Search Documents

By D. C. R. Espinosa, P. Aliprandini, F. P. C. Silvas, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel ores are divided into two types: sulfide deposits and lateritic deposits. About 60% of nickel resources are found in laterite ore, while the remaining 40% is contained in sulfide ore. Laterite ore is usually processed via pyrometallurgical means or through hydrometallurgical techniques that include acid leaching and metal value recovery from solution. In this study, copper and nickel adsorption by Dowex M4195 ion exchange resin from an acidic sulfate liquor was investigated. The acidic sulfate liquor was collected from an atmospheric leaching process (AL) of laterite ore. Ion exchange experiments were conducted in a batch system by varying parameters such as pH, time, metal concentration and temperature. Initially, mono-elemental synthetic solutions of nickel and copper were used in the experiments and then a synthetic solution simulating AL liquor was tested. Test results showed that the resin exhibited high selectivity towards copper and nickel, however, a high concentration of iron in the synthetic AL solution interfered with the recovery of nickel and cobalt by the resin.INTRODUCTION Nickel is one of the most important industrial metals in the world. It is widely used in industrial applications, such as the production of stainless steel, magnets, electroplating and special alloys (Dizge et al., 2009). The main sources of industrial nickel production are sulphide deposits; only 40% of industrial production uses lateritic ores. However, it is estimated that 60% of global nickel resources are found in nickel laterite deposits (Kuck, 2016). Since industrial nickel demand continues to grow, the development of new technologies for the extraction of nickel from laterite ores has become an interesting research topic (Agatzini-Leonardou, 2009)."

Jan 1, 2017

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014

By R. W. Luhning, S. D. Gittins, J .. A. Haston

"The Underground Test Facility (UTF) project operated by the Alberta Oil Sands Technology and Research Authority (AOSTRA) north of Fort McMurray has achieved marked success in field testing mining access and horizontal well in situ recovery of bitumen from the Athabasca oil sands.Mine access has provided for effective placing and operation of horizontal wells in the oil sands from a tunnel system in the underlying limestone. Performance of the in situ recovery process, Steam Assisted Gravity Drainage, has substantially exceeded forecasts made at the start of the project. Over-all results of the program to date show great promise for horizontal well in situ technology as a competitive source of bitumen from Alberta's vast oil sands deposits. The potential economics of a commercial expansion at the site are reviewed in this paper.IntroductionIn situ recovery o f bitumen from the Athabasca oil sands has puzzled the oil industry for many year s, but a breakthrough appears close at hand. The Underground Test Facility (UTF) project initiated by the Alberta Oil Sands Technology and Research Authority (AOSTRA) has had notable success in the piloting of horizontal well processes, which offer prospects for commercial development even under the highly competitive situation facing the Canadian industry . This paper describes the project briefly and presents the potential economics of commercial development on the UTF lease."

Jan 1, 1990

By C. O. Aksoy, H. Kose, K. Ozfirat, T. Malli, A. Gonen, S. Gurgen

In selecting mobile mining equipment, factors including availability, useful economic life, maintenance and operating costs, and spare parts availability are considered. Given these factors, trucks and shovels with different capacities are selected. Optimizing equipment for pit and hillside quarry cases, where 8% and 10% ramps are commonly in use, were examined; the effect of other mining activities such as drilling and blasting on unit cost were considered. In principle, 20 m to 25 m high benches should be economical for downhill haulage, and 7 m to 10 m low benches economical for uphill haulage. However, practice of both mining styles favours 10 m to 15 m bench heights. Hence, the analysis here was carried out with the field experience bench height range. In the study, a truck-shovel optimization was based on the movement of 5 to 20 million cubic metres (in 2.5 million cubic metre increments) of overburden stripping at the Eynez open pit mine in the Soma region of Turkey. The outcome showed that low-capacity shovels were unfavourable due to high production expectations. High-capacity shovels were also unfavourable due to health and safety issues causing high instances of impact vibration on trucks during the loading cycle and a decrease in foreseeable unit lifetimes. The number of shovel passes required to load a truck ranged from three to six. Trucks with high-capacity bodies were deemed uneconomical due to high investment and operating costs.

