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By Mario Giavani

"IntroductionBy the 1980s, the continuous casting process had almost replaced the ingot casting of steel in Japan, Europe and North America. While economic benefits were probably initially the prime motivator, the transition rapidly proved that continuous casting in conjunction with ladle metallurgy offered a much greater degree of process control and made possible routine steel specifications not previously available.This new technology demanded improved procedures for the quantitative addition of the required metallurgical reagents, especially as regards the more volatile or toxic elements such as calcium , boron, carbon, sulphur, lead and tellurium. The injection of a thin steel tube containing the additive into the metal bath of a ladle refining station offers the best procedure for this. In the industry this has been referred to as ""Cored Wire "".Operators using this technology find that they are faced with balancing the injection speed against the small cross section of the tube to feed the required amount of reagent within the short time span available to the operation. Large-ladle shops requiring major quantities usually resort to multiple machines and high speeds. Many machines approach a maximum feed rate of 400 m/min. Higher speeds exceed the melting rate of the system, and the ferro static buoyancy of the tube will cause it to coil up the ladle wall and possibly resurface into the slag layer, and even eject itself above the surface. Under these conditions, exact control of element recovery becomes difficult, especially with the commonest addition, calcium silicon alloy.Many experts are persuaded that the final melting position of the carrier tube has major importance in establishing consistent element yield to the bath.For instance, the vapour pressure of calcium at l500 °C is close to I bar. Reaching a melting depth sufficient to accommodate this value is considered to be critical to achieving an acceptable and reproducible yield.Many studies have elaborated semi-empirical formulae to establish the melt zone depth, connecting this value essentially to the diameter of the tube , the injection rate and the superheat of the steel. The author's experience in steelmaking could not confirm such formulae in many cases, and he set about to develop a mathematical model which would be useful in addressing this problem, taking into account the several parameters which will regulate the behaviour of a filled tube immersed in molten steel."

Jan 1, 1991

By A. Tabereaux

The reduction of perfluorocarbon (PFC) emissions from aluminum electrolytic cells is a key issue in reducing greenhouse gases at all aluminum smelters, The emission of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) gases during anode effects at smelters can be calculated using two different methods; anode effect-minutes slope and anode effect overvoltage, This work demonstrates that the optimum method depends to a large extent on the type of anode effect kill algorithm utilized at each smelter, CF4 emissions vary widely from aluminum cells depending on the type of anode effect kill method utilized; fast, aggressive anode bridge movements vs. slower, moderate anode bridge movements.

Jan 1, 2005

By H. W. Manley

SULPHUR, like the minerals of coal, iron and petroleum, is one of the essential materials in our modern expanding industrial civilization. Before discussing the salient features of the production of sulphur from the Canadian sour gas, it seems appropriate to outline the historical past and probable future utilization of sulphur. The ancient Greek writer Homer spoke of its "pest-averting sulphur" and the "divine purifying fumigation". Ancient alchemists found sulphur to be a fascinating and baffling material. The discovery of gun powder in the year of 1250, and its application to the art of war a, century later, made sulphur an important commodity in the progress of mankind. The initial manufacture of sulphuric acid in the year of 1736 by the Englishman Joshua Ward, established the basis of a chemical industry that today utilizes 80 per cent of the consumption of elemental sulphur. Commercial production of the chemical soda ash ( N a2C03) discovered in 1787 by the famous Leblanc Process, in-creased international demand for the element sulphur and marks the birthday of the Sicilian sulphur industry.

Jan 1, 1961

By K. Ebrahimi-Nasrabadi

The dependence between the extent of conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally in the temperature range of 400?1200 °C and for calcination times up to 8 h. A TGA?DTA analysis showed that decomposition begins at temperatures as low as 340 °C and is completed at 600 °C. Measurements of specific surface area (SSA), iodine adsorption number (IN), crystallite size, and loss on ignition were carried out to characterize the product quality. It was found that while all the parameters are dependent on the extent of calcination, densification of the product caused by grain coarsening affects their final values. As a consequence, SSA and IN went through a maximum with time. The study showed that high quality caustic calcined magnesia can be produced in a narrow range of temperature (600?650 °C) and time (1?4 h). Medium quality caustic calcined magnesia can be made within a wider range of parameters.

