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By W. D. Madeley

Synthetic minerals were made from pure starting materials and galena samples were doped with the title metals. Microscopic, microprobe and X-ray examination confirmed that the dopeants were in solid solution. Paired flotations in a Hallimond-tube apparatus were performed to determine relative flotation response using Aerofloat 238 promoter. Results of these tests show that silver-doped galena floats more readily than pure galena and that galena doped with bismuth floats less readily than pure mineral to a 95% confidence level. Galena doped with both silver and antimony as AgSbS2 shows no detectable effect. Antimony-doped galena followed the expected trend, but not to 95% confidence. The results are consistent with the theory that flotation by thiol-type anionic collectors is enhanced by p-type semiconduction.

Jan 1, 1978

By D. Naden, D. J. King

"The high capital and operating cost of liquid-solid separation circuits in hydrometallurgical plants has led to an increased focus on the use of in-pulp systems for metals recovery in order to eliminate the need for solids washing and to reduce the need for liquid-solid separation.Carbon-in-pulp (CIP) has now been accepted in Canada and around the world as the leading process for recovery of gold and silver, replacing the Merrill-Crowe process and thus removing the need for CCD thickeners or belt and drum filters. The overall design of conventional CIP adsorption circuits was established in the late 1970s and it has remained substantially unchanged until now. Most of the development work since 'hen has been concentrated on improving methods of separating pulp and carbon and on reducing carbon losses during transportation and agitation.Resin-in-pulp (RIP) has been used for many years in uranium mills in the USA. However, most of the plants were built in the 1960°s and RIP was only chosen when liquid-solid separation of leach pulps proved very difficult. The plants are far from ideal as they have high resin losses and high maintenance costs. Consequently, there is room for improvement.Davy McKee has taken a fresh look at the engineering development of in-pulp contactors leading to a fundamental redesign of the adsorption units. The improved in-pulp technology uses a modification of the proven air-swept screen techno1ogy together with a new technique of process operation. The new contactor operates at high pulp throughput rates with high concentrations of carbon or resin in the recovery stages, resulting in a significant reduction in the contactor size over conventional design. As a result of this reduction in the size of the contactor by up to 80%, significant savings can be made in equipment and building costs. In addition, the plant 1s easier to operate than a conventional CIP plant."

Jan 1, 1987

By Jian-bin Xie, Lin-fang Shen, Zhi-liang Wang

"In order to research temperature field for construction of connecting passage in Metro using artificial freezing method, the finite difference software FLAC3D is employed to numerically simulate construction process of connecting passage. During construction, the overall distribution of temperature field around connecting passage, the relationship between soil temperature and freezing time, the distribution and variation for the thickness of freezing wall are studied from the perspective of numerical analysis. The results show as follows: after 55 days’ freezing, the soil temperature surrounding connecting passage is about -24 oC ~ -28 oC, and the minimum thickness of freezing wall is about 4.0m, which is larger than the design value 3.1m. So construction conditions have satisfied to the excavation of connecting passage and pumping station. During the excavation of connecting passage, soil temperature has almost no obvious change and the thickness of freezing wall remains constant mainly. After 45 days’ normal thawing, the temperature of freezing wall rises 12 oC approximately. And the soil temperature rises faster at the beginning of the normal thawing stage. In the whole process of construction, the frozen area is about 5m outside the edge of connecting passage, and the cooling area is about 10m outside the edge of connecting passage. INTRODUCTIONThe first recorded application of the artificial freezing method is on a mineshaft project in 1862, and it has been widely used in foundation pit engineering, subway tunnels, mine shaft engineering and so on (Wang Zhiliang, 2010; Zhang Juanxia, 2012; Qiu Fan, 2007; Zhou Xiaomin, 1999). This method has many advantages of enhancing soil strength; decreasing permeability and adopting various unstable soils (silt clay, sand, gravel, etc.). It has been applied successfully in metro engineering construction in Beijing, Shanghai and Nanjing. According to incomplete statistics, the construction of connecting passage using artificial freezing method accounted for 98% in Shanghai metro (Qiu Fan, 2007)."

