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By S. Itoh, T. Nagasaka, J. Ono

With respect to the recycling of used lead-batteries, a pure lead is required to prepare a lead-calcium alloy electrode for a new maintenance-free battery. The pure lead can be obtained by means of electrolytic and/or pyrometallurgical refining. In the lead electrorefming, antimony is concentrated in anode slime. From the viewpoint of the recycling and recovery of metal values from used lead-batteries, especially from anode slime, oxidation experiments were conducted for pure liquid antimony in the temperature range between 973 and 1373 K to elucidate the oxidation kinetics and mechanism. Furthermore, since lead anode slime generally consists of antimony, lead and bismuth, experiments have been also carried out using antimony-lead-bismuth alloy. The equation relating to the mass transfer characteristics in the gas phase was then applied to analyze the oxidation kinetics. As a result, it was found that the anode slime treatment, that is, an oxidation of antimony concentrated in anode slime followed by vaporization as antimony oxide Sb406, should be operated with higher oxygen partial pressure and sufficient amount of gas flow rate at lower temperature around 1073 K. The feasibility of the oxidation treatment for anode slime has been also discussed.

Jan 1, 2004

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By W. Melnyk, L Pokhilenko, J. A. McDonald, A. Hall

The Camsell Lake property comprises 270 000 acres located about 240 kilometres northeast of Yellowknife in the Northwest Territories. Kimberlite has been located in two areas of the property:

Jan 1, 2001

"Real-time, on-stream analysis of the metal content of process slurries is an essential prerequisite for process monitoring and advanced control of mineral processing circuits. On-stream X-Ray Fluorescence (XRF) sensors for base metal applications are available commercially and form the basis of many plant monitoring circuits. To date, these commercial technologies have been insufficiently sensitive to measure precious metals such as gold and platinum group elements, typically present at part-per-million (ppm) and sub ppm levels. CSIRO has developed a novel X-ray based technology, called UltraGold, which enables detection of gold in slurries on a real-time basis with a precision below 100 parts-per-billion. This technology is based on the use of advanced X-ray optics, extensive Monte Carlo computer modelling for analyser design, high accuracy X-ray spectrum fitting where the X-ray intensities are matrix corrected. In this paper, we will introduce this technology and discuss the results of a proof of principle study performed in the laboratory with plant slurries (tailings and concentrate) from an Australian beneficiation plant. Finally, we will discuss further planned improvements. As projected grades in (gold) mining around the world fall and several large-scale mines approach the limits of their economic reserves, this method can enable significantly reduced operating costs by rapid analysis to improve circuit efficiency and hence improve recovery significantly.INTRODUCTION This paper describes a study undertaken to explore the feasibility of applying CSIRO?s UltraGold XRF technology to the on-stream measurement of gold in process slurries. The provision of rapid, accurate information of gold grade in feed, tailings and concentrate streams would facilitate significantly improved process control and early detection of plant upsets, resulting in substantial cost-savings. CSIRO have patented X-ray fluorescence (XRF) techniques for the analysis of key elements in slurries present at part-per-million (ppm) and sub-ppm levels. Conventional, commercially available on-stream XRF instruments generally have detection limits in the tens of ppm range, precluding their use for analysis of elements like gold that are mined and processed at much lower concentrations."

Jan 1, 2017

By S. Masambi, S. M. Bradshaw, C. Dorfling

The presence of iron in base metal leach solutions complicates nickel and copper recovery processes. Leach solutions are commonly purified by precipitating iron as hematite, jarosite or goethite. Fast oxidation of ferrous to ferric is an important step to remove iron by precipitation at low pH values. This study reviews the ferrous oxidation mechanism and reaction rates in chloride media using molecular oxygen. This work contributes to the development of a better understanding of iron precipitation processing steps, which continues to be an important matter in hydrometallurgy. The specific objectives were to investigate (1) the effect of key process variables (acid concentration, copper concentration, and temperature) on the rate and extent of ferrous oxidation by dissolved oxygen and (2) the oxidation mechanism by varying chloride and hydrogen ion concentrations separately. Batch oxidation tests were performed using synthetic chloride solutions containing 45 g/L Fe and 3 g/L Ni at 50 and 80°C, dissolved Cu concentrations (0.3 to 3 g/L) and HCl concentrations (2 to 4.6 M). Regression analysis indicated that the significance of the effect of different variables on the extent of oxidation achieved after five hours decreased in the following order: HCl concentration > Cu concentration > temperature. Increasing the HCl concentration from 4 M to 4.6 M caused the degree of oxidation achieved after two hours to increase from 58.3% to 98.1%. The catalytic effect of dissolved copper on ferrous oxidation was more significant at low acid concentrations. Experimental data suggest that rapid oxidation of ferrous is possible at high HCl concentrations for two main reasons. First, the formation of ferrous chloride complexes allows ferrous oxidation to proceed without the formation of superoxide as an intermediate product (the rate limiting step in dilute acid solutions). Second, the formation of ferric chloride complexes stabilises the oxidation product.

