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By M. D. Gerst

The degree to which copper will continue to be in an integral part of the world economy in the future will depend largely on the dynamics of global economic development, the primary and secondary copper resource stock, technological change, and potential environmental constraints. We have characterized the copper cycle of 1994 for all of Earth's regions and for the planet itself (T. Graedel et al., Environmental Science & Technology, 38, 1242-1252, 2004) and recently updated that cycle to year 2000. In this paper, we compare various features of the 1994 and 2000 cycles. The three largest-using regions, Asia, Europe, and North America, all increased their absolute rate of copper use between 1994 and 2000, and all increased the per-capita rate of copper use as well. Globally, the use of copper increased by about 32%, from 11.7 to 15.3 million metric tons, while population increased by only 8%. Various changes are seen in scrap trade, finished products trade, and other parameters of the cycle. We conclude by considering how the rates of technological change and growth in demand, especially in Asia, may influence the copper cycle in the years ahead.

Jan 1, 2007

By Tim Watson

Andacollo Hypogene Project ?Overview Project description: Sulphide copper concentrator Throughput:55,000 tpd Location: Approximately 50 km from La Serena Elevation: Approximately 1,000 m ASL Start feasibility study: July 2005 Start of construction: May 2007 Construction completion: December 2009 Final cost(1,2,3):435 Million US $ (1) Excludes third party costs, 220 kV power line (2) Cost is based on a Chilean Peso to US Dollar foreign exchange rate of 535 to 1 (3) Does not include US$40.3 million for the Elqui River Pipeline Project or US$8.0 million for the stock pile cover

May 1, 2010

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006

The article presents an outline of methods and certain results of laboratory tests, underground tests and model tests, aimed at assessing performance of a powered shield support on the floor of low strength parameters. The tests were conducted within the framework of GEOSOFT project co financed by Research Fund for Coal and Steel (RFCR-CT-2010-00001). The described research works were conducted by Central Mining Institute (Glówny Instytut Górnictwa), Janina coal mine and Becker-Warkop

Aug 1, 2013

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By M. L. Jeremic

"The syngenetic and epigenetic mechanics of sedimentation and deformation of coal seams resulted in various types of internal structure, as listed below:TYPE I-massive structure with evenly distributed coal constituencies of integrated mechanical properties.TYPE II-broad-banded structure, with bright and dull coal bands of differential mechanical properties.TYPE III-heterogeneous structure, with sheared coal bands and partings of sectional mechanical properties.TYPE IV-contortional structure, with refolded coal layers and deteriorated mechanical properties.TYPE V-porous structure of orogenically crushed and pulverized coal, with disintegrated mechanical properties.The study suggests criteria for the estimation of coal seam internal structure (gamma-gamma density log and cracks density log), which might be related to the evaluation of strata stability and coal mineability.IntroductionIt is common knowledge that coal seams have various internal structures due to different syngenetic and epigenetic events. Investigations of the internal structure of coal seams have been carried out in the coal fields of Western Canada, as follows: geological field studies of coal-bearing strata;?,geophysical borehole surveying studies;?,geological borehole logging and crack density;?,underground phenomenological studies of mine structure;?,chemical coal analysis; and?,mechanical testing of coal samples.These investigations eliminated a large number of criteria previously established for the estimation of coal seam internal structure and indicated that, from an engineering point of view, only two of them are sufficient:(I) density of seam profile (inferred from gamma-gamma log);(2) density of crack s (inferred from geological log).On the basis of these criteria, five main structural types of coal seams have been classified, which might be related to mechanics of deformation and ' failure of mine structures."

