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By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By Neal Harries

Ground movement is normal in open cut mining operations, mainly caused by excavation response and blasting. Movement of the ground can be acceptable provided it is not unexpected and catastrophic. However, in steep mine walls and the very large open pits being developed today the consequence of slope collapse can be catastrophic. Such risks can be minimized at the planning stage by reducing slope angles, but this carries a very high cost. Also, instabilities which develop whilst mining can lead to ore reserves being quarantined, which represent a high cost to the mining operation. In spite of such safety measures, unexpected failures have occurred in the past. These issues motivated the development and production of the slope stability radar (SSR). There are currently over 80 GroundProbe SSR systems deployed in metalliferous and coal mines in 17 countries. The unexpected failure of rock walls at mining sites is a major cause of death and serious injury. Slope failure is also one of the major causes of economic and production losses. An unexpected wall failure can bury critical equipment. It also disrupts the mine plan. It is common to cease mining for several days or weeks following a wall collapse due to uncertainty over stability. Direct economic losses in remediation alone can easily exceed $1,000,000 per incident. The economic costs of injury or fatality are much higher including closure of mines during the incident investigation process. Massive wall failure can result in direct and indirect costs measured in millions of dollars. This paper will present some recent case studies of the SSR operation in open cut mines in North America, including Thompson Creek Mining Company (Idaho), Smoky Canyon Mine (Idaho), and a general case study on extreme cold weather use of the SSR.

May 1, 2009

By Th. Hassel

The application of magnesium as an absorbable biomaterial demanded the consideration of the alloy composition, the mechanical properties and the corrosion a special adapted material development in terms of the human biological system. Magnesium for technical applications mostly comprised alloying elements up to 10 wt%. Thereby often metals (e.g. rare earth and aluminum) with high toxic potentials are used to optimize the mechanical properties. To minimize toxic reactions during the degradation of a absorbable magnesium alloy, the Mg-Ca system is being selected and investigated because both elements belong to the mineral nutrients. Rods and small tubes are produced by extrusion of gravity die casting billets (Ca-content 0.4 to 4.0wt%). The positive grain fining influence of calcium and its improvement of the corrosion behavior are additional advantages. The microstructure, the mechanical properties and the corrosion attitude are investigated. The results show that an optimal composition of micro alloyed Mg-Ca and ideally processing parameters lead to 16% strain and a tensile strength up to 185MPa. Electrochemical investigations and measurements of the hydrogen production demonstrate the influence of the Ca-content to the corrosion behavior of the investigated alloys.

Jan 1, 2006

By William M. Luff

"The Bathurst area has recorded mining production as early as 1837, although the bulk of the production has come in recent years. Production has been mainly from the well-known massive sulphide deposits, but vein, gossan, and a variety of other deposits have also been mined. This paper summarizes the history of the mined deposits, along with tonnages and grades produced.A number of ""firsts"" have been noted in the Bathurst area. The A Zone deposit, located in the Heath Steele area, was the first in the world discovered using airborne electromagnetic methods. Heap leaching of gold from the gossan zone at Caribou was the first operation of its kind in Canada. The Keymet mine was the first base metal (lead-zinc) mine in New Brunswick. For the past few years, the Brunswick No. 12 mine has been one of the largest zinc mines in the world.IntroductionThe Bathurst area (Fig. I) first had mining production in 1837 when copper was mined from a deposit on the Nepisiquit river (MacKenzie, 1958). The majority of the production, however, has been in recent years from massive sulphide deposits, but there are also other significant operations.Table I is a summary of Bathurst area mineral production, showing concentrator feed tonnages and mill feed grades. The table does not include peat deposits, sand and gravel, dimension stone or rock quarries. Figure I is a general geology map of the Bathurst area, indicating deposit locations. The deposits are divided into four categories: massive sulphide, vein, gossan and other. The deposits in each category are described in chronological order of exploitation."

Jan 1, 1995

By William M. Luff

"The Bathurst area has recorded mining production as early as 1837, although the bulk of the production has come in recent years. Production has been mainly from the well-known massive sulphide deposits, but vein, gossan, and a variety of other deposits have also been mined. This paper summarizes the history of the mined deposits, along with tonnages and grades produced. A number of ""firsts"" have been noted in the Bathurst area. The A Zone deposit, located in the Heath Steele area, was the first in the world discovered using airborne electromagnetic methods. Heap leaching of gold from the gossan zone at Caribou was the first operation of its kind in Canada. The Keymet mine was the first base metal (lead-zinc) mine in New Brunswick. For the past few years, the Brunswick No. 12 mine has been one of the largest zinc mines in the world.IntroductionThe Bathurst area (Fig. 1) first had mining production in 1837 when copper was mined from a deposit on the Nepisiquit river (MacKenzie, 1958). The majority of the production, however, has been in recent years from massive sulphide deposits, but there are also other significant operations. . Table 1 is a summary of Bathurst area mineral production, showing concentrator feed tonnages and mill feed grades. The table does not include peat deposits, sand and gravel, dimension stone or rock quarries. Figure I is a general geology map of the Bathurst area, indicating deposit locations. The deposits are divided into four categories: massive sulphide, vein, gossan and other. The deposits in each category are described in chronological order of exploitation."