Jan 1, 2005

By Richard W. Hutchinson, Christopher Osterman

The Selebi-Phikwe deposits are hosted by amphibolite to granulite facies gneisses of the Limpopo belt. The sulfide orebodies are generally stratiform and conformable to the foliation of the wallrock gneiss. Sulfide remobilization has occurred during metamorphism and has produced discordant sulfide veins, called piercement structures, which project into the hanging wall and footwall gneisses. These piercement structures are compositionally similar to the stratiform sulfides, consisting mainly of pyrrhotite, pentlandite and chalcopyrite. However, texturally the piercement sulfides are coarse grained and inclusion-free, whereas the stratiform sulfides are fIne grained and packed with tectonically produced wallrock inclusions. The piercement structure sulfides and adjacent stratabound sulfides were sampled and analyzed for major base metals and PGE's for comparative purposes. Most of the piercement structures were enriched in Cu, Ag and Au, whereas they were generally depleted in Ni, Co, Fe and PGE's. Changing elemental associations were observed from the stratabound sulfides and along the length of the piercement structures. This and the degree of depletion or enrichment of various major and minor elements in the sulfide piercement structures may reflect the relative mobilities of metals under metamorphic conditions. The similarities between sulfIde piercement structures and the footwall Cu-PGE veins in some Sudbury deposits are reviewed.

Jan 1, 1994

By N. F. Faria, F. Monteiro, B. O. Taiwo, A. Palangio, D. Fonseca, J. Manuel

This paper explores the interpretation and application of Particle Size Distribution (PSD) curves in optimizing blast design and enhancing downstream operations. The study looks at important factors like D50, D80, fines content, and the uniformity index to show how PSD curves affect the efficiency of different mining processes. The first section of this paper discusses the impact of blast design parameters such as burden, spacing, and explosive energy on the resulting PSD, highlighting their significance for downstream operations like crushing, and material handling. The section concluded that proper alignment of PSD with downstream size classes, like primary crusher inlet sizes, among others, can result in substantial cost reductions and productivity gains. The second part presents a case study from dstgroup aggregate quarry in northern Portugal, utilizing fragmentation analysis to evaluate blast performance and promote continuous improvement. The section specifically examines the effect of stemming material size on blast fragmentation, comparing the impact of using aggregate with a D80 of 12.32 mm versus a D80 of 21.94 mm. The D80 value represents the particle size at which 80% of the stemming material is smaller, making it a critical parameter in evaluating the stemming's effectiveness in confining explosive energy. The drilling and blasting designs were meticulously planned using O-PitDev and O-PitSurface software to ensure accuracy in blast parameters and layout. To assess the fragmentation resulting from these different stemming material sizes, the study utilized WipFrag 4 software. The software allowed for precise measurement of particle size distribution after the blast, as well as a detailed comparison between the two stemming sizes. Results from the analysis indicate that using bigger-sized stemming material led to improved blast confinement, which in turn resulted in better fragmentation compared to the smaller-sized material. The reviewed blast videos demonstrate that the larger aggregate effectively contained the explosive energy within the borehole, thereby reducing premature venting and directing more energy towards breaking the surrounding rock mass. This led to finer fragmentation with D80 = 1240.1 mm, D50 = 685.9, and Dmax = 2580 mm, which is advantageous in downstream operations like crushing and milling. On the other hand, the smaller stemming material (D80 = 21.94 mm) did not confine the explosive energy as efficiently, resulting in coarser fragmentation (D80 = 1327.37 mm, D50 = 750.76, and Dmax = 2370 mm) and reduced overall blast efficiency. These findings highlight the significant influence of stemming material size on blast performance and fragmentation outcomes. 

