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By J. Abrahams, A. Nesbitt

Over the past half-century, researchers have commented on the complexities of ion-exchange processes, but have been forced to use gross assumptions to simplify the associated mathematics sufficiently for mathematical models to be of practical use, given the available computational power. This paper reviews the development of increasingly complex models as computational power has increased over the past half-century, from the direct application of Fick's Law in 1947, through to today's models requiring finiteelement methods. The assumptions required for and the associated limitations of the various models are presented and the associated computational complexities are discussed. A case study is presented in which a continuous loss of capacity in an acid resin was observed over about sixty cycles of loading and elution. Resin poisoning does not explain this observation. This paper presents the capacity loss data, speculates on possible causes of the phenomenon, discusses why conventional kinetic and equilibrium mechanisms cannot explain it and concludes that the need to develop a more rigorous model is apparent. The significance of this observation is that standard tests done for a new resin application could significantly overestimate the commercial performance of the resin concerned, highlighting the importance of computer simulation in this field of process engineering.

Jan 1, 2005

By A. P. E. Dirige

The stability design of cemented backfills is normally conducted using conventional approaches. Analytical or numerical models, backed by trial-and-error methods, are the primary means used to describe or predict the support performance of backfills during mining. The stability of paste backfill free-standing faces is a major concern due to potential consequences to production, ore dilution and safety. Available analytical or mathematical models are developed based on assumptions of the failure modes that may occur when vertical fill faces are exposed during adjacent mining. Numerical modeling serves to provide an understanding of backfill strength and deformation behaviour. Such approaches offer inherent limitations and generally result in conservative designs. In this paper, centrifuge physical modeling was conducted not only for performance evaluation studies, including stability analysis, but to develop an understanding of the strength and deformation behaviour of paste backfill exposed faces when the adjacent ore zone is removed. The failure mode and mechanics of failure observed in the centrifuge model of a given prototype situation are discussed in detail. Centrifuge model results were compared to numerical modeling and it was concluded that a sliding block failure mechanism that resembles a circular slip appears to be the predominant failure mode.

Aug 1, 2013

By L. R. Bower

"This paper describes a highly versatile variable speed unit with a torque multiplication feature as a direct replacement for a fluid coupling .The unit is comprised of a modulating clutch with torque converter and lock-up options.The UCD does not start or stop the motor. This is carried out in the normal manner.The UCD continually monitors and rapidly regulates the output speed to the requirement of a set point demand from input signals or a pre-set program with full manual override.The pre-set program can include start and stop ramps, top speed and minimum speed regulation and also mid-speed set point with security for man-riding, etc. Speed variation is from zero to 100% on a constant duty basis.The input signals can be from any source, e.g. belt weigher. load profile bunker probes, mine monitoring system, etc.The UCD when fitted with a torque converter has a torque multiplication feature which automatically provides a starting torque up to two and a half times greater than the full load torque without exceeding the normal motor power levels.IntroductionIt is common practice in the mining industry to drive conveyors, whether they be belt or chain, through a transmission system incorporating a fluid coupling between the driving motor and gear-box .However, there are drawbacks and in an effort to attain a better degree of drive and control, two-speed motors - inverters cycle- converters - hydrostatic drives, etc ., have been introduced."

Jan 1, 1986

By J. A. Beesley

This paper reviews contemporary international law concerning the seabed, current developments in the United Nations on the seabed, and the main outstanding problems. It emphasizes the importance that the Canadian government attaches to this area.

Jan 1, 1969

By A. Gourlie

"This paper describes the performance properties of a new 95 ksi minimum yield strength, oil well casing grade designed specifically to resist hydrogen sulphide stress corrosion cracking, SSCc. The new grade, Soo-95SS, demonstrates NACE Tensile threshold values greater than 90% specified minimum yield strength, SMYS, and NACE Bent Beam values in excess of 12.7 x 1()4 psi. The new Soo-9588 grade also exhibits superior collapse and notch toughness values. IntroductionIn recent years, a trend toward casing grade specialization has resulted in the introduction of numerous proprietary grades designed specifically for particular production environments, In response, Algoma Steel has developed, as part of a "" grade for service"" philosophy, two new 95 ksi minimum yield grades. The two grades are Soo-95, High Collapse (HC), and Sour Service (SS). This paper describes the development of Soo-95 Sour Service.Four main objectives were established:1. Definition of the steelmaking and continuous cast processing practices2. Determination of the acceptable maximum and minimum levels for all chemical elements3. Definition of special processing requirements4. Definition of the physical characteristics and ranges of the product properties.This paper provides a description of the experimental approach, followed by a presentation and discussion of the trial results . Finally, a number of conclusions are given."

