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By S. Mamonov, V. ?shikhin

"The purpose of work was the significant increase of copper recovery from slag at a concentrating plant. Analysis of study of slag phase composition showed the perspective of a slow slag cooling method due to its recrystallization and transition of primary copper minerals to secondary.Copper content in base slag varied between 0.71 and 0.96%. The study of a degree of copper minerals release of the slowly cooled slag in comparison with a yielding slag showed that in a flotation size grade –0.071 mm of yielding slag the weight ratio of released copper minerals grains is 58.95% against 86.73% in samples of slowly cooled slag. The process flotation sheet consists of three main, one control and two cleaner flotation operations with aftergrinding of middling products. A reagent mode was differed from a factory one by decreasing the slurry pH from 11–12 to 8–9. This paper shows research results of the slurry alkalinity impact on technological indexes of beneficiation (flotation).Industrial testing of a resulted batch of slowly cooled slag at “SUMZ” concentrating plant showed the efficiency of such processing: copper recovery to a copper concentrate increased by 15–19%.INTRODUCTIONIntensive development of mining and metallurgy industries within a 250-year period in the Ural region led to forming of approximately 315 man-made mineral formations at the territory of the Sverdlovsk region. The region contain over 32.5 billion tons of barren rocks and out of balance ores, over 1.5 billion tons of tailings, over 115 million tons of slimes, and over 100 million tons of metallurgical slag (Demin et al., 2000). Latters, at average, contain 407 thousand tons of copper, 2519 thousand tons of zinc, 7 tons of gold, and 150 tons of silver (Rudoy et al., 2011). Wastes generated in mining processing and metallurgical sector of economy contain not only thousands tons of copper and zinc, but cause significant damage to the environment where they are located. The reduction of negative impact of anthropogenic wastes on the environment as well as the storage volume reduction of valuable metals from dump slags is possible by improving the efficiency of the melting and further flotation of slags formed during this process."

Jan 1, 2016

By R. L. Bruening, N. E. Izatt, S. R. Izatt

"Rare earth elements (REE) are essential and unique components of many high-technology products without which functioning of modern society would be greatly impaired. Commercial deposits of REE are limited to a few geographical locations. Largely untapped sources of REE are available in endof- life (EOL) magnets, rechargeable batteries, and electronics. Presently, < 1% of REE in EOL wastes is recycled. Conversion of EOL wastes to liquid streams allows use of IBC’s Molecular Recognition Technology (MRT) process to selectively recover, separate, and purify target REE and associated metals at g/L to mg/L or lower concentration levels. The MRT process together with its applications to separations of REE and associated metals in recycling as well as in mining are described. Economic and environmental advantages of MRT are presented. INTRODUCTIONRare earth elements (REE) include the lanthanide series (La-Lu), Y, and Sc. These elements are not rare, but concentrated minable deposits are scarce (Cordier 2012; Haxel, Hedrick, & Orris, 2002). Over 95 % of the world’s supply of REE is controlled by China (Hanson, 2011a) where they are mined, processed, and the pure elements incorporated into a growing number of consumer and military products. The consumer products are marketed worldwide. Since REE are vitally important in consumer and military products, this situation has caused other nations to scramble to develop the capability to produce their own supply (Cordier, 2012).In the U. S., Molycorp has reopened the Mountain Pass REE mine in California and production has begun (Goldenberg, 2010). Development of a reliable internal source of REE is of high national priority in the U.S. (Hanson, 2011b; Hess, 2012: “Obama Announces”, 2012). These elements have in recent decades been incorporated into new consumer and military products that are essential to our economy and defense. These products range from wind turbines, high performance magnets, hybrid car rechargeable batteries, energy efficient lighting electronics, flat screen televisions, and smart phones to advanced weapons systems (Haxel et al., 2002; Levkowitz & Beauchamp-Mustafaga, 2010)."

