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By K. Lillkung, J. Kourunen, M. Latva-Kokko

"Carbon-in-leach (CIL) and carbon-in-pulp (CIP) processes utilize activated carbon to adsorb solubilized gold for recovery. Due to carbon attrition and non-ideal carbon management, however, some of the gold is lost in carbon fines and to the solution. The carbon attrition mechanism inside CIL/CIP reactors is mainly abrasion-related. This is critical to gold loss since gold loading takes place predominantly in the outer shell of the carbon particles. Thus fine carbon dust has a relatively high gold content and such a small particle size that it cannot be captured with safety screens. The attrition rate depends on ore and carbon characteristics, but it is always proportional to the mixing power intensity. This rate can be minimized by continuous suspension level measurement and control of agitation speed. In addition, a novel tank bottom structure can significantly reduce the required mixing power input compared to a flat bottom tank. A major challenge in carbon management is infrequent and inaccurate measurement of carbon concentration in the reactors. In order to reduce soluble gold losses by means of improved carbon management, Outotec has been developing a continuous in-situ measurement for carbon concentration that is tolerant to changes in slurry density.INTRODUCTION Cyanide leaching has been utilized since the late 19th century as a standard technology for hydrometallurgical gold production. Since then, gold and silver recovery rates have increased due to technological development, but very similar recovery methods are still being used. The original recovery method was to use zinc precipitation – similar to the Merrill-Crowe process, which is still common for feed materials with low throughput and high silver content. However, in most cases, activated carbon recovery is preferred due to its improved efficiency. The carbon-in-pulp process (CIP) and its modification, carbon-in-leach (CIL), have a lower residual soluble gold level and are not similarly affected by soluble base metals. The main alternative for the use of carbon is ion exchange resins. The principle of resin processes is similar to the CIL/CIP processes, with a different type of adsorbent material. Carbon processes are usually preferred over resin processes due to the significantly higher cost of resin material and the possibility to use simpler, well-established technology with carbon processes."

Jan 1, 2017

By N. Bartie

Realising the circular economy (CE) is faced with some significant challenges. Process metallurgy and its infrastructure play key roles at the heart of making the CE work. Therefore, the enabling role of process metallurgy within the CE will be central to the discussion in this paper, touching among others on product and system design as well as the key metallurgical and other process fundamentals that need to be investigated and understood to make the CE a reality. The central role of materials and its processing will be discussed in an integrated circular cities perspective. A key focus will be a discussion on designing a resilient “Smart Materials Grid” using and innovating metallurgical process engineering tools, which will manage the flows through Sustainable Circular Cities. The discussion will be using copper as leitmotiv of the discussion i.e. from copper ore, to metal, to complex products, recycling, product design and simulation and its impact. INTRODUCTION The transformation of our economies from linear to circular models in which waste materials become resources is the focus of the Circular Economy (CE) paradigm. Its important intentions: to take control of the damage we have been doing to the planet to ensure its livability and the welfare of future generations. This can only be achieved through careful utilisation of human, natural and economic resources. The concept is derived from several others (Beaulieu et al., 2015), of which Cradle-to-Cradle, Extended Producer Responsibility (EPR), Industrial Ecology, and Life Cycle Thinking are just a few. Other relevant concepts include resource efficiency (RE), design-for-recycling (DfR), and various others discussed by Blomsma and Brennan (2017) and Homrich et al. (2018), as well as various R-hierarchies e.g. Reduce, Reuse, Recycle (3R). However, does society comprehend these concepts, the actors and actions that influence them and how they interact? Do we know the limits of CE? Does society understand the key role of Copper and other metals to rendering the CE operable? True life cycle and systems thinking, focussed on simulation-based, process and metallurgical design are required to answer these questions. Lieder and Rashid (2016) identify nine widely-varying fields that study the concept ranging from sustainability sciences and engineering to economics, business, law, and social sciences. Overlap between questions addressed highlights the need for interdisciplinary collaboration (Nanz et al., 2017) in the assessment of the current status, and further steps needed to transform to CE. This doesn’t apply just in academia, but also in industry where concrete implementation of CE needs to occur at multiple levels, thus necessitating cooperation between government, civil society and other stakeholders (Beaulieu et al., 2015).

