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By V. Omaynikova, A. Lossin, H. Salomon-de-Friedberg

In 2009, Aurubis AG and Teck Resources Limited, recognizing a growing industry need, joined together to advance and further develop technology to deal with arsenic-bearing copper concentrates in an effective and environmentally sustainable manner. The work that followed included extensive bench testwork and 3 months of continuous, fully integrated pilot campaigns on high arsenic-bearing copper concentrate as well as environmental testing, market studies and economic assessments. The success of the CESL Process in processing arsenic-bearing copper concentrates, at levels of up to 4.6% arsenic, has been previously presented. The present paper discusses aspects of similar, equally successful trials on copper concentrates with grades of arsenic approaching 12%. Key parameters to the successful processing of these types of concentrates are discussed. In addition, data on subsequent continuous, pilot gold recovery from the leach residues and the longer term stability characteristics of these residues are also included.

Jan 1, 2014

Over the years, efficient on-line monitoring of performance and status of an electrolytic copper refining process has been challenging due to the need for complex electrical measurement systems and the management of the enormous volume of data. Recent innovative developments by Kennecott Utah Copper Corporation and Outokumpu Technology in wireless cell voltage and individual cell temperature sensing opens new possibilities to improve and modernize tank house management. This paper describes the powerful Outokumpu CellSenseTM refinery monitoring system for efficient interpretation of data produced by wireless CellSensorTM system with traditional refinery measurements. Examples from commercial tank house installations demonstrate the benefits of the system to improved process control and operation. The Outokumpu CellSenseTM monitoring system is simple to operate and accessible to all the plant operation teams.

Jan 1, 2007

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By Maria D. Mastalerz, Wei Wang, Maria E. Holuszko, Amit Kumar

In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal and its components (macerals) and these were directly correlated to the coal hydrophobicity as measured by the contact angle before and after reagent addition to understand the suitability of the reagent for flotation. The micro-FTIR technique can provide a semi-quantitative analysis of the chemical functional groups on coal surface, exactly where the contact angle is being measured. Selected functional groups and their ratios that provide information about aromaticity, the contribution of oxygenated groups, and aliphaticity are used to evaluate the reactivity between reagents and various coal components. The observations made in relation to the susceptibility of some reagents towards certain coal components should lead the way to a smarter way of using process design in terms of reagents selection for coal flotation.

Jan 1, 2017

By L. G. Smith, C. A. Shook, W. H. W. Husband, W. Schriek

"The flow of slurries in pipelines is governed by many variables, and the study of the influence of each of these variables is difficult, if not impossible, in some cases. Many correlations are available which fit data within a given range. However, no one method is yet available to design a slurry pipeline for all desired conditions without at least some physical measurements on the slurry itself. For this reason, the slurry pipeline facilities at the Saskatchewan Research Council have been developed during the past 12 years and it is hoped that the development will continue until the process is thoroughly understood and test facilities are no longer necessary. This paper outlines methods currently used and under development at the Saskatchewan Research Council for measurement, control and study of the variables governing the flow of slurries."

Jan 1, 1973

By J. H. Pee, Y. J. Kim, H. U. Lee, G. H. Kim

The general recycling process of tungsten scrap to produce tungsten raw materials (tungstic acid, ammonium paratungstate (APT) and WO3) have been carried out by the oxidation, milling, sodium-fusion, dissolution, and extraction processes. Many studies on the high temperature oxidation of tungsten scrap have investigated various aspects such as swelling kinetics, fracture resistance, and the effect of alloying composition. However, the accelerating factors on the scrap oxidation rate during oxidation were not considered here. In general, oxidized products were fused with sodium carbonate or sodium hydroxide to produce Na2WO4. Later in the process, solid Na2WO4 was dissolved in water. This process required considerable reaction time and was a costly process. Therefore, the aim of this study was to increase the solubility of solid oxidized products to produce Na2WO4 solution by hydrothermal reflux method. Na2WO4 solution was used to produce CaWO4 and H2WO4 by general chemical reactions with calcium chloride and hydrochloric acid. Ammonia solution was also added to the tungstic acid to produce APT. In this study, the effect of ammonia addition on the APT precipitation process was investigated in detail.

