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By Ferrin Prince

New Gold?s New Afton mine is an 11,000 tonne per day block caving mine, located 8 km west of the city of Kamloops, British Columbia. The reserve is estimated at 52.5Mt with grades of 0.65 g/t Au and 0.93% Cu. Block caving requires a considerable amount of infrastructure development before production can begin. Each excavation had its own challenges, often further complicated by interactions with the caving stresses and fault structures. The main areas of interest were: the production crusher complex, the surface to underground infrastructure, and the footprint interaction with the faults. The ore zone at New Afton is bounded by two very weak fault zones, with large fault affected areas and associated splays. The resulting rock mass rating (RMR) is 35-50, with some areas significantly weaker due to clay infill. These conditions created a unique and decidedly difficult environment in which to develop New Afton?s infrastructure. Despite these difficulties, the mine began production on schedule in July 2012. The main production crusher for the mine is a gyratory crusher that allows for direct truck dumping, with a smaller jaw crusher in series to facilitate the initial development and production. The crusher chamber was redesigned several times to minimize the chamber volume, resulting in a 40% decrease in volume without losing functionality. After drilling and geotechnical testing, the location of the crusher was changed to eliminate the threat of fault affected ground in the area; the entire complex moved a short time before mining began on the chamber. The mining techniques used enabled tight control of the crusher pocket excavation, while also allowing for the timely completion of the chamber. The locations of the surface to underground infrastructure were tightly constrained by geology, surface infrastructure, and an existing open pit. The VR5 raise was drilled and abandoned part way through the reaming process when the drill string became stuck in fault gouge material. It was relocated and successfully completed. The VR7 raise hit a region of poor rock strength and deviated more than 11 m. Poor ground conditions caused a 130m section of the raise walls to fail. An innovative rehabilitation program was undertaken to re-establish the raise for ventilation. A surface to underground slick line was also installed to ease the material movement underground. A layout of the Extraction level was changed from herring bone to straight through drawpoints that resulted in a net reduction of 1.3 km of development. The Apex level was added to aid in the breakage over the major apex pillar and allow for geological mapping. A portion of the caving footprint is located within the footwall fault. The low strength, high clay content, and small joint spacing of the material resulted in blast-hole cut-off and drift deformation. Drift rehabilitation was a key factor in the successful development of the cave footprint. Innovative drilling and loading techniques were used to keep the holes open and to impede movement along the joint structures.

Aug 1, 2013

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By A Hitchen

A general outline is given for the determination of copper, nickel, cobalt, zinc, lead, cadmium, bismuth, manganese, uranium, molybdenum, vanadium, sulphate and fluoride by polarographic or amperometric methods in a variety of ores or metallurgical products. The detection of oxygen in gas mixtures by an amperometric method used as a safety device is also discussed. Introduction I N this paper, a general outline will be given of the polarographic and amperometric methods used for the chemical analysis of various ores and metallurgical products in the Chemical Analysis Section of the Extraction Metallurgy Division of the Mines Branch. The methods to be discussed will be confined to those based on the use of normal D.C. polarography and will not include those methods which utilize a cathode-ray, square wave, pulse or A.C. type of polarograph. For the sake of convenience, ? the polarographic methods will be discussed according to the type of supporting electrolyte employed, as the same electrolyte may serve to determine more than one element in more than one type of ore. Amperometric methods will be discussed according to the element to be determined rather than

Jan 1, 1965

By C. E. White

The depletion of higher grade mineral reserves will accelerate the trend toward production from progressively larger and lower grade deposits. The discovery of adequate reserves of leaner ores will require the development of improved exploration techniques with a greater depth range. The principal challenges to the Canadian mining industry are to find the mineral resources required to meet fast growing world demand and to develop mining methods and equipment to ensure production costs which will strengthen our position in export markets in the face of in-creasing world competition. The challenges cannot be met without intensive efforts to attract more technical men to the industry and to improve their training.