Jan 1, 2016

By Antonio Fontana

"Environmental problems encountered with the use of diesel equipment in underground mining operations are discussed. The concept and procedure o implementing the Health Effects Index equation as a means of quantitatively assessing an underground working environment is outlined and sample calculations are present ed. Advantages and disadvantages of utilizing this method are also discussed.IntroductionWith the introduction of diesel-powered mining equipment in the 1960s there arose several question s for the environmental engineer to consider. These included: 1. What are the constituents of diesel exhaust and how can they be detected and evaluated?2. What are the toxicities and long-term health effects of these constituents?3. What is the ventilating volume required to maintain the concentration of these constituents below toxic levels?Diesel engines are a class of reciprocating, internal combustion engines in which relatively high compression ratios are used to generate high air-charge temperatures, which cause ignition of fuel to occur spontaneously. Ideally, perfect combustion of the fuel would produce an exhaust consisting solely of nitrogen (N2), water (H2O), carbon dioxide (CO2) and oxygen (O2). However, because no combustion process is perfect, relatively small quantities of imperfect-combustion products, or pollutants, are also generated. These include hydrocarbons (HC), carbon monoxide (CO), nitric oxide (NO), nitrogen dioxide (NO2), carbon (C) or soot, and sulphur dioxide (SO2).Currently, the Regulations for Mines and Mining Plants, made under the Occupational Health and Safety Act (Section 176), stipulate that weekly tests shall be made to determine the carbon monoxide (CO) concentration in the undiluted exhaust and at the operator's position, and the nitrogent dioxide (NO2) concentration at the operator's position. Also, the aldehyde (as HCHO) concentration in the atmosphere, at the operator's position, is to be measured at least every three months. Threshold limit values (TLVs) have been established for each of the three combustion products, and each is regarded as a separate entity. Consequently, this does not allow for consideration of interactions and possible synergistic effects between the various exhaust components."

Jan 1, 1982

By Jessica Hurst, Mark Holdsworth, Jeff McKay

"In 2002, Kennecott Utah Copper Copperton Concentrator installed an Expert Control system for optimization of their SAG and Ball milling circuits. The advanced process control has been well received and is utilized well over 95% of the time. In the years since, many lessons have been learned and many advances have been made. Improvements have produced millions of dollars of benefits and have included directly controlling feedrate with complex logic as opposed to using a bearing pressure controller, modifications to how sound is used for control, modifying logic for maximizing asset utilization and using advanced control for automating equipment restart. INTRODUCTIONRio Tinto’s Kennecott Copperton Concentrator produces copper, molybdenum, gold and silver. The mill has 4 SAG mills (SAG 1-3, 34 foot diameter and SAG 4 36 foot diameter), 8 ball mills and copper and molybdenum flotation plants, as seen in Figure 1. The 2010 average data is shown in Table 1.In 2002, a Metso Cisa OCS Expert Control system was installed at Copperton for SAG and Ball mill advanced control. The expert control was first placed on SAG 2; data from the first few weeks compared with operator performance indicated approximately an 11 percent increase in throughput. After full commissioning, the system was gradually refined further by plant personnel to develop key performance indices based on SAG feed size, refinement of the sound setpoint for control of mill speed and throughput, specific rules to help the adjustment of speed based on loss of a feeder, etc. With the addition of the pebble crushing circuit, the expert control began utilizing a model estimation of crushed pebble bin level to help stabilize the impact of returned crushed and uncrushed pebbles on the SAG mills. As the ore and limitations change, it is necessary to evolve the SAG logic to better handle any constraints."

