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By Jochen Petersen, Alison Lewis, Cledwyn Mangunda

Run-off and waste water streams high in dissolved metal content are generated in all mining operations. The metals pose a threat to life due to their persistent bio-accumulative toxic (PBT) characteristics. Hence, there is a need to treat mine waste water effectively. Lime precipitation is the technology of choice through which Fe, as the major metal species, is removed as Fe (III) oxyhydroxides with other metals co-precipitated and/or adsorbed. Sulphates are removed as gypsum or incorporated into the Fe phases. The resulting sludge has poor dewatering characteristics and is deposited in landfills, with an inherent risk of returning the Fe back into the water cycle through leaching. This study seeks to understand the mechanisms behind the formation of this sludge in terms of product quality. The relationship between process conditions and product characteristics has been investigated through exploring the effect of Fe (III) concentration on the precipitate product characteristics (particle size distribution (PSD), size, morphology and structure) and quality (in terms of filterability, settling ability, etc.) in a simplified system. Neutralisation of acidic synthetic aqueous Fe (III) sulphate streams containing 50, 400 and 800 mg/L Fe(III), respectively, was effected by mixing it in a continuous stirred tank reactor (CSTR) with dissolved calcium hydroxide for pH control at a residence time of 15 minutes. Precipitate samples analysed for morphology and PSD, using nanoSEM and Zetasizer respectively, showed a general decrease in PSD and zeta potential with increases in feed Fe (III) concentration. These results were used to infer the particle size enlargement mechanisms of Fe (III) oxyhydroxide precipitates under a given set of operating conditions. Preliminary product quality results indicate that a high concentration (800 mg/L) leads to the rapid formation of metastable precursors with poor product quality, whilst a low concentration (50 mg/L) leads to formation of thermodynamically more stable precipitates with good product quality. The approach demonstrates a potential route forward in terms of linking operating conditions to the attainment of desirable characteristics rather than specific precipitate phases which are difficult to identify.

Jan 1, 2016

By B. K. Mishra, P. Patnaik, B. C. Tripathy, I. N. Bhattacharya

Cobalt is an essential metal considering its numerous industrial applications. The demand for the metal is increasing due to its wide range of use in, for example, rechargeable batteries and as an alloying element in super alloys. Cost effective production of Co is critical. Electrowinning from aqueous sulphate solutions is the preferred technology available for the production of Co. Attempts are being made to produce uniform, smooth and bright deposits of cobalt metal. Use of organic additives in the electrolytic bath improves current efficiency and deposit morphology of the metal. We investigated the effect of quaternary amines TEABr, TPABr and TBABr during cobalt electrowinning from aqueous sulphate solutions. Among the additives studied, TEABr yielded the best results. Smooth and bright deposits of cobalt were obtained at low concentration of TEABr (10 mg/L) maintaining a very high current efficiency of 99.6%. X-ray crystallography indicated that (100) is the most preferred plane of crystal growth.

Jan 1, 2014

In the leaching and recovery of gold from copper containing gold ores using cyanidation, some copper minerals also dissolve which can have a detrimental effect on the process efficiency and economics. There are also environmental concerns with current operations discharging cyanide and copper cyanide species into tailings dams, and strict regulations prohibit this for greenfield plants. Cyanide destruction however is not an economic option for new plants treating copper-gold ores. This paper evaluates a potential recovery process to overcome the copper cyanide problem. Despite gold dissolution occurring in copper cyanide solutions having no free cyanide, gold recovery from ores is lower compared to free cyanide. Thus, cyanide addition has to be optimised to maximise the gold recovery whilst endeavouring to eliminate free cyanide at the completion of leaching (CN:Cu less than 3:1). Subsequently, copper cyanide can be recovered using activated carbon. The loaded copper cyanide is easily recovered from the carbon with a cyanide soak and distilled water wash such that the eluted CN :Cu ratio is less than 4:1. The copper could be recovered efficiently by electrowinning, by decreasing the pH of the eluant to 5. The remaining cyanide solution, after electrowinning, is then neutralised to form NaCN and recycled.

