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By G. M. Ritcey, M. Silver

"The processing of uranium ores produces tailings that could constitute environmental problems. At most operations the tailings are dumped into a designated area, with the ultimate acid drainage occurring if sulphides are present, together with the release of metal constituents to the rivers and streams. If the chemical reactions occurring within the tailings could be predicted, perhaps methods could be developed to either increase or decrease 'the rates of reaction. One such study has been in progress at CANMET during the past three years. The paper describes the use of Iysimeters containing low-grade and complex uranium tailings to determine the effects and interactions of bacteria, sulphides and solvent extraction organics on the release of radionuclides and on acid production. A simulated rain cycle nine-fold the normal was used and the Iysimeters were subjected to timed intervals of light and darkness. As a result, the tests simulated a 25-year period.IntroductionAlthough Canadians derive major benefits from uranium, there are environmental and health consequences, not yet fully understood, from the associated mining and milling operations. A major project at CANMET (Canada Centre for Mineral and Energ y Technology) has the ultimate goal of ensuring that any adverse effects on man and environment, now or in the future, resulting from the processing of uranium should be acceptably low. The magnitude of the task was exacerbated by the fact that the increased demand for electrical energy and the resultant increased prices for uranium oxide during the 1970s led to a rapid expansion in the industry. Annual world demand for uranium was expected to increase 12-15 fold in the next quarter century, with annual requirements of between 200,000 and 300,000 metric tonnes anticipated by the year 2000. Currently, the demand is low and the prices for the oxide have decreased."

Jan 1, 1982

Post--Crunch Financial Management -An Overview A. The Industry and the Capital Markets B. .The SME -De-risking the Current and New Assets Followed by: C. The Lender?s Perspective on Re-financing?Jeff Stufsky, BNPParibas, NYCD D. .The Agency/Export Credit Lender Perspective?Doug Macaulay, EDC, Ottawa E. The Foreign Political Insurance Perspective?Pierre Vieillescazes, Carrick-Bend, Washington, DC ?Four Fundamental Metal Models No Longer Prevail. ?Mining is in new ?waters?: so be prepared (next page). ?Capital markets are uncertain-so be your own financier first ?If tight capital may remain, prepare to triage based on cash-flow production (not oz, lbs, tonnes, etc) ?Know your banker/financier(and it should know mining) ?In the past, it was ?know your borrower? ?The climbing team can fall if one climber carries too much ?Constantly re-assess the risk matrix (and j/v?s), and ?De-risk/diversify both the asset and the capital base

May 1, 2010

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By H. Salomon-de-Friedberg

The amount of pyrite in copper concentrates fed to the CESL Process can vary appreciably. The fraction of pyrite that oxidizes influences both capital and operating costs and is therefore an important variable. The present paper explores operating conditions that influence the extent of pyrite oxidation and the probable overall reaction chemistry under CESL conditions.

Jan 1, 2014

By V. Fiedler, H. Lachmund, R. Bruckhaus

"After producing some 50 million tonnes of crude steel the two BOF vessels at Dillinger Hüitte steel plant had to be replaced in 2000/01 due to large deformations. The new vessel design was optimised after a number of theoretical evaluations.Refractory investigations were carried out as well as temperature measurements of the shell to provide a basis for selecting a suitable steel grade. This was found in a DH-GTS development - P420M HT - with high strength at elevated temperatures and excellent weldability and made it also possible to build the vessel without any cooling system.After putting the first vessel into operation the metallurgical results showed no remarkable improvement compared to the old vessel, and were therefore not satisfying. With the help of cold model investigations the arrangement of the tuyeres was modified to improve the flow conditions and the interactions between oxygen jet and the heterogeneous plume of the bottom stirring gas. Further optimisations were obtained by a variation of lance tips and a newly developed lime addition model."

