Search Documents

By N. Haghdadi, D. M. Maijer, A. B. Phillion

B206 is a recently-developed high-strength Al-Cu casting alloy with reduced Ti and Fe, as compared to the well-known AA 206 alloy, for improved hot tearing resistance. In the current study, the solidification kinetics of this alloy as a function of cooling rate from 1 to 15 K/min were studied using differential scanning calorimetry (DSC) and microscopy. Specifically, the evolution in fraction solid, grain size, and secondary dendrite arm spacing have been characterized. The DSC results show the occurrence of three peaks during cooling from the liquid state, which are related to the formation of primary aluminum, a pre-eutectic intermetallic, and the eutectic phases. Thermal analysis also indicates that while the liquidus temperature is not sensitive to the cooling rate, the temperatures at which the pre-eutectic and eutectic phases form are strongly coupled to the rate of heat extraction. A decrease in the latter temperatures was observed when the rate of solidification was increased, leading to a lengthening of the freezing range of the primary phase. The results will be useful for improving B206 casting processes, specifically through modification of mould cooling conditions.

Jan 1, 2014

By Jan Butra

In copper ore mines located in the Pre-Sudeten Monocline the deposit mining using room and pillar systems has been carried out for more than forty years. When implementing mining systems in deep copper ore mines it appeared to be necessary to adapt them to variable geological conditions and natural hazards. In the initial period of exploitation there were mainly caving and rockburst hazards. The adaptation of room and pillar system was connected with a state of knowledge in the scope of identifying, forecasting and controlling rock mass hazards. The new solutions allowed the safe and efficient exploitation of a blanket deposit of variable thickness from about 2 to 15m, seated on progressively increasing depth. They included exploitation in constrained conditions, such as in protective pillars. In the exploitation period, technical and organisational activities aimed at rockburst hazard control were introduced including active methods for controlling rockburst hazard and procedures for conducting mining works in the rockburst hazard conditions. When mining at a depth exceeding 1,200 m, the exploitation method and technique are additionally affected by thermal hazard and by gas and rock breakout hazard. New solutions of the room and pillar system and a longwall system with mechanical mining have been developed for exploitation in the associated hazard conditions. The require application of many innovative solutions in the scope of mining process and ore haulage mechanisation, excavation support and forecasting and control of existing hazards. The main purpose of these solutions is to conduct the safe and economically effective exploitation of the deposit.

Aug 1, 2013

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By D. H. Wilton, C. I. Godwin, A. J. Sinclair

"A computer-based drill core logging system used to examine computer-based drill core logging system used to examine copper mineralization hosted in volcaniclastic rocks at the Sustut deposit, in north-central British Columbia, has many advantages over conventional logging. A relatively simple format for recording geological information allows complex, but significant, geologic parameters to be recorded consistently, accurately and quickly. This allows graphical presentations and statistical interpretation of the data that lead to rapid and detailed analyses of the control and distribution of copper mineralization at the Sustut deposit.Ore mineralization is concentrated in lens-shaped bodies and is zoned from native copper cores through chalcocite, bornite and chalcopyrite to a margin containing pyrite. Chalcocite, the principal mineral, occurs mainly in volcaniclastic agglomerate characterized by a specific grain size, a narrow range of matrix and fragment proportions, and a specific sorting.IntroductionWe report here a case history of the practical application of a detailed computer-based drill core logging system applied to the Sustut copper deposit of Falconbridge Nickel Mines Ltd. The Sustut deposit, containing a few tens of millions of tons of ore grading slightly more than one per cent copper (Church, 1975), is in north-central British Columbia about 875 km north of Vancouver. The deposit is contained in volcaniclastic sedimentary rocks of the Upper Triassic Moosevale Formation, which is within the upper part of the Takla Group (Monger and Church, 1977) of basic volcanic and associated sedimentary rocks. Takla rocks occur along the eastern fringe of the Intermontane Belt in the Canadian Cordillera (Sutherland Brown et al., 1971). The deposit consists of concentrations of copper sulphides, native copper and pyrite within pods and lenses parallel to bedding in the host sedimentary rocks. These sheet-like deposits exhibit a mineral zoning from pyrite at the fringes successively through chalcopyrite, bornite and chalcocite to native copper at the core (Wilton, 1978; Wilton and Sinclair, 1979)."