Jan 1, 2015

By Eric L. Hoffman

Sample preparation technology changes Rock Soil Vegetation Analytical Innovation Assay or Geochem Choice of Digestions Choice of analytical method Whats new in analytical technology? Innovations in surface Geochemical Methods Hydrogeochemistry Biogeochemistry Soil Gas Hydrocarbons (SGH) Selective Extractions Glacial Environment Arid Environment

May 1, 2008

By R. S. Forgan

The synthesis and study of a systematic series of phenolic oximes have shown that substitution in the 3-position can greatly affect extractive efficacy. Solid state, solution and gas phase analytical techniques, including X-ray crystallography, EPR and IR spectroscopy and collision induced dissociation mass spectrometry have been assessed for their applicability in interpreting the origins of differences in extractant strength. The dominant substituent effect on pH0.5 is the change in ligand pKa, with the more acidic ligands being stronger extractants. The influence of the 3-substituent on the stabilising intracomplex H-bonding of their copper(II) complexes also affects extractant strength. The 3-NO2 substituted ligand shows the lowest pH0.5 value, due to a combination of its low pKa and a stabilising bifurcated H-bond assembly around the copper(II) centre. Appending an aminomethyl group to the 3-position gives a ligand capable of binding a metal and its attendant anion. These metal salt reagents show potential to open up new flowsheets for the processing of high tenor copper feeds.

Jan 1, 2007

By C. Zangerl, T. Strauhal, S. Perzlmeier, M. Holzmann

"In high mountainous regions, deep-seated rock slides are often observed in foliated metamorphic rocks such as paragneisses, micaschists and phyllites. Given that comprehensive investigations of deepseated rock slides are extraordinary costly and therefore are rare, most studies are related to investigations in the surroundings of infrastructures and human settlements. In the framework of this study there is an excellent opportunity to gain new insights in the fundamental processes and mechanisms of slowly moving deep-seated rock slides from a case study in the surrounding of a large dam reservoir in Austria. New fundamentals for comprehensive slope stability analyses and hazard assessments and sound prognoses focussing on the long-term stability and deformation behaviour of slopes under changing boundary conditions (e.g. impounding of a reservoir) and/or concepts for mitigation measures can be obtained. Within this contribution, geological field surveys, deformation monitoring, geophysical and drilling data were analysed and presented. Based on the compiled and analysed data, some key-properties of the rock slide will be presented, whereby special attention will be given on the geometry and internal structure, the slope kinematics, as well as hydrogeological and geomechanical aspects.INTRODUCTIONIn high mountainous regions, deep-seated rock slides are often encountered in highly foliated metamorphic rocks such as paragneisses, micaschists and phyllites (Agliardi et al. 2012). Critical situations may occur when deep-seated rock slides fail in a rapid manner characterised by very high sliding velocities, and/or when they develop into long run-out rock avalanches. However, many rock slides in foliated crystalline rock masses either do not move at high velocities nor do they accelerate seriously and form extremely rapid slides. Displacement rates in the range of a few millimetres or centimetres per year are common for this type of rock slide (Bonzanigo et al. 2007, Tentschert 1998, Watson et al. 2007). Nevertheless, some case studies show an activity behaviour characterised by acceleration phases reaching velocities of even metres per day. However a slope collapse is not expected and these slopes decelerate to much lower base activities. The trigger for these phases can be manifold and include heavy rainfall and snow melt, initial reservoir impounding and water level fluctuations, changes in the slope’s equilibrium state due to antecedent slow deformation processes, ongoing erosion processes along the toe of the slope, and others (Zangerl et al. 2010)."

Jan 1, 2015

By L. Fernandes

A two level factorial study was undertaken to investigate the relative impacts of factors affecting the kinetics of polytetrafluoroethylene, PTFE, assisted pressure oxidation of chalcopyrite. A copper flotation concentrate, principally composed of chalcopyrite, was leached in 850 mL of leach solution under conditions similar to those of the CESL process. The factors manipulated were: the amount of 1/8" PTFE beads added (100 g or 650 g), oxygen pressure (690 kPa or 1030 kPa), and concentrate addition (10 grams or 65 grams). Copper extraction data, which indicated complete leaching under certain conditions, were fit using a shrinking core model from which rate constants were estimated and further used to generate a statistical model containing only the factors of significance and their interactions. Results indicated a strong positive effect of PTFE addition and a strong negative effect of increasing pulp density. A weak negative interaction between increasing PTFE addition and pulp density was attributed to PTFE/concentrate agglomeration.