Jan 1, 1967

By Murray Pearson, Jack Murray

"The danger of autoclaves lies in the high temperatures and pressures that exist in autoclave vessels. The usage of autoclaves will continue to expand in the mining industry because of their efficiency and environmental friendliness. But increasing attention must be paid to ensuring their safety. Safety Instrumented Systems (SISs) play a critical role in autoclave plants by detecting potentially dangerous conditions, taking the plant to a safe state, informing the operator about the plant status and the cause of the trip and expediting safe plant restart. The SIS should ideally be fully integrated with but functionally independent of the Basic Process Control System (BPCS) and provide redundant logic solvers to increase safety and plant availability while reducing spurious trips.INTRODUCTIONWikipedia defines an autoclave as follows: “An autoclave is a pressurized device invented by Charles Chamberland in 1879 designed to heat aqueous solutions above their boiling point to process materials.” A typical autoclave system used in the metallurgical industry includes, besides the autoclave vessel, heat recovery (heater) vessels, high pressure positive displacement (HPPD) feed pumps, vessel lining systems, specialized internals and components, agitators, pressure letdown or flash vessels, isolation and control valves, over 2,000 I/O points and related instrumentation, and emergency relief systems."

Jan 1, 2009

By J. C. Gilbert

"IntroductionTHE PURPOSE of this paper is to discuss in a general way the heavy oil situation in Western Canada, and particularly to acquaint those in the oil industry who have not participated in the heavy oil end of the business with past and current developments. The author has covered •briefly the location of the heavy •and asphalt-base oil fields, their geology, current drilling and production practice, the location of the •refineries capable of handling heavy crude, their products and markets, and the problems and future prospects of the industry.Location and Description of FieldsThe term heavy oil is generally used to denote crude of 20.9° gravity and under. Since the products from heavy oil are also to a lesser extent obtained from asphalt-base crudes of higher gravity, some mention will be made here of the latter; but in general the emphasis of the paper is on heavy oil as such.In the order of their production to date, the heavy oil fields and those light oil fields which produce asphalt-base crudes are : Lloydminster, Taber, Vermilion, Conrad, Princess, and Wainwright.The Lloydminster oil field has not only produced most of the heavy oil, but also is currently the largest producer, supplying at the present time about 80 per cent of the heavy and asphalt-base crudes produced in Western Canada."

Jan 1, 1952

By E. M. De Souza, A. M. Coode

"When Canadian potash was brought into production in the 1960s substantial research was carried out to develop the technology needed to cope with the unique conditions in Saskatchewan mines. The intense research has established Saskatchewan's position as a leader in production technology on a world scale, and as a leader in setting international standards for potash production. The industry is now more than two decades old and, although the mines operate efficiently, there are a number oj prominent areas of concern. High among these is the prediction, prevention and control of sodium rich brine inflows. Control has proven difficult or elusive in the potash mining horizon, but work continues in this area. Control of brine in the superincumbent limestone formation has proven to be easier and more conclusive.The first part of this paper describes the rehabiltation, diamond drilling, and grouting completed at Central Canada Potash, which reduced the brine inflow from approximately 82 l/min . at the beginning of the work to O.9/1min. when the backfilling was placed.The second part of the paper describes the rationale for choosing the rock mechanical instrumentation, the reasons for their placement and the rock mechanical data recorded with some interpretation.IntroductionCentral Canada Potash is located approximately76 km southeast of Saskatoon, near the Yellowhead Highway. The commercial production of potash at CCP started at the end of 1969 at a depth of 1021m below surface. The potash zone, which is presently mined, is approximately 3.35 m thick . Stress relief methods using yielding pillars are used in the design of the mining layouts. The planned extraction ratio averages 35070 . The mine is designed to produce approximately 3.3 million tonnes of sylvinite per year to give approximately 1.3 million tonnes of finished product (muriate of potassium) per year."

Jan 1, 1990

"Far from being eclipsed by petroleum and natural gas, Canadian coal continues to command wide (and apparently growing) interest.Major R & D investigations are currently heavily oriented toward coal beneficiation (e.g., cleaning and utilization of fines) and toward a broad range of studies on metallurgical coals and cokes. However, active work is also being carried out in the areas of coal geology, mining, transportation and combustion; and, in some laboratories, increasing stress has been laid on developing a number of new, essentially non-fuel uses for coal and coal products.This review summarizes the work of Canadian coal research agencies during 1966 and indicates some of the more important advances made by them."