Jan 1, 2012

By K. J. Fair, G. Van Weert, J. E. Schneider

"IntroductionCyanidation is the principal process for extracting gold from ores . Many primary gold ores, however, are partially or totally refractory in the conventional cyanidation process.Considerable success has been achieved with new gold leaching techniques, such as intensive cyanidation, pressure cyanidation, carbon-in-leach cyanidation, etc. These techniques however, do not offer substantial gains in gold extraction from refractory pyrites.The more drastic pretreatment processes such as roasting, chemical oxidation, autoclave oxidation, and bacterial oxidation all utilize oxidation to break down the structures of pyrite and arsenopyrite. This generally renders the gold amenable to cyanidation.Comparative cost studies indicate that the oldest commercial pretreatment method, i.e. high temperature roasting, is currently the least expensive option if the sulphuric acid can be sold. It operates with air at atmospheric pressure and is characterized by fast reaction rates. For an alternative hydrometallurgical con centrate treatment method to be competitive, it too should operate with air at atmospheric pressure and with fast reaction rates. The NITROX process meets these conditions."

Jan 1, 1986

By Rocky (Yaokun) Wu

Rock burst is one of the biggest challenges to ground control in the mining industry. With increasing mining depth and mining scale, there are more and more industry requirements on yielding rock support. Since 2008, Jennmar has been conducting large scale research and development works to develop a technically reliable and cost effective yielding rock bolt. This paper introduces a new yielding rock support - Yield-Lok bolt. The bolt is characterized by the designed yielding ability to produce 150 ~ 250 mm of deflection at 8 ~ 10 metric tons (Mt) loads for every 16.4kJ energy input. Its performance characteristics are consistent through multiple and varying amplitude of impacts. In this paper, the design criteria of the bolt and the principle of performance are described, the dynamic testing results are discussed; and the features and application of the bolt are presented.

Oct 1, 2010

By J. W. M. Porritt, M. P. Brameld, R. H. McCorkell

"Soil-gas Rn was measured by two types of alpha-particle-track detectors, by emanometry and by counting alpha-activity on Rn-decay-product collectors. Soil samples were analyzed for V by fluorimetric and fission-track methods, their Rn-emanation by decay-product collectors and their total alpha activities with track detectors. The same uranium anomalies were revealed by each method. Fission-track analysis of leaves for V showed only random variations with sampling site, and the Rn emanation of trees and leaves removed from them was barely detectable . The agreement among the other methods is significant, total alpha and collector methods are simple, rapid and useful, and a combination of methods at a site would reveal disequilibrium in the U-decay series if present. Track-Rn measurements are highly reproducible and insensitive to apparatus design and their sensitivity is not enhanced by covering the detectors with thin foil or placing them in large containers.IntroductionIn the past two years , a number of methods of geochemical exploration for uranium have been tested by the authors over the known copper-uranium occurrence at South March, Ontario. This was done partly to compare methods and partly to develop and test new ones. The South march deposit has been described a number of times by others(1,2,3,4). The methods included in this study were the following.Emanometry, Radon in soil gas is measured by pumping the gas into the cell of a scintillation counter or emanometer(5,6). Alpha particles from radon (222Rn) and its decay products (218Po and 214Po) produce scintillations of light in the silver-activated zinc sunphide (ZnS(Ag) covering the walls of the cell. These are counted by a photomultiplier tube and scaler, the count ra sulphide (ZnS(Ag) covering the walls of the cell. These are counted by a photomultiplier tube and scaler, the count rate being proportional to the concentration of radon in the soil gas."

Jan 1, 1981

By M. S. Badollet, W. C. Streib

"AbstractA commercial method .has been developed for controlling the texture of chrysotile asbestos fibers so that they may possess properties comparable with natural sem1-harsh fibers for use in wet •processes.The physical properties of the soft, silky and slimy fibers are partially altered by a flash-heating process which removes a portion of the molecular water.The heat-treated fibers show an improvement in filterability, an increase in bulk, absorption, and surface area and better electrical properties, such as volume resistivity.IntroductionCHRYSOTILE ASBESTOS fibers are found in nature having varying degrees of texture, referred to as soft, semi-harsh, and harsh. Fibers of each type of texture have inherent characteristics which directly affect their usefulness to industry. Visual differences are apparent under a microscope where it is seen that the soft-textured fibers have a silky, serpentine or wavy appearance, whereas the harsh-textured fibers are coarser and spicular. Semi-harsh fibers, of course, have properties intermediate between these extremes.Fankuchen and Schneider ( l) have shown by the use of low-angle X-ray scattering that the diameter of the harsh type of chrysotile fiber is somewhat greater than tha of the soft variety. Surface area measurements on various chrysotiles of different textures tend to confirm their findings. By nitrogen adsorption methods, it was found that the surface areas of soft types of chrysotile asbestos are approximately 23M2 / g whereas for the harsh types they are as low as 11M2/g."