Jan 1, 1988

By E. M. De Souza

"A scientific testing program, sponsored by the Mining Industry Research Organization of Canada (MIROC), was undertaken on the surface and underground facilities of Inca's Crean Hill Mine to investigate the effectiveness of using dry drilling with a dust control system.The surface test work consisted of the monitoring of advance rates and bit life white a series of 165 mm holes, wet and dry, were drilled at both mine air (0.69MPa) and high pressure air (1.72MPa). The results, based on statistical evaluations of field data, indicated that penetration rates can be increased by an average of 24% when drilling dry with high air pressure and by approximately 27.5% when drilling dry with mine air as compared with wet drilling under the same conditions. Dry drilling also has the effect of reducing button wear by approximately 69% using high pressure air. The underground test work employed a dust collection system developed for use with large diameter holes (165 mm) and high pressure drilling. The testing program has indicated that an average increase in penetration rate of 35% can be achieved when dry drilling in rock (waste) and of 49% when dry drilling in ore with high air pressure. Although preliminary dust monitoring did not indicate any appreciable increase in dust concentration during dry drilling, further dust monitoring is still required.A comparative cost analysis has indicated the potential for reduction in drilling costs when dry drilling is utilized. Further testwork is to be conducted to develop a reliable dust collection system for underground production."

Jan 1, 1992

By J. Weyer

"Threshold limit values (TLVs) for NO and NO2 have been reduced drastically in 2016. Emissions of diesel engines have been reduced in the last decades. In many cases this is not enough to stay under required TLVs. Remaining gas in the blasted rock is set free during loading and transport. At the end, only a combination of measures with a further reduction of diesel motor emission, replacement of diesel driven vehicles by electric equipment, new explosives with reduced NO and NO2 production, changes in the organization and effective ventilation measures can ensure that the TLVs are not exceeded. KEYWORDS Blasting fumes, Gas measurement, Gases, Threshold Limit Value (TLV) SHORT HISTORY OF EXTRACTION OF RAW MATERIALS The extraction of raw materials—besides haulage and transport—is one of the main processes in mining and tunneling. The principal objective is the creation of a material which can be transported from the place of extraction (face) to another place for further processing or direct use. Furthermore, recently a desired grain size distribution has become more important. A revolutionary development took place in the course of centuries. With the use of primitive tools like shovels, chisel and iron in the 12th/13th century in Freiberg, ore mines performances of 12 16 cm per man and week could be reached in cross section of 1 m2. Recalculated with an assumed average density, this is a performance of 0.006 t/h. With the introduction of black powder into the subsurface in 1627 by Caspar Weindl in the city of Schemnitz (nowadays Banska Stiavniza), performances increased. A part of the hard extraction work was now done by the explosives. But first in 1767, it was recognized in a mine in Freiberg that more than 1 hole could be drilled (hand-drilling) and blasted. This discovery was so important that a plate with an inscription describes this event. The performance was increased more than 10 times compared to the extraction with chisel and iron. Since this time, drilling and blasting has been the most important innovation force for the increase of the performance. Problems with noxious blasting fumes led to the construction of the first tunneling machine by Henry Joseph Mouse in 1846 (beside shield machines from 1825) (Stack, 1982)). The triumph of mining machines started only interrupted by the two world wars. The development of hard rock boring machines (including roadheaders) was enforced after 1945. An almost complete extraction by hard rock boring machines was predicted for the turn of the millennium. And, indeed, one could find powerful machines in Canadian potash mines which were able to mine 1000 t of potash in 1 hour. That was an increase in the performance by several powers of ten. But already in the 1980s, it was recognized that the ambiguous goal could not be reached. Problems with wear of the tools, radius of curves, minimal length of openings, size and costs of the machines led to a more or less parity between drilling and blasting on one side and machines on the other side, of course depending on the field of use. For this reason, drilling and blasting is still the dominant extraction technology for raw materials. In the development of drilling and blasting technologies, the focus was mainly on the improvement of the safety but also on the increase of the blasting power and performance. Examples are tests for the increase of the power of ANFO explosives which were carried out in the 1970s and 1980s, in the former teaching mine “Reiche Zeche”. In the 1980s vehicles for loading and mixing of ANFO explosives have been developed, the blasting cab sensitivity of ANFO has been increased, emulsion explosives have been developed and up to now further developments like PMMA LOX EX explosives are on the way. At the turn of the millennium, 6 million t/a explosives have been used worldwide. Annual rates of increase of 2% have been predicted (Weyer, 1999). Meanwhile the focus changed from an increase of the performance"