Jan 1, 2015

By P. A. Bahri, D. G. Dixon, T. M. Woodward

A comprehensive mathematical model of the Sherritt-Gordon ammoniacal pressure leaching process at K winana Nickel Refinery has been constructed. The process is comprised of six autoclaves functioning as a three-stage leach circuit, operating over the temperature and pressure ranges of 85-95°C and 750-1000 kPa, respectively. The process chemistry forms a complex series-parallel reaction network, characterised by: (1) the gas-liquid mass transfer and reduction of oxygen, (2) the oxidation of eight distinct minerals, (3) the oxidation of sulphur, and successive reactions involving various intermediately oxidised sulphur species, and (4) the oxidation of Fe(II) to Fe(III), and subsequent precipitation as a hydrated ferric oxide. Material balances were developed for species in all three phases, and an energy balance to account for all reactions and phase conversions. The multiple convolution integral (MCI) statistical reactor model was employed for the scale-up of particle kinetics. The model has been validated against plant data, and simulation results are in agreement with plant performance.

Jan 1, 2005

By Z. D. Hora

"There has been a number of new developments in British Columbia's industrial minerals field over the past few years. Several new industrial operations were started to diversify the line of British Columbia mineral production by magnesite, perlite and fuller's earth. Industry activities and geological projects have identified occurrences of rare earth minerals, niobium, kaoline, fireclay and zeolites. The Geological Survey Branch significantly improved its database on industrial minerals. New geological concepts based on recent work are opening a number of new opportunities f or further industrial minerals' exploration and development in British Columbia.IntroductionTraditionally, the value of industrial minerals produced in British Columbia in any given year comprises between 100/0and 15% of the combined value of minerals, coal, petroleum and natural gas. Over the years a wide variety of industrial minerals has been produced , often with different levels of marketings success. For some products, such as dimension stone and clay or shale products, initial strong demand gradually dissipated; for others such as asbestos and magnesite, new discoveries or new industrial activities created demand and new markets . In some cases, such as fluorite , talc, pyrophyllite and perlite, wider use has been prevented by small size, poor quality or remote location of the deposits. Also, British Columbia , with 2.6 million inhabitant s, provides only a limited market and the industry therefore has to look beyond provincial borders."

Jan 1, 1990

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By T. Vovan, A. Galibois, M. Fiset

"In order to establish some links between the 22 specimens found on the site of Les Forges du St. Maurice, their slag inclusions have been analyzed by electron microprobe. Comparison between their contents of various specific oxides allowed us to segregate them into two major groups and even to isolate two sub-groups possibly characterized by some equilibrium between their oxides and/or the type of ores used.In all probability, limes/one coupled systematically with a soil rich in hydrated aluminum silicates was used as a flux.Based upon the existence of a pseudo equilibrium between the slag and the metal, the elaboration of the bulk of the specimens can be ascribed to the indirect rather than the direct method whereas the process temperature can be estimated at at least /400°C.RESUMEDans le but d'etablir des liens entre les 22 objects provenant des Forges du St-Maurice, leurs inclusions de scories ont été analysées par microsonde. La comparison des teneurs en divers oxydes a permis de les séparer en deux groupes majeurs et même d'y distinguer deux sous-groupes pouvant être reliés à la forme d'équilibre entre certains oxydes et/ou au type de minerai utilisé. Selon toute vraisemblance, le fondant utilisé était de la pierre à chaux à laquelle on ajoutait systématiquement une terre riche en silicates hydratés d 'aluminium.Des considérations sur l'existence d'un certain équilibre entre les scories ei le métallaisset croire que la plupart des objets ont été élaborés plutôt par la méthode indirecte que directe et que la température d'élaboration se situait à au maint 1400°C."

