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By Alfred B. Annor

The introduction and application of paste backfill over the past two decades has resulted in substantial benefits being realised by many backfill reliant mining operations who have used this technology. Paste preparation over this time period has relied basically on mechanical dewatering approaches that have included the use of centrifuges, thickeners, and vacuum and pressure filtration. In large bulk mining operations, this method of paste preparation has usually involved the construction of big and complex surface plants to meet large tonnage demands. These large plants usually have attendant high capital, maintenance and operating costs. The application of paste backfill in narrow-vein mining requires more flexibility in terms of fill preparation, transportation and placement. The method of paste fill preparation should take into consideration low manufacturing and operating costs, ability to use existing facilities at mine sites, simplicity of operation and flexibility of preparing fill over a broad range of consistencies. This paper will review alternative paste fill preparation methods and indicate those that might be better suited to narrow-vein mining.

Oct 1, 2001

By C. A. Anderson, C. A. Young, H-H. Huang, L. G. Twidwell

An equilibrium calculational computer program (STABCAL) can be used for titration simulation. The program can handle various forms of titrants: solid, aqueous, gaseous or another solution, and various type of reactions: reductive, oxidative and adsorption. Background chemistry, mathematical considerations, and program development will be illustrated. Also, simple titration applications such as how to determine the acidity of aqueous solutions and alkaline sulfide leaching of gold are presented. Processing of an acid mine water from the Berkeley Pit in Butte, Montana has been used for illustration purposes. The treatment studies included: cementation, sulfidization, and neutralization. The calculational results for the neutralization treatment using various alkaline reagents are compared to actual experimental data and potentially appropriate processes are discussed. Computational

Jan 1, 2005

By Vincent H. Hartung

The process of estimating tailings deposition for a given basin is a relatively tedious process without dedicated software tools. The amount of time required to generate a tailings surface for a given set of conditions tends to limit the number of design alternatives that can be considered for a particular project. Recent innovations in the Surpac Vision mining software include the widely used scripting language TCL (Tool Command Language) that brings with it the ability for non-programmers to extend the software functionality beyond mining applications alone. A software tool was developed using the Surpac Vision scripting language to take advantage of 3D visualization and create a flexible tailings modeling solution. The result is an application that removes much of the drafting overhead required to produce a tailings surface. It provides the means for reviewing alternatives and performing sensitivity analysis with variables such as pond elevation, dam or spigot location and height without a significant increase in overall time for a project.

May 1, 2001

By A. Suzue, T. H. Okabe, Y. Taninouchi

Methods for the physical separation and enrichment of platinum group metals (PGMs) from autocatalyst scrap were studied in order to develop an environmentally friendly and efficient recycling process. In general, an autocatalyst has a honeycomb-structured ceramic substrate that is coated with a catalyst layer containing platinum (Pt), palladium (Pd), and rhodium (Rh). Therefore, physical separation of the PGM-containing catalyst layer directly from the ceramic substrate is favorable for upgrading the autocatalyst scrap. In this paper, the authors present a scrap-upgrade process consisting of electroless iron plating and magnetic separation techniques. Iron was plated on the surface of a catalyst sample used to represent an autocatalyst, which was then crushed and magnetically separated. The Pd in the catalyst sample was successfully extracted and concentrated in the magnetic powder. Under certain conditions, the process increased the Pd concentration by a factor of 4 and recovered 89% of the Pd in the autocatalyst sample.

Jan 1, 2014

The AG/SAG circuit discharge P80 is now increasingly referred to as the ?Transfer Size? or T80 for short. From the literature it is apparent that in circuit design some approaches to the sizing of AG/SAG mills as well as the ball mills that they feed use this parameter. This paper reviews whether the use of the T80 is appropriate in this context. In the course of the review examples of AG/SAG discharge size distributions measured from range of operating circuits are used to illustrate the arguments made.

