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By Georges Houlachi, Akram Alfantazi, Maysam Mohammadi

Manganese ions in zinc electrowinning electrolytes form a protective MnO2 layer that ultimately decreases Pb contamination in the zinc product. In this study, the effect of dissolved Mn2+ on the electrochemical performance of Pb, Pb-Ca and composite Pb-MnO2 anodes was investigated. The properties of the MnO2 layer formed on these anodes were studied and compared. Potentiodynamic polarization and cyclic voltammetry experiments were performed in 180 g L-1 sulphuric acid to study the electrochemical reactions occurring on the anodes. The anodes were subjected to galvanostatic polarization at 50 mA cm-2. The morphology and uniformity of the MnO2 layer on the anodes were examined using scanning electron microscopy (SEM). Experimental results revealed that the MnO2 layer formed on the composite anode was more compact and uniform compared to that formed on the Pb and Pb-Ca anode. It was also observed that the cell mud formation rate, and consequently manganese ions consumption, depended on the anode type. Although initial formation of the MnO2 layer decreased the oxygen evolution overpotential, its growth might negatively affect electrocatalytic activity of the anodes.

Jan 1, 2014

By Kosei Ishida

To achieve renovation work without noise, the authors developed techniques of manufacturing pre-cut interior finishing components for renovation work. In this paper, to achieve the system of pre-cut interior finishing components, the authors describe a measuring method of reinforced-concrete structure by 3D laser scanner and then describe a method of making a design of pre-cut interior finishing components with the polygon model. Using these two methods, the steps of manufacturing pre-cut interior finishing components consist of the following four steps: First, measure the building shape using a 3D laser scanner. Secondly, integrate a point cloud data and retrieve the markings on the floor. Then, create a polygon model of the building based on the point cloud data. Lastly, make a drywall design using a polygon model. To evaluate the technique feasibility of manufacturing pre-cut interior finishing components, the authors have conducted an experiment of the finishing interior work of the drywall. Using pre-cut interior finishing components, the authors have been able to achieve interior finishing work without noise.

Aug 1, 2013

By C. A. Pickles, K. Mackowiak

Black Thor chromite ore from the Ring of Fire deposit in Northern Ontario was carbothermically reduced in a microwave system to produce a ferrochromium alloy. The as-received ore contained 43.0% Cr2O3, 19.9% Fe2O3, 14.5% MgO, 13.4% Al2O3, and 7.0% SiO2. Activated charcoal was utilized as the reducing agent. Firstly, TGA/DTA and permittivity studies were carried out in order to determine the relationship between the reduction process and the microwave susceptibility. Secondly, microwave reduction experiments were performed on the chromite ore. The variables investigated were; the amount of carbon, processing time, input power and type of atmosphere. A maximum chromium grade of 76.1% and a chromium metallization of 82.7% were obtained for a processing time of 20 minutes, a power input of 800 W, and a carbon addition of 15% in an argon atmosphere.

Jan 1, 2017

By Derek H. C. Wilton

"The Cape Ray Fault Zone of southwestern Newfoundland contains two notable electrum/ base metal sulphide quartz vein lode occurrences hosted by two contrasting lithological units, viz. a graphite schist horizon and a granite. The two occurrences, although in proximity, are not in direct contact, but, based on geochronological, geochemical and isotopic evidence, they were apparently deposited from hydrothermal fluids generated as a vapour phase from the magmatic progenitor of the Windowglass Hill granite.This paper provides further evidence, from REE and background A u and Ag data, for the magmatic origin of the hydrothermal fluids. Wall rocks to the electrum-bearing quartz veins in both the schists and granite have experienced a LREE depletion probably due to leaching by Cl-bearing solutions. Gold and silver contents are typically low in all rock types but there is a slight elevation in gold concentrations in those units in contact with the Window glass Hill granite. The granite also has the relatively highest gold and silver contents of any unit in the region.IntroductionThis paper presents the evidence from rare earth element (REE) and gold/silver concentration data for the magmatic origin of hydrothermal fluids responsible for deposition of the Cape Ray electrum deposits of southwestern Newfoundland. The two deposits occur in the Cape Ray Fault Zone (Fig. I) within the Windsor Point Group and Window glass Hill granite. The larger occurrence is called the Main Shear Showing and consists of a deformed quartz vein horizon, which extends for - 6 km, within the late Devonian Windsor Point Group. This unit is an intermixed ignimbrite and mafic tuff sequence with associated schists (metasediments) and gabbros. The host rocks to the mineralized quartz veins are interleaved graphite, chlorite and sericite schists. Basal ignimbrites within the Windsor Point Group have been dated, by Rb/Sr isotopic methods, at 377 ±21 Ma (Wilton, 1983a). The basal ignimbrites also have enriched REE patterns, an elevated initial Sr ratio (0.709) and a peraluminous-siliceous nature which suggest they resulted from the partial melting of continental crust (Wilton, 1984)."