Jan 1, 1995

By D. O. DeGagné, J. F. Archibald

Spray-on polymer linings, as partial or full replacement for traditional forms of area rock support, have seen rapid growth in interest within Canada. A wide variety of lining types, ranging from polymer chemical to water-based cementitious materials, have been developed and commercially introduced to the underground mining market. Following approximately one decade of development work, several general conclusions have been reached regarding the performance of this class of area support media, these being that: health and safety assessment of the broad range of materials has shown the majority of them to be acceptable and safe for underground use; significant ground support potential can be offered by them, being equivalent to or better than capabilities offered by traditional support forms such as bolt-and-screen or shotcrete, and; their abilities to be rapidly deployed and provide near instantaneous support restraint offer considerable operational and cost benefits to underground operators. A review of currently available liner materials, their historic development within the Canadian mining industry, and overviews of support, health and safety, operational considerations and cost benefits are provided in this paper.

Jan 1, 2001

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001

By Funsho K. Ojebuoboh

With several “green” applications on the horizon, bismuth has become an even more important minor metal in the smelting and refining of lead. Smelters with a complex sulphide feed invariably deal with bismuth. Its behavior during the smelting of lead in conventional sinter-blast furnace operation is discussed. Because it readily deports to the lead phase during the refining of lead, its separation from refined lead remained unsatisfactory in early lead production. When commercial requirements of bismuth in lead became more stringent early this century, the procedure where by calcium and magnesium is used todebismuthise lead was developed. The present conduct of this 1936 process, the Kroll-Betterton process, is discussed with emphasis on operational improvements.

Jan 1, 1996

By A. Warczok

The mechanisms and kinetics of copper oxidation and reduction have been investigated in small scale thermal gravimetric experiments as well as in laboratory pilot scale, packed bed reactors. With blister copper flowing gravitationally down through a packed bed of ceramic particles, counter-current to low oxygen containing combustion gases, the rate of oxidation was found to be very high due to the large surface area created. Similarly, reduction by flowing copper through a packed bed of charcoal lead to rapid de-oxidation. Based on these laboratory measurements, fundamental rate data have been obtained. Modeling of industrial sized packed bed reactors using the laboratory results, opened up the possibilities of developing a new, very intensive, continuous process for copper fire refining. The developed mathematical model together with a computer process simulator, allowed for the design of the industrial-pilot installation to be built and tested at the ENAMI Paipote smelter in Chile.

Jan 1, 2007

By John T. Whetton

"FROM 1850 when the annual production was around 50 million tons, coal output in Great Britain expanded rapidly to 225 million tons in 1900 and 287 million tons in 1913. However, during the First World War, countries which had previously bought large quantities of coal from Britain sought other sources of sup-ply or developed their own coal re-sources. Thus from the record figure of 73 million tons exported in 1913, Britain's coal exports declined until in 1938 they stood at 39 mil-lion tons. An important reason for this was the development of oil engines for marine propulsion. Today, nearly all the navies and mercantile shipping in the world have turned to oil engines. Sometime in the future, however, it is reasonable to expect nuclear power to replace oil.During the Second World War, coal output in Great Britain and manpower at the mines were reduced considerably and in 1.945, 175 mil-lion tons were produced by 709,000 miners. Exports were meagre, only 8.""7 million tons went to foreign consumption. During the severe winter of 1947, inland demand for coal exceeded production and exports were prohibited. Even importation of coal was required to meet inland demand. These were years when the coal industry of Great Britain made immense efforts to secure maximum output irrespective of economy. The energy needs of Great Britain appeared insatiable; but had it been possible to export, the nationalised mining industry could have made huge profits as there was a world shortage of coal. However, home needs were considered to be the priority and many overseas markets were lost. Other producers moved in and secured long-term contracts. Not only was the British export market lost, but also the nationalised industry had to sell the imported coal at the same prices as home-produced coal and suffered losses up to of:3 per ton. Bence, at a time when the National Coal Board might have ac-cumulated a reserve fund to cope with less prosperons times, it was having to spend large sums of money securing sufficient coal for inland consumption. This was a time when intensive efforts in the mining industry, comparable with those of many industries and establishments inclusive of the armed services during the war, would have produced a greater amount of coal and have been of immense value to the country as a whole."