Jan 1, 2012

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations for the smelting and refining of non-ferrous metals, and it is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate. It is also the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y zinc. Since then, production capacity has increased, and at present, it stands at 240,000 t/y zinc. In this paper, the leaching process and particularly the operation of the jarosite circuit is reviewed, specifying process improvements to treat high iron calcines.INTRODUCTIONTwenty years ago the Electrolytic Zinc Plant in Peñoles was treating high quality zinc concentrates with low concentrations of iron (~7.5 wt.%) and silica (1.8 wt.%). Nowadays the quality of zinc concentrates is poor with a typical iron content of around 11 wt.% and silica at 2.0 wt.%. This has created numerous processing problems in our roast-leach-purification- electrolysis sections. In order to meet customer requirements it is necessary to find processing solutions to assure the operational continuity of the plant. These processing solutions are the focal point of this paper.REVIEW OF THE LEACHING PROCESSThe purpose of the leaching process is to recover the metals, mainly zinc, through a series of extraction stages with sulphuric acid solutions, which progressively increases the zinc dissolution. After the series of acidification stages, the solution, which is rich in iron, is sent to the jarosite circuit to separate zinc from iron (Garcia & Valdez, 1996). The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper. Then this solution is sent to the tank house to feed the electrolytic cells."

Jan 1, 2016

By M. A. Halim, V. I. Lakshmanan

Recycling is one of the key elements for sustainable process development for the recovery of value-added products and reducing environmental impact. Process Research ORTECH Inc. has developed several innovative and sustainable technologies, which minimizes the use of water, and chemicals for the recovery of gold, vanadium and gallium from secondary sources by maximizing the recycling of reagents, and reuse of water from process effluents.

Jan 1, 2015

By L. Szecowka, M. Poskart, Siwka M. . J.

Oxides of nitrogen, created during combustion, are the most hazardous components of atmospheric pollution. However, it is possible to limit the negative influence of hazardous components on the natural environment. An experimental appartatus was built to determine the influence of the following "primary methods" on the reduction in concentration of NOx: air staging, reburning and flue gas recirculation. The influence of the simultaneous usage of the primary methods on reduction in NOx emissions was also examined. A significant increase in the efficiency of NOx reduction was achieved in two cases.

Jan 1, 2004

By H. Nakano

The codeposition behavior of impurities such as Ag, Bi, Fe, Ni, Pb and Sb with Cu was investigated galvanostatically at 5-3000 A/m2 using a Pt cathode at 60 °C in acidic copper (I) chloride (cuprous chloride) solution at pH1-2 containing 1.0 mol/L of Cu+ and 4.9 mol/L of Cl-. The impurities were classified into two groups: Group I (Ag, Bi) which codeposits with Cu as a metal, and Group II (Fe, Ni, Pb, Sb) which is slightly involved in the deposited Cu in nonmetal form from the electrolyte. Silver and Bi in Group I behaved as more noble metals than Cu, and significantly codeposited with Cu, showing typical features of regular-type codeposition. When Cu was deposited dendritically, the Ag and Bi content in the deposit increased with increased duration of electrolysis as a result of decreased net current density caused by increased cathode area. The current efficiency for Cu deposition in impurity-free solution was 95-100% over 100-1000 A/m2, but it abruptly decreased at above 1000 A/m2 when the limiting current density of Cu was attained. Although Fe, Ni, Pb and Sb in Group II were involved to 0.01-0.02 mass% in the deposit, they had no influence on the current efficiency or morphology of Cu.

Jan 1, 2007

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By J. R. Perumareddi, V. S. Sastri, M. Elboujdaini

It is well known that high strength steels used in aerospace industry, are generally susceptible to hydrogen embrittlement during surface treatment such as electroplating with zinc on cadmium. Hydrogen embrittlement reduces ductility and results in brittle fracture rather than failure by plastic deformation. Hydrogen embrittlement of high strength steels is mitigated by surface treatment such as plating with other metals. Data on the hydrogen contents of steels before and after surface treatment by hot extraction-thermal conductivity, secondary ion mass spectrometry (SIMS) and UV-visible spectroscopy along with the mechanism are presented.