Jan 1, 1955

By P. O. Rag, Daniel E. Walsh

"Gravity concentrators are evaluated either in closed or open circuit. The process developed by MIRL employs the use of neutron activated gold (/98Au) and radiation detection circuits which monitor the concentrator&apos;s product pulp streams. Concentrator recovery is determined from the ratio of the number of gold particles detected as passing into the concentrate to the total number of gold particles detected over all monitored pulp streams. This system eliminates the experimental errors introduced by sampling, sample reduction, and assaying and allows recovery to be evaluated for gold particles of specific sizes, shapes, and flatness. In addition to allowing for a more accurate and detailed recovery analysis, this process significantly reduces the time and cost required for unit evaluation when compared to other gold recovery analysis procedures. This system enjoys its greatest utility where a large number of tests are to be run in order to evaluate a concentrator over a variety of operational settings, i.e. factorial designs, and allows accurate testing of concentrators operated in closed circuit systems.IntroductionThe surge in gold prices of the late 1970s and early 1980s was followed closely by a renewed interest in gravity concentration processes, especially in concentrators claiming efficient recovery of fine placer gold. Cones, spirals, spinning bowls, jigs and cyclones are all considered potential fine gold concentrators. Fine gold, in this context, is defined as not only that gold finer than 250 um (60 mesh""), but also coarser gold, whose low shape factor may decrease its recovery by conventional, large-scale sluicing operations.Adoption of fine gold concentrators by the Alaskan placer milling industry was retarded by the lack of reliable, accurate, and reproducible data on concentrator efficiency with respect to fine placer gold recovery. In most cases, concentrator performance was based on a limited number of tests run on placer material, about which only slight knowledge of gold size and shape characteristics existed. In order to be prepared for the resurgence of interest in fine gold concentrators, which will follow the next upturn in gold prices, a detailed study of the fine gold recovery characteristics of gravity concentrators needs to be conducted."

Jan 1, 1986

By J. Day, Matthew X. Yao, Lijue Xue

Hardfacing overlays are commonly applied on the shroud Z-section of turbine blades for enhanced wear resistance. Among various processes that are used to apply the hardfacing overlays, the plasma transferred arc (PTA) welding process offers several advantages including lower heat input, less base material dilution, rapid process time, and reduced operating cost associated with the capability to apply materials in the powder form. The development of a robust PTA process is crucial for overlay performance and repeatability, particularly in the aerospace industry where a quality intensive manufacturing environment prevails. For this reason, the Taguchi method of experimental design was selected to develop a test plan. A 4-factor 3-level (L9) orthogonal array (OA) was used in the experiment. The L9 OA allows for a more detailed (3 level) investigation of critical process parameters, namely plasma gas flow rate, traverse speed, powder feed rate, and arc current. Two hardfacing materials, Stellite 694 and Tribaloy T-800, both Co-based wear resistant alloys, were investigated by deposition onto a cast IN738 Ni-based superalloy substrate. Performance measurements of the hardfacing deposits included deposit hardness, substrate hardness, deposit density (porosity), degree of cracking/inclusions, and a quantified visual inspection. The procedure resulted in optimized PTA hardfacing parameters for both Stellite 694 and Tribaloy T-800 on IN738 turbine blade material.