Jan 1, 2019

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By C. Ayora

The Iberian Pyrite Belt (SW Spain and Portugal) contains one of the largest reserves of pyrite in the world with mining activities dating back to prehistoric times. About one hundred abandoned mine wastes and galleries release a huge acidity and metal load to the Tinto and Odiel rivers. Once the mining activity is over, polluting discharges can persists for decades or even centuries with no specific responsible entity. In-situ passive remediation technologies are especially suitable for these orphan sites. The concept is to insert a reactive porous material in the natural flow path of contaminated surface and ground waters, and it is implemented through infiltration ponds and reactive barriers, respectively. Calcium carbonate pea-size gravel is the common alkalinity supplier to neutralize acidity and precipitate metals. These remediation systems have been traditionally implemented in coal mines. However, the acid drainages from the Iberian Pyrite Belt contain metal concentrations one to two orders of magnitude higher than those from coal mines and require special designs to avoid quick clogging or passivation (coating) of the grains of reactive material. To overcome these problems, a Dispersed Alkaline Substrate (DAS) mixed from fine-grained limestone sand and a coarse inert matrix (e.g. wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate. The high porosity and the dispersion of nuclei for precipitation on the inert surfaces retard clogging. However, limestone dissolution only raises pH to values around 6.5, which is sufficient to precipitate the hydroxides of trivalent metals (Al, Fe), but it is not alkaline enough to remove divalent metals. Magnesium oxide, which hydrates to Mg hydroxide upon contact with water, buffers the solution pH between 8.5 and 10. A DAS system replacing limestone with caustic magnesium oxide has been tested to be very efficient to remove divalent metals (Zn, Cd, Mn, Cu, Co, Ni, Pb) from drainage previously treated with limestone.

Aug 1, 2013

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

By J. R. Meyer, P. L. Dean

"The Department of Mines and Energy is at present investigating the dimension-stone potential of the Nain anorthosite complex. These rocks are known to host occurrences of labradorite, a semiprecious gemstone known for its beautiful play of colours (chatoyance). Test blocks that contain 5% to 18% chatoyant labradorite were extracted from three prospects south of Nain. These have been slabbed and polished for further evaluation.Second-grade labradorite stockpiled around the Grenfell quarry on Tabor Island is also being evaluated as a potential source of aggregate for use in terrazzo tiles, precast concrete and epoxy-backed wall panels.IntroductionThe Nain anorthosite complex consists of approximately 10000 km2 of anorthosite and related basic rocks , which are well exposed along the coast of Northern Labrador (Fig. 1) (Emslie et al., 1972). These rocks have been known for centuries to host deposits of gem-quality labradorite. The chatoyant nature (i.e. the play of colours or labradorescence) of this semiprecious feldspar has been utilized mostly in the making of jewelry and other polished, handcrafted products. In the early sixties, Brinex Limited (now Brinco Limited) attempted larger scale commercial exploitation of labradorite, including use 'as building stone and in polished precast concrete for facings on buildings' (Brummer, 1984). After six years of work, which included market studies, Brinex decided that, at that time, the demand did not warrant further production.In recent years, there has been a dramatic increase in the markets for dimension-stone. In the period from 1980 to 1985, the demand in the United States for granite, much of which is imported, has increased 1735070 (Marble Institute of America, 1986). The dimension-stone industry's remarkable growth rate has, in part, resulted from new technology that makes it easier and faster to quarry and cut stone. This has allowed natural storie to compete with other building materials. Now, it is not only used for exterior cladding and walkways, but also on interior walls and floors, and in home and office furnishings, such as countertops for kitchens and bathrooms, table and desk tops, stairways, window sills, and fireplaces."

