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By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016

By Kris Inwood

"In 1879, when the Dominion government initiated its controversial program of industrial promotion, iron smelting in Canada was limited to one company producing coke iron on the mainland of Nova Scotia and three small charcoal blast furnaces in Quebec. There was no steel production. By the eve of the First World War, iron and steel were being produced in very large quantities, the companies active in 1879 had disappeared and new centres of integrated iron and rolled steel production at Hamilton, Sydney and Sault Ste. Marie had come to resemble the industry as we know it today. The most dramatic change was that at Sydney, Nova Scotia, where in the early 1900s, two steelmaking companies established works. The Sydney developments have been explained as the result of resource discovery and technical change. W.J. Donald, in his authoritative account of the Canadian iron and steel industry, observes:(1) ""The most rapid growth of the Canadian iron and steel industry has occurred since 1897 ... The remarkable growth has been caused largely by the new conditions of the industry. The discovery and use of Newfoundland ores, together with the availability of Cape Breton coal, has made the Nova Scotia industry not only possible but profitable .... It is a safe conclusion that the Canadian industry would not have been an important one, had it not been for the discovery of the Michipicoten and especially the Wabana (Newfoundland) ores:' Donald also argues that metallurgical progress had been necessary to render the ores valuable. ""Newfoundland ores ... contain a considerable amount of phosphorus, and were made available for steel-making by recent inventions:' The purpose of this paper is to re-examine Donald's story. It will be argued that the origin of steel-making at Sydney is somewhat more complicated than Donald has indicated. The difficulty with Newfoundland ore extended beyond its phosphorus content and a resolution required more than the basic open hearth furnace identified by Donald. Moreover metallurgical change was only one of several developments necessary to induce industrial investment at Sydney. Surprisingly, however, the discovery of iron ore in the late nineteenth century does not appear to be part of the explanation."

Jan 1, 1999

By T. E. Morimoto

Summary The Research Council of Alberta has made a series of tests with the cyclone washer to investigate the influence of the following operating variables: underflow apex diameter, .specific gravity of medium, pulp ratio, density distribution of the feed, and size analysis of the feed. The results obtained for all the variables studied, except size analysis of the feed, are included in this paper. The tests were made with smaller underflow apex diameters and lower specific gravity .suspensions than have been recommended by Cerchar for the sharpest separations. However, what is considered to be sufficiently good cleaning was accomplished with a suspension of 1.30 specific gravity and an underflow to overflow diameter ratio of 0.56. It was found that the sharpness of separation was not affected appreciably by variations in specific gravity of suspension or underflow apex diameter provided that the density of separation was within the normal range of washery operation. Cyclone performance was not too adversely affected by decreasing the pulp ratio. The minimum figure which gave reasonable separation was 4 to 1. The tests with various density distributions of feed revealed .that the degree of washing difficulty had no detrimental effect on the .sharpness of separation given by the cyclone. Introduction A major problem of the bituminous coal industry today is that of reducing the ash content of the finer sizes (minus 1/4-inch) of coal. This problem is particularly acute in Alberta, where, because of tectonic movement subsequent to deposition, the coals have been rendered friable, and bands of impurities have been intimately mixed with the clean material. As a consequence, most Alberta coals, as mined, contain a large proportion of fines and have a high inherent mineral-matter content. The advent of mechanized mining and stripping operations ?has further aggravated this problem.

