as it is often referred to - is used in a number of special areas dictated mainly by the nature of the separation.On the other hand, ion exchange resins are much more widely used and consequently a great deal more is known about their application to a variety of metal separations.In both systems there is a loss of the ion exchange material which in the case of solvent extraction results in hydrocarbons going to waste. The ion exchange resin systems lose resin in the form of small particles, referred to as ""resin fines"", and these are insoluble.The loss of liquid ion exchanger is due to the fact that it is slightly soluble in water and consequently the loss is a function of the volume of liquid with which it comes into contact and is not related to the amount of metal processed."

Jan 1, 1975

By W. B. Boggs

This is a rather comprehensive subject and cannot be thoroughly covered in the short rime allowed for its presentation. This article will touch only upon a few of the chief points of the difficulties encountered in recovering copper from brass shell cases in a primary smelter which was not designed to treat scrap metals. Owing to the fact that the plant is at present (Dec., 1946) closed, and our tests were not completed, full details of the results are not available. As is well known, most primary smelters are situated near the mines in the interior of various countries and are not close to seaports or large industrial and railway centres. Consequently, iris unusual for a primary smelter to be asked to treat scrap metal of any kind. When so required, iris obvious that the primary smelter is at a great disadvantage, for the simple reason that it probably has to pay the freight on the scrap from the seaport or industrial centre to the smelter and then also pay the freight on the recoverable metal from the smelter to the refinery, or seaport or industrial centre. Another disadvantage is that a primary smelter is not equipped to sample and unload the scrap nor bas it usually the equipment adaptable for treating the scrap efficiently, as the plant bas been designed to handle large tonnages of ores and concentrates. This short paper will describe some of our difficulties> and how they were corrected. However, it might be advisable to state briefly some of the methods used in treating brass shell cases in other plants. In the first place, a brass plant producing new brass- especially those producing brass billets for extrusion to make brass tubes or rods, or to be drawn into wire, or making brass cake to roll into brass sheets- generally insists upon using new electrolytic copper and zinc and is opposed to using any scrap or secondary brass . Consequently, such a plant usually will not treat brass shell cases. Therefore, the usual procedure is to ship brass shell cases to a secondary smelter, where it is generally sorted, melted, fire-refined, and returned to the market in the form of a high or low brass ingot which can be sold to brass foundries for making brass castings. This evidently is the cheapest and simplest method. Another method is to ship to a smelter which is a combination of a primary and secondary smelter attached to or near an electrolytic refinery. In plants of both these types, that is a primary smelter with Cottrell dust collectors or a combined primary and secondary smelter with Cottrells or a bag house, the zinc may be wasted. However, if a bag house is used, some of the zinc is recovered, but it is usually contaminated with other metals and further processing is required to recover it.

Jan 1, 1947

By S. C. Ells

Within the Dominion of Canada occurrences of petro-liferous shales have been known for many years. Nevertheless, with the exception of a comparatively brief period, Canada has had to depend largely on foreign sources for its supplies of crude petroleum and petroleum products. Attempts were made to retort local shales in 1859, near Collingwood, Ontario, and again in 1862, near Baltimore, New Brunswick. In each instance these attempts were abandoned owing to the rapidly increasing production of well petroleum from the newly discovered pools of western Ontario and Pennsylvania. Now, after a lapse of nearly sixty years, attention is again directed to the commercial value of Canadian shales as a possible source of crude petroleum. Province of Nova Scotia: The principal deposits of oil-shales occur in Pictou and Antigonish counties and have been known for more than 60 years. During the three years following its discovery, several thousand tons of a particularly rich sub-variety, known as stellarite (stellar coal or oil coal) was mined near Stellarton in Pictou county. It is stated that stellarite yielded upwards of 10,000 cubic feet of 36 candle gas, and that selected samples gave a yield equivalent to 170 Imperial gallons (204 U.S. gallons) of crude petroleum per ton. The average petroleum content of a cargo shipped to Boston was 48 Imperial gallons (57.6 U. S. gallons) and the associated shale or &apos;bat&apos;, gave a yield of 39 Imperial gallons (46.8 U.S. gallons). Part of the above output was shipped to retorting works in Boston and in Portland, and part was mixed with bituminous coals for the enrichment of illuminating gas. Following the discovery of well petroleum in Ontario and in the United States, the mining of stellarite ceased.