Jan 1, 2019

By E. Fritz

This paper reviews the history, developments and 10 milestones of the oxygen steelmaking processes, with a special focus on conventional autothermic converters, high-speed converters with a blowing rate up to 5 m3n/t min and allothermic converters with coal addition, post combustion and the possibility to increase the scrap rate up to 50%. Related operating results are introduced. A new process route, which is based on hot metal and chromium ore, is outlined. The cost advantage for the production of 304 stainless steel grade is higher than 100 USS/t. The synthesis of EAF and oxygen converter steelmaking, a comparison of decarburization rates, refining combustion burners for optimized oxygen-management in EAF and an example for a large advanced EAF are outlined. Possibilities of flexible steelmaking and the growth and outlook of worldwide oxygen steelmaking are described.

Jan 1, 2004

By F. McCarthy, R. McDonald, G. Woodbridge, G. Brock, D. Robinson

"The Direct Nickel process is a hydrometallurgical technology being developed to treat nickel laterite ores by leaching at atmospheric pressure. The leaching process uses nitric acid in a relatively large excess, is thus non-selective, and much of the soluble iron goes into solution. The first stage of solution purification is iron hydrolysis and the Direct Nickel process utilises the colligative properties of the pregnant leach solution (PLS) to enable the removal nitric acid of varying concentrations via distillation. Once sufficient acid has been removed, the boiling point of the solution is increased allowing high temperatures (up to ~170°C) to be achieved under atmospheric pressure. The higher temperatures initiate the precipitation of the iron primarily as hematite and allow the removal of the acid generated by the hydrolysis reaction. The rejection of the iron is near complete with solution tenors typically falling from 65 g/L Fe, or more, to less than 50 mg/L Fe. The separation of clean nitric acid from the PLS at this stage allows for relatively simple acid recycling. A hematite product with iron content above 60% could also provide an extra revenue stream.INTRODUCTION The Direct Nickel (DNi) Process is a novel hydrometallurgical processing route designed to treat all types of nickel laterite ores in a single flow sheet using nitric acid under atmospheric conditions. A simplified flow sheet is shown in Figure 1.Between 2007 and 2012 the process was developed and refined at Direct Nickel’s laboratory within the CSIRO Minerals’ facilities in Perth, Australia, and in 2013 a series of pilot plant trials were run under continuous operating conditions. The process is designed to treat both limonite and saprolite in the same flow sheet, and after comminution, the blended ore is mixed with nitric acid and leached just below boiling point in agitated atmospheric leach tanks. The acid is added in excess, so typically for a blend of limonite and saprolite the acid addition can be in the order of 1.8-2.0 t acid/t dry ore. After a residence time of between 4-6 hours the majority of the soluble metals have leached into solution and the insoluble leach residue is separated from the pregnant leach solution (PLS) via counter-current decantation."