Jan 1, 2004

By G. Lucas

"Material substitution occurs continuously in response to competitive and economic pressures. Technical development can accelerate or slow substitution by improving the performance of the invading or defending material. The choices are seldom simple and have to be made in the context of continuous commercial change.The development and commercialization of a new aluminum material is examined. The material has been introduced into· several different markets, so it is possible to compare and contrast the degree of success obtained in each.IntroductionAluminum-based materials have been in use for over one hundred years and , therefore, the development of a new family of alloys is rare. In the early 1970s, Dr. L.R. Morris and his coworkers at Alcan&apos; s Kingston Research Centre started work on what was, at the time, something of a scientific curiosity-a family of alloys strengthened by an unusual mechanism.This paper deals with the development and commercialization of what became known as the Alcan 255 alloys"". These alloys have found uses in several markets, usually as improved substitutes for existing materials. Forecasting the usefulness of a substitute material in an existing marketplace is difficult, in part, because even material users are seldom able to specify precisely their requirements. This uncertainty can cause the failure of some substitutions but can also lead to opportunities which were not initially obvious.Technical BackgroundPure aluminum is a soft, weak material. It can be strengthened by the addition of various alloying elements and by work hardening. Alloying elements usually act by forming solid solutions which are stronger than the pure metal or by precipitating during heat treating or aging and so preventing the easy movement of dislocations during deformation. Elements which can perform either role had been investigated for decades and were thought to offer little chance of technical breakthrough in 1970. An outgrowth of the then new and exciting research on directional solidification seemed, however, to offer such promise.Some aluminum-iran-manganese alloys will solidify under certain conditions as &apos;coupled growth&apos; eutectics (Figs. I and 2). The microstructure shows one phase growing as long rods through the other. This is an uncommon structure and it was investigated to see if it had equally unusual properties. On deformation by rolling the rods were broken up into small equiaxed , evenly-spaced particles (Fig. 3). Materials with this structure were found to be stronger than other alloys with similar amounts of alloying addition, and to resist thermal softening remarkably well. This combination of properties was thought initially to be due directly to the particles by a dispersion strengthening mechanism, but later this was found not to be strictly true."

Jan 1, 1987

By Juliana Parreira

The past decade shows record increases in global demand for minerals and metals with an accompanying significant decline in skilled personnel. Mining companies today are examining new technologies to maximize production, reduce costs, and create safer work conditions to deal with this shortfall. Automation of an open-pit mine haulage system is receiving attention as a beneficial option since it provides more consistent and efficient operation of mining equipment, it removes workers from potential danger, it reduces fuel consumption significantly reducing greenhouse gas (GHG) emissions, and it can help optimize vehicle repairs and equipment replacement because of more-predictable and better-controlled maintenance. This paper describes a simulation model under development using the EXTENDSIM software package to examine scale-up issues and constraints of autonomous vehicles in comparison to a manual system. The software can predict and manage Key Performance Indicators (KPIs), such as productivity, safety, cost, equipment failures, fuel consumption, and tire wear under different road and load conditions. By breaking-down the various systems of an autonomous haulage truck and simulating the overall haulage system using a Monte Carlo approach, the model becomes a flexible and powerful tool to use within a mining organization. Direct comparison to a manuallyrun system can be done to show the cost and operational benefits of automation. Project managers can use this tool to guide decision-making about possible application of autonomous haulage trucks at a specific mine site.

May 1, 2010

By Pim van Geffen, Dave Lawie, James Cleverley

A growing problem facing geoscientists, metallurgists and process engineers is the lack of knowledge transfer between the exploration and production teams. This siloing is generally unintentional, as a typical project may change ownership several times over several decades before it reaches the feasibility and operation stages. Many exploration projects generate vast amounts of high-quality, quantitative data with great spatial resolution, but unfortunately these data are often ignored in subsequent deposit modelling. Instead, deposit models tend to rely on subjective, non-standardized, qualitative classification of geological materials (e.g. rock type, mineral abundance) and processes (e.g. alteration style and intensity), obtained through visual logging of drill core. When projects advance to feasibility studies, the required quantitative data are obtained through expensive metallurgical test work and detailed quantitative mineralogical analysis, such as QEMScan or qXRD. These detailed tests are generally only performed on a small number of large composite samples and the results are extrapolated throughout the deposit, inherently underrepresenting their true variability. Geochemical data obtained during all stages of the project provide comprehensive data coverage at much greater detail and spatial resolution, which allows for the estimation of key metallurgical performance parameters that are required for accurate deposit modelling and domaining.