Jan 1, 1988

By Gordon Smith

ABSTRACT Gold-bearing quartz veins in the northeastern Ontario and north western Quebec mining camps are shown to have been mineralized in part by epithermal solutions. The vertical gradient of pressure during this stage of mineralization is calculated, using decrepitation temperatures of quartz and thermoelectric potentials of pyrite. The base of the Cobalt sediments, which lie uncomformably over part of the mining region, may be taken as datum level in calculating the depth of erosion into the basement below that level. The vertical extent of the epithermal gold mineralizaiton in this region is at least 9,000 feet below the datum level. INTRODUCTION IT WOULD have been difficult a few years ago to convince economic geologists that after making a series of measurements in a laboratory in Toronto, the depth of erosion which has taken place below the base of the Cobalt sediments at any place in the Ontario-Quebec mining region can be calculated to the neare.st 500 feet, or that the same series of measurements would also serve to allow a prediction of the minimum vertical depth of probable ore in a producing mine in the same region, with the same degree of certainty. Possibly it is just as difficult today, but the following description of the data and calculations may help to demonstrate the reliability of the method.

Jan 1, 1951

By Craig H. B. Leitch

"In describing the alteration of porphyry systems, the term ""secondary K-feldspar"" appears to be an oversimplification. A better term would be ""alkali feldspar"" alteration, because in actual fact the replacement feldspars show gradational changes from an albite, which is important in some systems, to an alkali feldspar containing minor orthoclase molecule, to true orthoclase.There are several textural varieties of secondary alkali feldspar present in the porphyry systems studied from British Columbia, Australia and New Zealand. These include, in apparent increasing order of alteration intensity: clear albite (An10); patchwork albite (An5-10); chessboard albite (An0-10); ""irregular albite "" (An0Ab100 to Ab90Or10); untwinned ""anoralbite"" (Ab90Or10 – Ab70Or30); and orthoclase (Ab40Or60 - Or100)·The exploration significance of these varieties of alkali feldspar is that their gradation in composition, from sodic to potassic, may be linked to a corresponding increase in intensity of alteration. Thus, there is a tendency for more sodic alteration feldspars to characterize weak, sub-economic deposits, or the fringe zones of stronger deposits; the more potassic alteration feldspars may provide an exploration vector toward more highly mineralized zones."

Jan 1, 1981

By F. F. Roberto

Sulfuric acid has been demonstrated to be an efficient lixiviant for in situ extraction of copper in the past. It has also been proposed that microbial production (by iron-oxidizing acidophilic bacteria) of acidic ferric solution either in situ or ex situ could provide an economic strategy to generate an effective lixiviant for secondary copper sulfides like chalcocite and covellite. Copper heap bioleaching also takes advantage of this approach. One of the major environmental challenges for in situ copper recovery projects is the containment of acidic solution within the ore deposit, and ultimate restoration of the depleted ore body to its original state. A perhaps overlooked aspect of projected site operations is the possibility that transient acidic conditions and pumping of solutions from surface reservoirs into the subsurface could stimulate the growth of iron- or sulfur-oxidizing species of acidophilic microbes in the ore body, leading to additional generation of sulfate, acid, and ferric iron. This outcome would benefit extraction of copper in mixed oxide/sulfide deposits in the near term, but could complicate restoration activities. Possible impacts of pumping acidic solutions into the subsurface on microbes resident in, or introduced into the extraction zone will be discussed in the context of our understanding of copper heap bioleaching and acid rock drainage. INTRODUCTION As high-grade deposits of metals such as copper continue to decline, conventional mining methods have evolved to mine and process larger and larger quantities of ore. What is currently defined as ore today often contains less metal than the tailings of past operations. The throughput of current-day mines also leads to tremendous amounts of waste rock and tailings that may threaten the environment and communities around the mines, as has recently been experienced by 3 major tailings disposal facility (TSF) dam failures in the past 5 years. Community acceptance of large mine operations thus becomes more difficult to achieve—loss of the social license to operate. In response, the mining industry urgently pursues innovations that can fundamentally change the way in which metals are mined. In situ recovery (ISR) of metals represents one approach to a more sustainable mining industry, by virtually eliminating the need for a pit or underground excavation, eliminating the excavation and transportation of ore to a process plant and the ensuing noise and dust that is generated, and any need for waste rock dumps or TSFs. An ISR mine could have very little visible footprint beyond a network of wells, pumps, and piping to transport pregnant solution to a recovery facility, such as a solvent extraction- electrowinning (SX-EW) plant for copper. Some solid waste streams and/or storage ponds may still be necessary to treat and store bleed streams, PLS and raffinate, or as part of groundwater restoration activities. Thus capital and operating investments would be potentially much lower than that required for a conventional mine. In theory production could also be controlled to adjust to subsurface ore grade and match market demand. A not insignificant challenge of in situ recovery is the requirement for an efficient, low-toxicity, and ideally selective lixiviant for the metal that is targeted.