Jan 1, 1982

By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By P. Ashtari

Influence of Sr and Mn single and combined additions on the modification of the Fe-containing intermetallic compounds and mechanical properties of Fe-rich AA319 aluminum alloys have been investigated, The microstructural features e,g, morphology of the Fe compounds and eutectic Si has been correlated to the mechanical properties, It was demonstrated that modification of the Fe compounds from the platelet ß-Al5FeSi to the Chinese script a-Al8Fe2Si compound improves the UTS and elongation of the alloys by 10.3% and 83.9%, respectively. Moreover, the simultaneous modification of the Fe compounds and eutectic Si increases the UTS and elongation of the alloys by 15,3% and 116,1%, respectively.

Jan 1, 2005

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007

By Vic Briccardi

Energy Management Challenges The Holistic Standard to Energy Management Energy Management Information System (EMIS) "Best Practices?: Energy Management Maturity Curve De Beers Canada Profile & Mine Locations Significant ROI Driven by Real-Time Energy Visibility Mining Energy KPI?s Summary: What Does EMIS Deliver? Q&A Session

May 1, 2013

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By X Dai

This paper investigated the loss of cyanide via oxidation in CIP or CIL processes by relating the cyanide oxidation to its major oxidation product, cyanate. The results showed that the oxidation of both free cyanide and copper cyanide complexes are substantially enhanced by the presence of carbon. The rate of cyanide oxidation was found to occur in the order: Cu(CN)32- > CN- > Cu(CN)2-. The cyanide oxidation rate in the presence of copper and carbon increased significantly with increasing dissolved oxygen concentration, typical of CIL vs. CIP conditions. Cyanide oxidation rate of iron, zinc or nickel cyanide complexes was minimal.

Jan 1, 2011

By T. Rahimzadeh, C. W. Trueman, S. Farzaneh, S. V. Hoa, I. Abdalla

This paper presents the shielding effectiveness (SE) of woven continuous carbon/epoxy composite materials. The theoretical and physical concepts behind the experimental results are demonstrated in details. The influence of frequency, the overlapping angle between overlapped layers and the number of overlapped layers upon the EMI shielding of composite sheets are discussed. In this work, in particular, the epoxy layers are considered as dielectric apertures of the conducting carbon fiber slab for the interpretation of the experimental results. The experimental results, using ASTM standard D4935-89, indicate that the SE can reach values greater than 90 dB above 500 MHz.

Jan 1, 2006

By D. Tao

The adverse effects of clay particles on coal and mineral processing processes such as gravity separation, flotation, filtration, and thickening are well known in the mining industry. In particular, the presence of ultra-fine clay particles deteriorates froth flotation performance, which has been attributed largely to slime coatings that inhibit bubble attachment and to adsorption of the frother and/or collector by the clay particles. The present study was conducted to evaluate the performance of clay binding agents developed by Georgia-Pacific Resins, Inc. in enhancing coal and mineral flotation performance. Mechanical and column flotation tests were carried out using coal and potash samples. Process parameters investigated include slurry solids percentage, impeller rotation speed, binder dosage, collector dosage, etc. Flotation results show that use of GP reagents significantly enhanced flotation efficiency under different conditions. The required binder dosage and conditioning time was about 1 lb/t and 0.5-1 min, respectively. More significant improvements in process performance were observed at higher solids percentage and higher impeller rotation speed.

Jan 1, 2006

By D. W. Rogers

Several commercial polyacrylamide flocculants most widely used in Western Canadian mineral processing plants have been analyzed chemically and compared in standardized settling tests as aids to thickening and clarification. Data are included for both dry and liquid-type flocculants. Percentages of active ingredients in these commercial products varied Widely. Performances were compared on the basis of: equal additions of active ingredients, nearly equal molecular weights and nearly equal degrees of ionic character. Based on zone settling velocities and supernatant clarities of siliceous slurries coagulated by lime additions, dry flocculants proved more economical than liquid flocculants. Using these same two criteria, the most highly anionic were more effective than either weakly anionic or non ionic polyacrylamide- type flocculants.