Jan 1, 1985

By M. J. Nicol

The leaching of gold with thiosulfate solutions in the absence of ammonia and copper ions was investigated using electrochemical and kinetic methods. In sodium thiosulfate solutions, the electrochemical oxidation of gold was hindered and the leaching rate using pure oxygen as the oxidant was very slow. It was found that the addition of a small amount of thiourea or formamidine disulfide to the thiosulfate solution greatly enhanced the oxidation of gold. However, the enhancement to the overall dissolution of gold using dissolved oxygen as the oxidant was limited. This was attributed to the fact that the oxygen reduction process was unaffected by the additives and remained slow, which limited further improvement to the overall kinetics. An alternative oxidant, the ferric EDTA complex having a reduction potential of approximately 0.12 V, was found to be promising. The cathodic reduction of ferric EDTA was fast and reversible at neutral pH. While the ferric EDTA complex was effective in oxidizing gold, it did not appear to significantly oxidize thiosulfate. A thiosulfate solution containing thiourea and ferric EDTA has been shown to quickly dissolve gold in the form of a powder as well as from gold ores. In the leaching with the ores high gold recoveries of above 90% was achieved with the best performance obtained in neutral solutions (pH 6-7).

Jan 1, 2005

By A. Desbiens, M. Maldonado, R. del Villar, Aguilera. R.

This work details the application of a multiple model approach to estimate frother concentration in flotation processes. The methodology consists of identifying a set of linear dynamic models representing the effect of gas rate on the collection-zone gas holdup at different known frother concentrations (calibration step). An adaptive law is then obtained using Bayes' rule to evaluate the conditional probability that each model represents the observed system behavior. In this way, a frother concentration estimate is calculated as a weighted sum of model probabilities and their associated (known) frother concentrations. Experimental results conducted in a two-phase system using Dowfroth250C are promising. Modeling and analysis for MIBC frother are also provided.

Jan 1, 2009

By V. K. Srivastava1

Coal mine fires burn about 20?21 million tons of coal per year throughout the world, which not only results in loss of valuable coal reserves, but also cause serious environmental hazards over large areas. The famous Jharia Coalfield of Dhanbad, India is no exception; here a coal mine fire originally reported nearly a century ago is still continuing unabated in vast areas of the coalfield. In this paper, an attempt has been made to analyse high resolution multispectral thermal images of ASTER for mapping and delineating surface and subsurface coal mine fire areas of this coalfield. From the generated temperature gradient map, as well as from the surface temperature anomaly map, it has been possible to differentiate shallow and deep coal mine fire regions and other erroneous cultural features. It is observed that the coal fires are distributed mostly in the eastern part of the area, which has branched into two major coal fire zones: one along Lodna- Tisra-Bhulanbarari-Kujama-Jealgora Jharia and the other along the Kusunda-Kendudih area. The western fire zone is restricted in Dumra-Nadkhurkee-Jayramdih area. From ASTER thermal infrared data from 2006, the total affected area is estimated to be about 7 km2, of which the deep subsurface coal mine fire area is around 3 km2 and the shallow surface coal mine fire area is around 4 km2, as compared to 18 km2 coal mine fire area estimated in 1987 using Landsat TM thermal band data. In other words, the fireaffected region has decreased by about 50 % during the last 18 years. However, such decrease in coal fire area is seen in the central portion only, and has in fact increased in the south eastern parts of the Jharia coalfield. Study of Differential Interferometery images, generated from Earth Resources Satellite (ERS) synthetic aperture radar (SAR) tandem data has shown that the active coal mine fires are in general associated with low topography/subsidence areas.