Jan 1, 1980

By Xiaowen (Wendy) Ma, Hans Liang, Xiaoying Chen, David Way

"The mineralogical characteristics of the process streams provide key indicators to the potential improvement in the metallurgical performance. Therefore, the process mineralogy and diagnostic metallurgy have been widely used as a tool to assist the metallurgists at the operating plants. The challenge of this study was then how to characterize the diagnostic flowsheet of the minerals of interest in the process streams across the flotation circuit. The investigation from this study indicates that the minerals chematic flowsheet can visibly demonstrate the sources that caused the gold losses during the mineral processing.In this paper, we present studies of the flotation process stream samples, representing the feeds, intermediate products, final concentrate and final tails, which were produced from the flotation concentrators of Mt Carlton mine in Queensland, Australia. This study was focused on characterizing the process streams and learns how the gold in the process streams was associated with other sulphide minerals and host minerals on a size by size basis. The automatic QEMSCAN/MLA Particle Mineral Analysis (PMA) and Trace Mineral Search (TMS) were applied to identify the minerals and to detect the gold in the sized fractions of process streams. The Laser Ablation ICP-MS (LA) spot analysis, QEMSCAN EDS spot analysis and electron microprobe spot analysis were employed to identify and quantify there fractory gold concentrations in the sulphide minerals, like pyrite, and the elemental concentrations of visible gold grains. The diagnostic flowsheet of gold recoveries by the process streams, by mineral association classes and by the particle sizes were generated and discussed."

Jan 1, 2017

By A. Gakwaya, P. Vachon-Joannette, P. Gagnon, J. Lévesque

"Predictive numerical methods are essential tools for reduced development cost and improved high performance designs of modern aircrafts. Their use leads to savings in terms of design cycle time and experimental trials. Composite materials subjected to impact loadings demonstrate various damage modes such as matrix cracking, fiber breakage, delamination and, ultimately, fabric fracture. Composite laminates are extensively used in the aerospace industry, and their damage modeling is complex due to their inhomogeneity and anisotropic behavior. Damage evolution affects both in-service properties and performance of these composites. In this work, the drop-weight impact test has been simulated. Using a material model that accounts for both delamination and intralaminar damage, laminates response is analysed using numerical simulations based on 3-D finite-element models of the commercial code Abaqus/Explicit. Experimental and simulation results are compared, in terms of energy absorption and contact force. The obtained numerical results show good agreement with experimental data.INTRODUCTIONAs primary aircraft structures are increasingly being made from advanced fiber-reinforced polymer matrix composites and are in general exposed to a variety of impact scenarios (bird, hail, debris etc.), an understanding of the impact event and the performance of composite materials during impact is important in the development of new structures. This work is focussed on low velocity impacts that typically occur when foreign objects hit the aircraft during maintenance or other on-the-ground operations. These impacts can cause non visible damage that affect the structural integrity of the composite components. While for metallic structures, damaging impact events typically leave noticeable dents due to plastic deformation, in contrast, for high strength carbon fiber reinforced composites, they can deform elastically to strain levels exceeding 1% and the internal damage can often occur without the formation of a visible dent. The identification and effect of impact damage on the performance of the structure is thus of great concern to the aircraft industry as the durability and damage tolerance of these composite structures are strongly influenced by the size of detectable internal damage."

Jan 1, 2016

By I. P. Swainson, A. Ilbagi, H. Henein

Powders of Al-50wt%Ni, Al-40wt%Ni and Al-36wt%Ni were produced using the Impulse Atomization technique, a rapid solidification technique. The molten droplets were cooled in-flight by the stagnant helium or nitrogen in the atomizing chamber. The resulting powders were sieved into different size ranges. X-Ray diffraction and neutron diffraction were used in order to quantify the phase fractions in the samples. The computer software GSAS was used to calculate the weight fraction of the existing phases, namely Al3Ni2, Al3Ni and Al, by profile refinement method. The effect of processing parameters, alloy composition and particle size will be discussed in this paper. In brief, no AlNi was found in any of the samples analyzed. Higher cooling rates resulted in the reduction of the ratio of Al3Ni/Al3Ni2. Also, at high cooling rates, Scheil closely predicted the ratio of Al3Ni/Al3Ni2. Some metastable phases were found in Al- 36wt%Ni.