Jan 1, 2004

By Douglas W. Reeve, Hoc Nghia Tran, David Barham

"In kraft pulp mills, the spent pulping liquor is concentrated and used as fuel in the recovery boiler. Extensive deposits are formed in the upper section of the boiler due to the very high ash content of the fuel and the volatite nature of the ash. Deposits are composed of Na2S04, Na2C03 NaCI, some potassium salts and reduced sulphur compounds. Chloride and potassium salts are enriched in the deposits compared to the smelt due to their greater volatility.Severe corrosion of the superheater tubes in a recovery boiler has been traced to three factors: a non-uniform temperature profile in the flue gas, relatively high operating steam temperatures and high chIoride and potassium concentrations in the fireside deposits.The role of chIoride and potassium in superheater corrosion has been explained by increased Iiquid phase in deposits. Together with corrosion studies, this information has shown that kraft recovery boiler superheater corrosion due to the chloride and potassium enriched deposits can be avoided by proper boiler operation and by judicious superheater and furnace design.IntroductionThis investigation of recovery boiler superheater corrosion was initiated by the discovery of severe corrosion of the final stage superheater in a Canadian closed cycle kraft pulp mill(1,2). Metal wastage leading to tube failure was believed to be due to three major causes : the relatively high operating steam temperatures, the uneven distribution of flue gas temperature across the boiler which created a "" hot spot"" and the high chloride and potassium concentrations in the superheater fire side deposit. The mill responded to the problem by i) lowering the superheater steam temperature from 475°C to 380°C, ii) minimizing the chloride content in the spent pulping liquor, by controlling the NaCI input with recovered bleach plant effluent, and iii) changing metallurgy of a portion of the bottom section of the final stage superheater platens from ferritic steel T-22 (2.25% Cr, 1% Mo) to austenitic steel Incoloy 800H (21% Cr, 32% Ni, 46% Fe, 1.5% Mn, 1% Si, 0.6% Al) (Fig. 1). Details of the superheater corrosion experienced in the closed cycle mil! have been reported in previous papers(l ·2,) ."

Jan 1, 1984

By B. Dubreuil, J. -M. Lalancette, D. Lemieux, C. Chouinard

The extraction of gold and silver has been examined via the use of mixed halogens: chlorine and bromine. The reaction was performed in a brine of sodium chloride with a small amount of sodium bromide at 40-50°C, in an atmosphere of chlorine, at atmospheric pressure. The process takes advantage of the very high reactivity of bromine towards gold, while the higher oxidation capacity of chlorine leads to gold chloride as end product with recycling of bromine. Fast reaction rates are observed along with gold recovery at the level of 95%. Chlorine-consuming common elements are removed prior to chlorination.

Jan 1, 2011

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By Ben Burger

This paper describes the design, the first three years of operation and optimization of a large, single stage SAG mill at Minera Yanacocha?s Gold Mill facility located in northern Peru. The Gold Mill was commissioned in March 2008 with a 32? x 32? EGL, 16.5MW single stage SAG mill, to process 5 million tonnes per annum high grade oxide Au/Ag ore. Operational control, feed size distribution, grinding media, mill liner, grate and pulp lifter optimisation have allowed the mill to operate 15-30% above design throughput rates, but with a product P80 coarser than design. As part of the optimization, full grinding circuit surveys were conducted. Historical operating data and survey data were analyzed and used to evaluate possible circuit changes and determine alternative operating strategies. A number of changes were implemented which allowed the SAG mill to operate similarly to a large ball mill and achieve finer mill product that was closer to design. This paper summarizes life to date data analysis and improvements made by Minera Yanacocha as well as the grinding circuit optimisation study conducted by Metso Process Technology and Innovation.

Jan 1, 2012

By G. F. Round

In order to obtain values of angle of shearing resistance and initial resistance for McMurray oil sand for use in general design calculations, the shear strength of this oil sand was measured in a controlled strain type tester, modified so that the rate of deformation could be varied between 0.01725 and 0.1869 inches per minute. Effect of temperature was investigated by adapting the equipment to operate at both 71 ° and 185 °F. The data are reported in terms of angle of shearing resistance and initial resistance for varying rates of deformation, composition and temperature. While the main sets of results reported here were obtained at a bulk density range of 108.7- 109.5 lb. / cu. ft., some results were obtained at a bulk density range of 101-102 lb. / cu. ft. Analysis of varance tables have been drawn up from the results obtained from least squares correlations and significance tests applied. It was concluded that oil content and temperature were significant variables for the degree of shear strength developed by the oil sand; increase of oil content and decrease of temperature each cause an increase in shear strength. The bulk density range 108.7 to 109.5 lb./cu. ft. gave angles of shearing resistance from 30° to 40° and initial resistance values of 0.37 p.s.i. to 0.85 p.s.i. For the bulk density range 101 to 102 lb. / cu. ft., lower values of shear strength were obtained, indicating that compaction density was also of importance