Jan 1, 1925

By J. T. Liu, G. H. Han, W. C. Chai, Y. F. Huang

"In beneficiation process, metal ions could adsorb onto clay mineral surfaces or interact with flotation chemicals, and then result in the flotation behavior changing of desired minerals. Al(III) is the dominating ion existing in the bauxite flotation system. In this research, the adsorption behaviors of Al(III) on two silicate clay minerals (including bentonite and kaolin) were investigated by means of UV-Vis spectra, zeta potential testing and scanning electron micrograph analysis. The adsorption experiment results show that the adsorption capacity of clays for Al(III) ions increases with the initial Al(III) concentration, contact time and solution pH. There are some different adsorption behaviours for two clays. Increasing the clay concentration decreases the adsorption capacity of bentonite, while increases first then decreases for kaolin. Higher temperature favours the adsorption of Al(III) on bentonite but goes against for kaolin. The adsorption capacities of bentonite and kaolin for Al(III) respectively reach 12.48 and 0.875 mg/g at initial solution pH 5. Zeta potential results show that the adsorption of Al(III) on two clays is characterized by electrostatic attraction mechanism.INTRODUCTIONIn beneficiation process, there is inevitably a wide variety of metal ions generated from mineral crushing, mineral dissolution and water chemistry conditions. Metal ions adsorb on the mineral surfaces or interact with the beneficiation agents, affecting the flotation efficiency of desired minerals (DiFeo et al., 2001; Parolis et al., 2008; Shackleton et al., 2012; Shengo et al., 2014). Therefore, it is necessary to have a detailed investigation on the adsorption behaviour of metal ions on clay minerals.Having good ion exchange capacity and negative surface charge, the clay minerals could take up various metal ions from the mineral-water system. Bentonite and kaolin are very common aluminosilicate clays in the mineral processing system. These two clays both hold a permanent negative charge, =X- on the basal surfaces, and a smaller variable charge, =SiOH on the mineral edges (Gu & Evans, 2008; (Gu et al., 2010). Adsorption experiments are usually used to study the adsorption affinity of metal ions for clay minerals (Sen & Bhattacharyya, 2012). The adsorption of Zn(II), Cu(II) and Pb(II) onto natural bentonite showed that the adsorption amounts of metal ions increase with contact time, solution pH and metal ion concentration, but decreases with adsorbent concentration and system temperature (Sen & Gomez, 2011; Melichova & Hromada, 2013). Cr(III) adsorption on bentonite was significantly pH dependent. The adsorption process followed pseudo-second-order model and the equilibrium adsorption was consistent with Freundlich isotherm (Lollino et al., 2015). The adsorption behaviours of Pb(II), Cd(II), Ni(II) and Cu(II) onto kaolin indicated that increasing pH favoured the adsorption of metal ions (Jiang et al., 2010). The adsorption of Cd(II), Cu(II), Pb(II) and Zn(II) onto kaolin showed that an ion-exchange reaction occurred at pH<7.0 and inner-sphere surface complexes were prone to form at higher pH (Srivastava et al., 2005)."

Jan 1, 2016

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By K. Wood, R. McIvor, P. Blythe, M. Lavallee

A new analytical approach for characterizing and improving the performance of ball milling is presented. Individual ball mill circuit design and operating variables can be related to overall circuit performance through two distinct parameters for classification and breakage. The ball mill circuit functional performance equation is presented.Total mill x Classification x Test specific x Grinding power draw system efficiency grinding rate rate ratio= Production rate of new product size materialExamples from industrial plants and applications in the research and development field are discussed.

Jan 1, 1990

By Robert B. Parsons

"A joint federal/provincial/industry subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWG) has published an informative and readable report on taxation matters concerning Canada&apos;s mining industry. The report, which was presented to the federal and provincial mines ministers in September 1986, identifies and discusses key tax issues relating to this industry. The report is mandatory reading for anybody with an interest in mineral exploration or production in Canada.IntroductionIn 1986, Canada&apos;s federal and provincial mines ministers were presented with an important report concerning the taxation of this country&apos;s mining industry. This document is important for a number of reasons, two of the reasons being: first, the report contains an objective analysis of the key mineral taxation issues of the day; and, second, the report is the product of a cooperative exercise involving representatives of various facets of the industry and government. The report should be regarded as compulsory reading for anybody who has an interest in fiscal matters affecting mineral exploration and production.The ""Report on Fiscal Proposals"" was prepared by a subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWO). IOWO is a group of senior federal, provincial, and territorial government officials concerned with the analysis of mineral policy issues in Canada."