Jan 1, 2010

By W. M. Armstrong, John A. H Lund

The paper describes an investigation of some of the tensile properties of single crystal vanadium, poly-crystalline vanadium and polycrystal-line tantalum, in the range of: W°C to -196°C. Techniques employed in the preparation and testing of specimens are discussed in detail. Some results of determinations of the temperature dependence of yield stress and ductility are given, and discussed in terms of the Cottrell-Bilby Theory of yielding. At subnormal temperatures, all the body-centred cubic transition metals in the Periodic Table exhibit; a) the "yield phenomenon" in tension, b) a strong temperature and strain rate dependence of yield stress, and c) a large decrease or complete loss of ductility. The yield phenomenon (existence of an upper and lower yield point) has been explained by Cottrell and Bilby ( 1) in terms of the dislocation-locking effect

Jan 1, 1961

By J. P. Mogan, E. D. Dainty

Polynuclear aromatic hydrocarbon (PAH) levels were measured in underground mines in the vicinity of diesel vehicles equipped with several types of emission control hardware. In general, the emission control devices appeared to reduce PAH levels, but the companion mutagen study suggested that the reduction might not always be beneficial. All underground PAH concentrations were below the threshold at which a significant impact on health might be expected, but recent animal exposure studies have indicated that PAHs may not be the primary hazard from chronic diesel fume exposure.

Jan 1, 1994

By Steve Scott

Green Economy Toyota Prius Hybrid contains about 50 kg of copper. All-electric cars have about 100 kg of copper. From where will all the copper come? Wind turbines have 1 metric ton of copper China is building 221 cities of 1 million people by 2025 (13 cities per year from 2008) = 10 New Yorks. The Greater Toronto Area has 5.6 million people, so a new GTA every 22 weeks!

May 1, 2013

By Brad Ross

? Value in number of children ? Polygamy common ? Support of extended family and friends ? HIV/AIDS ? Not a culture of savings ? Minimal mechanical experience ? Supportive ? Unintended hindrance ? Mining claims ? Export Permits Lack of funding

May 1, 2011

By J. C. Moreno, G. Rios, M. Palacios

The Huelva smelter was commissioned in 1970 coinciding with the shutdown of the old smelter in the Rio Tinto mine site. That new smelter consisted of two Momoda blast furnaces with a capacity of 500 dmtpd of concentrate. Nevertheless, soon after their start-up, it was clear that an increase in the smelting capacity was needed. After an analysis of the existing alternatives at that time, the flash smelting technology was chosen. The new Outokumpu Flash Smelting Furnace (FSF) came into operation on 18 September1975, with an initial capacity of 900 dmtpd of concentrate, using four Venturi-type burners and preheated atmospheric air. Since that date the Huelva Smelter team, together with Outokumpu (now called Outotec), have continuously improved our FSF design, process conditions and operational practices, leading to a present capacity of 3,500 dmtpd of concentrate. Since 1975, five smelting campaigns have been completed, the last ending in November 2013 with the rebuilding of the original FSF hearth. This paper describes the history of these improvements and the lessons learned.

Jan 1, 2014

By V. Songmene, A. Tahan, J. P. Michaud

The machining of thin wall parts, often used in the aeronautical industry still creates a number of problems, including panel deformation. Quality and productivity are often affected. This study seeks to determine the optimal conditions for cutting in order to guarantee a competitive fabrication of parts while still maintaining quality and delivery deadlines. The studied model (Spar) is a typical structural part used in the assembly of airplane wings. The main objective of this study was to improve two performance aspects: surface quality finish (quality criteria) and the rate of cutting by stock removal (economic criteria). To achieve this objective, we used an evaluation process of the geometrical error issuing from the machine-tool. We also determined the stability zones of the machine-tool's dynamic system. Finally, a series of high-speed machining tests (finishing cuts) were conducted using an experimental structured approach (16 000 - 24 000 rpm). Profile measures of surface roughness and cycle times registered during trials allowed us to establish optimal cutting conditions. Surface roughness improved as well as cutting by stock removal. Four parameters were taken into consideration: axial depth of cut, chip load, spindle speed, and cutting fluid. Finally, the influence of the type of cutting fluid was evaluated to show that it did not significantly affect machining results.