Jan 1, 1952

By Michel Chouteau

"A very conductive zone was revealed in 1977 and 1978 by magnetotelluric (MT) measurements carried out near Ste-Mathilde, 6 km northeast of La Malbaie . In order to identify the structure causing the anomaly, thirty-five MT soundings were recorded in 1980 and 1981 on and around the conductor within a radius of4 km. Results confirmed that the conductor is of limited extent (less than 2 km by 0.4 km). The proposed model is a highly conductive vertical slab, the top of which is within 200 m from the surface. At a depth of approximately 825 m this structure joins a conductive layer which extends to the northwest but not to the southeast. The large conductivities and the depths involved can only be explain ed by a fractured zone flooded with electrolytic solutions, by graphite veins or by metallic mineralization (sulphides). The former seems to be the most likely hypothesis because an EW fault running across this zone could have allowed percolation of water and the leaching of disseminated pyrite out of a mylolisthenite filling the fault.IntroductionLa Malbaie is located 130 km northeast of Quebec City on th e North Shore o f the St. Lawrence River (Fig. I). Four major groups o f rocks have been mapped in this area: charnockitic rocks to the west , granitic rocks in the north east and southeast, gneiss and pegmatites northwest and south of La Malbaie , and Paleozoic sediments in the Clermont-La Malbaie Valley and along the shore of the St. Lawrence River (Rondot, 1966). Two major features dominate the structure of the region: Logan ' s line , a major thrust fault beneath the St. Lawrence which separates the Grenville Province to the north from the Appalachian regime to the south, and the Charlevoix Crater , a large Paleozoic impact crater that created an almost perfect annula r structure centred on Mont des Eboulements (Rondot, 1970). Ste-Mathilde is a village lying 6 km northeast of La Malbaie, just outside the ring-like graben zone caused by readjustments after meteorite impact. The survey area spreads over a granite body which is more than 2 km long and 0.6 km wide, surrounded by a wide migmatite zone which is injected by many bodies of pegmatite, the latter likely related to the granite body (Fig. 2). A zone of leptynites lies west of the area. An east-west trending fault (FA1) related to the Charlevoix Crater runs mid -way across the survey area; a second parallel fault (FA2) south of FAI separates the gneissic rocks from the Paleozoic sediments. The overburden is usually thin with outcrops frequently encountered except for the centre of the survey are a where 10 m of glacial sediments are expected (E. Gaucher, 1982, personal communication)."

Jan 1, 1985

By Aidan Giblett, Michael McGlynn, Peter Radziszewski

"On the basis that 99% of the energy input into a mill is converted into heat, it is possible to estimate the amount of energy captured in the slurry, the amount that is lost to the environment as well as the possible means to reduce such losses. As a result it becomes possible to estimate the potential amount of energy that can be captured by technologies such as thermoelectric generators or even Sterling engines. Furthermore, it has been suggested that the energy recovery potential dry grinding circuit could be as high as twice that of wet grinding circuits.In this paper, the energy recovery potential of dry grinding will be explored by examining the case of the Newmont Carlin mine dry grinding circuit. The paper will open with a review of the energy recovery potential of a few wet grinding applications followed by a description of the dry grinding circuit and a definition of the control volume around that circuit. A thermodynamic model will be used to estimate the circuit discharge temperature and an estimate of any losses as well as provide an estimate of the potential impact of different means to reduce energy losses. The paper will close with a discussion of the assumptions used in model development."

Jan 1, 2016

By C. Lambert

It has been shown that contacts between host rock and engineered barriers may be critical in the design of deep radioactive waste repositories. Water is expected to reach the interface zone after the re-saturation of the geological massive and its presence may lead to concrete leaching. Such a phenomenon could increase the interface transmissivity and compromise the confinement of radioactive waste. Recent experimental results from Buzzi et al. (2008) have enhanced how concrete leaching can drastically change the mechanical behaviour of such interfaces. Because of the local loss of strength resulting from leaching, shearing resulted in a degradation of the interface asperities. Similarly to rock joints, intact interfaces exhibit a usual contracting-dilating behaviour. On the contrary, depending on the extent of leaching, the degraded interface can display a fully contracting. This paper intends to investigate the influence of concrete leaching on the mechanical behaviour of host rock-concrete interfaces. The leaching process consists in the dissolution of some of the hydrates of the cement paste, leading to a reduction of the strength and Young's modulus. A discrete model has been developed with PFC3D where a simplified interface morphology has been introduced using a saw-tooth description of the asperities.

May 1, 2009

By G. Anger, J. Enser, H. Antrekowitsch, S. Koch

Homogeneous chemical composition and microstructure are always necessary, but not always attained in practice. As-cast aluminium alloys tend to have a segregation microstructure. Features of the cast structure, which affect subsequent processing or properties, can be altered by the homogenization. The main task of the Department of Nonferrous Metallurgy was to investigate the effect of homogenization treatment on precipitation hardening of aluminium alloys 6061 and 6082. The effect of the solution heat treatment (SHT) temperature on the mechanical properties was also analyzed. The homogenized and non-homogenized rolling slabs were produced according to the usual conditions and methods. The metallographic investigations were carried out on the as-cast samples, after homogenization, after the hot and the cold rolling mill, and after natural and artificial ageing. Then, Brinell hardness measurements and tensile tests were conducted on both alloys in order to examine the influence of the homogenization.