Jan 1, 2019

By F. Musuka, D. Jenkins, A. Keyes

BHP Olympic Dam operates a Direct-to-Blister copper flash smelting Furnace (DBF) and an Electric Slag Cleaning Furnace (ESCF). Tapping blister copper from these furnaces via tapholes is a routine task carried out by trained personnel. Blister tapping is a high-risk activity with personnel operating in close proximity to molten metal. BHP’s risk management framework has identified taphole integrity as key to managing the potential for loss of molten metal containment and molten metal – water steam explosion, both of which have the potential to cause multiple fatalities. As part of the focus on managing this risk, since 2017, a dedicated Taphole Development Team has been embedded in the operation to run an accelerated improvement program focused on safely and sustainably embedding an improved taphole design with greater integrity. The program of works includes selecting and testing of new materials as well as improving operating discipline by collaborating with tapping personnel to convert their knowledge into codified condition monitoring and operating strategies. Computational fluid dynamics (CFD) is being used to derive critical risk controls, and to develop live-alerts to infer excessive refractory insert wear. To date, improving DBF blister taphole mudgun clay has led to more consistent drilling depths and subsequently reduced oxygen lancing requirements, resulting in improvements in taphole insert service life. On the ESCF, insert performance testing and development of a new taphole condition monitoring strategy, is being used to increase taphole insert tonnages to more sustainable levels. Operations personnel have been closely involved in different phases of the change management, this has led to standardization of tapping practices for both furnaces, and improved ownership of the proposed changes. The paper discusses the maturity in taphole integrity risk management as a result of recent and ongoing developments. It then provides an overview of future taphole developments proposed at Olympic Dam. INTRODUCTION Tapping operations at Olympic Dam and learning from significant events The Direct-to-Blister furnace (DBF) at Olympic Dam was built with a conventional design blister taphole, which was designed for manual oxygen lancing and clay stopper bar plugging tapping operations (Campbell, 2005). Manual tapping is a high-risk activity, where personnel work in close proximity to molten metal, and molten metal personal protective clothing and equipment must be used. Opening tapholes by oxygen lancing is a skilled activity and unintentional damage to the taphole inserts can occur. Since 2008, a Mudgun and Drill unit has been developed and trialled and is now in use on the DBF blister tapholes, to remove personnel from the line of fire when opening and closing tapholes. This has the additional benefit of reducing lancing damage to taphole inserts. A new taphole design labelled the Modular Blister Taphole (MBTH) was developed at Olympic Dam for the Mudgun and Drill operation. The intent of the design was for mudgun clay to fill the entire tapping channel when plugging after a tap. The drill would then drill through this clay plug to open the taphole.