Jan 1, 1984

By B. T. Lu, J. L. Luo, H. X. Guo

This paper investigated the synergistic effect in the slurry-erosion process of carbon steel. In line with the mechanisms of material loss, the synergism due to interaction of erosion and corrosion was divided into the corrosion enhanced by erosion and erosion enhanced by corrosion. The erosion-corrosion tests were conducted with A1045 steel in slurries containing silica sand. Experimental results showed that the rotating of the sample in corrosive media raised both OCP and corrosion rate, but the impingement of solid particles did not affect the corrosion current significantly. In the quiescent solutions, the Faraday's law gave a good prediction for the weight loss caused by corrosion but for rotating samples, the weight loss experimentally measured was virtually greater than that predicted by the Faraday's law, indicating that the corrosion-enhanced erosion could occur in corrosive fluids in absence of solid particles. A half-logarithm relationship was observed between the weight loss due to corrosion-enhanced erosion and the anodic current density.

Jan 1, 2004

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By Steve Piercey

Introduction ? VMS Deposits: The Target ? Key points for every belt: heat flow and extension. ? Good felsic rocks ? Good mafic rocks. ? Petrochemical assemblages. ? Summary Key Points Throughout ? Common themes: ? Heat ? driver of the hydrothermal system ? Extensional geodynamic setting ? conduits to focus fluid flux ? (e.g., Lesher et al., 1986; Swinden et al., 1991; Barrie et al., 1993; Lentz, 1998; Syme et al., 1999; Piercey et al., 2001, etc.) ? We must identify rocks, belts and tectonic environments that encompass these two criteria (among others but?) ? e.g., forearc rifts, intracontinental rifts, arc rifts, and back-arc basins.

Apr 1, 2005

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005

By B. Loveday, G. W. Delaney, S. Cummins

"Applying DEM to prediction of tumbling mill performance is challenging because several different modes of breakage are active in the process. As our knowledge of breakage and computational capacity improve, it is worth revisiting previous simulation tasks which did not produce a satisfactorily realistic description of a measured process. At SAG 2006, we reported the simulated and measured outcomes of treating a well characterised ore in a 1.2 m diameter mill. This well instrumented, pilot scale mill at the University of KwaZulu-Natal has been combined with some new approaches to ore testing to allow different modes of breakage to be tested. The mill design allows the rate of generation of fine material to be measured in close to real time for autogenous and SAG mill charges. The updated simulation model estimates mass loss with particle evolution and embeds the cumulative damage and breakage.The simulated results are compared with the measured results. Issues such as relating modelling inputs to particle breakage characterisation data and the accuracy of the predictions of the models are discussed."

Jan 1, 2012

By P. Hickey, G. Hubert, P. Healy

"J. S. Redpath Limited, an underground contractor with a worldwide presence, has implemented innovative techniques in various projects in Canada to shorten the development cycle. Conventional methods currently used for installing primary ground support are compared with the Australian technique of bolting and meshing with jumbos equipped with twin telescopic booms, in-cycle shotcreting, and the use of two jumbos and two scissor bolters set up side by side in wide headings. Recommendations and lessons learned are presented with the aim of providing realistic expectations with regard to development advance rates in a mining environment.RÉSUMÉ J. S. Redpath Limitée, un entrepreneur minier souterrain d’envergure mondiale, a complété plusieurs projets au Canada où des techniques novatrices ont été mises en oeuvre pour raccourcir le cycle de développement. Cet article présente une comparaison entre les méthodes conventionnelles fréquemment utilisées pour le support de terrain, la technique australienne de boulonnage et d’installation de grillage au moyen de jumbos équipés de flèches télescopiques doubles, du béton projeté appliqué durant le cycle de développement et de l’utilisation de deux jumbos et deux boulonneuses côtes-à-côtes dans des galeries de grandes dimensions. Les recommandations et les leçons apprises sont présentées dans le but de fournir au lecteur des attentes réalistes quant aux taux d’avancement du développement dans un environnement minier."

Jan 1, 2016

By C. A. Young, H-H. Huang, L. G. Twidwell

Equilibrium calculational software programs can be effectively utilized to model important parameters in aqueous and aqueous/solid systems, e.g., activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation. In this regard, the calculational program ST ABCAL will be demonstrated. Illustrative examples for the creation of diagrams such as potential-pH, and activity or concentration-pH will be presented to demonstrate the fundamentals in real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Berkeley Pit water from a flooded abandoned copper open-pit mine will be used to illustrate the modeling process. According to analytical results the water contains about 20 important constituents. In addition to measured potential and dissolved oxygen, there are two distinctive oxidation/reduction couples. Concentration and other experimental parameters are seldom matched to each other and 12 different conditions have been identified. Water for each condition must be speciated in order to find the best-fit model. The STABCAL program will be used for the modeling calculations and the implication of the water chemistry to defining treatment opportunities will be discussed.