Aug 1, 2013

By Y. Béliveau

Emission of perfluorocarbon gases, CF4 and C2F6, produced during anode effects from aluminum electrolytic cells are a significant part of the total equivalent CO2 emitted by aluminum plants. With the current concerns about global warming, the reduction of these PFC gases is a key issue in reducing greenhouse gases for a smelter and achieving GHG emission agreement goals. This paper will present the approach taken by the Alcoa vertical-stud Soderberg plant in Baie-Comeau to reduce GHG emissions generated during anode effects and close emission gaps with other Alcoa Soderberg plants. The approach has been to adapt the existing technology in place at the Baie-Comeau Soderberg plant. PFC emissions were lowered by reducing both the anode effect duration and frequency through different methods. Examples of change include: implementing skimming practices and wider side crust break area for better alumina dissolution in bath, increasing the ratio between reacted and pure alumina, reducing the time to declare anode effects in the potrooms, implementing best work practices and finally educating the workforce on the importance of reducing PFC emissions.

Jan 1, 2007

By Te Gao

It is a general expectancy that in most of the construction and renovation project, the contractor is going to hand over the as-built documents to the owner or the facility management team at the completion of the project. The main challenge for the handover process is to ensure the completeness of the captured building information and the accuracy of it in terms of how well it represents the reality. Building information models (BIMs) can be used as an information repository to store and deliver as-built information. However, due to changes made in the construction and renovation phases and errors made in the design and modeling phases, discrepancies can exist between BIMs created in the design phase (asdesigned BIMs) and actual building conditions. Laser scanning technology is able to efficiently capture accurate geometric information, which provides an opportunity to identify and quantify discrepancies and update as-designed BIMs into as-built BIMs. This paper presents a case study, within which the asdesigned BIM of a newly renovated research lab was updated into an as-built BIM using laser scanned data captured in the renovation phase. This paper introduces the challenges associated with the updating process for the as-designed BIM. In order to address these challenges, this paper introduces a framework that supports the update of an as-designed BIM by incorporating point clouds captured by the progressive laser scans.

Aug 1, 2013

By H. T. Kennedy, D. L. Flock

"The project described in this pa-per was undertaken to provide a more thorough understanding of the effect of contamination by drilling fluids on the electrical properties of porous systems. The basic work per-formed was filtration tests on both consolidated and unconsolidated sands and the determination of their resistivity profiles with the aid of screen-type electrodes spaced at convenient intervals along the core.Four drilling fluids were selected, ranging in resistivity from 447.0 ohm-cm. to •5.76 ohm-cm. The permeability of three unconsolidated and four consolidated cores, on which resistivity measurements were made, varied from 1,257 md. to 4,560 md. Five additional cores with permeabilities as low as 49 md. were tested to investigate the effect of permeability on the depth of invasion of drilling fluids.The effect of drilling fluid invasion on resistivity profiles was determined on cores containing brine only, and on those containing 80 to 90 per cent oil and 20 to 10 per cent brine. The study included measurements of (a) clay content of different sections of the core, (b) saturation of the invaded fluids and oil in different parts of the core, and ( c) changes in resistivity as a result of gravitational re-distribution of fluids and diffusion of electrolytes.The data showed that the resistivity of an invaded core is, as was expected, controlled by the resistivity of the filtrate, the resistivity of residual core water, the resistivity of the clay particles, and the amount and distribution of the filtrate, clays, residual oil, and brine. In most cases there was a significant increase in resistivity owing to the presence of clay solids which had invaded the core. The change in resistivity, as a result of the diffusion of salts, was substantial after a period of five hours. There is evidence in some cases that the residual oil and core water saturations of the unconsolidated cores, after substantial invasion, are very low, indicating almost complete displacement by invading fluid."