Jan 1, 2019

"The ore currently being milled at Delnite is a high pyrrhotite ore with the gold intimately associated with the pyrrhotite. To get maximum recovery of the gold with the lowest reagent cost, it is necessary to keep the pH as low as possible In the laboratory the best results were obtained with a pH of 10 but in the plant it was found that a pH of 11 was the minimum practical pH. With the n1anual control it was difficult to maintain this figure.The Mines Branch had a conductivity probe (see Fig. 1), developed by Dr. G .G. Eichholz that they wished to try out in plant operation.On June 17, 1963, the probe with all necessary control equipment was installed in the regrind circuit (see Fig. 2) at Delnite Mines. Crushed quick lime is fed at this point but it is also necessary to feed hydrated li1ne at two other points in the cyanide circuit in order to maintain the pH close to 11. 0 throughout the circuit. Only the feeding of the quick lime at the regrind mill was controlled in this test.One thing that concerned me with the operation of the probe was whether the reading on the probe chart would correspond to the pH. A look at the graph accompanying this paper will show that except for very minor variations the graphs of the chart reading and the pH reading are parallel. The upper graph shows that the pH reading and the lime titrations also correspond and that the cyanide titrations appear to have little effect on the pH reading.Table 1 gives the results obtained for the two months before and after the instal1ation of automatic control as well as the two months of control. Unfortunately there was a decided change in ore just after the automatic controls were removed. There was much less pyrrhotitc in the ore than usual thus changing the need for lime and cyanide."

Jan 1, 1964

By M. Bustin, A. Hosseinian, G. Preisig

Hydraulic fracturing and hydraulic shearing techniques are essential for the development of unconventional oil & gas and geothermal resources. Such techniques will also play a key role in the development of CO2 sequestration, and management of high stresses encountered with deep mining. However, the optimal design of hydraulic injections is often limited by continuum treatments of the rock mass without consideration of the influence of the natural fractures present. These may interact with the hydraulic fracture to promote offsets or arrest, or may cause the natural fractures to undergo shear and dilation. Given the limited access to the rock afforded by deep boreholes common to oil & gas and geothermal projects, advanced numerical modeling is critical for understanding key mechanisms and interactions. In this work, we first present a coupled hydromechanical distinct-element model focusing on the propagation of a hydraulic fracture. Normal and shear displacements arising from the generated hydraulic fractures are subsequently integrated into a fracture flow model for detailed analysis of specific flow behaviour and fracture permeability. For this, a scanned 3-D profile of a natural fracture is used to correlate surface roughness to dilation as a function of shearing. Fracture flow is computed at different time steps corresponding to different fracture propagation states and geometries. Modeling results indicate that the opening of a tensile hydraulic fracture is accompanied by millimetre-scale shear displacements associated with slip and wedging between adjacent blocks. This may leads to a mismatch between the upper and lower walls of the fracture if asperities are irregular and strong enough. However, fluid-induced tensile fractures have low Joint Roughness Coefficients (JRC), and associated millimetre-scale shear displacements are too small to ensure a significant offset of asperities that prevent a fully-elastic closure when the hydraulic fracture is depressurized. Injection of proppant is thus critical to keeping hydraulic fracture apertures open. Future work is planned that will see the models calibrated against field data including microseismic event locations, magnitudes and source mechanisms, tiltmeter deformations, stress change, and pore pressures.

Jan 1, 2015

By N. Shi, T. G. Joseph

ABSTRACT: An interactive cable shovel simulation has been developed to mimic any shovel dipper geometry for a given cable shovel operating in any homogeneous face material. This interactive cable allows the user to predict shovel performance in any face material encountered and track both its ground stability and the dipper-ground interaction. An embedded Microsoft® Visual Basic spreadsheet was used as the platform for developing an interactive simulation that allows for maximum user-defined parameter input and interactive visual output. The result is an analytical dipper-ground interaction solution that yields crowd, hoist, and digging effort as a function of face activity position.

