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By Ozdemir. O.

Magnesium additions to aluminum enhance strength and hardness, lowering density, and improving corrosion resistance. However, during melting and casting processes, significant amounts of magnesium are lost due to selective oxidation. Preventing these losses would reduce the production cost and improve the quality of the final product. The effects of strontium addition on the oxidation behaviour of aluminum-0.5% and 1% magnesium alloys were investigated by monitoring sample weight gains with time with a thermogravimetric balance at 750°C. Sample cross sections have been examined using Field Emission Gun Scanning Electron Microscope.

Jan 1, 2004

By Derek J. Barratt

This paper compares a number of operating conventional and semi-autogenous grinding circuits and analyzes them in regard to operating and capital costs, specifically as applied to porphyry copper ores.

Jan 1, 1979

By A. H. Winckers

"The Sullivan Mine and Concentrator are owned and operated by Cominco Ltd. and are located in the Rocky Mountain Trench, in Kimberley, British Columbia.The Sullivan Concentrator commenced operation in 1923 at approximately 2,500 tons per day. The concentrator was enlarged in several stages and by 1945 was treating 8,500 tons of ore per day. In 1949, the capacity of the concentrator was expanded to 10,000 tons per day with the completion of the sink and float plant, the installation of the rod mill, an underground crushing plant and a 4-mile underground and surface electric railway from the underground crushing plant to the concentrator. Throughput now averages 7,000 tons per operating day, or 2,400,000 tons per year.The concentrator operates 7 days per week, 24 hours per day while the underground crushing station operates 5 days per week, 24 hours per day. The ore is essentially a replacement deposit in argillaceous quartzite of Precambrian age. The ore bodies are massive deposits consisting of fine grained mixtures of sulphides, sometimes interbanded with the country rock and varying widely in their content of lead, zinc, iron and silicates. The principal economic minerals are galena and marmatite (7 ZnS:FeS). Iron is mainly present as pyrrhotite, and to a much lesser extent as pyrite. The intimate association of these sulphides necessitated the development of a successful differential flotation process before the ore could be beneficiated profitably."

Jan 1, 1981

By L. Gutierrez, M. Pawlik

The rheology artificial mixtures of bitumen with fine quartz of varying bitumen content, as well as actual oil sand ores, was investigated under different physicochemical conditions (pH, temperature). All rheological measurements were conducted using a Haake Rotovisco VT550 rotational viscometer, connected to a fixture specifically designed to measure properties of settling suspensions. It was found that at low bitumen contents (1 %, wt.) the pH of the slurries was the most important parameter that controlled the rheology of quartz-bitumen slurries. At higher bitumen contents (10%, wt.), it was a combination of high temperature and high pH that gave the lowest apparent viscosities and yield stresses of the model mixtures. These model observations correlated well with the rheology data obtained for slurries of actual oil sand ores. The overall results were discussed in terms of aggregation-dispersion phenomena between bitumen and mineral particles.

Jan 1, 2009

By A. J. Rigby

Anode vessels are often relined with refractory every one to two years and a typical reline time can take between 16-20 days. Modem refractory designs using dense, corrosion resistant brick applied directly to the vessel shell in the high wear areas around and above the tuyeres and at the slagline can yield a lining life of up to 4-5 years before a complete reline is necessary. Installation methods using brick delivery on roller conveyors through an endwall access port and complete anchoring of the brick to allow for lining self-support can take days off the installation time. It is possible, therefore, to reduce the refractory relining period by 50% and increase lining life by 100% compared to typical anode repair schemes. Cu2007

Jan 1, 2007

By Gil Espejo, Denise Duncan

"In Alberta, several initiatives are under way to form partnerships between educators and industry to work together in preparing a skilled and technically competent workforce for the future. One successful initiative is the Teachers in Business program which provides high school teachers one month paid internships in Alberta businesses. Initiated by the Science Alberta Foundation in 1992, this program has offered participating teachers a variety of work experiences and job shadowing tours in industry.A Growing Need of Education and Industry PartnershipsIn our ever evolving world, industry is in a tight race to keep up to date with new technology and to remain competitive. Industry is relying on the education system to provide them with the core base for their future workforce. To accomplish this, the education system needs the support of industry to develop the right focus to prepare its students for the race. What skills will our future workforce need? How can we best prepare our students for these needs?Teaching the latest in technology, especially at the high school level, is a major challenge. It is difficult for educators to keep abreast of the rapid changes in technology. High school graduates need exposure to the latest advancements. And so do their teachers. Students must be prepared to adapt to the challenges of the future, Le. global competition, rapid technological change and an expanding knowledge base."