Aug 1, 2013

By A. Navarra, Norman Toro, T. Marín, Fernando Ayala

The quantitative techniques to evaluate the enhancement of a particular unit operation should consider the corresponding changes to the adjacent unit operations. For example, the expansion of off gas handling capacity should consider the corresponding changes in converter cycle times, matte grade, and other operational parameters, that can provide the optimal system-wide benefit. In general, the upgrading of smelter equipment is risky due to the size of capital investment, as well as any unforeseen impacts on rest of the operations. However, this risk can be mitigated by applying the principles of Front End Loading (FEL) in the formulation of multiphase re-engineering projects. The initial phases of engineering are relatively inexpensive, and determine whether or not to pursue the subsequent phases that are comparatively more expensive. Each phase of engineering depends on increasingly detailed descriptions regarding the critical phenomena that can effect design decisions; the increasing levels of detail may result from numerical simulations, as well as laboratory and plant trials. The quantitative framework should be sufficiently flexible to accommodate these increasing levels of detail, regardless of the particular phenomena, so that it may evolve throughout the project. The current article describes the combined usage of mass balancing, thermochemistry and multiphysics, in the development of discrete event simulation (DES) and finite differences (FD). The incorporation of finite differences into a DES framework depends on adaptive time-stepping, to determine threshold-crossing times, e.g. when the matte temperature surpasses a critical level that necessitates the addition of cold charge. The hybridization of DES and FD is appropriate for multiphase smelter development projects, as it supports semi-continuous material flows, operational policies and scheduling, as well as unexpected events and trends, in increasing levels of detail. This type of framework will support the installation and tuning of modern control systems, including state-of-the art sensors and machine learning algorithms.

Jan 1, 2019

By K. Liu

"In the present work, two-step heat treatments with preheating treatments at different temperatures (175, 250 and 330°C) as the first step followed by the peak precipitation treatment (375°C/48h) as the second step have been performed in Al-Mn-Mg 3004 alloys to study their effects on the formation of dispersoids and evolution of elevated-temperature strength and creep resistance. During the two-step heat treatments, the microhardness is gradually increasing with increasing time until to a plateau after 24 hours when first-treated at 250°C and 330°C while there is a minor decrease with time at 175°C. Results show that both the yield strength and creep resistance at 300°C reach the peak values after the two-step treatment of 250°C/24h+375°C/48h. The formation of dispersoids is greatly related to the type and size of pre-existing Mg2Si precipitated during the preheating treatments, in which that coarsened rod-like ß’-Mg2Si strongly promotes the nucleation of dispersoids while finer needle-like ß’’-Mg2Si has less influence. Under optimized two-step heat treatments and modified alloying elements, the yield strength at 300°C can reach as high as 97 MPa with the minimum creep rate of 2.2×10-9 s-1 at 300°C in Al-Mn-Mg 3004 alloys, enabling them as one promising candidate in lightweight aluminum alloys for elevated-temperature applications.INTRODUCTION Due to the rapid demand from weight-sensitive automotive and aerospace industrials for the light alloys, such as aluminum alloy on the elevated-temperature applications, Al-Mn 3xxx alloys has been developed to obtain the good properties at both room temperature (RT) and elevated temperature, in which the dispersoid-strengthening mechanism plays a significant role (Li & Arnberg, 2003; Li, Muggerud, Olsen & Furu, 2012; Liu & Chen, 2015, 2015). In our previous works (Liu & Chen, 2015, 2015; Liu, Ma & Chen, 2017), the yield strength and creep resistance at 300°C of Al-Mn-Mg 3004 alloy were further improved by modifying the alloying elements, such as Fe and Mo, to optimize the characters of dispersoids, including the size, distribution and the dispersoids free zone (DFZ). For instance, Mo was introduced in aluminum alloy to further improve the volume fraction of dispersoids and reduce the area of DFZ, leading to increasing on both the strength and creep resistance at 300°C (Liu, Ma & Chen, 2017). On the other hand, the mechanical properties became worse at higher Fe content due to its consumption more Mn to form Al6(MnFe) intermetallics, resulting in less available soluted Mn for the precipitation of dispersoids (Liu & Chen, 2015). Therefore, optimizing the characters of dispersoids is always the key to improve the elevated-temperature properties of dispersoid-strengthened aluminum alloys for elevated-temperature applications."