Jan 1, 2016

By Z. D. Hora

Brick shales and refractory clays are mined at Sumas Mountain near Abbotsford. Sholes and stoneware clays elsewhere in the province have not been developed. THE SUMAS MOUNTAIN deposit near Abbotsford, 80 km east of Vancouver, has been in continuous production since 1905. The deposit is exposed in a small outlier and comprises a sequence of alternating beds of clay and sand. Beds are of Eocene age. Within the 400 m thick ness of sediments are seven distinctive conglomerate members, some up to 20 m thick, interbedded with fine grained sediments including claystones and siltstone , or "shales". Shale is quarried to produce a variety of bricks, sewer pipes and similar products; it is also used for cement. Several different shale beds have been mined over the years and exhibit a variety of fired colours ranging from buff-pink grey to deep red; pyrometric cone equivalents (PCE) range from 3 to 20. A layer of fireclay 3 to 4 m thick that occurs at the base of the sequence has pinkish white to light buff fired colour and PCE of 30 to 33. It is used as a 266 primary component to produce refractory bricks. The shale is quarried and processed by Clayburn Industries Limited of Abbotsford. Another similar but smaller outlier of the same geological formation is known from Blue Mountain, about 20 km northwest of Mission. Other ceramic clays in British Columbia are reported from Quesnel (7 m bed of white stoneware clay, PCE 17 to 19), Giscome Rapids (25 km north of Prince George, 10 m bed of stoneware clay to PCE 31) and anaimo-Comox area (buff to red firing "shales", PCE 8 to 10-1 12) . From 1959 to 1974 Cretaceous shale from Saturna Island in the Strait of Georgia was used to produce lightweight aggregate. Similar deposits of expanding shale are known from the vicinity of Duncan on Vancouver Island.

Jan 1, 1984

By T. W. Wlodek

"AbstractIn this paper a new type of durable 'spiral-rolled' drill set is introduced and its performance discussed. Efficient and economical mine drilling-depends to a great extent on durability of the drill-set employed. Premature failure of this element damages the drill bit and is costly when tungsten carbide bits are used.Time of drilling of 'spiral-rolled' drill sets introduced at present in Canada is considerably larger than for the presently used drill steel, but laboratory simulated service tests and practical field tests show that the 'drilling life' of the spiral-rolled drill set is several times that of ordinary drill steel.Some features of differential plastic deformation and differential surface rolling, so called 'spiral-rolling', are given.Relations between the drilling machine drill set and characteristics of the ore are discussed. The effect of shims on conical drill rod attachments, the mechanism of failure of drill steel, .and stresses during mine drilling, are analysed.IntroductionIN MINE DRILLING operations, the main interests are: the drilling machines as a source of working energy, the drill set as the tool transferring the working energy to the cutting edges of the bit, and, finally, the drilling characteristic of the .ore or waste rock.This paper includes a review of the possibilities of metallurgical and mechanical improvements in the drill set, with particular attention to drill steel and the attachments.For economical and efficient mine drilling operations, a durable drill rod, attachment, and drill bit are essential. Premature failure of any of these parts interferes with mining operations and is costly."

Jan 1, 1955

By Asfahani. Jamal, Randa Mohamad

"Abstract - Electrical and structural characteristics of formations favorable for sulfur occurrences in northeast Syria are described using geo-electrical prospecting methods. Simple (VES) and combined (CVES) Schlumberger vertical electrical soundings and geo-electrical profiling using a Wenner configuration were applied to the Teshreen structure. Six profiles (A, B, C, D, E, and F) at the borders of anticlines, where positive and negative structures are joined and salt formations have a tendency to disappear, were studied.Secondary structures, characterized by high apparent resistivity exceeding 3000 Ohm.m were located on each profile using a Wenner profiling configuration. These secondary structures are demonstrated to be favorable for sulfur prospecting by both drilled wells and vertical electrical soundings. Traditional interpretation of the 84 VES measurments is supported by data from 14 CVES measurments. The CVES technique is a powerful tool, due to its improved resolution of the electrical boundaries.Thicknesses and resistivities of the Lower Al-Fares, Al-Garibeh, and Al-Dibbaneh formations were determined through the interpretation of VES measurments. The same VES measurments were then interpreted using the Pichgin method, whereby all the subsurface tectonic features were determined for depth penetration corresponding to AB/2 = 1000 m. The integration of the first and second VES phases creates a clear picture of the subsurface, including tectonic, geometric, and geoelectrical information. In summary, the sulfur occurrences in the research area are controlled by tectonic paths that are well defined by geo-electrical methods. These diverse geo-electrical methods could be used successfully for sulfur prospecting in similar environments."