Jan 1, 2012

By K. Yamaguchi

To contribute highly efficient and environmentally conscious copper smelting process, several topics in chemistry of the continuous converting were discussed. Through the reviewing the authors' thermodynamic simulations, it is recognized that small amount and low copper content of the coexisting slag is preferable. Some discussions were added to the Takeda's diagram for Cu20-Fe0x-Ca0 ferrite slag, and the activity curves of the constituents were derived. Thermodynamic calculations were carried out on the copper contents of the slag during the blister copper formation. The dissolution of copper in slag decrease somewhat with increasing temperature, but the effects of increasing S02 pressure and decreasing %S in copper are considerable to increase in copper content of the slag. The optimum oxygen enrichment in the supplied air, and regulation of the oxidation degree for the blister copper are important in practice. The gypsum phase separation in the calcium ferrite slag was also evaluated thermodynamically, and concluded that decreasing temperature, increasing CaO content or S02 pressure, and extensive oxidation of the blister copper tend to separate CaS04. 0

Jan 1, 2007

By E. S. Moore

In order that a logical conclusion may be reached regarding the possible occurrence of commercial iron deposits in Canada it is necessary to consider some important producers found elsewhere on this continent. A study of such deposits reveals the fact tl:~at a number of distinct types are producing large tonnages of ore. These types may be classified according to origin and occurrence as follows: (1) Bedded sedimentary deposits. (2) Contact metamorphic deposits. (3) Residual ores. (4) Lenses in metamorphic rocks and m some cases of uncertain origin. In addition to the types listed there are other deposits which have contained or do contain considerable ore and they either have not been worked on a large scale or they have been nearly exhausted. These include the following types: (1) Magmatic segregations. These are mostly titaniferous magnetites. (2) Dikes of magnetite of igneous origin. (3) Bog and lake ores in glacial drift. (4) Black sand placers.

Jan 1, 1925

By Dale L. McKinnon, Jean-Pierre Farant

"Dust collectors are used to reduce airborne dust levels generated during crushing at a mining operation and their adequate maintenance is required to ensure effective control of health and safety hazards associated with dusty conditions. Although the pitot traverse technique is commonly employed to balance these dust collectors, the use of an alternative-the equilibrium concentration tracer gas method-is proposed in this paper. This method, which uses sulphur hexafluoride as a tracer gas, can be used to balance airflows in dust collectors and to determine hood collection efficiency accurately and effectively. This technique also reduces some of the errors inherent to pitot tube measurements. IntroductionIndustrial dust collectors are used to reduce dust genera ted by processes like cru shin g, and these must be periodically checked and balanced to ensure continuing effective control of health and safety hazards associated with dusty conditions.To date, the pitot tub e traverse technique has been commonly used to balance air flows in dust collectors. However, this technique is both time -consuming and cumbersome. The equilibrium concentration tracer gas method, described in this paper, is proposed as a viable alternative as it is faster, more reliable, and amenable to automation. The use of tracer gases for such task s is not new. This approach has been used in a variety of mining situations to determine volumetric flow rates in underground openings, leak age through mine stoppings, the effectiveness of face ventilation, pollution migration patterns, mine air recirculation rates, and rock porosity."

Jan 1, 1986

By Amir Asadi

Various damage modes that evolve with time in polymer composite laminates, such as transverse cracking, vertical cracking, delamination, and fiber fracture, as well as the interaction among them, influence the time-dependent degradation in modulus (creep) and strength (creep rupture) of polymer composite laminates. This study is focused on modeling the time-dependent evolution of transverse cracking in [90] plies of a multidirectional polymer composite laminate [0m/190n]. This model uses a two-dimensional variational analysis to determine the stress state at any given creep time. The elastic stored energy, determined using this stress state, is compared with a critical energy for fracture to determine the crack evolution with creep time. Model predictions are compared with experimental results to validate the model.

Jan 1, 2010

By M. M. Helm

Samples sourced from the Goldstrike property in Nevada USA, have been evaluated in terms of their preg-robbing capacity and the physical structure of the graphitic carbon component in the carbonaceous gold ore. The study highlights a wide range in preg-robbing capacity between samples collected from the Betze-Post open pit and Rodeo underground mine. The physical structure of the graphitic carbon was assessed using Raman spectroscopy, and is found to play an important role in influencing preg-robbing behaviour. Differences observed in the physical structure of graphitic carbon are thought to be the result of hydrothermal events that occurred at Goldstrike.