Jan 1, 2017

This paper presents the results of research aimed at proposing new solutions in the area of belt conveyor elements. Many factors, such as energy consumption costs, and operating costs of belt conveyor elements, including belts, idlers and drives have an impact on the operational costs of conveyors. The paper presents special tests of new materials for the bottom cover of an energy-saving belt conveyor, which decrease rolling resistance. It also presents large-scale in-situ tests of a high-output belt conveyor for the purpose of simultaneous measurements of various types of conveyor belts (standard vs several energysaving types) under typical operating conditions of a lignite surface mine. Improvements in materials used for the bottom belt covers, supported by specially developed comprehensive tests of the new types of belts have provided valuable results of various proposed solutions. Since the tests of belts were done at exactly the same time and in the same operating conditions, direct comparison of the results is valid and should lead to a substantial decrease in the conveyors? drives? energy consumption, which will improve the effectiveness of belt transport and minimize its negative influence on the environment.

Aug 1, 2013

By N. Morrison, I. Holl, R. Welyhorsky, A. Hempstock

ABSTRACT: The Victor diamond mine is located in the James Bay lowlands, 90 km west of the First Nations village of Attawapiskat. The project was the first of its kind in northern Ontario. The process plant was designed to produce a 95 to 98% by weight diamond concentrate through three stages of comminution, dense medium separation, and proprietary X-ray technology for final recovery. The plant was commissioned over a period of six months, commencing prior to substantial completion of construction. Through effective planning of the commissioning phase, the Victor mine start-up was safely completed nine months ahead of schedule.

Jan 1, 2011

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By Guoxiang Chi

This paper consists of two parts: the first part describes the principles and functionality of the BsnMod program, and the second part presents preliminary application of this program to paleo-fluid flow modeling in the Anticosti Basin. The BsnMod program simulates fluid flow and heat transfer during the evolution of sedimentary basins through numerical solution (finite difference method) of three partial differential equations, which describe sediment compaction, fluid continuity, and heat conservation. It can be used to estimate the evolution of fluid overpressure, flow rate, and temperature during the basin history. The program was written in C++, works under Windows environments, and has a user interface allowing inputs in dialogues and outputs in both tabular and graphic forms. The program was applied to the Lower Paleozoic Anticosti Basin in eastern Canada. The basin history consists of a passive margin stage and a foreland basin stage. Preliminary simulation results indicate that no significant fluid overpressures were developed in the passive margin stage and during the early period of the foreland basin stage, but strong overpressures were developed within the foreland basin succession during the middle and late periods of the foreland basin stage. Fluid flow rates were generally slow, and thermal profiles were not significantly disturbed by fluid movement throughout the basin history. Potential source rocks of hydrocarbons were found in the foreland basin succession. The strong overpressures in the foreland basin succession could have been a major driving force for hydrocarbon migration from the source rocks to the underlying potential reservoir rocks.

May 1, 2001

By N. Morrison, I. Holl, R. Welyhorsky, A. Hempstock

ABSTRACT: The Victor diamond mine is located in the James Bay lowlands, 90 km west of the First Nations village of Attawapiskat. The project was the first of its kind in northern Ontario. The process plant was designed to produce a 95 to 98% by weight diamond concentrate through three stages of comminution, dense medium separation, and proprietary X-ray technology for final recovery. The plant was commissioned over a period of six months, commencing prior to substantial completion of construction. Through effective planning of the commissioning phase, the Victor mine start-up was safely completed nine months ahead of schedule.

Jan 1, 2011

By E. Esmaeilzadeh

There arc 8 primary ball mills in the concentrator plant and their task is material crushing. At the time of balls charge to mills, a lot of noise is produced. This noise would affect all grinding areas. The aim of this research was a reduction about 16 dB at source sound power level (SWL was 129.1 dB). With considering two noise control principles, noise producer sources and propagation paths were specified. For removing and reducing of noise producer sources, rubbers with a thickness of 5-20 mm were used on the all inside surfaces of charge box, ball transferring box and exit canal. For increasing transmission loss and damping coefficient of charge box body, rubber with thickness of 1 cm at outside surface of box was used. For reduction of noise propagation a secondary metal cover was designed and made. This cover includes two parts and was set around the charge box. Glass wool (75 kg/m3) with 10 cm thickness was used as acoustical absorbent between free space of two body's layers and from secondary cover side. The of the rest space was left empty. After installing of secondary cover on the ball charge box no.4, SWL showed a reduction about 16 dB. For studying of control system effect on noise reduction at points far from of charge place, measuring results at these points showed the maximum reduction 12.1 dB and the minimum 11.8 dB.