Jan 1, 2006

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006

By Ross Dimmock

The productivity of a mine has the same goals as the quest to complete a tunnel project both safely and within time. A key aspect to achieving this goal is to excavate and support the working face as quickly as possible, allowing early re-entry to start construction of the next advance in safety. As with tunnels, the use of high performance wet-mix sprayed concrete has increased in mines dramatically over the last few years, and year on year has seen a stepwise increase in shotcrete performance, particularly in the first few hours. Shotcrete early age strength development clearly offers mining teams enormous advantages by allowing early, safe re-entry to the face. This paper illustrates that in the hard rock tunnelling field, modern shotcrete approaches do not cause delays in re-entry, but allow a continuous construction cycle. Furthermore, the paper identifies the most suitable, up-to-date shotcrete admixture and equipment technology available to the mining community to permit early re-entry.

May 1, 2003

By L. Mercier, A. El-Hsaeri, L. Amaratunga

Laboratory scale studies of the development and application of high capacity heavy metal ion adsorbents with uniform nanoscale porosity (denoted MP-HMS, mercaptopropyl - hexagonal mesoporous structure) to extract gold from solutions is described. The adsorbents are selective towards gold ions. The adsorption capacities of these materials are also among the highest reported. MP-HMS has shown the capability to adsorb 330-mg gold per gram adsorbent (up to 30% of their weight). Gold uptake by the adsorbent was found to increase dramatically with solution agitation. The adsorbent was found to be extremely effective in adsorbing gold ions from ultra- low concentrations, like those found in mine effluents. Experimental studies indicated that MP-HMS maximum adsorption of gold (99.9%) occurred under all solution concentrations. Another promising attribute of these materials is their favorable adsorption kinetics. The contact time required for 80% adsorption of gold was found to be less than 60 seconds. The efficiency of these nanoporous materials for the recovery of gold from mining effluent is evaluated and their prospect for application in the mining industry discussed. The process thus has the prospect of becoming an efficient and environmental friendly method to recover gold from aqueous solutions, such as gold mill effluents.

Jan 1, 2004

By B. K. Gorain

Barrick' s Buzwagi copper-gold deposit in Tanzania comprises oxide, saprock and sulphide mineralized zones averaging approximately 0.058oz/t gold, 0.13% total copper and 0.03% cyanide-soluble copper. A comparative evaluation of the project based on two potential flowsheet alternatives is presented. The first flowsheet included a gravityconcentration and carbon-in-leach (CIL) plant. The second flowsheet was based on a Gravity-Flotation-CIL plant, which proved to be more economically robust. Selective flotation of copper minerals to produce a saleable copper concentrate proved to be challenging. Detailed characterization of the Buzwagi deposit was carried out through understanding of ore mineralogy, mineral liberation, floatability and selectivity, reagent chemistry and regrinding issues. With this insight, a flotation concentrate of greater than 25% Cu was achieved, recovering a significant amount of copper minerals and tellurides. The overall economics of the project improved significantly with the addition of flotation. Leach tests on gravity and flotation tailings showed an overall increase in gold recovery of approximately 6% for a Gravity-Flotation-CIL plant compared to that for a Gravity-CIL plant.

Jan 1, 2007

By Jie Li, Xinyu Liu, Yan Chen, Linjian Ma, Yasong Wang

Nonlinear time-dependent response analysis of salt cavern under extreme loads in disaster mode is of great importance to the safety and disaster prevention of gas storage group. Uncontrolled blowout is one of the extreme conditions for compressed-air cavern operation. Based on the geological structure of Jintan salt deposit, China, the numerical model of the complete process of water solution, cyclic operation, and internal pressure runaway was developed. The effects of rapid unloading on the stress filed, the progressive failure of surrounding rock, the volume convergence of storage cavern, and the ground subsidence were simulated employing an elasto-viscoplastic damage constitutive equation for rock salt. The results indicate that the damage and failure zones propagate much larger in the mudstone interlayer than in the host salt. The volume of damage and failure zones surrounding salt cavern induced by unloading process is 5~6 times that of cyclic injection and withdrawal process. The average volume convergence rate of salt cavern reaches 0.012%/d~0.013%/d, which is 6~6.5 times that induced by cyclic operation. The ground subsidence exhibits a typical funnel curve. The affected region of ground subsidence due to rapid unloading in the blowout period is about two times the maximum cavern diameters. Furthermore, double cavern analysis reveals that the interaction between adjacent caverns may be ignored so long as the pillar width is larger than two times the maximum cavern diameters.