Jan 1, 2006

By F. N. Smith

Corrosion was observed on the aluminum pressure plates and dress-caps that hold the glazing in place on a curtain-walled building, The multi-storey building in question is situated in the downtown area of a busy Canadian city, For aesthetic reasons, the original design required the dress-caps (which have L-shaped cross-sections) to be externally clad with thin copper sheet. Since the aluminum was in direct contact with the copper trim, galvanic corrosion developed that resulted in damage to the aluminum components, Soluble corrosion products washing off the copper trim may also have contributed to the accelerated corrosion of the aluminum, The aluminum pressure plates and dress-caps are being systematically replaced with components made of fibre-reinforced plastic. The outsides of these new components will be clad with thin copper sheet in order to preserve the original appearance of the building.

Jan 1, 2005

By Vincent Jourdain

Located in the James Bay Territory of Quebec (figure 1), the Clearwater property is jointly owned by SOQUEM Inc. and Eastmain Resources Inc. Exploration on the property since the early 70's has resulted in the discovery of several gold showings. Exploration work by the joint venture since 1995 has led to the definition of the Eau Claire Zone containing an indicated resource of 540 000 tonnes grading 11.1 g/t Au (8.7 g/t Au cut at 34.28 g/t Au). Hosted by the archean Eastmain Greenstone Belt, the property geology is dominated by mafic volcanics containing thin horizons of felsic volcanics and/or sedimentary rocks (figure 2). The sequence is metamorphosed to the amphibolite facies and contains two small toalitic intrusions. Regionally, the structural trend is oriented E-W but in the area of the Eau Claire Zone a second trend oriented NE-SW is also present. The first exploration work on the property was conducted by SEREM and SDBJ from 1973 to 1976. It consisted of an airborne electromagnetic survey and a ground follow-up program on several grids. This program, comprising geological mapping, geophysics and drilling, led to the discovery of the Natel showing where a drill intersection returned 8.89 g/t Au over 2.65 m. From 1978 to 1985 the area was withdrawn from staking because of the hydroelectric projects of the James Bay. In 1985, Westmin Resources Limited and Eastmain Resources began an exploration program based on a helicopterborne electromagnetic survey. Once again, a ground follow-up program was conducted on several grids. This program included a soil geochemical survey that identified a strong (up to 10 g/t) gold anomaly. Drilling of the anomaly led to the discovery of the Eau Claire Zone where resources were estimated at 270 000 tonnes grading 6.1 g/t Au at the end of 1990. In 1995, SOQUEM Inc. took an option to gain a 50% interest on the property and obtained its interest in 1998. Since 1995, two principal mineralization zones were identified on the property. The "Rosemary Zone" consists of veinlets and disseminations of pyrite and chalcopyrite within a magnetite-rich amphibolite. The mineralized zone was identified by stripping within an area of 1000 by 500 metres. Drilling indicates copper grades up to 0.32 % Cu over 49.2 m. with locally grades of 0.75 % Cu over 5.9 m. The mineralised zone is associated with QFP dykes and corresponds to a strong magnetic anomaly and a strong copper and molybdenum soil anomaly. The "Eau Claire Zone" consists principally of a set of gold bearing quartz-tourmaline veins oriented E-W and dipping at 45-50??to the south (figure 3). More than ten different veins are recognised in the zone and up to eight veins were observed in a single trench (figure 4). The host rock between the veins shows a degree of deformation similar to the regional volcanosedimentary rocks. Each vein is hosted by a unit of actinolite-tourmaline-biotite schist up to one meter thick. The veins and their hosting schist clearly cross-cut the schistosity of the hosting lithologies and the contacts between amphibolites and felsic to intermediate rocks. Usually, the veins are less than a meter thick and are composed of quartz, tourmaline and calcite. The proportion of quartz and tourmaline varies from 0 to 80% within a single vein. The veins commonly show massive, banded or brecciated texture. Sulphides, mainly pyrite, pyrrhotite and chalcopyrite, generally form less than 5% of the vein material.