Jan 1, 1959

By J. C. Thornley, H. L. J. Drummond

"Fifty years of wear on the original carbon steel shaft of this hydro turbine necessitated repair operations in 1980. Both austenitic and martensitic stainless steels have been used individually as journal materials in separate trials on an80-inch long and 22-inch diameter radial bearing but neither one nor the other has been successful.The wear and cracking problems of the stainless steels leading to the present abandonment of both classes of stainless steel are described. In particular the dependence of the toughness of type 410 stainless steel on its tempering temperature and the susceptibility of that steel to quench cracking are highlighted because problems have been caused by both of these metallurgical factors.IntroductionAs part of a desire to improve the efficiency of a fifty-year old hydro-electric generating station on the Saint John River, the decision was made to change the journal and bearing material for the shaft bearings, which are stave-type bearings. For the initial fifty years of operation the bearings had been wooden (lignum vitae) and had run on the carbon steel shaft directly. For one of the four unit s at this station the performance of this combination has been truly excellent, and the remaining three sets of bearings had performed well. However there had been shaft wear on the units and the wear had made the shafts somewhat elliptical when a decision was made to install some sort of new journal on to three of the old shafts. [In addition to the wear on the carbon steel journals it was found that one shaft was significantly softer in the bearing area than it was immediately above the bearings (180 Vickers in comparison with 230 to 250 Vickers)] ."

Jan 1, 1985

By J. Paturaud, A. G. Villemiane, J. Y. Buffiere, D. Fabregue, M. Perrier

In this work, a detailed characterization of the cyclic damage mechanisms on duty in car heat exchangers has been carried out in order to improve their reliability. The material which consists in very thin (<0.3 mm thick) sheets formed of 3 co-rolled aluminum alloys (4045 /3916/ 4045) has been brazed in order to obtain metallurgical and surface conditions representative of those of the real components. Fatigue tests at constant stress amplitude have been performed at room temperature and 120°C in order i) to characterize the cyclic resistance of the studied materials and ii) to study the effect of temperature on the fatigue damage mechanism. The mechanisms leading to failure have been identified from post mortem fractographic analysis. The Wohler curves obtained show that, contrary to common structural Al alloys, this type of thin sheet brazed multi material can be cycled for several hundred thousand cycles at very high stress level (> ~ 80 % of the tensile strength). This behaviour is analysed with respect to the microstructure resulting from the brazing process and the low number of grains present in the sample thickness (around 5 grains).

Jan 1, 2015

By Mark Weidenbach

OZ Minerals owns and operates the Prominent Hill copper-gold concentrator in South Australia, built in 2008 and commissioned in early 2009. The concentrator operates via semi autogenous grinding in a thirty four foot ThyssenKrupp Polysius mill followed by a twenty four foot Polysius ball mill in closed circuit with hydro cyclones, designed for an ore throughput of eight million tonnes per annum. The main aspects of designing the circuit are discussed along with the issues faced in the early stages of operation. A review of the optimization strategy applied to the milling circuit such as cyclone optimization, advanced process control strategy implementation and reline management to improve availability is then discussed highlighting areas of significant process improvement that have seen the plant exceed nameplate throughputs above nine million tonnes per annum.

Jan 1, 2012

By D. Milne

Laser profilometers exist for obtaining very accurate two and three dimensional profiles of joint surfaces. The application of this technology is not commonly applied to the collection of field data on discontinuity surface roughness. Rugged and portable field devices are not commonly used and the value of the possible field data that can be collected has not been well recognised. This paper reviews commonly used field techniques for assessing discontinuity roughness, discusses the value of this data and presents a new laser profilometer design for field application.

May 1, 2009

By Yasuo Iizuka

We have had studied CO oxidation on unsupported Au powder (mean particle size, ca.100nm) manufactured by evaporating ultra high purity gold metal (>99.99%) in inert gas and reported that it showed some activity after oxidizing pretreatment in O2 at 423 K?453 K. However, recent XPS analysis of the Au powder revealed that it contains much amount of impurity metals such as Ag and In at levels which far exceed those expected from the impurity level of raw gold metal in the bulk. Several samples of Au powder containing different amount of impurity metals were prepared to examine whether the activity depends upon the existence of surface impurity or not. Activity measurements were performed at 273 K after undergoing the powder under various pretreatment conditions. Although the activity of Au powder varied to some extent according to the pretreatment condition, it is strongly correlated to the surface concentration of Ag. Such dependence was not found for In, indicating that the activity of unsupported Au powder is mainly due to the existence of Ag in the surface layer. The activity attributable to ?particle size effect? was not recognized for Au powder with a mean particle size larger than 80 nm.