Jan 1, 2005

The PEMAC Commitment to World Class Industry in Canada The Plant Engineering and Maintenance Association of Canada PEMAC is a national, not-for-profit industry and technical association for plant and facility maintenance, engineering and physical asset management practitioners and professionals. Founded mid 80?s in the last century PEMAC is a knowledge based organization that focuses on sharing knowledge with our members and the profession. We provide education and professional development programs and certification for maintenance practitioners and professionals. We develop, produce and participate in conferences, seminars and trade shows.

May 1, 2008

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By H. E. Johnston

There are currently a number of options in terms of plant feed comminution tests: Bond work index tests, JK drop weight and SMC tests, SPI, low impact crusher work index tests, to name a few. However, information regarding specific energy requirements for regrind mills is often requested, which can be difficult or very expensive when only a small mass of concentrate is produced from bench-scale flotation tests. This research was aimed at developing a test methodology that would produce a similar result as an IsaMill Signature Plot but require less sample mass allowing for preliminary estimates of regrinding power at a lower cost. Initially, the laboratory test methodology was completed on a single sample in comparison to the IsaMill Signature Plot for that sample. Results indicated a very good correlation between the laboratory tests and the IsaMill Signature Plot for this sample, though some parameters did impact laboratory regrind mill efficiency. The developed methodology is subsequently being applied to a range of concentrates, investigating a range of material particle sizes and material types, in comparison to a full IsaMill Signature Plot on the same sample. This new test procedure has been called ‘The Eliason Test’.

Jan 1, 2014

There are many inherent risks in creating a mine plan for a new ore zone in an underground mine; one of such risks is the redistribution of stresses that could be a cause of instability. Using numerical modelling tools, it is possible to model the planned stope extraction sequence and evaluate the influence of mining induced stresses on the stability of remnant pillars, and use this information to remedy potential setbacks. This paper demonstrates this approach through a case study of the short-term mine plan of the Lapa mine of Agnico Eagle Mines Ltd., an underground gold mining operation near Val d?Or. Three-dimensional boundary element modelling is used to compute the stresses induced by the stope extraction sequence as planned with a longitudinal retreat mining method. The proposed methodology can be generalized to other mines that require an understanding of the stress concentrations at the pre-feasibility stage of mine design.

May 1, 2009

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

"“Developed by the CIM Sub-Committee, these guidelines are an addition to Guidelines Specific to Particular Commodities which are appended to the CIM Estimation of Mineral Resources and Mineral Reserves Best Practice Guidelines.Rock Hosted DiamondsJennifer Burgess, Consultant, Sechelt, BCNeil Buxton, WWW International Diamond Consultants Ltd.Darren Dyck, BHP Billiton Diamonds Inc., Kelowna, BCMartinus Oosterveld, (De Beers retired), Plettenberg Bay, South AfricaRichard Routledge, Scott Wilson Roscoe Postle Associates Inc., Toronto, ONMalcom Thurston, De Beers Canada, Toronto, ONPreambleDiamonds are produced commercially from intrusive rock, consisting of kimberlite and lamproite, and from alluvial and marine placer deposits. These guidelines apply to rock deposits; the term ""diamonds"" herein refers to natural diamonds; ""diamond deposits"" refers to diamonds hosted in kimberlite and lamproite rocks; and ""diamonds"" and ""stones"" are interchangeable.The CIM Best Practices General Guidelines for other commodities are also applicable to diamond deposits, however, because of diamond's distinguishing aspects, additional guidelines are appropriate as published in the CIM Guidelines for the Reporting of Diamond Exploration Results and these Best Practice Guidelines for estimating Mineral Resources and Mineral Reserves (MRMR).Diamonds differ from other minerals. Firstly, they occur as discrete particles in concentrations as low as parts per billion. Secondly, the release of diamonds from the kimberlite or lamproite host rock is a function of the excavation and treatment process. Thirdly, the value of diamonds varies from deposit to deposit and varies with stone size within a given deposit. These aspects must be considered when sampling, evaluating the resource and establishing the reserve of a depositThe product from metallic mineral mines is generally quite liquid in terms of number of potential buyers, and the commodity prices and price structure are published daily. In contrast, most diamonds are valued in the overall market context only 10 times a year in ""sights"" and the marketing of diamonds is dominated by a small number of organizations. Diamond valuation is more akin to industrial minerals valuation in that process recovery is important at the ""assay stage"", the impact on price of new goods arriving on the market must be evaluated, and product quality must be acceptable to potential buyers."