May 1, 2001

By Jared Onyirimba, Jim Viellenave, Hal Demuth, Dale Verran, Chad Sorba, Errol Lawrence, David Bronkhorst

As outlined within the Denison Mines Corp’s (“Denison”) Pre-Feasibility Study ("PFS") completed in late 2018, additional work is required to increase confidence and reduce risk associated with the application of the In-Situ Recovery (“ISR”) mining method at the Phoenix deposit, located on the Wheeler River Uranium Project (“Wheeler River” or the “Project”) in northern Saskatchewan. The successful application of ISR in any geological environment largely hinges on three fundamental requirements, 1) permeability (of the deposit), 2) containment (of the mining solution) and 3) leachability (of the mineralization). Denison has designed several staged technical programs to progressively reduce risk associated with these requirements as the Company advances the Project toward a Feasibility Study (“FS”) and Environmental Impact Assessment (“EIA”). This paper will discuss the scope and results of certain technical programs being undertaken as the Company aims to develop the first ISR mining operation in the Athabasca Basin.

Jan 1, 2020

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By L. Vu, V. Popov, J. Beland, R. Darling

"The Ferderber gold deposit is of Archean age. It consists of a series of gold-bearing quartz lenses within a shear zone that crosscuts the central part of the quartz dioritic Bourlamaque batholith. On average, this zone strikes N70E and dips 65SE. The Ferderber shear zone, which hosts the ore lenses, has been affected by a succession of tectonic events. A possible early period of brittle shear, accompanied by the formation of quartz lenses, resulted from strike slip movement along the zone. These early quartz veins were subsequently folded and boudinaged during reverse movement that accompanied a prolonged period of ductile shear. More quartz veins were emplaced in the shear zone at this time; these were also deformed by the thrusting. The latest tectonic event to affect the shear zone was a period of brittle fracture.Early dextral strike-slip movement on the shear zone is suggested by the local occurrence of Riedel shears, the preferred association of ore with east-northeast oriented segments of the zone, and by the apparent en echelon arrangement of some ore lenses. The most important event, a reverse movement, is indicatedby the attitudesoffoliation, folds, boudins, COS tectonites and slip planes. The late brittle fracturing formed narrow gouge filled faults, locally flanked by brecciazones, whichrun generally within and parallel to the shear zone, and also conjugate fractures that crosscut the zone.The Ferderber and six other adjacent gold deposits were formed in a structural regime dominated by a generally horizontal north-south regional compression. The Y axis of the strain ellipsoid is east-west and varies from horizontal to a plunge of 25 0 w."

Jan 1, 1987

By Erik C. Westman

Knowledge of the orientation and relative magnitude of in-situ stresses at the mine scale is important for safe and efficient production from an underground mine. With this knowledge, stope location and scheduling can be optimized. Passive seismic tomography was used for imaging horizontal stress distribution at the mine scale. Microseismic measurements from the Creighton mine were used as input for the tomography calculations. The double-difference tomography algorithm was used, which provides the most precise results. The results clearly show a low velocity zone in the previously mined areas bounded by two high-velocity lobes located adjacent to the mined openings at locations consistent with those expected due to the horizontal stresses at the mine. The overarching goal of the research is to provide a tool that can augment both numerical modeling results and underground geotechnical measurements to allow the mine operator to produce in the safest and most efficient manner possible.

Jun 1, 2012

By William M. Luff

"The Bathurst area has recorded mining production as early as 1837, although the bulk of the production has come in recent years. Production has been mainly from the well-known massive sulphide deposits, but vein, gossan, and a variety of other deposits have also been mined. This paper summarizes the history of the mined deposits, along with tonnages and grades produced. A number of ""firsts"" have been noted in the Bathurst area. The A Zone deposit, located in the Heath Steele area, was the first in the world discovered using airborne electromagnetic methods. Heap leaching of gold from the gossan zone at Caribou was the first operation of its kind in Canada. The Keymet mine was the first base metal (lead-zinc) mine in New Brunswick. For the past few years, the Brunswick No. 12 mine has been one of the largest zinc mines in the world.IntroductionThe Bathurst area (Fig. 1) first had mining production in 1837 when copper was mined from a deposit on the Nepisiquit river (MacKenzie, 1958). The majority of the production, however, has been in recent years from massive sulphide deposits, but there are also other significant operations. . Table 1 is a summary of Bathurst area mineral production, showing concentrator feed tonnages and mill feed grades. The table does not include peat deposits, sand and gravel, dimension stone or rock quarries. Figure I is a general geology map of the Bathurst area, indicating deposit locations. The deposits are divided into four categories: massive sulphide, vein, gossan and other. The deposits in each category are described in chronological order of exploitation."