May 4, 2025

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By G. M. Ross, I. M. Ross, J. A. Scott

"The otherwise waste heat in many water streams in the mining industry can be used to provide space heating of adjacent infrastructure including laboratories, workshops, and offices. This can be achieved by using heat pump systems, which can work as a replacement or in conjunction with existing space heating. In the example investigated—process cooling streams at an ore smelter—the analysis provided illustrates that annual heating costs can be 19% lower and a simultaneous 62% reduction in CO2 emissions can be achieved.RÉSUMÉ Dans l’industrie minière, la chaleur qui serait normalement perdue des circuits d’eau pourrait servir à chauffer des structures adjacentes incluant les laboratoires, les ateliers et les bureaux. Cela pourrait se faire en utilisant des systèmes de thermopompes, qui pourraient remplacer ou s’ajouter au chauffage existant. Dans l’exemple étudié, des circuits de refroidissement de procédé à une fonderie, l’analyse fournie illustre qu’il est possible de réduire les coûts annuels de chauffage de 19 % et d’obtenir une réduction simultanée de 62 % des émissions de CO2."

Jan 1, 2016

By J-F. Magnan, M-A. Thibault, R. Boulianne, C. Gauthier, J-P. Gagné, G. Dufour

During the production of aluminium in smelters, the anodes used in electrolysis cells have to be replaced frequently. Anode butts are usually placed on anode trays for transportation and cooling, a practice during which Hydrogen Fluoride (HF) is emitted in large quantities. Covers developed in 2000 by Alcoa Deschambault to fit on the anodes trays were implemented, resulting in significant reductions of HF emissions. However, the covers are expensive to maintain and use short-life consumable parts. In January 2004, STAS and Alcoa decided to develop a more efficient design of cover, with lower maintenance costs and no need for consumable materials (like soft cushions). This paper presents a summary of the work performed to develop the new design as well as a summary of the test results.

Jan 1, 2006

By R. I. Iacobescu, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, P. Knops

In this work, we explore a novel mineral processing approach using carbon dioxide to promote mineral alterations that lead to improved extractability of nickel from olivine ((Mg,Fe)2SiO4). The precept is that by altering the morphology and the mineralogy of the ore via mineral carbonation, the comminution requirements and the acid consumption during hydrometallurgical processing can be reduced. Furthermore, carbonation pre-treatment can lead to mineral liberation and concentration of metals in physically separable phases. In a first processing step, olivine is fully carbonated at high CO2 partial pressures (35 bar) and optimal temperature (200 °C) with the addition of pH buffering agents. This leads to a powdery product containing high carbonate content. The main products of the carbonation reaction include amorphous colloidal silica, chromium-rich metallic particles, and iron-substituted magnesite ((Mg1- x,Fex)CO3). Carbonated olivine was subsequently leached using an array of inorganic and organic acids to test their leaching efficiency. Compared to leaching from untreated olivine, the percentage of nickel extracted from carbonated olivine by acid leaching was significantly increased. It is anticipated that the mineral carbonation pre-treatment approach may also be applicable to other ultrabasic and lateritic ores.

Jan 1, 2014

By Pierre C. Vieillescazes

MIGA: Unique Multilateral Risk Mitigator ?A World Bank Group agency established in 1988 to promote and facilitate sustainable foreign direct investment in emerging coufacilitate countries ntries (north(north--south and southsouth south--south) ?Guarantees equity and debt and many other types of investments against non-commercial risk. ?Can cover the following type of risks: ?Expropriation ?Breach of Contract ?Currency Transfer and Inconvertibility ?War and Civil Disturbance ?Non-Honoring of Sovereign Financial Obligations

May 1, 2010

By L. Avramovic, B. Han, R. Jonovic, Z. Stevanovic, K. Haga, S. Dimitrijevic, A. Shibayama, L. Godirilwe, Y. Takasaki