Jan 1, 2003

By D. C. Martin, P. M. Hawley, C. P. Acott

"In bedded deposits such as coal or sedimentary iron, economic limits of mineable reserves are clearly defined by the footwall of the seams or ore-bearing units. Where open pits are developed in dipping strata, a long, high footwall slope may result. In many cases, unbenched slopes excavated along the base of the lowest mineable seam are operationally simple, economically desirable and geotechnicalty practical, although a variety of failure mechanisms may develop. This paper examines the engineering geology and rock mechanics parameters of importance in the design of footwall slopes. Possible failure mechanisms and stability analysis methods are described. Design considerations for benched and unbenched slopes are discussed with prime consideration given to development of long high stopes without benches or with a minimum number of benches. IntroductionIn bedded deposits, the ultimate depth and economic viability of an open pit in dipping strata may be controlled by the design of the footwall slope. The stability and, hence, design of footwall slopes is strongly influenced by the engineering geology and rock mechanics parameters of the slope forming materials. A clear understanding of the structural geology, engineering geology and tectonic history of the deposit is essential to assess the behaviour of the slope. This is particularly important for long high, unbenched footwall slopes such as shown in Photo I.A rational footwall slope design requires identification and assessment of all possible slope failure mechanisms with respect to the proposed slope geometry. Stability analyses of each potential failure mechanism are used to identify the main controls on slope stability and to develop appropriate slope design criteria. The optimum slope design is based on the most economic and geotechnically practical slope geometry with due consideration of operational constraints and of the possible advantages of specific remedial measures."

Jan 1, 1986

By D. H. Wilson

"This paper examines the increasing need for mechanical-electrical people within the industry and some of the reasons why such a shortfall exists. It is suggested that, in part, it is image related. The present industry-education relationship in addressing the situation is examined and some thoughts are expressed on how these may be built on, in order to help solve the problem of attracting people to this critical area.IntroductionAs a long-time proponent of plant engineering and maintenance as a management function, I would like to review the progress made by the industry/ educational approaches in satisfying the needs in that area. In doing so, I would like to make the following points:1) that there has been an accelerating shortfall of mechanical-electrical people relative to the needs of the industry;2) that the condition will probably get worse before it gets better; ,3) that the past industry I educational approaches to alleviate the problem have met with limited success; and finally4) I would like to review some of the things being done and consider how these efforts might be extended."

Jan 1, 1981

By C. Boudreault, M. Fortier, S. Fafard

In the forging industry, the increasing trend is to use DC cast billets as forging stock to replace extruded stock. However, there is little technical information available in open literature. In order to gain a better understanding of the behaviour of cast stock during deformation, a study was initiated to evaluate the impact of an homogenisation treatment on the billet prior to cold forging. Axisymmetric upsettings of cylindrical samples machined from DC billets were achieved in order to evaluate and compare flow stresses, crack initiation and propagation. Results show a 30% decrease in flow stress after homogenisation. Observations of the deformed samples show major cracking for the as-cast material. Optical microscopy and SEM observations have related the crack initiation to decohesion around ß -AlFeSi particles and subsequent growth along the constituent path. Homogenisation effectively breaks up and transforms the ß phase, present as platelets in the cast product, into smaller spherodised a-AlFeSi particles. This has the effect of preventing crack growth in the forged product. The homogenisation treatment also resulted in the reduction of Mg and Si in solid solution. The softer matrix generated 29% less die wear when compared to the as-cast structure. Based on the results of this study, it is thus recommended to homogenise cast billets prior to cold forging.