Jan 1, 2014

By J. A. Eisele, D. L. Pool

"The Bureau of Mines has developed a particle agglomeration technique to improve the flow of leaching solution through heaps of low-grade gold-silver ores which contain clays. Benchscale experiments and industrial practice have shown that the percolation rate of cyanide leaching solution is greatly enhanced by mixing the ore with Portland cement as a binder, moistening the mixture, mechanically tumbling to form agglomerates, and aging before heap building and leaching. A slight modification ofthe technique allows its application to precious-metal-bearing tailings, which cannot normally be treated by heap leaching because they are too fine. IntroductionMany low-grade gold and silver deposits and tailing materials from former mining operations in the western United States are potential sources for precious metals. These sources are too low grade or too small to support the capital cost of a conventional cyanidation plant but have stimulated the development of lowcost procedures, such as extraction of the precious metals by heap leaching with cyanide. The Bureau of Mines has investigated methods to improve the recovery ofgold and silver by heap leaching these low-grade materials.For heap leaching to be successful, the crushed and stacked ore must have good permeability so that uniform distribution of the cyanide leaching solution through the heaps can be achieved. Some of the most difficult gold and silver ores to treat by heap leaching are those containing excessive amounts of clays, or fines generated during crushing. Excessive amounts of slimes, generally minus 50-micrometre or 270-mesh Tyler sieve size particles, in the heap feed will slow the percolation of the leaching solution, cause channelling, or produce dormant or unleached areas within the heap, resulting in long leaching periods and low extractions. In extreme cases, the clays or slimes can seal the heap and cause the leaching solution to run off the sides of the heap rather than through it."

Jan 1, 1987

By A. Tohn, K. Adham, R. Lu, D. Lemieux

"To remove sulphur, carbon and arsenic from the gold concentrates of Dundee Sustainable Technologies (DST), Hatch has designed a demonstration plant roaster using the fluid bed technology. The fluid bed was selected for its ability to maintain stable temperatures and uniform reaction conditions. Data points from a small pilot plant (operated by DST) were used for setting the parameters of the demo plant roaster.The DST demonstration plant is being built to further prove their patented gold extraction process at an industrial scale. Their gold extraction process is based on halogenation at atmospheric pressure and relatively low temperatures. Before the halogen leaching, most of the sulphur, carbon and arsenic should be roasted out of the feed concentrate.The Hatch fluid bed roaster design includes a moist feed introduction system, simple bed cooling for temperature control, and cyclone fines recirculation. The demonstration plant roaster is planned for construction in 2014, and the performance results will be presented in a future paper."

Jan 1, 2014

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By M J. Daniel

Comminution is the science of size reduction of brittle materials. It is integral to mineral extraction and is one of the most energy intensive processes in the mining industry. There are a number of tests used to quantify the strength of ore, which are then used to size the AG / SAG mill in circuit design. The calculated energy utilized for breakage in these devices is based on the assumptions that the materials treated are of average shape and that the processing equipment is designed to break the ore as efficiently as possible under the given operating conditions. In drop weight tests, it was found that shape significantly influences the measured rock strength. Controlled experiments with variations in blends of rock shape show that mill throughput increases with the addition of weaker shaped rocks.

Jan 1, 2012

By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée."

Jan 1, 2017

By A. R. Guest, R. Clayton, J. Jakubec

"The potential for mudrushes is a potential hazard that should be evaluated during cave mining studies. Mudrushes are a phenomenon that can have very different origins, but produce the same results: injury, loss of life, damage to property, excess dilution, production delays, or mine closure. Although mudrushes are more common in cave mines than other mines, any mining activity that enables the accumulation of fine particles and water is susceptible to mudflow. This paper describes the process developed by the authors during the past decade to evaluate the risk of mudrushes, specifically in caving and sublevel caving mines.RÉSUMÉ Un danger potentiel qui devrait être évalué durant les études d’exploitation par blocs foudroyés est la possibilité d’afflux de boue. Le phénomène des afflux de boue peut avoir des origines très diverses; les résultats sont cependant les mêmes : des blessures, des pertes de vie, des dommages à la propriété, une dilution excessive, des délais de production ou des fermetures de mines. Bien que les afflux de boue soient plus fréquents dans les mines exploitées par blocs foudroyés, toute activité minière qui permet l’accumulation de particules fines et d’eau est sujette à des coulées de boue. Le présent article décrit le processus développé par les auteurs au cours de la dernière décennie pour évaluer le risque d’afflux de boue, surtout dans les mines exploitées par blocs foudroyés et par sousniveaux foudroyés."