Jan 1, 2011

By Tetsuya Yumoto, Toshikazu Shiratori

Information on the elements contained in E-Waste is important from the viewpoint of recycling. We analyzed several components of waste electrical and electronic equipment (WEEE) collected from citizens. The distributions of the minor metals in WEEE were determined with elemental mapping and chemical analyses. The annual change in elemental composition was investigated by analyzing equipment manufactured in different years. The information will be of use for separation techniques required for future advanced recycling.

Jan 1, 2011

By M. Cimenti

Fuel cells have tremendous potential as power sources but much fundamental research is still required. One key component of the research is the experimental set-up used. In particular, the placement of the reference electrode is extremely significant in measuring the half-cell overpotential of solid oxide fuel cells, since differences in area, misalignments, and also differences in the kinetics of the working and counter electrodes can cause both scaling errors and frequency distortions of the measured impedance. The impedance of thin solid electrolyte cells of different electrode geometries has been calculated using the finite element method and the results compared to experimental values obtained for the oxygen reduction reaction on platinum.

Jan 1, 2005

By T. R. Yu, D. B. Counter

"In an effort to increase productivity, the use of fly ash as a binder for consolidated backfill was studied. From laboratory and underground tests f or its cementitious properties and environmental effects, it was found that a portion of Portland cement could be replaced by the same amount of type ""C"" fly ash to produce an acceptable consolidated rockfill product for use at Kidd Creek.The environmental concerns in terms of dust control and emanation of radon gas were unfounded from measurements. The dust count was comparable to the use of Portland cement only, or with ground blast furnace slag, and the radiation readings were low, averaging one-seventh the regulation level.Since May 1984, a total of over 100 000tonnes of fly ash has been consumed as a binder blended with Portland cement, producing over four million tonnes of consolidated rockfill. To date, the fill in the stopes has performed very satisfactorily, while yielding considerable cost savings.IntroductionThe Kidd Creek minesite, located 27 km north of the city centre of Timmins, Ontario, produces 4.5 million tonnes of base metal sulphide ore annually. The mining method for both No. I and No .2 mines is mainly sub-level blasthole stoping with delayed backfilling.No. 1 mine was developed with a shaft to a depth of 930 m in 1973 to recover the ore between the floor of the open pit at the 216 m horizon, and the 792 m horizon. Stopes are normally 18 m wide, 22 m to 65 m long, with heights varying from 90 m to 135 m. Vertical rib pillars between stopes are typically 24 m wide and sill pillars are 30 m thick.Pillar recovery is implemented after the consolidated rockfill placed in the mined stopes has cured for a period of at least three months. This allows a maximum recovery of the ore with a minimum of dilution, while also maintaining safe working conditions.No. 2 mine was developed from a second shaft, sunk to a depth of 1530 m in 1978, for the recovery of ore beneath the No. I mine. Sub-level stoping in No .2 mine is similar to No.1 mine in methodology, yet differs in sequencing, as no rib pillars are left."