Oct 1, 2003

By F. Roemer, D. Goldmann, T. Elwert

Tantalum is an important minor metal for the production of high performance capacitors. Approximately 60% of the annual tantalum production is used in this application. Despite its high price of 298 US$/kg (average price 2010–2014), at the moment, no recycling from end-of-life products takes place. In the established recycling processes of waste electrical and electronic equipment (WEEE), tantalum is lost in the slags of copper smelting, where it is highly diluted. An economic recovery is not possible at that point. Although tantalum must therefore be extracted from the WEEE stream before it enters smelting, no industrial recycling processes exist. The main reasons are its low concentration in the WEEE stream, lack of information about tantalum bearing devices, technical difficulties of extraction, and conflicts of interests regarding the recycling of other valuable metals in WEEE. In this paper, the results of a cooperation research project are presented. The aforementioned challenges are addressed and a novel tantalum recycling process is developed. Small pilot scale experiments show that a mechanical processing route can produce marketable tantalum-concentrates of 30% tantalum with yields between 60 and 70%. This is reached through a manual pre-sorting of potentially tantalum bearing products followed by a combination of an optimized comminution, sieving, air classifying, eddy-current (EC), and two stage magnetic separation. Key to the implementation of this process was a detailed survey of the tantalum concentrations in different products carried out by the industrial partner.

Jan 1, 2016

By Rodney S. Read

This paper outlines a reasoned argument why no large-scale fracturing or faulting will be induced in the host rock by a deep geological repository (DGR) for nuclear fuel waste. Four DGR designs in three possible host rocks, including crystalline and sedimentary rock types, are considered. The reasoned argument draws from results of previously conducted thermal- mechanical analyses and new scoping calculations, along with evidence from experiments conducted in Canada and elsewhere. It is concluded that large-scale fracturing in the far-field is implausible given the expected in situ stress conditions in relation to rock strength. Near-field damage development and fracturing are expected in DGR scenarios in the different rock types, but these near-field effects are not expected to lead to large-scale fracturing that could compromise the integrity of the DGR and surrounding rock mass. Additional analysis and characterization activities are recommended to further validate the reasoned argument. Thermo-poroelastic loading of the rock mass is identified as one possible driving mechanism that should be studied further.

May 1, 2009

By J. -F. Blais, M. -O. Simonnot, J. Mocellin, G. Mercier, J. -L. Morel

Large quantities of ferromanganese sludge are generated as waste material by blast furnace during the manufacturing of ferromanganese. These slags are very rich in manganese, zinc and lead (5 to 40 %). These residues have been deposited in a pond in periphery of the steel industry. Considering the market value of the metals, these brownfield sites can now be considered as secondary resources. We have developed a hydrometallurgical process for selectively leaching Zn, Mn and Pb in order to produce compounds of Mn and Zn pure enough to be economically recoverable and a residue rich in Pb. Batch laboratory experiments were carried out to determine appropriate leaching conditions to maximize zinc extraction (100 %) and manganese extraction (90.0 %) with sulfuric acid and to generate a residue containing 15 to 30% of lead. This Pb residue is recyclable by another process.