Pyrite (FeS2) and chalcopyrite (CuFeS2) which could not be recovered, are present in mine tailings discharged from Bor copper mine. About 0.3% of copper (Cu) is contained in these tailings, therefore it can be considered as a useful copper resource. At the same time, pyrite is known to promote acid mine drainage, therefore it is necessary to detoxify the tailings. An efficient method has been proposed to recover copper and reduce the environmental impacts of tailings by a combined hydrometallurgical process of high pressure leaching (HPL), solvent extraction (SX) and electrowinning (EW) process. HPL process yielded high copper leaching rate (>95%) when water (H2O) was used as a leaching media. On the other hand, pyrite contained in the tailings was converted to iron oxide by high pressure leaching. Stability evaluation of the residue obtained from high pressure leaching, confirmed almost no elution of metal ions. The percentage of copper extracted and stripped from the Cu-loaded organic phase reached 97.4%. Moreover, it was confirmed that a low iron concentration in the electrolyte of copper electrowinning, resulted in the improvement of current efficiency of copper electrodeposition. INTRODUCTION Mine tailings are a by-product obtained from the flotation process and there are billions of tons of already existing tailings all over the world. Moreover, several billion tons of additional copper tailings will inevitably be produced in the coming years (Onuaguluchi & Eren, 2012). With the declining average copper ore grade, alternative sources of copper are highly sought, mine tailings have a comparable copper grade to that of low-grade ores (0.2–0.3%) therefore, it can be said that copper mine tailings present a very important source of secondary raw material for copper production (Antonijevi´c et. al., 2008). Consequently, it is necessary to confirm the possibility of the valuable metals (such as copper) recovery from mine tailing in which copper content is about 0.2–0.3%. Our group investigates the flotation and high pressure leaching processes for recovering of copper from mine tailings. Previous work on related samples include copper and nickel flotation tailings from Botswana, and a low–grade copper ore sample from Chile. Impurities, which are associated metals in mine tailing such as iron (Fe) and aluminum (Al) co-dissolve into the solution during the HPL treatment process. Therefore, separation of copper from impurities is necessary for selective extraction of copper from mine tailings and upgrading the copper concentration in the leachate to enable further purifying of Cu by electrowinning. Thus, it is important to investigate the possibility of applying solvent extraction for concentration of copper from leachate solutions of mine tailings (Onuaguluchi & Eren, 2012; Antonijevi´c et. al., 2008). In this study, LIX-84I was used as an extractant of copper from the leachate of high pressure leaching of mine tailing. As a fundamental solvent extraction investigation, the extraction behavior of copper was studied using a simulated solution of the leachate from the high-pressure oxidative leaching of mine tailing. The effects of; solution pH, extraction time, extractant concentration and phase ratio on copper extraction and sulfuric acid (H2SO4) concentration on stripping were investigated.

Jan 1, 2019

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

In addition to the harsh environment, materials for high-temperature applications are often subjected to a significant mechanical loading. Several researchers have noted that the rate of oxidation can be affected by stress in a range of materials. We have recently studied this effect in y-TiAl, based on the preliminary work of Magnan and Weatherly which showed that nitridation rates on the tensile side of a flexural creep specimen could be 10 times higher than on the compressive side. We have since developed a four-point bending creep setup capable of controlled atmosphere testing. We present quantitative data on the effect of creep on scale growth under a range of atmospheric conditions. Finite element analysis will also be used to show how modest applied stresses can have a large effect on scale growth rates through the generation of large stresses due to the mismatch of creep rate between the metallic substrate and the scale.

Jan 1, 2004

By J. Fujioka, Y. F. Gu, C. Cui, D. Ping, A. Sato, H. Harada

"A new kind of cast & wrought (C&W) Ni-Co base superalloys named as ""TMW alloys"" are developed recently for compressor or turbine disks of gas turbine engines in High Temperature Materials 21 Project at National Institute for Materials Science (NIMS) in Japan. These Ni-Co base superalloys combine the characters of two kinds of y- y' two-phase alloys (Ni-base and Co-18at%Ti alloys) and have higher tensile strength and creep resistance than C&W UNDIMET 720Li superalloy."