Jan 1, 1960

By M. Timmins

Campbell Mine operates a 100 tpd gold autoclave that treats sulphide concentrates at 305 psi and 200 °C. Autoclave feed consists of fresh pretreated concentrate, an acidic oxide slurry recycle as well as other high arsenic sources. The brickwork that is used to construct the five compartments of the vessel must be inspected and repaired periodically. Shutdowns are scheduled to inspect this brickwork and at times replace entire sections of the brick walls or lining. It also provides an opportunity to repair or replace other internal features such as agitator blades or oxygen spargers. Mechanics and contractors are scheduled around the clock to perform the maintenance requirements. There are many safety considerations and precautions that must be taken in order to protect the well-being of the workers and minimize damage to sensitive pieces of equipment. Heat, arsenic and lead contamination and confined space issues are just a few of the hazards involved. The following paper will describe how these safety concerns are addressed and will serve as a guide for future autoclave shutdowns.

Jan 1, 2004

By J. Kempken, R. Hagmann, C. -P. Reip, W. Hennig

The CSP technology symbolizes a highly productive process for the cost-effective production of steel grades with a range of sophisticated properties comprising both the inner quality of hot strip, its surface formation as well as the relating technological characteristics. Thanks to extensive development work undertaken during the last 15 years, the range of steel grades that can be produced was continuously expanded and the process technology optimized. The present paper describes the ongoing development work concerning the production of higher-strength, microalloyed pipe steels. The resulting hot strip, due to the associated thickness and the potential pipe diameters, is particularly suited for being processed to HFI-welded pipes. Based both on ferrite-pearlite as well as very fine-grained, ferrite-bainite hot-strip microstructures, strength levels of up to grade API X80 can be realized. It can be demonstrated that hot strip produced in a CSP plant has very good toughness values at temperatures down to -60°C and can even make application with required sour-gas resistance possible.

Jan 1, 2005

By Cheryl L. Allen

Increasing energy costs associated with mining have become an issue that must be addressed by industry to ensure sustainable production. As underground mine ventilation systems account for 40% to 50% of a mine?s total energy requirement, initiatives to maximize their efficiency have been introduced worldwide. A control method known as Ventilation-On-Demand (VOD), which adjusts the ventilation system by responding to the activities of mine personnel and air quality, has been commissioned at Vale?s Coleman Mine. This initiative is an effort to reduce energy consumption, maximize efficiency of the ventilation system while ensuring air quality. There are five control strategies that can be executed with the VOD control system in place at Coleman Mine: Manual real time control Time-of-Day Scheduling Event-based control Environmental control Activity Based Control/Tagging This paper describes the system, control strategies and impact on energy consumption and flexibility of airflow distribution as applied at Vale?s Coleman Mine.