Jan 1, 2007

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By J. M. Skeaff

"The main solution, ore and residue pulp streams in the Rio Algom Quirke I uranium mill at Elliot Lake have been sampled and analyzed for radium-226. Analysis of the ore and leached residues indicates that Ra-226 dissolves and precipitates within the first pachuca tank. A maximum of approximately 0.2% of the Ra-226 in the ore remains in solution during leaching.IntroductionConcern over the acid drainage and radionuclide dissolution problems associated with uranium tailings disposal sites in Canada has prompted investigation into methods for improving current uranium processing practice.Present commercial practice usually involves leaching of the uranium ore with sulphuric acid, ion-exchange separation of the uranyl sulphate complex from the leach liquor and"" precipitation of the uranium as yellowcake. Daughter products of U-238, such as Th-230, Pb-21O and Ra-226 remain with the tailings and undergo long-term dissolution.Table I summarizes the probable behaviour of the radionuclides during milling. The concern here is with Ra-226, because it will deposit in the bones if ingested and is ""thus considered a serious health hazard(1), Similarly, Po-218 and Bi-214, which are daughter products of Rn-222, can be retained in the lungs and are considered to be the principal sources of radiation dosage(2) arising from the inhalation of Rn-222. Previous investigations(3-9l indicate or imply that Ra-226 undergoes redistribution during milling. However, detailed published information on the behaviour of Ra-226 in the uranium milling process appears to be lacking. A knowledge of the behaviour of Ra-226 in uranium mills, particularly during leaching, could lead to improved methods for its control.This paper reports the occurrence of Ra-226 in the Rio Algom mill. The main objectives of the study were to determine (1) the distribution of Ra-226 within the solids, (2) at what point, and how rapidly, redistribution occurs and (3) whether there are high concentrations of Ra-226 in solution."

Jan 1, 1981

By John Rowson, Caitlin Brown, Kebbi Hughes, Joseph Esslifie-Dughan

The McClean Lake mill in northern Saskatchewan, Canada, is operated by Orano Canada Inc. and has been in production for the last 20 years. The tailings preparation process at the mill has been designed with decommissioning in mind, to produce tailings that are geochemically stable over the long-term within the site’s tailings management facility. Twenty years of study have contributed to a detailed understanding of geochemical and geotechnical properties of the McClean Lake tailings. Validation of the tailings properties has occurred through in-situ sampling campaigns conducted initially every year, and later every five years. Each sampling campaign has applied the same rigorous sampling procedure to provide data with useful correlations year over year. Each campaign result compares elements such as the inherent variability of the tailings, consolidation of the tailings and variations in the tailings placement methods. We will discuss lessons learned from seven sampling campaigns over 20 years and present data to show the reliable tracking of geochemical evolution of the in-situ tailings over time; providing opportunities for continuous improvements.

Jan 1, 2020

By S. A. Beeson, C. Poole

"This paper reports on the development of selective flocculation processes for the direct recovery of KCl values from low-grade Canadian sylvinite and carnallite potash ores.Two reagent suites, consisting of either a non-selective cationic or selective non-ionic flocculant, together with the same selective anionic dispersant, were evaluated. Initial data from component mineral behaviour investigations, reagent adsorption studies and selective flocculation tests on a synthetic potash ore were used in the successful development of processes capable of recovering KCl values without the necessity for desliming to remove water-insolubles.Enhanced multi-stage treatment (involving redispersion and reflocculation) and subsequent floc recovery techniques (including sedimentation, hydrocyclones and froth flotation) were examined, and in all cases the influence of process parameters such as reagent dosages, conditioning times, solids concentration, particle size and other physical design criteria were investigated.The data reported clearly demonstrate the scale-up potential of these processes and possible applications in potash operations."

Jan 1, 2000

Despite the claims of energy efficiency and the considerable development that has gone into dramatically extending rolls’ life and facilitating rolls’ change-out, in the six years since the last SAG conference, only a few HPGR operations have entered the realm of mineral processing. Risk barriers to the take-up of new equipment or processes are: a massive increase in materials handling issues as well as in the number of pieces of equipment required, low total circuit potential energy savings, and similar or higher capital costs. An alternative route is to make use of the complementary strengths of the HPGR and SAG in hybrid circuits. Minimising materials handling issues, providing an ideal balanced feed to the AG or SAG mill, and improving controllability through shifting grinding load as the RoM feed changes, are all potential major advantages to this approach. Conceptual circuit layouts, based on real measured ore and equipment data, are presented here to illustrate the potential production upside, the reduction in operating costs and the reduction in the physical and energy footprints.

Jan 1, 2012