Jan 1, 2015

By F. Mackay, S. A. B. da Fontoura

"The theoretical solution for a viscoelastic well was presented by Gnirk and Johnson in 1964. From this an exercise was executed to validate the numerical simulation of a cemented salt well. The exercise comprised the geomechanical behavior through time of a cemented salt well, this was achieved using a finite element commercial software. This simulation showed the accuracy of the theoretical solution for viscoelastic materials such as salt rock. The theoretical solution presented elastic and viscoelastic analytic equations for the tangential and radial stresses. The equations for the elastic material (casing and cement) and for the viscoelastic material (salt rock) are presented here: Where equations 1a & 1b are the radial and tangential stresses of the elastic material; equations 2a & 2b are the radial and tangential stresses of the viscoelastic material; and a, r and b are the geometrical parameters explained in Figure 1. These equations are function of Pb, a stress time dependent factor that comes from the Burgers model of viscoelasticity. This is well explained in Gnirk and Johnson (1964) and for the sake of simplicity is not disclosed here. Po is the stress at section A-A’ dependent of the depth h."

Jan 1, 2015

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007

By Z. Abbasloo, A. Masoomi, L. Ebrahimi, A. Mortazavi, A. Keshavarz

"Investigation and 3D analysis of Heap no. 2 of Meydook copper complex was the subject of this study. In this project all geological and geotechnical investigations conducted in the mine were evaluated aiming at determination of Heap no. 2 design parameters. The main objective of the project was to evaluate the potential for construction of Heap. No. 2 on a waste dump built in a valley in the north side of the pit.Considering the space limitation for dump location this was a viable alternative to reduce the costs associated with heap no. 2 construction. Moreover, it allowed for a significant reduction in overall mining costs. Considering the project condition, a 3D analysis of heap major structures including; valley rock foundation, waste dump, and low grade ore was carried out. Five sets of analyses were conducted and the displacement and stress fields were calculated within the heap no. 2 components. In all analyses conducted the subsident profile was determined for the valley base rock and heap foundation (waste dump). Moreover, the shear interaction between heap and waste dump was evaluated at the heap interface. The analyses results showed that the maximum settlement at the heap base is about 4-5 cm and the waste dump provides a safe and reliable base for heap construction. Moreover, the analysis results showed that the selected %5 grade for the heap interface is good and does not pose any risk in terms of heap Interface shear displacements. A sensitivity analysis of heap mechanical parameters was also conducted. The obtained results show that if the friction angle of heap material is reduced below 25 degree due to acid spraying process, the heap walls become unstable and the heap geometry must be redesigned."

Jan 1, 2015

By F. Hassani, E. Aflaki, M. Nokken, M. Kermani

"This paper presents and compares the physical properties of Gelfill and cemented hydraulic fill (CHF) obtained by lab experiments. Gelfill consists of tailings, different binders such as Portland cement, fly ash and blast furnace slag and an alkali activator such as sodium silicate. The CHF and Gelfill samples with various mixture designs were cast and cured for 28 days. The influence of sodium silicate concentration, pulp density and mixing time on the mechanical properties of samples were evaluated using the uniaxial strength test. Mercury intrusion porosimetery (MIP) was used to analyse the microstructure of CHF and Gelfill samples.This study concludes that: (i) The mechanical properties of CHF can be improved by the addition of appropriate amount of sodium silicate. (ii) The rate of strength acquisition in Gelfill samples is faster than CHF samples over 28 days of curing period. (iii) Mixing time strongly influences the mechanical properties of Gelfill samples but did not have any effect on CHF samples. (iv) The MIP analyses indicate that the pore size distribution and total porosity of Gelfill and CHF were different, and this did contribute to higher strength development of the Gelfill samples. INTRODUCTIONThe increased depths of mines in the Canadian Shield and the high stress associated with these depths favour a new method of mine backfill that can both meet strength requirements and help mine productivity. The mine backfill mainly consists of tailings, water and binder materials, the latter being most expensive. Gelfill is a new mine backfill material whose binder usually consists of alkali activators such as sodium silicate and other cementitious materials such as blast furnace slag and normal Portland cement. Although sodium silicate has been used in concrete manufacture, the use of this material in mine backfill is relatively new (Doucet, 2007, Razavi, 2007). Until very recently there have been only a few isolated publications, mostly out of McGill University, regarding mine Gelfill (Razavi, 2007 and Kermani et al., 2009 and 2010). These papers have investigated some of the basic mechanical properties and mechanical behaviour of Gelfill. However, the physical performance of Gelfill in various conditions has yet to be understood. Therefore, the main objective of this study was to investigate the influence of mixing time and sodium silicate concentration on the mechanical performance of Gelfill and CHF through a series of experiments. Moreover, the microstructure of the Gelfill and CHF samples was studied."