Jan 1, 1995

By P. G. Hallof

The exploration staff of Campbell-Chibougamau Mines Limited has used past experience to delineate several areas of geologic interest under Lake. Chibougamau. Du• ring the winter of 1964-65, a reconnaissance induced polarization survey was carried out on the lake. First, several lines were surveyed over the known mu1.erahza-tion at the Henderson mine; the grid was then extended into the areas of interest. Several anomalous zones were located and drilled; one, of these proved to be of economic interest.

Jan 1, 1967

By R. W. Boyle, W. Dyck

"Scientists throughout the world have observed radioactive disequilibrium in the uranium decay series. Radiometric and fluorometric determinations of U in plants from the Goldfields district and in sediments and rocks from the Beaverlodge district exhibit marked radioactive disequilibrium. The eU/U ratio in plants rooted in mineralized ground shifts from greater than unity to less than unity for those rooted in background soils. A similar shift is observed in the transition from rocks to stream sediments and to lake sediments in the Beaverlodge district.Results of a Rn-Ra-U survey of lake bottoms in the Key Lake district show that anomalous hydromorphic U from U mineralization is parallelled by anomalous Rn, even though there is much less Ra in the lake-bottom sediments than one would expect from the amount of U present. IntroductionDisequilibrium in the U decay series has been studied for many years and is observed in almost all surficial environments. Rosholt (1959) measured U, 234Pa, 23O'fh, 226Ra, 222Rn, and 210Pb in a large number of U ores and outlined six types of situations to explain disequilibrium. Davy (1974) outlines the geological significance of radioactive disequilibrium situations with respect to exploration. Levinson and Coetzee (1978) discuss possible mechanisms by which separations of parent and daughter elements are affected and suggest analytical pitfalls that may be encountered in the use of radiometric techniques when disequilibrium has occurred. Generally, it is the oxyphile and easily complexed parent 238U (with its associated isotopes 235 U and 234U) that is leached from rocks and soils at a faster rate than are the daughters, 230Th, 226Ra, 2loPb, and 206Pb. This mobilized U is adsorbed on sediments in streams and lakes, or enters groundwaters, where it is eventually precipitated under reducing conditions, occasionally in oregrade concentrations. This surface leaching and"

Jan 1, 1980

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By I. H. Warren, F. A. Forward, A. Vizsolyi

"Observations are reported on the pressure leaching of material produced by subjecting chalcopyrite to two types of heat treatment. Calcination of the mineral at 825°C, in the absence of oxygen, induces some sulphur loss by volatization, producing a material from which copper can be leached more rapidly than from chalcopyrite. Treatment of the mineral with elemental sulphur at 475°C leads to sulphur uptake accompanied by a change in mineralogical structure of the chalcopyrite. Copper is prefer-entially and rapidly leached from the sulphur-treated material. A tentative explanation of the sulphur-chalcopyrite re-action is presented."

Jan 1, 1968

By J. Y. Liu

In Comparison to the application of HPGR (high-pressure grinding rolls) in the cement industry and in iron ore processing, the introduction of this energy-efficient comminution technology to processing of nonferrous base-metal ores has progressed slowly as yet. In the field of minerals industry, challenges lies not only in the large variety of the feed material with respect to particle size, density, hardness, moisture and mineralogy of the material but also in complexity of the processing flowsheet, which need to be addressed from case to case based on result of HPGR comminution test work. Whereas conventional comminution test with HPGR in lab-scale or pilot scale needs quite a large amount of feed material, a compressive stressing test of particle-bed in piston-die device provides an effective way to study interparticle breakage behavior of ore material with much less feed. In the present study the effects of interparticle breakage on comminution of a copper ore has been investigated by compressive stressing of particle bed in a piston-die device. The feeds to the particle-bed stressing tests were four narrow size fractions in the size range of 0.3~3.35 mm and a broad size fraction of 0/3.35 mm. The pressures applied were in the range between 30 and 180 MPa. The results showed that the specific energy consumption increases linearly with the pressure; the product fineness increases also with the pressure, but the magnitude of this increase declines as the pressure goes up. Under the same stressing intensity, the product size distribution curve becomes steeper as the particle size decreases, so there is no self-similarity between product size distributions of different feed sizes. The suitability of a material-characterization model for interparticle breakage was verified for this ore. In addition, the effect of interparticle breakage on comminution of this ore with respect to its influence on the downstream flotation were analyzed in terms of size-metal distribution and mineral liberation.