Jan 1, 1986

By Glen A. White

The level of impact and mitigating measures that are forecast in an environmental assessment (EA) for a new, or significantly modified, metallurgical processing facility or mine are taking on increasing importance during the subsequent life of the facility. The basic premise is that one is authorized to operate within the envelope defined by the approved EA. Operations inevitably change as they develop and mature, and at some point, one is faced with the prospect of re-doing the original EA work. This can lead to significant development delays. Cameco Corporation (Cameco) has played a major role in developing the northern Saskatchewan uranium mining industry over the past decade. Through the EA process, the company has developed ideas on what works well in generating approvals that give the operator some future flexibility. Early introduction of concepts for potentially different mining and processing methods, as well as contingency plans if things do not work out exactly as predicted in the original EA, can make subsequent regulatory approval for change a more efficient process. One must also preserve the principles of open consultation upon which the EA process was originally based. As such, involvement and support from local communities and other stakeholders is required to ensure the long-term success of the EA process.

May 1, 2004

By J. H. Brown

"THE need for continuing education has been recognized only in fairly recent years as a major concern of the engineering profession. Formerly, it was acknowledged that engineers were required, at least informally, to follow the professional literature and to give some attention to new technical and technological developments. However, those relaxed days, when progress could be followed in a casual or incidental evening of reading, have disappeared in these days of mushrooming information. The engineer is now in the position of the man trying to control the flow from a fire hydrant with a child's pail. Our problem is that of developing an effective flow system -be it trough, hose, pipe or a bigger pail.The first step in achieving an effective means for continuing the education process is to realize that the need for the system is really an outgrowth of an increasingly sophisticated society. It is merely one more symptom of that society; others would• include the facts that new engineering graduates are more highly trained than those of several years ago, that graduate schools are now the norm and that even some fairly recent technologies are becoming outdated. There-fore, let us examine the education-al systems from which the bulk of the increasing sophistication has grown."

Jan 1, 1966

By S. Caron, M. Bourassa, J. Châteauneuf, L. Tardif

"Since many years, the Yvan-Vézina gold plant custom mills and processes different ore types that show different behaviors. Because of this, cyanidation control is more complex than for a typical milling operation. In 1992, a Cyancor™ on-line « free cyanide » analyzer has been installed for monitoring and optimizing cyanidation. This implementation significantly reduced cyanide consumption for the overall cyanidation process. In order to further reduce cyanide costs, an automatic control strategy has been implemented to decrease fluctuations of« free cyanide » from their set points.This paper outlines the major steps of the project: process control audit, control strategy development, implementation and running-in period. Control strategy features include data filtering modules, adaptive PID algorithm and set points management modules are also presented. Finally, the strategy efficiency is illustrated with load-disturbance responses.IntroductionLocated in northwestern Quebec, the Yvan-Vézina plant has an average capacity of 1300 t/d using carbon-in-pulp technology. In 1991, the Yvan-Vézina gold plant was processing three types of ores (Beauchemin, Mouska and Silidor mines) and a pyrite concentrate (Beliveau mine). A cyanide reduction program was then undertaken to reduce « free cyanide» fluctuations <6>. To reach this objective, the optimum cyanide concentration was determined for each ore, a continuous monitoring method with the Cyancor™ on-line analyzer was developed and a tighter control of cyanide addition was applied. These modifications to the leaching practice significantly reduced cyanide consumption.After a while, it was observed that regulation of « free cyanide » concentrations could still be improved by the use of an automatic control strategy. Yvan-Vézina and CRM began collaborating in 1995 to develop and implement such a strategy. Results show that main disturbances of the circuit (e.g. ore mineralogy and pulp feed rate) can be significantly overcome in order to reduce their effects on the leaching operation."

Jan 1, 1998