Jan 1, 1995

By William M. Luff

"The Bathurst area has recorded mining production as early as 1837, although the bulk of the production has come in recent years. Production has been mainly from the well-known massive sulphide deposits, but vein, gossan, and a variety of other deposits have also been mined. This paper summarizes the history of the mined deposits, along with tonnages and grades produced.A number of ""firsts"" have been noted in the Bathurst area. The A Zone deposit, located in the Heath Steele area, was the first in the world discovered using airborne electromagnetic methods. Heap leaching of gold from the gossan zone at Caribou was the first operation of its kind in Canada. The Keymet mine was the first base metal (lead-zinc) mine in New Brunswick. For the past few years, the Brunswick No. 12 mine has been one of the largest zinc mines in the world.IntroductionThe Bathurst area (Fig. I) first had mining production in 1837 when copper was mined from a deposit on the Nepisiquit river (MacKenzie, 1958). The majority of the production, however, has been in recent years from massive sulphide deposits, but there are also other significant operations.Table I is a summary of Bathurst area mineral production, showing concentrator feed tonnages and mill feed grades. The table does not include peat deposits, sand and gravel, dimension stone or rock quarries. Figure I is a general geology map of the Bathurst area, indicating deposit locations. The deposits are divided into four categories: massive sulphide, vein, gossan and other. The deposits in each category are described in chronological order of exploitation."

Jan 1, 1995

By Juergen Antrekowitsch, Stefan Steinlechner

"Waelz oxide from steel mill dust recycling is usually sold to the primary zinc industry, where it is first charged to the roasters to eliminate the remaining fluorides and chlorides. This limits the overall amount of secondary materials which can be used because of different operating problems in the roasters. Another option, in the case where the halides are low, would be direct leaching with low or medium concentrated sulphuric acid. Unfortunately, because of the carryover of some steel mill dust, iron is also present in the Waelz oxide, reaching contents up to 5 wt.%. Since the objective is to treat the solution more or less directly by electrowinning, with only a few simple preliminary purification steps, iron in the solution is a very important factor. Various trials have been done to investigate the dissolution behavior of the iron contained in the Waelz oxide. Although the zinc extraction should reach a maximum, all other elements, especially iron, should be low. This paper describes the results of our research in this area and offers possible options for Waelz oxide utilization. There is also a focus on how other elements, present in the material, influence the dissolution behaviour of zinc and iron, and whether a loss of zinc is unavoidable, if low iron dissolution is required.INTRODUCTION One of the most important secondary zinc resources is the zinc oxide originating from steel mill dust recycling. For the treatment of high zinc containing steel mill dusts, the Waelz kiln process is the so called “best available technology” and it dominates the industry, with roughly a 90% market share. The product Waelz oxide contains mostly zinc oxide, but it also contains lead compounds and halides due to evaporation with the zinc. In addition, it contains iron and some slag compounds due to mechanical carry-over. The presence of halides limits the use of the material as an alternative concentrate for primary zinc electrowinning. Such halides can be reduced to a certain extent by washing and/or solvent extraction (see following chapter). Although lead is not troublesome and theoretically represents a second recoverable valuable metal, iron is unwanted and causes additional problems during leaching. Even though Waelz oxide is generally a highly welcome input material in primary zinc metallurgy, due to its high zinc content, it still contains halides, and in the majority of cases, the oxide must first be treated in a roasting process. Different circumstances, like accretion formation because of the lead and halogen compounds as well as unwanted cooling effects in the roaster, limit the amount of Waelz oxide which can be substituted for the primary concentrate. Another, even more limiting factor, is the allowable concentrations of chlorides and fluorides in zinc electrowinning, the last step in the primary zinc processing route (Ruetten, 2011)."