Jan 1, 2006

By M. B. McClenaghan

"The Ontario Geological Survey completed a regional till sampling project between 1984 and 1988 in the Black River Matheson (BRiM) area of northeastern Ontario. The project was designed to aid mineral exploration in the area by documenting the Quaternary stratigraphy and by providing a database of till geochemistry. This paper summarizes the results from the sonic overburden drilling component of the BRiM project carried out in areas of thick drift (> 5 m). Results from till sampling in areas of thinner drift (<5 m) have been presented in a separate paper. Approximately 1100 till samples were collected from 225 sonic drill holes. For each sample, the non-magnetic heavy mineral (>3.3 S.G.) and fine (-250 mesh) till fractions were analyzed geochemically and visible gold grains were recovered by panning.Gold and other multielement geochemical data were plotted using proportional symbols to highlight anomalous areas and to demonstrate how to evaluate and interpret a very large geochemical dataset. Thresholds for identifying anomalous concentrations of Au in till samples, defined using the 95th percentile, are 1500 ppb and 12 ppb for the heavy mineral and fine fractions, respectively. The heavy mineral fraction of older ti1ls and to a lesser extent, Matheson Till, display a number of significant gold anomalies in the study area, which in a few cases, are associated with base metal anomalies. The vertical position of gold anomalies in Matheson and older ti1ls varies from directly on bedrock to several meters above the bedrock surface and can provide information of relative ice transport distances."

Jan 1, 1994

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004

By G. A. Maki, P. J. Fullman, R. G. Roden

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing down the pile. With the new stacking system, slurried tailings are fed to mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. This paper deals with the various aspects of the project from conception to its present state.IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65010 solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dykes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1990

By M. Bryson, S. Broom-Fendley, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho, S. Al-Ali, F. Wall

The Songwe Hill Rare Earth Element (REE) Project in Malawi is a near surface carbonatite-hosted deposit with synchysite and apatite as the key REE bearing minerals. A strong focus has been placed on understanding the REE mineralogy of the Songwe Hill carbonatite as REE mineralogical characterization is a crucial component at all steps, ranging from exploration to production, in the development of REE deposits. Extensive mineralogical work has been completed at Camborne School of Mines (CSM), Natural History Museum (NHM) London, British Geological Survey (BGS), Nottingham, Aberystwyth University, Wales, Mintek, South Africa, and SGS Inc. Canada (SGS). The following analytical techniques were used: scanning electron microscopy (SEM), electron microprobe analysis (EMPA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and QEMSCAN®. The detailed studies have demonstrated that while synchysite is light-REE enriched as expected, apatite, abundant in all stages of carbonatite emplacement at Songwe, is anomalously enriched in mid- to heavy-REE relative to apatite in other carbonatite deposits. The distribution of REE within synchysite and apatite at Songwe has had important implications for the direction of the metallurgical work with respect to the behaviour of light and heavy REE through the flotation and hydrometallurgical stages of the flow sheet.

Jan 1, 2014

By P. D. Soares, H. R. Bullis, R. A. Hureau

"Echo Bay&apos;s Lupin Operation has produced more than 2.15 million ounces of gold since start-up in 1982. The mining method used to the£ present time has been longhole open stoping using trackless equipment. Because direct measurement of the open stopes has not been possible until recently determining the exact quantity of unplanned dilution in previously mined stopes has not been possible. Estimates of dilution hove been mode using comparisons between production tons and grades against ore reserve tons and grades.This paper discusses tracking of grade and tonnage measurements from reserve estimation through production. Comparisons between estimated and actual tons and grade are presented~ along with a brief description of methods used at the Lupin operation to control dilution."

Jan 1, 1994

By Bian Xue, Wu Wenyuan

In order to recycle the iron and rare earth from the Baotou tailings, a roasting method was developed involving the addition of C, Ca(OH)2, and NaOH, designed to both decompose the rare earth minerals and convert haematite into magnetite and allow its recovery. The effect of various parameters such as roasting temperature, roasting time, C addition, Ca(OH)2 addition, and NaOH addition on the reduction ratio of haematite (iron sesquioxide) and decomposition ratio of rare earth were investigated. The results showed that the reduction ratio of haematite and the decomposition ratio of rare earth could be as high as 85% and 95% respectively when the roasting temperature was 650°C, roasting time was 60 min, Ca(OH)2 addition was 4%, NaOH addition was 3%, and C addition was 1.5%.

Jan 1, 2014