Jan 1, 2015

By A. Bauer

The correct application of large crater blasts in unfrozen tar sand is an effective means of resisting frost penetration during winter. This results in much higher productivity and considerably less down time with excavators during winter operations. The resulting flatter angle of repose of the highwall has readily been accommodated with slight modification to bucket-wheel excavator operating procedure. Other mining schemes call for large draglines to be located on top of the highwall, which can be as high as J80 feet. The question now arises as to the effect that blasting might have on the stability of such a situation in which the highwall includes potential planes of weakness. This paper applies blast vibration data from large-scale blasting in tar sand to the stability analysis for typical production situations likely to be encountered and indicates safe scaled distances to be employed between dragline and blast.

Jan 1, 1979

By J. B. De Hart

This paper has been confined to the consideration of the working of thick seams, from six feet to sixteen feet, which are pitching at about thirty degrees to the horizontal. The discussion has been limited to these set conditions because they are the ones of commonest occurrence in the Southern Alberta bituminous coal district, because, from the point of view of safety, thin seams are more easily worked, and because a discussion of all the possible combinations of thick and thin seams pitching at angles varying from zero to ninety degrees with the horizontal would involve a task impossible in the time available. It has been assumed that the mine makes gas freely and that the coal is friable and tends to make inflammable dust which is highly explosive. Since the problem requires the taking into account means of maintaining a high proportion of lump coal, it is further assumed that lump coal commands a price considerably higher than the price which can be obtained for run-of-mine or for slack coal. Figure 1, tabulating the various factors which must be considered and their relation to each other, indicates diagrammatically the complexity of the problem. Any method of working becomes divided into two distinct components, the active workings of the mine and the old abandoned workings. While these are in a measure distinct, they are nevertheless inter-related, as shown in the diagram.

Jan 1, 1930

By D. W. Euler, B. J. Clauzier

"Implementation of an effective energy management system will reduce energy costs without impacting negatively on production.The energy management system must be designed to complement the operation and be integrated with the organization. It must be reliable and easy to use but most important, it must have an accurate and timely feedback reporting system to allow the operation to take appropriate action.Falconbridge Limited was one of the first three companies to be awarded the energy monitoring demonstration program in May 1987. The program is sponsored jointly by the Ontario Ministry of Energy and Ontario Hydro.This paper describes the approach taken by Falconbridge Limited to implement the Onaping Area Energy Management System.IntroductionThe objective of the project was to implement an effective energy management system, capable of reducing energy costs without impacting negatively on production.Energy management systems must be designed to complement the operation and to be integrated with the organization. The system must be reliable and easy to use, but most importantly, it must have an accurate and timely feedback reporting system to allow the operation to take appropriate action."

Jan 1, 1990

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory&apos;s waste water, was achieved at Tarbiat Modares University&apos;s mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By W. M. Silva, PAP. Miotto, M. A. P. Silva, V. P. Ramos, L. R. M. Bittencourt

The major cause of breakdown of anode baking furnace fluewalls is chemical corrosion, which leads to deterioration of the properties of the bricks. Subsequent deformation of the fluewalls occurs, and also extensive cracking of the lining is observed. The present work studies the major changes of the brick during the operation of the furnace, after 22, 60 and 90 cycles of baking; in two different regions: upper and lower. Due to excellent cleaning conditions of the butts, negligible amounts of fluorine were found in the bricks. The major contaminants found were carbon, sulfur and alkali compounds, all of them present in the anode baked during the process.

Jan 1, 2004