Jan 1, 2005

By P. E. Weidmark

"PART I - Published PapersBallivy, G., and Dupuis, M., ""Laboratory testing for the design of grouted rock anchors""; Proc 6th Pan Am Conf Soil Mech Found Eng; Lima; 1:277-291; 1979.Ballivy, G., Ladanyi, B., and Gill, D., ""The effects of moisture content on the strength of fissured rocks""; Proc 1// 1ntnl Congr 1.A.E.G.; Madrid; //:2:7-16; 1978.Baumgartner, P., and Stimpson, B., ""Development of a tiltable base friction frame for kinematic studies of caving at various depths""; Int J Rock Mech Min Sci Geomech Abstr; 16:4:265-267; 1979.Bawden, W.F., and Roegiers, J.-c., ""Discussion and interpretation of the mathematics governing radial flow in a single horizontal rock fracture""; ISBN 07727-7002-6; Dept Civil Engng publication 79-11; Univ Toronto: 134p;1979.Chatterji, P.K., Smith, L.B., and Insley, A.E., ""Construction of Saline Creek Tunnel in Athabasca oil sand""; Can Geotech J; 16:1:90-107: 1979.Coates, D.F., and Gyenge, M., ""A case history of pit slope design""; Proc 4th ISRM Congr; Montreux, Switzerland; Sept 1979; 1:Theme IV:591-596; 1979.Crawford, A.M., and Curran, J.H., ""A dynamic direct shear machine for determining the time-dependent behaviour of rock joints"": Dept Civil Engng publication 79-08; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A displacement discontinuity approach to modelling the creep behavior of rock and its discontinuities""; Dept Civil Engng publication 79-09; Univ Toronto; 1979.Crawford, A.M., and Curran, J.H., ""A higher-order displacement discontinuity element""; Dept Civil Engng publication 79-10; Univ Toronto; 1979.Cruden, D.M., ""A computer-based system for rock mass description""; Proc 1// Intnl Congr I.A.E.G.; Madrid; //:2:155-159; 1978.Cruikshank, D.J., and Curran, J.H., ""A.B.LE. approach to modelling of fluid flow in fractured rock masses""; Proc 7th Cdn Congr Appl Mech; May 1979; Sherbrooke, Que; 887-888; 1979."

Jan 1, 1980

By J. Gustavsson, S. Holmin, Å. Afvander, E. Rosseland, E. Zimmerman

There are numerous advantages in replacing lead-based anodes with mixed metal oxide (MMO) coated anodes in copper electrowinning; for example, lower energy consumption, improved working conditions for operators and less environmental impact. Since 2012, Permascand AB in Ljungaverk, Sweden has evaluated Permascand coated titanium anodes in copper electrowinning pilot trials at Glencore Nikkelverk in Kristiansand, Norway. The investigation has proceeded in three different steps (Phase I, II and III). In Phase I, different Permascand coatings, electrode structures and coating methods were investigated. The results showed that improved current distribution, lower energy consumption and longer service life could be obtained with expanded mesh electrode structure in a box configuration compared to rod anodes in a single-mode construction. In addition, improved current distribution and less coating wear was found when electrostatic spray coating was used instead of brush (manual) coating. It was also found that the extrapolated service life from controlled lab experiments at 200 A/m2 was much shorter compared to what was experimentally obtained in copper electrowinning pilot trials at similar current densities. This was mainly attributed to different coating failure mechanisms in lab and industrial copper production. INTRODUCTION Traditionally lead-based anodes have been used in copper in electrowinning due to lower cost. But there are many advantages in replacing lead-based anodes with mixed metal oxide (MMO) coated titanium anodes in copper electrowinning, such as lower energy consumption, higher corrosion resistance, improved working conditions for operators and less environmental impact. Still, many facilities are using lead-based anodes, although the progression of using metal oxide coated anodes in copper electrowinning has slightly increased (Robinson et al., 2012).

Jan 1, 2019

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006