Jan 1, 2006

By Ryan L. Veenstra

This paper presents a modelling study of a cemented paste backfill in an underground stope. The model was developed to help provide a better understanding of what is happening in the stope during the filling stage of the stope. In order to do this, the model incorporates the paste rise rate, stope geometry, and time-dependent input parameters. This paper looks at the effect of geometry in two parts. The first part compares a series of simple rectangular stope models. These models differ in size both in two and three dimensions. The second part compares the results of four 2D models together and then to the field instrumentation data. Part of this section introduces the geometry and instrumentation within the test stope.

Jun 1, 2012

By Y. Y. Yemelyanov, S. S. Gudkov, A. V. Boldyrev, A. V. Bogorodskiy, S. V. Balikov

"A series of tests to optimize pressure oxidation- carbon-in-leach process (POX-CIL) of goldbearing flotation concentrate with the addition of sodium chloride and activated carbon were carried out. Flotation concentrate which was generated during primary ores concentration from a large Russian deposit was used for these tests. The tests were performed with different concentrations of sodium chloride. It was found that the required sodium chloride concentration for gold leaching was 5 g/L. The tests performed with different additions of activated carbon showed that the amount of activated carbon should be at least 6% of the concentrate mass. The rate of sulfides oxidation was 67.7–99.8 %. The highest gold recovery was 98.6 %.INTRODUCTIONThe majority of gold-bearing ores are recommended to classify as amenable to cyanidation and refractory. Processes at elevated pressures and temperatures have become increasingly important in base metals hydrometallurgy (Lodeischikov, 1999, 2007; Naboichenko, Shneerson, Kalashnikova, & Chugaev, 2009; Thomas, 2005).Current pressure autoclaves – cyanidation flow sheets are capital intensive due to numerous circuits and the use of environmentally-unfriendly sodium cyanide. The use of halide-based lixiviants during pressure oxidation of precious metals can be a promising technique for refractory sulfide goldbearing mineral raw material hydrometallurgical processing (Fleming, 2002, 2007, Kotlyar, Meretukov, & Strizhko, 2005).In this paper, we presented the results of the research on finding the optimum process parameters of pressure oxidation using an adsorbent for a refractory gold-bearing concentrate. A proposed flow sheet involves (Bogorodsky, Yelelianov, & Balikov, 2012):1. Gold-bearing sulfides oxidation followed by precious metals dissolution and the formation of gold and silver chloride complex;2. Reaction of the precious metals chloride complex with a carbon-based adsorbent;3. Precipitation of precious metals onto the adsorbent by EW and smelting of cathode precipitates into Dore bullions.This process allows POX of gold-bearing sulfides, precious metals dissolution and their precipitation on the adsorbent to be executed in one single vessel. This study found that the most suitable lixiviant was sodium chloride. Fleming (2002) suggested that in the presence of a halide-based reagent (e.g. chlorine- ion reaction), the dissolution of gold during POX is achieved according to reaction 1:"

Jan 1, 2016

By K. Barbetti, J. Avraamides

"The processing of gold ores with high silver contents can provide operational challenges, such as high cyanide consumption, retardation of gold leaching and competition during adsorption stages of carbon-in-pulp/leach/column (CIP/CIL/CIC) circuits. In particular, the silver, which is about 1.5% of the value of gold, competes with gold during carbon adsorption due to its higher concentration in many Ag-Au ores, potentially leading to gold solution losses. Fresh and partially fouled (barren and regenerated) activated carbons were evaluated at various Ag:Au ratios and total metal concentrations with regard to the adsorption kinetics and equilibrium loadings. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the competitive adsorption environment. An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. The model performance and some of its salient features will be discussed.INTRODUCTIONThe processing of gold ores with high silver contents can present a range of operational challenges, such as high cyanide consumption, retardation of gold leaching and competition in carbon adsorption circuits. Silver is often present at significantly higher concentrations than gold in many gold-silver ores and competes with gold in carbon adsorption circuits, limiting the gold loading rate and capacity, resulting in gold solution losses and reduced gold recovery.Curtin University’s Gold Technology Group has evaluated fresh and partially fouled (barren and regenerated) activated carbons at various Ag:Au ratios and total metal concentrations to determine the adsorption kinetics and equilibrium loadings for gold and silver. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the presence of both gold and silver.An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. This paper describes the model performance and some of its salient features."

Jan 1, 2016

By Bradford C. Wesstrom

An overview of the challenges encountered at the Freeport McMoRan El Paso Copper Refinery with higher concentrations of antimony electrolyte will be shared. The observations will cover the detrimental effects on copper starting sheets, commercial cathodes and anode slimes. The study will show negative effects on quality and productivity. Experimental work will utilize a test cell to study the effects on electrolytes by different Antimony, Arsenic concentration and anode molar ratio. Best practices will be shared for producing high quality cathodes while effectively managing the detrimental effects of higher antimony electrolyte.