Jan 1, 2015

By Jianhong Xu, Hailong Hou, Yu Jing, Yundong Wang

Microcapsules containing extractants have been applied to the extraction of metal ions, organic acid, pesticide, and herbicide. The difficulties of conventional liquid-liquid extraction in phase mixing and phase separation (e.g. high energy consumption, emulsification phenomenon, and large equipment requiring housing) could be overcome in a liquid-solid system by using microcapsules. Even some extractants with high viscosity and poison can be encapsulated conveniently into microcapsules. In the work described in this paper, polysulfone microcapsules containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (P507) were successfully prepared. Then, the extraction rate of lanthanum, samarium, and erbium in dilute solution into the microcapsules containing P507 was studied. An extraction kinetic model is proposed based on the interfacial reaction model accompanied by intraparticle diffusion expressed by Fick’s law. The extraction efficiency was obtained by using the kinetic model with the separately determined complex formation rate constant and the intraparticle diffusion coefficient. From the results, it was confirmed that the kinetic model could predict the experiment in a microcapsule system over a wide concentration range of lanthanide solution. In the future, the model could provide good guidance for the design and application in extraction of lanthanides.

Jan 1, 2014

By M. Dupuis

In the present study, the heat balance of the Hirakud smelter aluminium reduction cell has been accurately assessed using only a surface thermocouple and a pyrometer, As it is well known that using a single linear or quadratic relationship to estimate the heat flux from the measured surface temperature does not provide the accuracy required to close the cell heat balance, this approach was not used in this study, Instead, the fundamental natural convection and radiation heat flux equations were used systematically for each measurement point, Practically, this means that the ambient air temperature and at least one ambient radiative temperature must also be known in addition to the surface temperature for each measurement point. Sometimes, the radiative heat flux could not be accurately estimated using a single ambient radiative temperature, In those cases, a more accurate estimation based on two ambient radiative temperatures and corresponding view factors has been used instead, It turns out that although at least three temperature measurements are required to estimate a single heat flux, it takes a lot less time to make those temperature measurements using a pyrometer than directly measuring the heat flux using an expensive heat flux meter, Furthermore, no loss in accuracy was detected when using this approach as the cell heat balance could be closed within 5%, the level of accuracy typical of cell heat balance assessment using heat flux meter.

Jan 1, 2004

By A Sadough Vanini

In this paper large deformation of smart functionally graded beams with initial imperfection and under thermal loadings is considered. Smart beam consist of two types of layers. One layer is made from functionally graded materials and a layer or a set of layers from active materials that usually is made from piezoelectric materials that are bounded on the surfaces of beam. An active controller is used for controlling the deformation and stress in functionally graded layer of beam. A simple Euler- Bernoulli beam theory is used for analyzing of beam. In functionally graded layer the material property vary continuously through the thickness direction and power law model is used for the variation of elastic modulus, heat expansion and heat conduction coefficients. Poisson ratio is assumed to be constant in functionally graded layer. The effects of varying the power law constants and the Gain of controller is considered here. The results are reduced and compared with smart functionally graded beam without initial imperfections.

Oct 1, 2011

By Stephen B. Hearn

The SLon Vertical Ring and Pulsating High Gradient Magnetic Separator was developed to overcome multiple disadvantages associated with traditional horizontal type Wet High Intensity Magnetic Separators (WHIMS) which have been in service for many decades for recovering iron ore and other minerals. Proven successful, with hundreds of units now upgrading low-grade iron ores and maximizing recovery of fines throughout China, the technology is now being tested in the Western world. This paper will discuss the drawbacks of traditional WHIMS, explain the operation of the SLon, and illustrate its practical use in processing hematite ores.

May 1, 2007

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT: As part of an overall study of properties and processes influencing consolidation of oil sands fine tailings resulting from different extraction processes, self-weight consolidation tests were per-formed. Fourteen 2 m and 1 m high standpipe tests were instrumented to monitor the rate and magnitude of consolidation of seven fine tailings materials. Tests provided valuable information about the variation of consolidation related to differences in fine tailings material properties that result from a change in bitu-men extraction process (caustic versus non-caustic). In addition, the effect of adding a coagulant to caustic fine tailings was measured. Test results are presented and discussed in terms of consolidation rate long-term volume decrease, compressibility, and downward drainage. Non-caustic fine tailings had fasterinitial consolidation, which is important in tailings ponds for reducing storage capacity and returning decant water at a faster rate to the extraction plant. Similar results were obtained for caustic fine tailings with a coagulant addition. However, long-term settlement of the different fine tailings appears to con-verge to a similar value over time because it is then governed by effective stress.

Jan 1, 2011