Jan 1, 1960

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

By J. A. Hudson

"The paper begins with a brief summary of Professor Müller’s formation of the ISRM and the contents of the previous six Müller lectures with their emphases on rock fractures. The geological origin of fractures is described via a deformational spectrum diagram and a matrix characterising the consequences of a sequence of superimposed deformational events. The different fracture frequencies encountered along lines in all directions through a fractured rock mass are explained. The value of computer modelling and simulation is demonstrated through an example of the effects of fracture zones on the distribution of the in situ stress field. The need to establish the validity of computer programs, i.e., that the modelling/simulation, does actually represent the rock reality, is discussed with reference to the work of the DECOVALEX project. Finally, examples are given of the effects of rock fractures on engineering design and construction, from pre-split blasting to caverns.INTRODUCTIONIt is a great honour to have been chosen as the recipient of the ISRM 7th Müller Award and I am grateful to the representatives of the International Society for Rock Mechanics (ISRM) National Groups who voted for me. In addition, I am especially pleased because my working life in rock mechanics and rock engineering has been devoted to understanding the geometry and mechanical properties of rock fractures and rock masses—which were the key subjects that Professor Müller promoted. In the ISRM 50th Anniversary Commemorative Book, Hudson and Lamas (2012), Professor Charles Fairhurst notes that on 24 May 1962, i.e., the day before the constitutional meeting of the ISRM took place in Salzburg, a reporter asked Professor Müller, “Do we know the strength of rock?”, to which Professor Müller replied, “For rock tested in the laboratory, yes. For a rock mass, no. This is what we need to determine. This is why we need an International Society for Rock Mechanics”. Also, in his Opening Address at the 1st ISRM Congress in Lisbon, Professor Müller, as the then ISRM President stated,“Many experts agree with me that discontinuity and anisotropy are the most characteristic properties of the material rock and that the properties of jointed media depend much more upon the fabrics bond of the unit rock block system than upon the rock material. Therefore any theoretical investigation of that material has to go its own ways, in the same way as the construction material of soils years ago suggested to soil mechanics its own methods, which differ greatly from the way of thinking of technical mechanics”."

Jan 1, 2015

By A. Chieregato, C. G. Oñate Salazar, D. Martinelli, D. Peila, M. Barbero

This paper is aimed to confirm the possibility to excavate fractured rock masses by using EPB shields, even in presence of relevant water tables. This verification is based on laboratory test experiences carried out at TUSC laboratory of Politecnico di Torino, where the natural material is tested in order to verify the suitability of a certain conditioning technique in particular conditions. This is due to the fact that every case should be studied apart from existing studies on a certain rock type, as other factors such as fragmentation of the rock mass, natural water content and porosity of the rock can considerably influence the final result of the conditioning process. The most important aspects that allow to consider the conditioning of fractured rock masses as suitable are: possibility to create a plastic paste that can transmit the pressure at the front in a effective way; reduce the permeability of the spoil material in order to reduce the possibility of water leakage inside the chamber and eventually in the tunnel; verify the consistency of the conditioned material for the extraction through the screw conveyors and the belt conveyors. For this research an argillitic schistose rock mass, with some quartzitic and calcareous inclusions, has been studied by using different level of conditioning in order to verify the suitability of an eventual EPB excavation through this formation.

Jan 1, 2015

By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée.AURIX®100 RESINAuRIX100 resin is a crosslinked polystyrene alkaline resin developed by Henkel (Virnig, Mackenzie, & Adamson, 1996). The resin beads are off-white in colour and spherical, with a nominal size of 100% +600 µm. This resin is highly selective for gold and silver over many metals, by way of extracting precious metal–cyanide complexes from leach solutions with a pH of less than 11.5. The higher end of the pH scale produces the best selectivity according to the order of preference: Au > Ag > Hg > Zn > Ni > Cu > Co > Fe. Purolite produces the resin and Gekko Systems maintains licensing of AuRIX100 resin for use in its G-REX column, as part of its unique suite of gravity gold–handling equipment.Significant cost savings over carbon-in-solution (CIS) systems are realized with AURIX100 resin: approximately 4–12% in capital savings and 27–40% in operating costs (Virnig, Mackenzie, Katsikaros, & Gray, 2004). Additionally, AuRIX100 resin is not susceptible to fouling; that is, the resin does not load with inorganic salts or organic compounds that would affect the loading and extraction of precious metals. To counter any potential for fouling by inorganic salts, a dilute acid wash is periodically conducted in service on the resin to unblock resin pores."

Jan 1, 2017

By M. Hawker, M. Kreuh

The mining and metallurgy industry is known to be of cyclical nature associated with price volatility. As such, some years are quite lucrative and other years require mining companies to tighten their belts. The field is a mix of junior, mid-tier, and major mining companies. One thing that is common to all of them is the time required and the cost to develop a flowsheet in accordance with best practices. Although a long list of factors can impact flowsheet development, this paper will include the impacts of: experienced metallurgical engineers and laboratories, representative samples for high quality and valuable testwork results, and following engineering development stages. The paper also provides typical time frames to complete selected engineering flowsheet development steps.