Jan 1, 2016

By A. L. Mackie

Mine water from base metal mines is generally characterized as having high concentrations of heavy metals and low pH, resulting in the need for treatment prior to discharge to receiving waters. In this study, two high-rate clarification processes were evaluated at bench-scale: the high density sludge (HDS) process and sand-ballasted flocculation. High-rate clarification processes generate larger, denser flocs which settle more quickly than those formed in conventional flocculation processes. The HDS process uses recirculated sludge in order to seed floc formation, whereas ballasted flocculation uses microsand. Both of these high-rate processes require the addition of quicklime or hydrated lime to increase pH and allow for the formation of insoluble metal hydroxides, which can then be removed in the clarification stage. Previous research has shown that cement kiln dust (CKD) can effectively replace quicklime in conventional sedimentation processes for metals and acidity reduction to meet discharge guidelines (Mackie & Walsh 2012). CKD is an alkaline by-product of cement manufacture that has fine particle sizes and varying free lime concentrations depending on the manufacturing process. The lower solubility (i.e., free lime content) of CKD requires larger doses of material to be added to reach treatment pH targets for metals precipitation. The purpose of this study was to evaluate the treatment efficacy of high-rate clarification processes for mine water treatment, compared with conventional sedimentation, at bench-scale with conventional (i.e., lime) and novel (i.e., CKD) pH adjustment additives. Results of the study showed that all treatment processes (i.e., HDS, ballasted flocculation, and conventional sedimentation) were able to reduce target metal concentrations to well below Canadian guidelines (i.e., total zinc and total nickel < 0.5 mg/L, total copper < 0.3 mg/L) using either CKD or lime. Additionally, mine water samples treated with CKD generated lower sludge volumes than those treated with lime (i.e., 50 versus 100 mL for conventional sedimentation and 100 versus 200 mL for HDS) even with increased concentrations of solids introduced during treatment. This is most likely due to slower neutralization rates when using CKD, due to its lower solubility, as well as finer particle size. The sand-ballasted flocculation process was able to reduce final turbidity in CKD-treated samples while the HDS process did not when compared to conventional sedimentation, making the ballasted flocculation process preferable for reducing final solids concentrations in CKD-treated mine water.

Aug 1, 2013

By G. A. Gross

Nearly 90 per cent of the iron ore produced in Canada is derived from iron-formation or bedded iron deposits. About 70 per cent of this consists of concentrates obtained fom iron-formation; another 20 per cent was formed by natural enrichment processes. Four principal varieties of iron-formation are recognized -the Algoma, Superior, Clinton and Minette types. Differences in their geology, mineralogy, chemical composition and environment of deposition are of special significance in their evaluation as ore.

Feb 1, 1966

By Penny C. Stewart

Narrow vein underground stope design engineers in Australia have expressed significant interest in the requirements and methodology for developing site-specific stability charts. This is largely due to a concern that existing stope stability charts inadequately take into account factors influencing narrow vein stope stability, such as the effect of backfill abutments and the effect of in stope pillars. This paper presents conclusions from a comprehensive statistical examination of case history requirements for a site specific stability chart and critiques literature arguments for site-specific charts. A new statistical analysis technique and a large comprehensive stability database enabled the authors to quantify case history requirements and any site-specific effects the model exhibits. The analyses indicated that a reliable stable-failure boundary requires at least 150 case histories, of which a minimum of 10 percent should be unstable stope surfaces. Marginal site-specific effects were observed for the operating conditions captured within the database. The authors conclude that the apparent site-specific effects noted in previous literature are attributable to operating conditions inadequately represented in the database. Such operating conditions could induce erroneous stability predictions at any site, and are therefore not truly site-specific. Following from these conclusions, a strategy for taking into account operating conditions particularly relevant to narrow vein mining has been proposed. In particular, the development of a chart that accounts for the effect of backfill abutments on stope stability. Backfill abutment effects are particularly relevant to mechanised narrow vein mining methods such as modified Avoca. Collaboration from at least five sites is required to obtain access to relevant data and underground drives for geotechnical mapping. Preliminary estimations indicate that approximately three months fieldwork is required to meet case history requirements. CMS data in conjunction with 3-dimensional design software will be used to calculate equivalent linear overbreak/slough (ELOS). In contrast to stable, failure, major failure and caving categorical variables, ELOS is an objective and continuous stability variable and is therefore, more conducive to mathematical modelling.