Jan 1, 2015

Several inorganic reagents and organic polymers were tested as depressants in the single mineral flotation of ultrafine iron oxide and hydroxylapatite with Dowfroth 250 as a frother. It was observed that the inorganic reagents and the low molecular weight polymers generally caused dispersion of the ultrafine particles, and consequently their recovery into froth products more or less equaled the recovery of water. On the other hand, the high molecular weight polymers caused different degrees of flocculation of the ultrafine particles, and their recoveries were much lower than the recovery of water. These observations pointed to a need to re-define flotation depressants in fine particle flotation. The traditional definition of a flotation depressant, i.e., to make particle surfaces hydrophilic by forming a hydrophilic film and/or by removing collector and activator coatings, is sufficient for relatively coarse particles. However, to prevent fine and ultrafine particles from floating, a successful depressant should not only make the particles hydrophilic, but also enlarge the particle sizes so that they do not enter the froth product by mechanical entrainment. Polymeric depressants are ideal for these purposes. The different schemes to use polymeric depressants in the selective flotation of fine and ultrafine particles were discussed These schemes involve the integration of the polymeric depressants into other size enlargement processes such as shear flocculation, oil agglomeration, etc., for hydrophobic particles.

Jan 1, 2004

By R. M. Kalanchey

The application of pressure oxidation processes to copper feed materials has gained increased exposure in recent years and some of these processes have made commercial inroads, although rather limited to date. Among the hydrometallurgical processes with significant commercial potential, Dynatec's copper pressure leaching process has been applied to arsenic-bearing copper materials and has shown, through a number of batch and continuous test programs, that pressure oxidation is a technically feasible option for the recovery of copper with coincident sequestration of arsenic in an environmentally benign residue.

Jan 1, 2007

By J. A. R. Faucher

"Autogenous grinding may be an efficient and economical solution to your ore comminution problem.An important potential economic advantage of autogenous mills results from the availability of very large capacity units.Autogenous grinding could be more economical in terms of both capital and operating costs.Satisfactory pilot plant testing and thorough economic evaluation are required for a sound decision in comminution plant selection.INTRODUCTIONMankind's first weapon was probably the wooden club, but men soon learned to shape, smooth and polish stone for tools and weapons by pounding and rubbing them with sand and water. It was only about four thousand years ago that rocks were first broken to concentrate, smelt and return the metals they contained. In spite of our recent great technological advances we still break rock in essentially the same manner that was used thousands of years ago - by pounding, rubbing and squeezing - and we still waste much energy and metal in the process"

Jan 1, 1969

By Yong-neng Feng, Xiao-ping Chen, Wei Guo

"While the uniaxial compressive strength of rock has been extensively investigated, the relation between the saturation and natural compressive strength is relatively unexplored. This paper studies on 1865 statistical data of Chongqing Rail Transit Line 1 and Line 6, which located in the Middle Jurassic of Shaximiao formation. The research focuses on the relation between the saturation and natural compressive strength. The statistical data are categorized and quantified in order to ascertain the softening properties of sandstone and sandy mudstone. The findings suggest that the saturation compressive strength is significant effected by its natural compressive strength, and an empirical formula is introduced to explain the relation. These findings have implications for researchers and engineer who concerned with Chongqing rail transit construction.INTRODUCTIONIn the engineering construction and surrounding rock classification, the uniaxial compressive strength index (Ministry of Water Conservancy, 1995; Ministry of Railways, 1999) is one of the essential parameters of rock mass. Usually, there are two types of the uniaxial compressive strength index, natural and saturation compressive strength, and the ratio of them is the softening coefficient. Most of the previous studies on rock strength had focused on the influence factors (Liu et al., 2008; Liu et al., 1998; Liu et al., 2013; Wang, 2013; Zhang et al., 2008; Zhang et al., 2010; Zeng & Lin, 2003) with experiment and in-situ tests. But few publications that reports a long and formal research project on the relationship between natural and saturation compressive strength. In order to figure out this issue, this study investigated the distribution of Solidity Classification of Rock Mass and softening coefficient based on the statistical data of Chongqing Rail Transit Line 1 and Line 6. Based on the analysis, an empirical formula was proposed to explain the relationship."

Jan 1, 2015