Jan 1, 2014

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By A. Lopez-Valdivieso

Particle size enlargement processes play an important role in solid/liquid separation, and in beneficiation unit operations. In the latter, not only the size of the formed aggregates but also their surface properties are very important. Oil agglomeration has a special place among such processes: it is a selective process in which hydrophobic particles are agglomerated into hydrophobic agglomerates which can be recovered by flotation. This explains the broad applications of oil-assisted beneficiation processes not only in the beneficiation of fine coal, but also in agglomerate flotation of many different types of ores, and in coal/gold agglomeration.

Jan 1, 2004

By Graham Davey

"Ultrafine grinding of minerals has been in wide spread use in the industrial mineral field for over 30 years. Within the last 10 years the metalliferous industry has shown interest in the ability to produce ultrafine particles, as chemical, physio-chemical and physical separation processes have advanced to be able to treat ultrafine metalliferous particles. Also as the primary mineral deposits are depleted, new more difficult deposits must be mined. Existing operations are also looking to maximize economic return from existing deposits, requiring new thinking and technologies.The recent development of industrially proven and cost efficient technologies for ultrafine grinding has opened up another processing option for the treatment of finegrained metalliferous and refractory gold ores. The current commercial designs are variations of stirred mills used in the industrial minerals sector for the past 30 years. For the purposes of this paper ultrafine grinding is considered to be P80 of less than 15 microns.Attrition milling to fine grind sizes presents some challenging issues relating to scale-up including the dearth of information on the quantitative impact of feed and operating conditions, as well as the precise and accurate measurement of particle size distributions. Two examples from recent installations will be analyzed including Thalanga Copper and Century Zinc Mines. Both have diverse grind size targets for the SMD, yet both have realized significant metallurgical gains."

Jan 1, 2002

By P. A. Mascaró, N. Chacon, A. A. Cecchi

"This document shows the development of a system called the “On-line charge level determination in SAG mills” (abbreviated as Jc). The Jc variable has certainly been difficult to measure due to the relevant number of factors and variables that affect the grinding phenomena inside semi autogenous (SAG) mills. To assess the feasibility stage of the proposed system, it was necessary to carry out two tests in different sized SAG mills, 38´ × 22´ and 36´ × 15´, respectively. In each test, the system was configured with a battery of sensors of the following types: (1) strain gauge, (2) accelerometer, and (3) gyroscope. The first step involved for charge level determinations was to determine kidney foot and shoulder by means of a study of the energy-impacts on shell structures. The second step consisted of correlating the measured grinding operational variables with the actual charge levels obtained from SAG mill crash stops. This system development is extremely useful and relevant for providing approximations about mass balances inside SAG mills. It will be a suitable tool for explaining “tonnes per hour” variations and determining optimal points under various operating conditions.INTRODUCTIONThere has been a growing necessity for technologies capable of obtaining “on-line data” of the main comminution variables in order to increase throughput. Computer systems have taken an important role in providing important solutions by means of processing on-line device signals (commonly referred to as monitoring). In semi autogenous (SAG) milling, there are many examples of monitoring devices that allow the operational staff to obtain detailed information both mechanically and electronically inside a grinding circuit. In this context, a new technology has been developed to obtain “Jc total charge (%) online” in two different SAG mills called Vibro-Energy® System.As part of the analysis performed by JKsimMet® the Jb/Jc was estimated because it has an important impact on SAG mill throughput. Different scenarios were simulated and contrasted at various theoretical Jb/Jc values in a baseline circuit (Figure 1)."

Jan 1, 2016

By F. C. Lendrum

Introduction The property of Normetal Mining Corporation is in Desmeloizes township, Quebec, twelve miles north of Dupuy on the main line of the Canadian National railway from Quebec city co Cochrane, Ontario. The ore bodies occur within a band of highly sheared and sericitized agglomerate which strikes N.60°W. and clips 82° north. Along a zone 1,000 feet or more in length and of variable width, the agglomerate has been replaced by copper, zinc, and iron sulphides, with copper usually predominant on the hanging-wall side and pyrite replaced in part by sphalerite on the footwall. A northsouth diabase dyke cuts through the ore zone near its east end. The Normetal mill produces a copper concentrate and a zinc concentrate which are shipped, respectively, to Noranda, Que., and Newcastle, Penn., U.S.A., for further treatment. The present paper deals with the milling of ore from what is known as No. 3 orebody. This is a lenticular body of high-zinc ore lying co the east of the diabase dyke, along the line of strike of the main ore zone, which extends westward from the dyke. On its northern side, No. 3 orebody is in contact along most of its length with a narrow band of copper ore which is highly oxidized.

Jan 1, 1948