Jan 1, 1988

By D. McConchie

The use of Bauxsol? (physically and chemically modified alumina refinery residues) to treat acid rock drainage (ARD), and sulphidic waste rock and tailings, provides new options for managing some intractable environmental problems at both derelict and active mine sites. Treatment of ARD waters using the Bauxsol technology shows that the effectiveness of raw Bauxsol material can be enhanced by including modest amounts of selected industrial minerals or common chemical additives. The type and amount of additive required and the amount of the blend needed to treat the water depends on the initial composition of the water and the target water quality; for some ARD waters, optimum treatment may require one or more changes in the type or amount of additive used. Maximum treatment efficiency can be achieved only when a balance is maintained between the rate of trace metal binding and the rate of change in water pH; adding treatment reagents faster than can be accommodated by the reaction kinetics will not result in more rapid water treatment. This paper presents the results for treating several ARD waters to illustrate the importance of blend selection and treatment procedure. Although treating ARD water is often necessary, this strategy treats the symptoms rather than the cause. The best permanent solution is to treat the sulphidic waste rock or tailings such that they do not continue to oxidise and produce acidic metal-rich leachates; sulphide oxidation needs to be stopped or slowed to a rate that can be accommodated by normal environmental processes. Capping lined impoundments is not a solution because all caps and linings will inevitably fail some time in the future creating a nasty surprise for some future generation. Adding lime is also less than ideal because the lime leaches from the treated material; treatment often appears to be effective for a few years and then fails. Bauxsol technology offers effective alternatives to conventional liming and capping procedures and Bauxsol blend application rates and procedures can be planned to ensure that no acidic or metal-rich water can ever escape from the site. Bauxsol can be physically mixed with the sulphidic mine wastes or it can used to form subsurface permeable reactive barriers, or both. Bauxsol treated waste rock and tailings can be immediately and effectively revegetated. In this paper we present leachate quality and plant growth rate data for several sulphidic waste rock and tailings deposits treated using the new technology.

May 1, 2003

By G. A. Kosick, M. Freberg, L. A. Kuehn

"Highly variable and higher than forecast lead miff feed grades were problems experienced at the Polaris Concentrator. Limited flotation capacity and poor operating flexibility prevented the plant operators from overcoming these difficulties, and resulted in grades and recoveries which were lower than necessary.Two column cells were integrated into the lead circuit in an effort to give the operators the tools they required to achieve the best grades and recoveries possible, regardless of the miff feed grade. Installation of the column cells increased lead concentrate grade from 76% to 79.3% Pb, and increased lead recovery from 9/% to 91.3% Pb.This paper reviews the design, development and operation of column flotation cells in the lead circuit at the Polaris Mine.IntroductionThe Polaris Concentrator was constructed in 1980 on a barge in Trois Rivieres, Quebec, and towed to its pre sent location on Little Cornwallis Island, Northwest Territories, about 1450 km from the North Pole. The plant presently treat s about 2800 mtpd of new feed with average feed grades of 3010 Pb, 13% Zn and 5% Fe. Current production averages 36 000 tonnes of lead concentrate and 220 000 tonnes of zinc concentrate annually.The barge design and min e location dictated that the concentrator .be compact with very little unused floor space. As a result, flexibility was limited in terms of expanding the plant.Mill feed grades were highly variable and above forecast and the lead flotation circuit was found to be under capacity. This caused continued overloads in the lead cleaning circuit, resulting in low concentrate grades and recoveries. It was evident that an increase in lead flotation capacity and flexibility was necessary. The existing floor space did not allow for the installation of additional conventional flotation cells, but one alternative was the installation of column cells."

Jan 1, 1988

By G. K. Quainoo

Investigation by researchers on the application of various thermo-mechanical process histories on 6000 series aluminum alloys have found improvements in mechanical properties of these alloys. However, natural aging, which is unavoidable in the automotive processing line, has been found to have deleterious effect on subsequent artificial aging properties in these alloys. In this study, the evolution of yield strength during natural aging modeled by Lloyd and Gupta has been adapted to investigate the effect of cold deformation on the natural aging kinetics in AA61 11 by means of tensile testing, differential scanning calorimeter (DSC) and scanning electron microscopy (SEM). Also, intermetallic particles in the alloy were extracted from the matrix and XRD performed on them to ascertain their composition and their role on the kinetics in the alloy. The results show that cold work effect on the natural aging kinetics of AA6111 is in very good agreement with the model proposed by Lloyd and Gupta. The kinetics of natural aging in AA6111 aluminum also decreases with increasing level of cold work. This is attributed to dislocations serving as sinks which consume quenched-in vacancies formed during the early stages of clustering. The phases of the intermetallic particles identified in AA6111 are those of a-A15Mn12Si7 and a-A15MnSi.

Jan 1, 2007

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019