Jan 1, 2006

By Guy Chevalier

QCM?s pellet plant, located in Port-Cartier, Quebec, produces up to 8.6 million tons of iron ore pellets annually. Four different types are produced: three for blast furnace operations and one for direct reduction furnaces. The paper presents the scientific approach that led to the installation of new process equipment to improve the reducibility of direct reduction pellets (DR pellet). The findings, the equipment selection and some post start-up modifications are presented. This low silica DR pellet is used in Midrex and HyL shaft furnaces. A good DR pellet has to meet strict chemical, physical and metallurgical specifications. An important metallurgical property is its ability to release oxygen when exposed to reducing gases. Considering that the market for DR pellets is expanding and being aware that reducibility is critical for our clients, a program to improve the latter was undertaken. Test work showed that one factor which has a negative effect on reducibility is the proportion of particles larger than 75 microns. Knowing that the best way to reduce the amount of coarse particles was to close our open grinding circuits, we began evaluating the most suitable classification equipment applicable to our process operations. We settled on hydro-classifiers based on their very sharp cut and their low operating costs. In light of the hydro-classifiers performance it was also decided to replace the hydro-cyclones of an already closed circuit.

May 1, 2003

By Lawrence B. Cochrane, Olivier Tavchandjian, J. Michael Anderson, Christopher R. Davis

"Abstract - Resource modelling is a complex process involving different specialists with relevant experience using a multi-disciplinary approach and the best available technology and reviews by independent auditors. The reliability of the final resource estimate is highly dependent on the quality control exercised at each stage of the process. At each step in the resource modelling process it is necessary to define the specific objectives, the methodology proposed to achieve those objectives and to establish a set of checks and validation tools to assess the effectiveness of the proposed methodology. Designation of responsibility and authority for meeting these objectives must also be clearly identified. External audits must also be incorporated to review and validate the implementation of new procedures.Resource modelling is the basis for any economic appraisal of a mining project and includes a number of steps from data acquisition and validation to resource reporting, classification, and risk analysis."

Jan 1, 2001

During heap leaching of secondary copper sulphide ores operated at low heap temperatures and high levels of leach solution salinity, copper recovery is usually unsatisfactory, due to a slow chemical and bacteriological leaching of the covellite minerals either formed from leaching of chalcocite or naturally occurring in ores. A laboratory test program was conducted to investigate the effect of leach solution temperature in the range of 20 to 50°C on copper extraction during stirred reactor, bottle roll, and short column leaching of fresh or heap leached secondary copper sulphide ores. It was demonstrated that increasing heap temperature is an effective approach for improving recovery of copper from secondary copper sulphide ores. A review of the technologies available for heating heap leach solution or decreasing solution salinity to improve copper recovery from secondary sulphide ore indicates that an integration of copper concentrate pressure leaching with heap leaching is potentially a cost-effective approach. A copper flotation concentrate sample was tested through pressure oxidation with the use of heap leach solutions of varying strengths for the repulping of the concentrate in order to examine its effect on pressure oxidation performance. The test results indicate that use of heap leach solution of high salinity in the pressure oxidation process does not cause a negative impact on the process performance for copper extraction, sulphide oxidation, and recovery of gold (if present) from pressure leach residue, and has additional advantages of removing the bacterially inhibitory aluminum from heap leach solution and generating more acid and ferric iron in the pregnant leach solution. A flowsheet configuration for full integration of the copper concentrate pressure oxidation with heap leaching of secondary copper sulphide ore is proposed and discussed.