Jan 1, 1967

By A. W. Davis

"The Red Rose mine is in the Rocher Deboule mountains about 8 miles east of Skeena Crossing and a like distance south of the town of Hazelton; the most northerly settlement on the Prince Rupert line of the Canadian National railway and 177 miles northeast by rail from Prince Rupert. The mine workings are on the north side of Balsam or Red Rose creek; a tributary of Juniper creek that drains via Kitseguecla river into the Skeena near Skeena Crossing. A truck road 11 miles long extends from Skeen a Crossing (elevation 650 feet) to the Red Rose mill (elevation 4; 100 feet). The mine workings lie between 5; 600 and 6; 300 feet above sea-level. Mine and mill are connected by a 1-mile aerial tramway and a tractor trail.The Red Rose claims were staked about 1910 by prospectors attracted to the district by the construction and near completion of the railway between Prince Rupert and Jasper. For a number of years interest centred in prospecting a sheared zone exposed in a ravine between elevations of 5,425 and 5,825 feet. Several adits were driven and some high gold assays were obtained in vein quartz in the sheared zone, but this work did not develop sufficient ore and the property finally closed down. In the early twenties of this century tungsten minerals were discovered in the northern extension of the vein, but nothing was done to test this deposit. Finally, in 1940, spurred by the wartime demand for tungsten, the Consolidated Mining and Smelting Company of Canada drilled the tungsten-bearing vein, and although results were none too encouraging, underground work was begun in June 1941. The latter work disclosed substantial amounts of ore. A small mill, subsequently enlarged, began operation early in January 1942 and by the autumn of 1943 some 1,194,000 pounds of tungsten concentrate had been recovered. Mining ceased in November 1943 because of orders from the Metals Controller that no more shipments would be permitted."

Jan 1, 1954

By F. Kitzinger

Electromagnetic testing of wire rope has become more and more reliable over the past two decades. This improvement is partly a result of an unprecedented progress of electronic technology, which permitted the development of a new breed of testing instruments. There are two basic methods for the electromagnetic testing of wire ropes, the AC method and the DC method. Both methods rely on magnetic field disturbance caused by mechanical anomalies in the rope structure. The wire rope under test is passed through a magnetic excitation field, which can be a weak alternating field or a strong static field. Because the alternating field is produced by an alternating current, these instruments are of the AC type(l). In the early days of ND-testing, strong permanent magnets were not yet available; therefore, the static magnetic field was produced electromagnetically with direct current. Instruments based on static excitation are still called DC instruments(2), even though the field is now produced by a permanent magnet. Both these methods have certain characteristic features. The AC method can detect loss of metallic area caused by corrosion or other effects, whereas localized faults such as broken wires are better detected by the DC instruments . The basic principles of the wire rope testers have remained unchanged over the years and the improvements present in the new instruments usually reside in the signal processing and recording sections. The Instrumentation Department of the Noranda Research Centre* has been involved in a four-year development program which resulted in a new type of wire rope tester, the Magnographv** . This new instrument in many ways represents a considerable departure from the traditional wire rope testers. The Magnograph has already been patented in Canada and the U.S.A.(3), and patent applications are pending in other countries.

Jan 1, 1979

By P. Erskine

"Hyperaccumulator plants can be utilized as ‘metal crops’ in agromining operations. This emerging technology produces ‘bio-ore’ by growing ‘metal crops’ on sub-economic ore materials, such as natural ultramafic soils. In a typical application plant material is periodically harvested, followed by air-drying and incineration to produce the bio-ore intermediate. The bio-ore is of very high grade (>15 wt. % nickel), and of high purity, and may be processed into a number of different products (including nickel metal, nickelbased catalysts and pure nickel salts). Current research efforts from our team focus on Mediterranean climate field trials (Albania, Spain) and tropical climate field trials (Malaysia, Indonesia). Field-scale demonstrations are required to provide evidence of real-life performance and of economic viability. If the trials are successful, agromining may in the near future support local livelihoods with income opportunities as an alternative type of agriculture: to farm nickel.INTRODUCTION AND BACKGROUNDHyperaccumulators, plants with the exceptional ability to uptake and concentrate trace elements in their shoots, can be utilized as ‘metal crops’ in agromining operations (Van der Ent et al., 2013a; Chaney et al., 1998; 2007; Baker et al., 2010). Agromining produces ‘bio-ore’ from harvested ‘metal crops’ grown on unconventional resources such as natural ultramafic soils (Van der Ent et al., 2015a). The bio-ore is a high purity and very high-grade (>15 wt. % nickel) product intermediate that may be turned into a range of different nickel products (nickel metal, nickel-based catalysts and pure nickel salts). The potential for agromining is greatest in tropical regions (Asia-Pacific Region: Indonesia, Malaysia, Philippines, Papua New Guinea and New Caledonia) where very large expanses of ultramafic soils exist (Van der Ent et al., 2013b). Agromine operations may replace existing marginal agriculture on poor ultramafic soils, for example oil palm plantations that require high fertilizer inputs to be profitable, or take place under a cocropping regime. The ability of ‘metal crops’ to achieve high nickel concentrations in biomass (and hence in harvested bio-ore) from soils with just <0.5 wt. % nickel, makes it possible to access non-conventional resources, not accessible by traditional mining techniques. For example, agromining could be implemented both on the large ‘halo’ around the mine leases, and as part of the progressive rehabilitation process after conventional resource extraction. As with all methods for resource extraction, agromining will be finite due to the diminishing concentrations of nickel in the zone accessible by plant roots (Chaney et al., 2014). Nevertheless, considering soil materials with 0.2 wt. % nickel and ‘metal crops’ with a yield of 100 kg nickel ha-1 the agromining venture may be sustainable for decades (Van der Ent et al., 2015a)."