Oct 1, 2001

By H S. Ellis

Flow studies have been conducted on nickel-water suspensions in a 1in.-diam., 42-ft.-long transparent lab-oratory pipeline at concentrations of up to 25 per cent, by volume, and slurry velocities of up to 15 ft/sec. The average size of the nickel powder was approximately 150 mesh (106J.L). Three flow regime were noted. At the highest velocities, i.e., above 10 ft/;sec., where the concentration distribution through the vertical diameter was most uniform, pressure gradients could be correlated with the Durand-Condolios equation (7,8). An intermediate region, i.e., from 7 ft/sec. to10 ft/sec., could be distinguished, the lower velocity limit being that at which nickel particles began to deposit. This region was also marked by decreasing pressure gradients, for a given concentration, as the velocity was reduced. The upper velocity limit in this region was also uniquely defined in that the friction factor for any nickel concentration was the same as that for water. In the third regime, below about 7 ft/sec

Jan 1, 1963

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

Concentrator Improvements -1990-1995Back to Basics ?pilot plant versus plant opportunities identified ?understand process fundamentals & baseline -1996-2000Point ?C?Projects ?strategy to improve global competitiveness ?structure implemented to generate & drive ideas ?capital investment for life of mine asset renewal - 2001-200?Six Sigma Methodologies ?emphasis on data, measurements & analyses ?dedicated, highly trained personnel on projects 1990-1995 Improvement Phase??Philosophy??back to basics?approach?understand what each piece equipment needed to do?understand reagents, control variables?confirm operating strategies ??probe, stabilize, institutionalize??test theories, confirm with lab and plant trials?process stability (equipment reliability, controls)?enhanced operator guidelines, operator training?focus on continuous improvement?optimize existing equipment capability?stop looking for ?magic?solutions 1990-1995 Improvement Phase??Technical?finer grind, same equipment?optimize media size/shape to grinding application?balanced available ball mill power to applications?lowered cyclone feed densities where possible?improved selectivity, same equipment?balanced available cells to applications?streamlined process (eliminate process steps)?added cleaning stages where required?understanding pulp/mineral surface chemistry?lowered flotation pulp densities 1990-1995 Improvement Phase??Effort?numerous studies to understand process?liberation and mineralogical characterization?pulp and mineral surface chemistry?flotation kinetics and entrainment?extensive internal and external manpower?Brunswick, Noranda Technology Centre?CanMet, AMTEL, MinnovEx, Lakefield Research, McGill University?small capital expenditure

May 1, 2002

By Ngonidzashe Chimwani, David Glasser, Diane Hildebrandt

"Milling circuits play an important role in achieving the desired product; tonnage, size distribution and properties, since they are directly linked to the comminution energy consumption for the whole process. A grinding model with a mathematical simulation was developed for an open milling circuit with a scalped feed from a hydro-cyclone. The circuit was optimized by determining the optimal conditions in terms of energy consumption which would produce a floatable product having a desired size range (i.e. -75 +9 µm) for a platinum-bearing ore. The simulation results showed an operating region comprising the best combination of the ball filling and mill speed to achieve the highest production of a floatable size class, with the minimum energy consumption.INTRODUCTIONBall milling is usually conducted in closed circuits in order to achieve a desired product size without material overgrinding. The technological importance of optimising milling circuits cannot be overemphasised (Toneva and Peukert, 2007). Previous work has brought significant insights into the benefits of modelling milling circuits (Austin et al., 1984; King, 2012; Toneva and Peukert, 2007). However, the ability to model these circuits is dependent on the performance of the classifiers and the fidelity of the grinding mill model used compared to the actual circuit (Toneva and Peukert, 2007). Austin et al. (1984) identified five types of milling circuits as shown in Figure 1 namely; the grinding circuits employing mill in an open circuit, normal closed circuit, reverse closed circuit, open circuit with scalped feed, and, the combined closed circuit. Depending on the presence of the first classifier, the second, or both as well as their corresponding loops (streams), the combined circuit (e) can reduce to; an open (d), a normal closed (b), an open circuit with scalped feed (c) or a reverse closed circuit (a). In the case of an open circuit, the mill is operated without being directly influenced by a classifier. The normal closed circuit does not have the first classifier and therefore the make-up feed is the actual feed stream. Conversely, the reverse closed circuit keeps only the first classifier. The open circuited with scalped feed has only the first classifier but does not have the second one. The overflow stream from the classifier is mixed with the mill product to form the final product for the downstream process."