Jan 1, 2014

By G. Shen, W. R. Tyson

In most fracture toughness test standards, such as ASTM E 1290 and BS 7448, crack-tip opening displacement (CTOD) is measured by using three-point bend (SE(B)) or compact (C(T)) samples with deep cracks. The loading mode and crack depth in these tests sometimes are different from that of pipelines. Pipelines usually have shallow defects and experience tensile loading when the supporting ground moves. As a result, the CTOD measured by these samples is lower than that of pipeline in tension. Recent researches suggest using single-edge-notch tension (SE(T)) samples to measure fracture toughness for pipelines. In the present study, shallow and deep SE(T) samples under fixed grip loading were analyzed by using the finite element technique. An equation to relate the CTOD to the area of the load/plastic crack mouth opening displacement (CMOD) is proposed. With this equation, the CTOD of a SE(T) sample can be evaluated by measuring the area under the load/plastic CMOD curve of a SE(T) sample.

Jan 1, 2005

By J. Dubinski

This paper describes the key circumstances of the underground coal gasification (UCG) process, which is planned to be carried out in the Polish hard coal mine ?Wieczorek?. The construction and field tests of a UCG pilot plant have key issues that need to be addressed to realize the research project goal: the elaboration of a highly effective technology of fuel and electricity production. The project will conduct several monthly tests of gasification in the pilot geo-reactor, which will be constructed based on the results of laboratory tests. The realization of the process requires numerous appropriately prepared actions adjusted to natural conditions in the hard coal deposit. Based on scientific principles, it is necessary to elaborate the procedures related to the location of the UCG installation (including its legal and safety aspects), and to perform a technical risk analysis. In addition, it is necessary to determine the required mining, geological, technical, economic and organizational circumstances, while at the same time considering the real but constantly changing process conditions.

Aug 1, 2013

By Sadan Kelebek, Gerhard W. Heinrich, Peter F. Wells, Peter J. Whittaker

"Based on plant mineralogical data & circuit modelling, a pilot plant campaign was conducted at Strathcona Mill to identify options for improving the performance and operating flexibility of the copper-nickel separation circuits. Emphasis was given to options for combined treatment of the two feed streams (primary nickel ore rougher concentrate and copper ore circuit concentrate) to obtain more flexibility in the use of existing column flotation capacities. The pilot test results demonstrated that circuits which incorporated preconcentration prior to column flotation gave the best metallurgical results. Maximum column carrying rates were also related to the preconcentration. Predictions that increased circulating loads from the column scavengers would improve copper-nickel separation performance were confirmed.IntroductionThe copper-nickel separation circuits at Falconbridge's Strathcona Mill produce a high grade (>30% Cu) copper concentrate most of which is treated at the Falconbridge Kidd Creek smelter near Timmins. The remaining nickel concentrate which still contains approximately 20% of the feed copper is combined with other lower grade nickel/copper concentrates and shipped to the Falconbridge nickel smelter. The separation is required because of the limited capacity for copper processing in and downstream from the nickel smelter. Since no nickel is recovered at present in the Kidd smelter, the challenge is to minimize the nickel content of the copper concentrate.At present there are two independent separation circuits treating the rougher concentrates from the copper and nickel circuits as shown in Figure I. The minerals treated are mainly chalcopyrite and pentlandite but there is up to 25% of the copper present as cubanite in the copper ore. The circuits were kept separate because the flotation rates and froth characteristics were very different, probably because of the presence of cubanite and the large difference in the concentrate grades feeding the circuits."