Jan 1, 2016

By T. R. Chari

The safe-level dilution of low-level radioactive wastes in large volumes of selected granular material is proposed as an alternative method of permanent waste disposal to current Canadian practice of concentration and encapsulation. Accepting the fact that a "background level" of radioactivity exists throughout the world, the authors feel that the concept of controlled dilution of radioactive wastes to a level in keeping with "background" is a plausible alternative to current thinking on the subject and is worthy of equal consideration.

Jan 1, 1979

By L. K. Walker, G. A. Kosick, P. D. Young

"MillEX is an information management system designed by mineral processors for mineral processors. The system utilizes ""cutting edge"" software technology to gather and store all automatically and manually recorded data from the plant operation and laboratories. This data is delivered to the desk of superintendents, metallurgists, technicians and managers, and permits the user to query, correlate, graph, report and present this data in minutes. In the past this task would have taken days and even weeks of tedious work to complete.MillEX allows the engineer/analyst to quickly develop a very thorough understanding of the complex relationships of process variables and equipment that exist in the plant, and their effect on product quality and quantity. The time and resources that are currently wasted on duplicating data entry will be an effort of the past.This paper describes the structure of MillEX and how it conforms to the needs of mineral processing personnel.INTRODUCTIONPicture a personal computer on your desk which will carry out the following commands:1. Plot a graph over the last six months, using weekly averages, of percent minus 200 mesh material in the primary cyclone overflow.2. Overlay this graph with a graph of concentrate grade versus recovery over the same time period.3. Retrieve a prior month end report, update all operating supplies tables and metallurgical performance with this months data, and embed the graphs created above.4. Edit text and print the current month end report. This is only one example of the type of power MillEX isbringing to the mineral processing industry."

Jan 1, 1992

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Alan Rice

The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultrama?c igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on ?uid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other ?elds dealing with suspended loads in ?uids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By Laxman M. Amaratunga, Glen G. Hein

"Most mining operations utilize the tailings coarse fraction for backfilling while the fines have been traditionally disposed on surface in tailings ponds. Recently, paste fill has been developed which uses a fraction of the fine tailings (10-30% w/w of <45 µm) in the fill (Brummer and Moss, 1991). This development allows a mining company to use a portion of the fines for backfill, but still requires surface impoundment of the unused tailings. Reactive tailings have the added problem of generating acid after being oxidized in the presence of air and water. Treating acid mine drainage (AMO) from these ponds has proven to be a costly environmental problem and a long term liability.One practical method to reduce the environmental impacts associated with the tailings pond is to modify the physical and chemical prope1ties of the fine tailings so that they can be utilized in an environmentally safe manner. This was accomplished by agglomerating the tailings into pellets and using theses pellets as a coarse aggregate in a total tailings paste fill. This technology does not require any supplemental sand or gravel to be added to the fill.This paper presents the ongoing research into utilizing these tailings agglomerates as a coarse aggregate fraction, in order to create a total tailings paste fill which has supe1ior strength characteristics.IntroductionThe Canadian mining industry produces more than 500 million tonnes of tailings and waste rock annually. The waste rock is usually returned underground for use as rock fill in underground support with the tailings remaining to be disposed of in tailings ponds. Tailings consist of a coarse and fine fraction, and can be either reactive (acid generating) or non-reactive. In an effort to minimize tailings disposal, the coarse fraction has been used underground in backfill along with alluvial sands. This diversion of the coarse fraction, however still requires that the fine fraction be disposed of in tailings ponds. This disposal creates the potential for acid mine drainage (AMO), since in the presence of air and water, reactive sulphide tailings can generate acid. It is therefore an important goal in the mining industry to minimize the disposal of fine tailings into tailings ponds since the treatment of AMO is a costly and long-te1m environmental liability."