Jan 1, 2002

By G. A. Peebles

"This paper describes the various types of radiometric instruments and the techniques of their operation for grade control, sampling, assaying and probing drill holes at Eldorado Nuclear's uranium mine in northern Saskatchewan. Modifications that have been made to these instruments are discussed, and suggestions are made for the development of more refined and specialized radiometric equipment."

Jan 1, 1969

By R. G. McDonald

"High iron solution concentrations often result in the formation of basic ferric sulfate during the high temperature oxidation of sulfidic materials such as base metal and refractory gold concentrates. Consequently, the “Hot Cure Process” followed by limestone neutralization is required to facilitate subsequent processing and/or disposal of the leach residue. The present paper discusses strategies that can be employed to influence the composition and nature of the high-iron content leach residues produced during pressure leaching.INTRODUCTION Control of iron deportment in hydrometallurgical processing remains a key challenge for a range of reasons. Strategies generally relate to the control of conditions under which iron is optimally rejected (Demopoulos, 2009). Supersaturation provides the driving force for crystallization and this can be controlled by a number of factors that include (1) pH and/or Eh control, (2) the presence of matrix anions and impurities, (3) dilution, (4) complexation and dissociation and (5) manipulation of the rate at which the metal to be precipitated is released to solution. Each of these factors is impacted by temperature. Good control of crystallization is essential to the control of precipitate properties such as the degree of crystallinity, stability, particle size and quality which covers both the extent of impurity uptake and suitability of the precipitate for waste disposal. The quality and properties of iron precipitates in turn can impact downstream processing. It is the aim of this paper to discuss the generation of iron-containing residues produced during the pressure oxidation of sulfidic ores and concentrates and how the nature of these can be controlled to potentially facilitate further processing. A brief overview of several related topics will now be given and include, where relevant, discussion of work undertaken in our laboratories. In addition, brief discussions of selected process options that enable good control of iron rejection will be provided."

Jan 1, 2016

By Y. H. Hatzor

"This is an extended abstract for a keynote lecture delivered by the author during the 2015 ISRM congress in Montreal on the application of the numerical discontinuous deformation analysis (DDA) method in rock mechanics practice. Due to the large scope of the topic this lecture will focus on studies performed by the rock mechanics group at Ben-Gurion University, alone or in collaboration which other research groups, and is not intended to provide a comprehensive review of everything that has been done on the subject worldwide during the past two decades. A forthcoming textbook (Hatzor et al., in preparation) will attempt to provide such comprehensive coverage.DDA has been developed by Dr. Gen-hua Shi while he was doing his PhD studies under the supervision of Professor R. E. Goodman at U. C. Berkeley (Shi, 1988). Dr. Shi has invented a new numerical discrete element method which provides a solution for dynamic deformation of block systems, hence its applicability to rock mechanics practice. The method is similar in essence to the finite element method in its implicit formulation of the time integration scheme and where in every time step the minimum potential energy of the entire system is sought, but here every element is a finite block with six degrees of freedom. The blocks are assumed to be stiff (simply deformable) so that most of the energy is consumed by slip along pre-existing discontinuities, the frictional resistance of which is assumed to obey the Coulomb-Mohr failure criterion for rock joints. The greatest advantage of DDA over alternative numerical discrete element methods is its robust area (volume) integration which ensures great accuracy even when the blocks are of irregular shapes, including non-convex blocks which may contain holes. The greatest disadvantage is the necessity to solve in every time step very large matrices of unknowns, imposing great CPU demand when the block system involves a large number of blocks. Another disadvantage is the sensitivity of the solution to the choice of the penalty parameter which is implemented in DDA in the form of stiff springs that are attached to contacts once detected automatically.The inherently dynamic formulation of the DDA method lends itself to solution of dynamic problems in rock mechanics. Dynamic analysis with DDA can be performed in different ways corresponding to different rock mechanics problems and loading conditions. Three main classes of loading conditions which are relevant to rock mechanics applications are discussed here: 1) dynamic loading of a single bock which rests on a stationary foundation, 2) response of a block to dynamic loading of the foundations, 3) wave propagation through a block system.The most common approach is to introduce the dynamic force to a specific block in an otherwise fixed block system and check the resulting deformation, typically the time dependent displacement or rotation of the loaded block. This approach is particularly useful for dynamic rock slope stability studies when a stability of a specific rock block against earthquake vibrations is in question. The first 2D-DDA benchmark test of this approach was performed by Hatzor and Feintuch (2001) who introduced harmonic acceleration functions into a block which rests on an inclined plane. The analytical solution proposed for this problem by Hatzor and Feintuch (2001) was later generalized by Kamai and Hatzor (2008). The first 3D-DDA benchmarking for this approach was presented by Bakun-Mazor et al. (2012) who studied single and double face sliding of blocks which rest on stationary foundations and subjected to harmonic input acceleration functions."