Jan 1, 2016

A study was made to determine the effect of increasing concentrations of dissolved oxygen on the floatability of galena pyrite and chalcopyrite. Adsorption, flotation and contact-angle tests were done in deoxygenated, in air-saturated and in oxygen-saturated solutions. The results showed that the adsorption of collector increased as the concentration of oxygen increased. Adsorption followed the exponential law r = kC'/"• Discontinuities in the curves were observed after the adsorption of several monolayers of collector. Although adsorption increased with increasing oxygen concentration, the floatability of the pyrite minerals did not increase, because oxidation had adverse effects on the floatability of these minerals. The floatability of galena was maximum in oxygen-saturated solutions, pyrite was depressed and chalcopyrite was also slightly depressed. Contact-angle tests proved that a bubble could not be attached to large flat surfaces in deoxygenated solutions, because sufficient surface free energy was not available for adhesion after the deformation of the bubble. In the presene of air, all the minerals yielded the same maximum angle of 72 degrees, characteristic of isopropyl xanthate.

Jan 1, 1970

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By I. G. L. Sinclair

"ABSTRACTTill geochemistry was the principal exploration tool employed by Selco in the investigation of a zinc prospect in Lanark Township, Ontario. The geochemical studies were undertaken after the discovery at surface of marble boulders containing bands of sphalerite and lesser amounts of galena.The source of these mineralized boulders was sought by means of B-horizon soil geochemistry, followed, where appropriate, by back-hoe trenching and till sampling. The thickness of the tiff in this part of Ontario seldom exceeds 3 m or 4 m and it was generally possible to sample complete profiles of the till and thus to obtain detailed information concerning the dispersion of zinc. Drilling and trenching at the up-ice extremity of the zinc dispersion trains showed the source of the float to be sub-economic bands of sphalerite in the Grenville marble. IntroductionTill geochemistry was used extensively by Selco during the period 1975 through 1980. It was the principal exploration technique employed in a program seeking carbonate-hosted lead-zinc deposits of the Balmat-Edwards type in the Grenville rocks of southeastern Ontario. This paper describes the use of the method to locate the bedrock source of a group of sphalerite boulders found at the surface near the village of Hopetown in Lanark Township (Fig. I) . Geochemical investigations at this locality were the subject of a previous publication by the author (Sinclair, 1979).All of the analytical work related to this project was done by Bondar-Clegg & Co. Ltd. in their Ottawa laboratory. In all cases the -80 mesh fraction of the till was analyzed. The total zinc content was determined by atomic ab sorption spectrometry after hot aqua regia digestion; readily extractable zinc was determined by atomic absorption after samples had been cold-leached for 18 hours in an ammonium citrate hydroxylamine hydrochloride solution, the pH of which was adjusted to 8.5"

Jan 1, 1986

By R. J. Allan

"CANADA HAS A GREATER LAKE AREA than any other country. Discountin the Great Lakes, this fresh-water area, mainly in the Canadian Shield, is listed as approximately 300,000 sq. mi. Densities of lakes range up to 7,500 in a 5,294-sq. mi. area of the Shield, southwest of Reindeer Lake, Saskatchewan. Five areas chosen randomly from the Shield (Figure 1) contained sufficient lakes to provide samples at a density of at least one per 10 sq. mi. Regional geochemical surveys in the Appalachian area (Nova Scotia, Boyle et al., 1958; New Brunswick, Boyle et al., 1966) and in the Cordilleran area (Yukon, Gleeson, 1965) of Canada and in many other areas of the world have relied heavily on analyses of stream sediments. These surveys show that sampling of material related to the drainage system reflects the over-all trace element content of the rocks and surficial deposits in the drainage basin. In the Shield, the classic types of dendritic (and other) stream systems found elsewhere in the world are very rare. However, impeded and disorganized stream systems that abound with lakes can provide the exploration geochemist with an ideal composite drainage system sample in the form of lake sediment. This paper attempts to demonstrate the feasibility of, and review the theory and problems involved in, the use of lake sediment as a regional geochemical exploration medium. Most of the references to field examples are taken from a regional survey using lake bottom sediment as the sample medium over 1,500 sq. mi of the Coppermine basalt group and adjacent rocks (Figure 2). During this regional survey, detailed sampling of several lakes was carried out and the results are referred to at appropriate places in the text."

Jan 1, 1971