Jan 1, 2016

By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007

By H. Henao, E. Kohnenkamp, L. Rojas

The slags generated in the copper conversion process are mainly composed of Cu2O-Fe2O3-SiO2 with the compounds CaO and Al2O3 in concentrations up to 10 wt%. The present work contributes to the knowledge of the conversion process, generating experimental data for the diagrams of phases Cu2O-Fe2O3- SiO2-Al2O3 and Cu2O-Fe2O3-SiO2-CaO. The experiments were carried out in a tubular furnace at temperatures of 1150°C and 1200°C under a condition of saturation with tridymite. Once the equilibrium was reached, the samples were fast quenched in water. The phases in the samples were observed in a Scanning Electron Microscope (SEM) and the elemental composition of the phases analyzed by means of Energy-dispersive X-ray spectroscopy (EDS) detectors. The addition of Al2O3 and CaO into the Cu2O-Fe2O3- SiO2 system resulted in an appreciable displacement of the liquidus lines, corresponding to an expansion of the liquid in the tridymite primary phase field. INTRODUCTION The conversion process of copper consists of oxidizing Fe and S present in mattes with 60 to 65wt% Cu (up to 16wt% Fe). This process is separated into two stages: 1- Slag blowing: Fe is oxidized, the addition of a flux such as SiO2 (silica) forms a second liquid phase called slag, this phase is removed from the furnace; 2-Copper blowing: in this stage, the matte with low concentration of Fe (<1% w/w) is again oxidized to remove S as SO2 in the exhaust gases. The product of these two processes is the formation of Copper Blister (> 98wt% Cu) (Schlesinger et al., 2011). Unlike the aforementioned conventional processes, in most Chilean smelters, conversion Peirce- Smith Furnaces are loaded with high copper matte (70–75wt% Cu) (Henao & Moyano, 2016). Due to the low concentration of iron in these matte (up to 5wt%), it is considered that separating the conversion process in two stages is neither operational nor environmentally convenient. Therefore, the process is carried out in a single stage (Pradena et al., 2006), generating a slag phase with a high percentage of Cu2O (wt%Cu>40).

Jan 1, 2019

By Patrick R. Taylor, T. A. R. Putra

A review of various methods to treat high arsenic copper concentrates through pyrometallurgical processing is presented. Examples are drawn from various past and current operations and research. Various aspects of the engineering alternatives for treatment methods are discussed. Some of the methods discussed include: controlled oxidation roasting, adaptation of some smelter technology to accept higher amounts of arsenic, complete oxidation with arsenic fixation; sulfation roasting; acid baking, soda ash roasting, and others methods. Other topics include: a short discussion of other problematic impurities; the effects of arsenic on copper electro-refining and product purity; and methods for the ultimate disposal, or marketing, of the arsenic. The latest work being done at the Colorado School of Mines on soda ash roasting is also presented.

Jan 1, 2014

By Jeffrey D. Oke

While significant progress in underground construction engineering has occurred in the past few decades, a number of fundamental deficiencies persist regarding the recognition, prediction, and mitigation of underground construction hazards associated with complex geological conditions in rock and soil works, such as tunnelling. Many of these shortcomings could be addressed by improving geomechanical models which, in turn, would provide more realistic frameworks for determining input parameters for design analysis. This would improve predictions of construction efficiency for tunnelling and the formulation of more accurate modelling techniques (2D, 3D and 4D) required to optimize the design of engineered rock structures. This research focuses primarily on the issues related to forepole temporary tunnel support within weak rock masses. This research attempts to determine how best to numerically model forepole support. The behaviour and mechanics of forepole support has not been quantified and/or optimized. As well, there is a lack of in-situ and/or laboratory forepole and weak rockmass interaction parameters available. In terms of numerical modelling, there is a lack of understanding of the use of proper interaction parameters associated with the forepole and the rockmass. The parametric study that has been conducted by the authors demonstrates the influence of each of the forepole-rockmass interaction parameters and their sensitivity. Introduction