Jan 1, 2015

By A. J. R. Smith

"CANADA'S ECONOMY TODAY is about two-fifths larger than it was six years ago, as measured by the total volume of production of goods and services. Such an achievement has been a rare phenomenon in Canada's first one hundred years. Excluding the forced-draft expansions which took place under war-time conditions, perhaps only the first decade of this century recorded a performance of greater dimensions, when, with massive immigration, the opening up of the West and a powerful array of well-de-signed development policies, the country was looking forward confidently to a great future of nation-building in the twentieth century.What makes Canada's over-all economic advance since 1961 all the more remarkable is that six years ago there was virtually no one in this country who anticipated an expansion of such dimensions. Back in the buoyant conditions of 1956-57, perhaps such an achievement would not have seemed beyond our grasp. After 1957, however, Canada stumbled through an extended period of slow economic growth, high unemployment and substantial and widespread under-utilization of its productive capacity. By the early 1960's, conditioned by the emergence of substantial, persistent and pervasive slack in the economy, t h e r e were few Canadians bold enough to anticipate that their economy was about to embark on a Great Expansion. However, this •is, in fact, what occurred. Beginning early in 1961, Canada moved forward into a sweeping advance which grew into the longest and largest peacetime business expansion in Canada's first century as a nation -a truly great expansion by any standard of measurement. This strong thrust has moved Canada into the front ranks of over-all economic expansion among the industrially advanced nations in the 1960's."

Jan 1, 1970

By G. H. K. Pearse

Sulphur is derived from both 'voluntary' and 'involuntary' production. The former category includes sulphur obtained from elemental sulphur deposits and from pyrite and gypsumanhydrite deposits. Sulphur in the latter category is produced by pollution abatement at fossil Juel plants and from treatment of metallic sulphides. Canada is the world's largest sulphur exporter and third largest producer. Main resources of Canadian sulphur are sulphurous fossil fuels, metallic sulphides and native sulphur. Only the first two sources have produced sulphur in Canada 10 date; the first source accounts for over 85% of total Canadian production. Future sulphur sources will be derived increasingly through pollution abatement and decreasingly through voluntary production.

Jan 1, 1984

By Pierre Buteau

Peat/ands distribution in Canada is widely spread thoughout the country and corresponds to a wide spectrum of wetland habitats which overlay peat deposits. The development and the evolution ofpeat/ands and peat deposits are closely linked together, since the vegetal remains of the peat deposits originate from the peatland habitats, and the peatland habitats constitute a response to many factors, including the properties of the substrate, which are the peat deposits. Peat/ands are defined as waterlogged terrains where the production of plant materials usually exceeds the rate of decomposition. The underlying peat deposits consists of organic residues associated to peatland vegetation, more or less decomposed, built up and kept under anaerobic conditions. Peat/ands evolution and distribution are determined primarily by climatic factors, but also by the geomorphology and edaphic conditions. All of these create particular hydrodynamical environments which will vary according to different regional settings, and sequentially to an evolutive time frame.

Jan 1, 2001

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015