Jan 1, 1997

By Linlin Tong, Xiangling Song, Guobao Chen, Zhenan Jin, Hongying Yang

Biooxidation of a high arsenic-bearing refractory gold ore was investigated to determine the arsenic removal efficiency by the cultured bacteria and to examine the effect of biological pretreatment on subsequent gold cyanidation. The biooxidation pretreatment process utilizes the ability of adapted acidophilic bacteria to oxidize pyrite and arsenopyrite and release the encapsulated gold. The released gold can be efficiently extracted by the subsequent cyanidation process. The biooxidation experiments were conducted with cultured bacteria using various sizes of agitation tanks. Leaching results showed that over 96.26 % arsenic extraction could be obtained from this ore after 6 days of bioleaching with continuous stirred tank reactor (CSTR). Gold extraction during the cyanidation process was increased from 29.35% to 96.71% after biological pretreatment. The content of arsenic in the biooxidation residue was reduced to below 0.3%. The transformation process of As was considered as [AsS]2- ? As (?) ? As (?) during the biological pretreatment.

Jan 1, 2014

By Javier Ramirez

"Recent R&D pilot plant testing was done to validate a full industrial scale system for recovering residual magnetite from the tails of an iron ore concentration plant. The recovery system is based on an autogenous heavy media separator treating a tailings slurry at 0.45% solids by weight. A 3,100 m3/h capacity concentrator was installed based on the testing findings. Excellent metallurgical results have been observed in two years of continuous operation. This experience is the basis for the proposal of a novel process consisting of the preconcentration of base metals ores; the idea being to obtain a heavy bulk concentrate of the polymetallic minerals and discarding in one step the light gangue mineral components. The bulk concentrate then proceeds to conventional froth flotation. The reduced volumetric flow of the bulk concentrate allows a reduction in the size of the subsequent flotation circuit. A prerequisite for the heavy media separation is a fine size grinding of the ore and a correspondingly high degree of liberation of the mineral species to be recovered. A process scheme is also presented in which the gravity concentrator works in conjunction with a companion tailings thickener for process water recovery. The underflow from this thickener, having paste consistency, can be sent to a tailings dam or mixed with Portland cement for mine backfill. The process water in the system is managed at an estimated recovery in excess of 98%. Additional R&D work using this novel approach is being considered by a large iron ore concentrator for removal of liberated silica from the final concentrate; and for upgrading 3.5 million tons of a marginal hematite reserve owned by the mining company.INTRODUCTIONGravity preconcentration (static and dynamic) of sulphides prior to froth flotation has been and is being practiced at various concentrator plants (Asarco´s Young Mill: heavy media cone; Mount Isa: DSM cyclone; Afton Mines: Denver jigs; Tsumeb Mine: Reichert cone) (Burt, 1984). The idea behind installing preconcentration equipment is to reduce the volume of feed processed on flotation, thus requiring smaller flotation plants although other advantages may be of importance, such as obtaining richer concentrates due to higher grade feed, better process water and energy management, and reduced flotation reagent consumption.The SedconTM solid/liquid separator is a versatile process unit patented in Mexico (MX/u/2007/000305). As a gravity device, it may be classified as an autogenous heavy media dynamic concentrator. Figure 1 depicts the Sedcon (Sedimentador de conos) separator. The four main components are as follows: the feedwell for efficient mixing of the pulp with dilution water and flocculant (and coagulant for water clarification); the inner cones (passive elements for solid/liquid separation); the discharge underflow cone; and the scraper mechanism. The standard discharge cone is a 60° inclined cone for general applications. For paste tailings thickening applications, a deep cone with a 69° inclined cone is used."

Jan 1, 2016

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999