Jan 1, 2014

By M. Hosseinzadeh

By changing the quality of consumed refractory bricks in burner zone of sarcheshmeh copper complex anod kiln removing of carbon precipitation phenomenon was studied. For blister deoxygenation LPG is blowing in anod kiln and cause destoring microsturcture and bonding of refractory bricks. Studies are shown that in a part of the bricks which have a temperature of 800 - 1000 °C , iron content phases in magesia - chromite bricks are like catalist and cause increasing the rate of carbon precipitation reactions . In a way that in comparsion of two bricks with best and medium quality with different analysis, this problem is more critical in best quality bricks containing high iron oxide. Therefore special magesia spinel bricks suggested and installed in burning zone.

Jan 1, 2004

By J. Dubinski

Passive tomographic imaging is a technique that can be used for assessing seismic hazard in mines with high seismic activity induced by mining. The basic idea behind such an interpretation is the assumption that there is a relationship between high values of seismic velocity and high values of stresses in the rock mass. This relationship was confirmed both in laboratory an in situ measurements and constitutes the basis for rock-burst and seismic hazard evaluation. In the paper seismic tomographic images of seismic P wave velocity and seismic P wave velocity gradient have been presented to determine rock-burst hazard and locate high seismic activity zones in the area of coal panel 306 in Zabrze Bielszowice mine. The zones of high values of P-wave seismic velocity gradient have been found to correlate with the distribution of high energetic seismic events. Passive tomographic images were obtained using modern bent ray tracing tomography algorithm with regularization. Recent study give rise to observation that not only high values of P-wave seismic velocity is important in seismic hazard assessment as many strong seismic events are located in the areas of high values of velocity gradient. This recent observation permits to increase quality of passive tomographic imaging for detection of seismogenic zones and is presented in the paper. The advantage of passive tomography comparing to active tomography is that sources of seismic waves are generated by rock mass itself and costly controlled explosions are not necessary. Another practical limitation of active tomography is the size of study area which usually do not exceed 200 m by 200 m. This restriction does not appear in passive tomography where area of study is usually 2000 m by 2000 m and the tomographic images delineate velocity structure in locations where mining induced seismicity take place. Passive tomography method utilized in analysis of rock mass state in underground mines encounter some difficulties concerned with the numerical stability of optimization algorithms. In the presented approach to passive tomography problem numerical stability is obtained by special regularization method and by application of very stable numerical seismic ray-tracing algorithm.

Aug 1, 2013

By Osamu Inoue, Takashi Yamashita, Takashi Ikemoto

The expansion project in Naoshima smelter and refinery to meet enhancing recycling business of E-scrap was successfully completed in 2016 to have a capacity of 110,000 tpa of E-scrap treatment. Increasing treatment of E-scrap has raised the Ni content of copper anode to 4000 ppm on average, which is double the level of 10 years ago, and to 6000 ppm or more occasionally. The tank house has refined such copper anode to copper cathode with starter sheets. Since most Ni in Copper anode dissolves in copper electrolyte, the Ni content of the electrolyte has increased to 27 g/L and more. Ni accumulated in the electrolyte has increased power consumption during the electrolytic refining of copper, although cathode quality has been controlled satisfactory so far. In order to ensure sustainable operation while growing E- scrap business, the NiSO4 process has been expanded recently so as to recover Ni in the electrolyte more and the pressurized-leaching technology will be introduced to the slime leaching process so as to enhance the capacity of slime treatment and to improve Ni recovery in the near future. INTRODUCTION In recent years, the treatment amount of E-scrap at Naoshima smelter and refinery has increased according to the growth of its recycling business as shown in Figure 1, while impurities from E-scrap have concentrated in copper anode as well. Especially, Ni content in anode has been increasing remarkably since 2012, causing to raise Ni content in the electrolyte as shown in Figure 2. The increment of Ni content in copper anode and electrolyte has adversely affected the electrorefining process, slime leaching process, and NiSO4 crystallization process at the tank house. Such severe conditions provided opportunities to redesign the tank house to establish a robust process to which more Ni is acceptable.

Jan 1, 2019