Jan 1, 1978

By T. -W. Hong, Y. Son, S. -J. Hong, D. Choi

The characteristics of indium-tin-oxide (ITO) nanoparticles recovered from TFT-LCD panel scraps were investigated. The ITO was separated from TFT-LCD panel scraps by dissolving the color filter layer located between the ITO layer and the glass substrate. The solution was filtered to separate the ITO from the color filter component, and the filtered ITO was dissolved in the acid solution. ITO nanoparticles were then precipitated with ammonium hydroxide and organic dispersing agent, followed by heat-treatment at 600 °C. HRTEM, EDX and XRD analyses revealed that the 20 nm sized particle were composed of 90 % In and 10 % Sn, and were well crystallized to in the (222) preferred orientation.

Jan 1, 2014

By Stefan Planeta

On discute les performances techniques et économiques des méthodes d'exploitation à haut rendement dans les mines métallifères au Canada. L'accent est mis sur la dilution et pertes des réserves minières et sur les coûts opératoires et totaux. Une analyse technique de quelques opérations minières est également effectuée. Il ressort de cette analyse que les résultats réels des opérations minières en cours diffèrent souvent de ces planifiés suite à la dilution du minerai et aux pertes importantes des réserves minières. On propose, définit et discute un certain nombre des facteurs de performances technologiques et économiques pour pouvoir mieux apprécier les problèmes rencontrés dans plusieurs mines en opération. À l'aide des études de cas on démontre impact négatif de la dilution et des pertes additionnelles des réserves minières sur la rentabilité des opérations en cours et sur les nouveaux projets miniers. On conclut, que l'application des indicateurs proposés donnerait un outil valable, aux opérateurs miniers, aux niveaux de la planification, du suivi des travaux d'exploitation et d'éventuelles études comparatives entre les différentes situations minières. ABSTRACT The paper discusses technical and cost performance of bulk mining methods in Canadian U/G metal mines. It focuses on ore dilution, ore reserves losses as well as on operational and total cost. Technical analysis of some mining operations has been performed. It indicates that due to dilution and significant reserves losses, the actual results of mining operations often differ substantially from those planned. The paper proposes, defines and discusses several indicators quantifying technical and economical performance in order to assess better the problems encountered in several operating mines. The case studies presented here have demonstrated an adverse effect of dilution and additional reserves losses onto profitability of existing operations and new mining projects. It is concluded that the application of the above mentioned indicators may be beneficial for mine operators. They may become a very useful tool at the stages of planning, follow-up of mining works and with regards to comparative studies between different mining situations.

May 1, 2001

By Elizabeth Edwards, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg, Kurtis Judd

Mineralogical characterization of the tailings showed the deportment of Ni to be similar in the Vale and Glencore tailings, with 60% of the total Ni locked in pyrrhotite, and the balance 40% associated with pentlandite. The overall Ni dissolution was correlated with the individual dissolution extents of pyrrhotite and pentlandite as functions of four leaching regimes: ‘anoxic acid’ (with and without pH control), ‘oxic acid’ (oxygen sparging), ‘oxic acid’ (air sparging), and ‘oxic ferric’ (air sparging). The results showed that the maximum Ni dissolution was obtained during the pH controlled oxic acid leach with oxygen sparging at pH 1.5, while the anoxic acid leach at pH 1.5 resulted in minimum Ni dissolution (10–15%) from pyrrhotite. An overall Ni mass balance showed that pyrrhotite and pentlandite dissolve simultaneously in the presence of Fe(III) and oxygen, in contrast to the preferential dissolution of pyrrhotite in the absence of Fe(III). Sulphur mass balances revealed that the yield of elemental sulphur is maximized (65%) during the oxic Fe(III) leach at pH 0.6. Furthermore, the kinetics of Ni leaching and elemental sulphur formation from pyrrhotite tailings leached with ferric sulphate between 55–80°C was investigated at constant oxidation-reduction potential. Elemental sulphur yield increased with increasing temperature, but no observable trend could be linked to ferric or ferrous ion concentration.

Jan 1, 2017