May 1, 2011

By Denis Racicot

"L'Abitibi québécois a produit essentiellement de l’or, du cuivre, du zinc et de I' argent, ainsi que de faibles quantités de nickel, de plomb, de molybdène, de bismuth, de lithium, de fer et d’amiante. Depuis l’ouverture de la mine Horne en 1927, cent-cinquante mines ont contribué à la production de 1 420 tonnes d’or de 4,1 millions de tonnes de cuivre et de 4,7 millions de tonnes de zinc. Les productions minières annuelles ont été d'importance variable: des records de production ont été établis en 1955 pour I' or avec 35 tonnes et, vers 1965, pour le cuivre, le zinc et la quantile globale de minerai extrait avec respectivement 130,000, 275 000 et 13 millions de tonnes. Deux dépressions généralisées ont eu lieu, l’une vers 1946 et l'autre, a lafin des années soixante-dix. Des ralentissements de la production ont été observes pour le cuivre en 1953 et le zinc en 1959. Depuis le debut des années quatre-vingt. I' or et, de façon plus irreguliere, le zinc sont en progression, landis que le cuivre, malgre une hausse en 1983. pour suit son dec/in.La teneur de récupération des mines d’or est demeurée régulière et n’a subi qu’une faible diminution au cours des quarante dernières années. Célie du cuivre a diminué d'environ 50% dans la même période, landis que celle du zinc a subi d’import antes variations, aussi bien positives que négatives. Près des trois quarts des mines d'or ont une durée de vie inférieure à 12 ans et la distribution des tonnages de minerai extrait montre un maximum pour la classe de 100 000 à 1 million de tonnes. Du cote des mines de métaux de base, la durée de vie est plus étalée et les volumes de minerai ont une occurrence maximale dans la classe de 1 à 10 millions de tonnes.Concernant la distribution géographique de la production minière dans l'Abitibi québécois, le camp minier de Rouyn-Noranda vient en tête pour l’extraction de minerai et la production d’or et de cuivre. L’est sui vi par le camp de Val d'Or pour le minerai et l’or, landis que le camp de Chapais-Chibougamau occupe la deuxième place pour le cuivre avec une production équivalence a 60% de celle de Rouyn-Noranda. Le camp de Cadillac-Malartic suit de tres pres celui de Val d'Or pour ce qui est de I' or. Finalement, dans le casdu zinc, le camp minier de Joutel-Matagami domine largement avec une production qui a connu un développement accélère depuis 1963. Une analyse pré liminaire de ces données indique qu' i/ subsiste unpotentiel encore élevé de production d'or, décuivre et de zinc dans I' Abitibi québécois. ABSTRACTThe Quebec portion of the Abitibi belt has essentially produced gold, copper, zinc and silver, as well as some small quantities of nickel, lead, molybdenum, bismuth, lithium, iron and asbestos. Since the opening of the Horne mine in 1927, one hundred and fifty mines have produced 1420 tons of gold, 4,1 millions tons of copper and4,7 millions tons of zinc. Annual mine production has fluctuated: production records were established in 1955 for gold with 35 tons, and around 1965 for all extracted ore copper and zinc with respectively 13 millions, 130 000 and 275 000 tons. Two main recessions have occurred, the first around 1946 and the second during the late seventies. Cut backs in copper and zinc production occurred in 1953 and1959. Since the beginning of the eighties, gold production and to a lesser extent zinc production have been in progression. Except for a small jump in 1983, copper production is still declining.The average recuperation grade of gold mines has been quite steady and has only slightly diminished in the past forty years. The average copper recuperation grade was halved during the same time interval. For zinc there have been important ups and downs. At least three quarters of gold mines have an average lifespan of 12 years the tonnage distribution shows a peak in the 100 000 to 1 million tons class. Base metals mines show a more widespread life expectancy and have a tonnage peak in the 1 to 10 millions tons range"

Jan 1, 1990

By J. Spross

"The Key Lake mill has operated since the fall of 1983. The ore from both Key Lake open pits will be depleted by 1997. It is planned to use this mill, located about 60 km southwest of McArthur, to process the McArthur River ore.While the geological data collected so far on the McArthur deposit are encouraging, more information of the deposit is needed before any detailed mine planning can begin.The surface drilling program identified the orebody and provided information on the geomechanical and hydrological properties of the overlying sandstone. It was proposed to conduct an underground exploration program to further delineate the orebody. This was air proved following a public hearing and review process. This program involves the sinking of a 630 metre deep shaft and the driving of one or two drifts along a portion of the orebody. From these drifts, exploration drilling every 10 m to 15 m through the orebody will provide the information required for the preparation of a feasibility study and an Environmental Impact Statement (EIS)."

Jan 1, 1994

By S. K. Schwartz

"This paper describes the general layout of the environmental monitoring scheme at Devco 's No. 26 Colliery, including wall face ventilation, fan performance and methane drainage, and then goes on to discuss the sensors, the outstation layout, the surf ace control room and the protection of the system.IntroductionCape Breton coal mines have been pioneers in the use of the latest technology in mining coal on this continent. To mention just one example, continuous methane monitoring at the coal face was started in 1976 and the idea of automatically stopping the face conveyor during high gas levels using the face signalling system was conceived and developed by CBDC engineers.With the introduction of remote environmental monitoring, No. 26 Colliery will be the first underground coal mine in Canada and possibly in North America to have computer-based comprehensive environmental monitoring.Traditionally, surveillance of the mine environment has been based mainly on periodic checks by portable or hand-held monitors. Although this method proved adequate, it has some limitations, namely:1) restricted 'number of observations and samples;2) relatively long time between taking measurements and availability of results for assessment.With remote monitoring, the above limitations are overcome because (a) monitoring is continuous and (b) monitored data are updated quickly (typically 5-7 sec.). Remote monitoring also provides a centralized 'information center' at the surface from where the entire mine environment can be monitored. Details of modes in which data can be displayed and features available at the location will be discussed later in the paper."