Jan 1, 2016

By E. Asselin, G. K. Yue

"In the present study, electrochemical measurements, especially cathodic potentiodynamic polarization (CPC) and cyclic potentiodynamic polarization (CPP), have been employed to study the kinetics of ferric reduction on chalcopyrite in aqueous Fe(II)Fe( III)H2SO4 solution at 90 °C and 110 °C. Results from the calculation of speciation in the above solution reveal that, at both 90 °C and 110 °C, the real Fe3+/Fe2+ ratio is much lower than the nominal ratio, which leads to smaller VALUES (for the reversible potential of the ferric/ferrous couple. Exchange current densities of the ferric/ferrous couple were obtained and are on the order of 106 10 5 A/cm2 a t 9 0 °C and 1 07 10 6 A/cm2 at 110 °C, respectively. The Tafel slopes from the CPP method are higher than those from the CPC method at both 90 °C and 110 °C. The transfer coefficients were about 0.360.59 at 90 °C and 0.370.65 at 110 °C. Based on the exchange current densities obtained, the rate constant kc was calculated. It was found that kc at 90 °C was slightly larger than at 110 °C, especially for the results obtained by the CPC method. The average rate constants are 862.17 cm/s for CPC and 65.30 cm/s for CPP at 90 °C, and 477.69 cm/s for CPC and 63.53 cm/s for CPP at 110 °C for nominal Fe3+/Fe2+ ratios ranging from 1:1 to 1000:1. INTRODUCTIONChalcopyrite is one of the most abundant copper-bearing minerals, accounting for approximately 70% of the world’s known copper reserves (Wang, 2005). Most of the currently proposed leaching processes are based on sulfuric acid with ferric ions and/or dissolved oxygen as oxidants. Some of these processes have been piloted in attempts to implement these technologies on an industrial scale, such as Activox (U.S. 5,232,491, 1993), Nenatech (U.S. 5,993,635, 1999), Dynatec (U.S. 5,730,776, 1998), AAC/UBC (U.S. 6,503,293, 2003), Total Pressure Oxidation (U.S. 5,698,170, 1997), CESL (U.S. 5,874,055, 1999) and Galvanox (U.S. 7,846,233, 2010).To date, much effort has been devoted to understanding the kinetics and mechanisms of the oxidative processes (Biegler & Horne, 1985; Córdoba, Muñoz, Blázquez, González, & Ballester, 2008, 2009; Ghahremaninezhad, Asselin, & Dixon, 2010; Hirato, Majima, & Awakura, 1987; Hiroyoshi, Kuroiwa, Miki, Tsunekawa, & Hirajima, 2004; Warren, Wadsworth, & El-raghy, 1982) or the cathode reduction reactions of chalcopyrite itself (Arce & González, 2002; Biegler & Swift, 1976; Biegler, 1977; Nava, González, Leinen, & Ramos-Barrado, 2008), by chemical or electrochemical methods. However, as the most important cathodic processes in chalcopyrite leaching systems, the cathodic reductions of ferric ions or dissolved oxygen are worth measuring due to their effects on the overall leaching rate, as predicted by mixed potential theory."

Jan 1, 2012

By Terry Bachynski

_ Regulatory Process _ Approval Timelines _ Trends _ Stakeholder Consultation Expectation _ Challenges _ Initiatives for Regulatory Process Reform _ A Better Way? Alberta Regulatory Process _ Regulatory Approval of a major capital development requires multiple approvals from several regulatory authorities: ? EUB ? Decision Report approves development scheme and recommends conditions for other regulatory agencies ? AEnv ? approvals to construct, operate and reclaim required prior to any in field construction activity ? Federal - approvals for federally regulated activities ? Municipal ? Development Permit

May 1, 2004