Jun 1, 2012

By Tony B. Szwilski

"The efficiency of operation and life of an advancing longwall coalface depends, to a great extent. on the face-end roof strata conditions and the stability of the gateroads. The factors that influence the rate of closure of gateroads are examined, in particular the gateside pack and the coal rib (crush) pillars. The performance of mechanized packing systems is briefly discussed. Gateroad deformation surveys were carried out at two coal mines to determine the influence of the rib pillar width on gateroad stability; also, the influence of the gateside pack on the immediate roof and floor strata is analyzed based on strata bed displacement measurements from instruments installed in the gateroad and pack-hole of a longwall advancing face operating in a thick seam (7.55 m). Concluding, an evaluation of the fac e-end systems examined is given and recommendations made f or the most suitable rib pillar width. face-end geometry and roof strata reinforcement.IntroductionKevword s: Coal mining, Pillars, Rib pillars, Ground control, Longwall mining, Gateroads , Packing systems, Roof control. The face-end region of a longwall advancing face is the center of mining activity, being the turn-around point for the coal cutting machine. and the place of gateroad formation and movement of special face-end supports. The design of face-end layouts can be aided by knowledge of strata control parameters, such as the effective loading of the immediate roof strata , convergence of the roof and floor, magnitude and distribution of fractures in the roof strata around the face-end , optimum placement of supports, coal seam thickness and strength characteristics, geometry of layout and interaction from neighbouring workings. Generally, the gateroad is formed by one of three face-end methods: (a) advanced headings, (b) in-line system (gateroad formed at the face) or (c) conventional ripping with or without stable elimination (also halfheading). The quality of gateroad is influenced principally by the face-end system employed, standard of gateside pack and width of pillar. A good standard of gateroad is generally achieved by employing the half-heading face-end system, the gateside pack and coal rib pillar having comparative support/ yield (stiffness factor) characteristics. However, the halfheading is often not favoured due to face operation restrictions."

Jan 1, 1981

By Esau Arinaitwe

The most extensively used methods and approaches for characterizing and selecting frothers for plant application are based on measurements in clean water in the absence of solids and without consideration of physicochemical factors that are known to influence the properties and behavior of practical flotation froths, and hence metallurgical performance. These factors include aquatic chemistry, collectors, modifiers, particle shape and size, and pH. Understanding interactions between these factors and the role and relevance that they play in characterizing frothers and froth zone properties will greatly aid in the frother selection and evaluation process. Such an understanding will also greatly enhance the ability to create frother solutions that are sufficiently robust to plant variability (such as mineralogical, comminution, operational, physical and chemical). This paper reports results of a “systems approach” study designed to probe ways in which physicochemical factors a) influence frothing and bubble size in 2- and 3-phase systems, and b) confound correlation of fundamental measurements with flotation outcome. The concepts and insights gleaned from fundamental frother studies, together with empirical laboratory flotation tests and a thorough understanding of plant needs and challenges were used to develop and implement customized frother formulation at a Cu-Mo flotation plant. Plant metallurgical data and qualitative assessment of froth zone properties showed that a frother formulation developed using the approach described here provided marked improvements in froth characteristics (mineralization, mobility, stability, persistence). These improvements resulted in better circuit control and significant performance advantages, such as improved coarse particle recovery, without detrimental downstream effects. INTRODUCTION Successful recovery of value minerals of sufficient grade via the flotation process requires selective manipulation of the value minerals to render them hydrophobic using collectors and modifiers. The hydrophobized minerals then attach to air bubbles and the mineral-bubble aggregates are selectively transported through the froth zone into the launder. Frothers play a critical role in froth formation and more importantly in achieving and maintaining desirable froth characteristics (for example, stability, mobility, persistence) that are essential in facilitating the selective transport and recovery of value minerals. Fundamentally, frothers contribute to the transient stability of thin liquid films and so aid in reducing bubble coalescence rates in the pulp and froth zones, thus maintaining the small bubbles required for efficient bubble-particle attachment. Invariably, the action of frothers at the liquid/gas interface in the pulp and froth zones impacts bubble stability, water and solids transport to the froth, which in turn impacts froth mobility, froth carrying capacity, and the concentrate grade. Consequently, selection and evaluation of frothers for flotation plants requires careful consideration of the frother type, though the choice is limited to only two main classes of compounds in terms of fundamental chemistry (short chain alcohols and polyglycols). Even with the selection of what is thought to be the best frother for a given application, practical knowledge of the froth zone and experience in controlling its properties is essential for maximizing metallurgical performance.

Jan 1, 2019

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987