Jan 1, 1982

By J. Kolacz

"A new sensor based sorting system has been developed, providing a possibility for laboratory scale testing and further scale-up of the separation results to the industrial operation. The new system contains different sensors as: X-ray detectors, visible light cameras, NIR cameras, ultraviolet cameras and magnetic sensors, in the same sorting unit. The sorting unit allows advanced calibration options and fine-tuning of the installed sensors to achieve the best separation effect under controlled conditions. Finally, the processed material can be analysed and separated by the rejection mechanism, similarly to the industrial scale operation. At the same time, the process is carried out with limited amount of material allowing detailed statistical calculations for processed particles and all sensor types. The optimal settings and sensor types are specified for the industrial application.The paper describes the scale up of the results achieved for iron ore and coal, where the test work was first carried out using the new laboratory sorting system and where the industrial scale sorting system has been built, in the final stage. The industrial scale sorting results showed a very good correlation between the laboratory and full scale operation. Thanks to the detailed study carried out in the laboratory equipment, the settings of the sensors in the full scale operation provided much better separation efficiency. It was especially important to provide proper setting for the X-ray sensor data calculations, which can be very critical for achieving the best results. During the industrial scale sorting of coal, the input material had 40-55% rock particles as the direct source of ash in the coal stream. The optimal laboratory unit settings and transferring these settings to the industrial sorter, provided 98.8% efficiency for removing rock particles with only few % losses of coal."

Jan 1, 2016

By J. D. Wright

This paper describes current milling practice at Endako Mines Ltd., a molybdenum producer in central British Columbia. The various steps in the crushing, grinding and flotation of the ore are outlined, with emphasis on the metallurgy of the latter operation. Tailings disposal and concentrate assaying methods are also described.

Jan 1, 1969

By Roméo Roussin

"The yearly production from the Asbestos Hill pit is 1,550,000 tons of asbestos ore, with a yield varying between 18 and 20 % . The orebody was exposed at the top of a hill, and initial production started without having to remove any overburden. The projected ratio of barren rock to ore, based on the present orebody, was 2 to 1. However, as it was necessary to push back the upper benches, this ratio has changed to 3 to 1. The final pit will be 2,300 feet long by 1,000 feet at the longest and widest points. The final depth will be 680 ft. A pit slope stability study was carried out and an average wall angle of 60-70 degrees must be maintained. Preshearing of final pit limits will produce good wall stability. Permanent access ramps will be 60 ft wide, with an 8 % maximum grade. Geological conditions and the low rock temperature are the major causes of the operation's drilling and blasting problems."

Jan 1, 1976

By N. Maleki

In recent years, research and development of magnesium alloys have been greatly promoted by the lightweight requirements in critical industries. The use of these alloys, however, has been restricted by their limited mechanical properties especially at high temperatures. The disadvantages can be overcome by producing Mg matrix composites. The Mg?Si alloys containing in situ Mg2Si particles have found a great potential as structural materials. Unfortunately, Mg2Si compounds are prone to form undesirable coarse Chinese script morphologies, which would deteriorate the properties of the materials. Refinement of microstructure is performed for improvement of wear and corrosion resistance. This paper investigates the microstructure and corrosion behavior of pure magnesium, unmodified and modified magnesium matrix composites reinforced with Mg2Si particles. The Mg2Si/Mg composite was prepared via a normal cast route, and then various amount of zinc was added to melt in order to modify the Mg2Si reinforcement particle morphologies. The microstrucrures were characterized by optical and scanning electron microscopy followed by EDX analysis. The corrosion behavior of Mg/Mg2Si composite was investigated by using potentiodynamic polarization measurements. The results showed that by addition of zinc, the average size of the primary Mg2Si became significantly decreased from about 100µm to about 20µm, as well as its morphology changed from dendritic to a polyhedral shape. However, by adding extra amount of zinc many primary Mg2Si particles become coarse again. It was also found proper amount Zn addition increased the corrosion resistance of Mg/Mg2Si composite.

Oct 1, 2011