Jan 1, 2011

By M. Rizwan

Mine workings are progressing to greater depths as shallow mineral resources are being depleted, and civil engineering projects are nowadays being developed at substantial depths. The threat to tunnel stability posed by rockburst events has increased as a result of these high stress environments. Rockbursts are violent events capable of mobilizing large volumes of rock. In addition to the threat to safety and equipment, rockburst damage can significantly impact on operations, and cause loss of mining production, often the largest cost component of such events. Rehabilitation of such damage requires significant effort and resources. Tunnel walls and roof are usually well supported, but the installation of rock support in the floor is uncommon, particularly in mining environments. In the absence of rock support, floors of the excavations are vulnerable to rockburst damage. New concepts for containing damage of excavation floors by dissipation of the large transient forces using simple techniques or preselected and designed elements of sacrificial floor systems are presented. Two approaches to calculate the demand are presented: estimating load demand by assuming displacement levels and a response modification factor; and using a limit displacement approach to calculate elastic stiffness of the selected elements of the sacrificial support system. The proposed conceptual support systems have the capability of dissipating rockburst energy while retaining sufficient serviceability. It is considered that the concepts presented, for discussion, in this paper are logical and developable into practicable and economic solutions for tunnel floor support in rockbursting environments.

Jan 1, 2015

By Jianglan Duan, Steve L. Cockcroft, Andre B. Phillion, Carl Reilly, Daan M. Maijer

"In the aluminum alloy wheel casting process, careful design of the cooling system in the die and its operation (cooling channel timing) are critical to achieve quality and productivity goals. The problem is challenging owing to the cyclic nature of the process and the relatively large thermal mass of the die in comparison to the wheel. For a given die geometry, a set of constraints have been defined to ensure directional solidification and an objective function, based on cooling rate during solidification, has been defined to reach a target secondary dendrite arm spacing. The methodology presented in this study employs the commercial finite element package, ABAQUSTM, and an optimization module based on the open source library, Scipy. The developed methodology has been applied to a series of geometries and cooling system configurations, including a 2-D axisymmetric wheel and die assembly generated from a prototype die. Preliminary testing has shown that careful selection of the objective and constraint functions have made it possible to reach desired solidification pattern.TM- Dassault Systèmes Corp."

Jan 1, 2014

By S. Yannacopoulos, L. Bichler, P. Wanjara, J. Gholipour

Characterization of a virgin and in-service Inconel 718 alloy was undertaken to study the changes caused by the service conditions on the grain size, ?? phase, MN-type nitrides and MC-type carbides. The size, distribution and volume fraction of these phases and grain size were studied using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and electron backscattered diffraction (EBSD) analyses. A considerable difference in the grain size, as well as distribution and volume fraction of the precipitates was observed in the in-service material as compared to the virgin Inconel 718. As a result of these microstructural changes, a notable dissimilarity in hardness between the materials investigated was observed. The results presented in this study are important for proper development of repair parameters and heat treatment of in-service Inconel 718 material.

Jan 1, 2014

By Charles G. Kemsley

IN view of the truly remarkable development of special steels for special purposes, the mining industry has for years looked forward to a time when steel makers would come forward with a product which would be an improvement over the straight carbon steel which has always held the field for drilling rock. In order to avoid making changes in conventional shop practice, the industry has perhaps been too insistent upon obtaining a water hardening steel which could be handled in the blacksmith shop by long established methods. As early as 1932 or 1933, an oil-hardening tool-steel of the one per cent carbon, plus chrome, plus molybdenum type was applied to hollow drill steel. It was known as a hard as well as a tough steel, and one that, theoretically, should give a good account of itself as a rock drill, if properly heat-treated; and so it has proved in actual trials. There were numerous deterrents which retarded adoption of this steel. For several years there has been a constant improvement in the drilling qualities of the straight carbon steel, and, considering the higher unit price ? of the alloy, there has been considerable doubt in the minds of some mining? men as to what advantage there might be in the use of alloy over straight carbon for hollow drill steel. The alloy being an oil-hardening steel, its adoption meant having two kinds of steel in the mine, for a time, and that spelled trouble, unless some positive means of identification was adopted. The hardening and forging ranges of alloy steel being narrow also made necessary much closer control over these operations if poor results were to be avoided. These thoughts undoubtedly prevented its use becoming wide-spread, for, as a matter of actual record, less than fifteen per cent of all the hollow drill steel used in Canada today is alloy.