Jan 1, 1995

By H. C. Cooke

"The Part of the Eastern Townships dealt with in this paper is shown in the accompanying figure. Each rectangle represents one of the topographic maps published by the Department of National Defence on a scale of one mile to one inch. Each sheet covers an area approximately 24 miles long and 17 miles wide, or slightly more than 400 square miles. The north-western part of the area figured, comprising the Upton, Aston, Becancour, and the two unnamed sheets, (Three Rivers and Yamaska), together with most of the Lyster, Drummondville, and St. Hyacinthe sheets, is largely covered by clays and sands deposited in interglacial and post-glacial time in the Champlain estuary, so that outcrops are widely scattered and in-formation is correspondingly sketchy. In the remainder of the area figured, comprising more than 4,000 square miles, outcrops are reasonably numerous and have been mapped on a scale of one mile to one inch, and the structure is moderately well understood.The Eastern Townships was an area of intense orogenic disturbance, apparently beginning late in the Cambrian or early in the Ordovician, and continuing till well on in the Devonian period. During this long period, which may have lasted for a hundred million years or more, the area was subjected from time to time to intense thrusts from the east and southeast. Each of these caused folding of the rocks, accompanied by faulting, raised parts of the area above sea-level, and presumably created ranges of mountains. Long periods of erosion cut away the mountains and reduced the area nearly to sea-level after which subsidence carried it below sea-level, and permitted further sediments to accumulate before the next thrust initiated the next cycle.The first of these movements, as stated, appears to have been in late Cambrian or early Ordovician time. The group of rocks known as Caldwell was folded and, south and east of the town of Asbestos, was thrown into great drag-folds before deposition of the next overlying series, termed the Beauceville, began. Unfortunately, the date of this orogeny is very imperfectly known, because both series of rocks have been so crushed and sheared that almost all fossil remains have been destroyed. Graptolites, found in one place in slates generally considered Beauceville, give that series a tentative Middle Ordovician age. In the Caldwell rocks, which underlie the Beauceville with great unconformity, no fossils whatever have yet been found. Thus, if the Beauceville rocks are correctly dated as mid-Ordovician, the best that can be said of the movement folding the Caldwell is that it took place at some time before Middle Ordovician."

Jan 1, 1949

By Richard C. Williams, Herman Pieterse, Ken Thomas, K. S. Fraser, Ron H. Colquhoun

"The Banick Goldstrike Mines Inc. (Goldstrike) operation is located in Eureka County in north-central Nevada on the Carlin geological trend. Gold in the sulphide mill feed, occurs primarily as submicroscopic inclusions or possibly solid solution in a pyrite and marcasite matrix. Sulphide mill feed is pretreated in a pressure oxidation plant allowing gold recoveries of 90 per cent and greater to be achieved. Anticipated 1994 gold production for the sulphide gold facility is approximately 1,500,000 ounces.In January 1989 American Banick Resources Corporation (Banick) announced the US$365 million Betze Development Plan for the Goldstrike property. The Betze plan was based on a three (3) staged expansion of the original 4,500 STPD oxide gold plant. This expansion would involve addition of ore and gold processing capacity and the total conversion of all ore handling facilities to treating Betze sulphide ores.Phase 1 of the Betze Development Plan involved the construction of a pressure oxidation circuit, including a single autoclave and supporting ancillary services. The pressure oxidation circuit was commissioned in February 1990. Currently a throughput of 2,000 STPD is being achieved.Phase II of the Betze Development Plan, commissioned throughout April and May 1992, included the expansion of grinding, leaching, and gold recovery facilities enabling the treatment of combined oxide, and sulphide ore. Pressure oxidation capacity was increased by the addition of two (2) autoclave circuits each treating 2,600 STPD of sulphide ore and other required ancillary services. By June 1992, the Phase II gold facility had achieved a combined throughput of 15,000 STPD of oxide and sulphide ore.Phase Ill, the final stage of the Betze Development Plan, was successfully commissioned in February and March 1993. This final stage of development increased the design throughput of the pressure oxidation plant to 15,000 STPD by the addition of three (3) autoclave circuits with combined capacity of 7,800 STPD."

Jan 1, 1994