Jan 1, 1942

By Subagyo, Geoffrey Brooks, Ken Coley

The generation of droplets and their subsequent reaction in the emulsion is critical to the overall kinetics of oxygen steelmaking. High temperature experiments have been performed at McMaster University to study this behavior. The results from this work and other previous studies has formed the basis of a number of physical and chemical models that attempt to describe the critical aspects of droplet behavior in Oxygen Steelmaking. These models include semi-empirical models for predicting droplet generation rate, droplet size distribution and droplet residence time as a function of blowing parameters.

Jan 1, 2004

By Robert B. Parsons

"For the fourth time in five years, residents of northern Canada have seen a change in the tax treatment of housing and travel costs. The latest changes announced in December 1990 by the Minister of Finance are to become effective in 1991. When will the tinkering stop?IntroductionFor man y years prior to 1987, certain travel and housing allowances received by employees in remote areas were generally considered by Revenue Canada to be tax-free, even though some observers suspected that such generous treatment was contrary to the provisions of the tax legislation. In the mid-eighties, Revenue Canada decided to reconsider the tax treatment of the mining industry's long standing practice of providing housing and travel assistance to these employees. The tax- free treatment was continued by virtue of annual remission orders, but only pending the enactment of legislation which would tackle the issue head-on and layout the rules in black and white to be seen by all. The sequence of events since then may be chronicled as follows:February 26, 1986-Finance Minister Wilson's budget present s the framework for the future tax treatment of travel and housing benefits provided to residents in remote regions of Canada.December 22, 1986-The Minister of Finance announces detailed rules to fill in the earlier announced framework.January 1, 1987-The new tax rules come into effect.April 29, 1988-The Minister of Finance announces the establishment of a Task Force to examine the existing criteria for determining the eligibility of residents of northern and isolated areas for tax benefits.October 27, 1989-The Task Force presents its report.December 7, 1990-Finance Minister Wilson announces a new system of tax benefits for residents of Canada's northern and isolatedregions.January 1, 1991-The new rules become effective."

Jan 1, 1991

By R. Ghomashchi

Wear, fatigue and corrosion are the most widely encountered modes of failure in materials used in engineering applications, including aero-gas turbines. Although wear is distinctly classified as adhesive, abrasive, erosive, fretting and so on, there are usually more than one wear mechanism involved in the failure of components in service because there are many systems and materials variables active in materials wear that makes it more difficult to study. This is further complicated by the discrepancies between the results of laboratory tests and field data. The present investigation was set up to examine the wear characteristics of M50 and T1 high-speed steels at both room and elevated temperatures to draw a thorough understanding of the wear behavior of this class of high-speed steels. This article focuses on the mechanical and microstructural characterization of wear for T1 and M50 high-speed steels using a pin-on-disk wear machine.

Jan 1, 2005

By Jan Rosenkranz, Anders Sand, Lisa Malm, Nils-Johan Bolin

Within flotation technology the general trend is towards very large cells. Scale-up is usually done by postulating geometrical similarity, which implies keeping the aspect ratio constant when increasing cell volume. Consequently, the design of flotation circuits typically involves several cells of identical geometry within a bank. Using a few standard sizes in a flotation plant simplifies design, manufacturing and maintenance of the cells, but does not necessarily guarantee optimal performance and selectivity of the flotation process. Geometry parameters for a given cell volume that influence flotation cell performance include cell height, which causes changes in the hydrostatic pressure and suspension hydrodynamics, and also influences the travel distance of particle-bubble agglomerates as well as the homogeneity of the mixing. Also the thickness of the froth layer depends on the aspect ratio of the cell. The objective of this work is to gain a better understanding of material distribution and properties within a flotation cell and, based on this information, elucidate how alterations of the cell geometry can influence separation efficiency. For this purpose systematic measurements and analyses of the spatial distribution of the different phases within a 160 m3 flotation cell have been carried out with a particular focus on an industrial, low-grade copper ore beneficiation process. The concepts for sampling at different vertical and lateral positions of the flotation cell are introduced. The results from the experimental work give an understanding of internal material distribution within flotation cells. Based on the measured phase distribution and concentrations as well as particle properties at various positions within the cell, the implications for an optimized scaling and design of individual flotation cells within a flotation circuit are discussed.

Jan 1, 2016