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By M. Hekmati, M. R. Garmsiri, S. M. Hosseini

"SAG/AG mills have been most common choice in grinding circuits last decades. In the most cases, at the discharge of SAG/AG mills, a trommel screen is used that is equipped with baffles to provide appropriate residence time and improve separation efficiency. Using baffles, with the resultant maintenance requirements could lead to decrease in mill availability. In this research, an innovation in the structure of baffles of a trommel is presented. The results show that using new baffles led to 67% decrease in SAG mill downtime due to problems of baffles and 80% decrease in fine particles on recycle conveyor.INTRODUCTIONComminution is a vital operation in mineral processing circuits and it helps to achieve a certain level of fineness in the ore material. About 60-80 % of the overall energy used in mining is consumed in comminution, and this is the reason that much research has been performed in this field (Kochnev, 2008).During the last decades the configuration of grinding circuits has been changing due in large part to the decrease in the grade of mineral resources and the need for large scale, energy efficient processes. The previous configuration of conventional grinding circuits was based on parallel primary circuits (mostly using ball mill), such as the grinding circuit of Sarcheshmeh concentrator plant no.1 (Figure 1). The new configuration of grinding circuits is based on using SAG/AG mills, such as Shahrebabak concentrator plant (Figure 2), sometimes incorporating new technologies like the HPGR. Nowadays, application of new configuration of grinding circuits using large SAG/AG mills up to 40 feet (Allan, Major, Flintoff, Klein, & Mular, 2006), in the minerals industry is continuing increase due to the significant reduction in capital and operating costs, and increase in the plants throughput (Banisi & Hadizadeh, 2007)."

Jan 1, 2012

By A. Boucher, D. Marcotte

"Abstract- The accepted practice for the estimation of thin (2D) vein deposits recommends the use of the grade x thickness service variable (i.e., the accumulation). Grade estimates are obtained indirectly by the estimated accumulation/estimated thickness ratio. This practice stems from the varying support (thickness) problem and the resulting non-additive nature of the grade variable. We compare the actual performance of the direct grade estimation approach used by some practitioners to that of the indirect approach using accumulation. Our simulated and real data indicate that the direct approach is more accurate for point grade estimation where the grade-thickness correlation coefficient is positive (and vice-versa). Moreover, the relative gain of the direct method increases with the (positive) correlation coefficient. This finding contradicts common thinking that the indirect approach should be the preferred method where grade-thickness correlation is strongly positive. Also, for a given positive grade-thickness correlation, the relative gain of the direct method increases with the coefficient of variation of the grade and thickness. Résumé - L’estimation de veines minces (2D) minéralisées est normalement réalisée à l’aide de la variable auxiliaire épaisseur x teneur (i.e., accumulation). Les estimés des teneurs sont alors obtenus indirectement du rapport accumulation estimée/épaisseur estimée. Cette pratique découle du problème du support variable pour la teneur, l’épaisseur de la veine, qui fait que la teneur est alors une variable non-additive. Nous comparons les performances de l’estimation directe de la teneur, utilisée par certains praticiens, à celle de l’approche indirecte. Pour l’estimation ponctuelle des teneurs, nos données simulées et réelles indiquent une meilleure justesse de l’approche directe quand la corrélation teneur-épaisseur est positive (et vice-versa). De plus, le gain relatif de la méthode directe s’accroît avec la valeur de cette corrélation (positive). Ce résultat contredit l’opinion répandue que l’approche indirecte devrait être utilisée en présence de forte corrélation positive de la teneur et de l’épaisseur. Nous montrons également que pour une corrélation positive teneur-épaisseur donnée, le gain de l’approche directe augmente avec les coefficients de variation de l’épaisseur et de la teneur."

Jan 1, 2001

By Jan E. Nesset, Phillip J. Mackey

"Studies have shown that there is a correlation between commissioning and start-up time, i.e. time to reach full plant design capacity, and the degree of innovation and technical/engineering uncertainty in the project design. The paper describes the types of start-up curves for plants according to the level of technology or uncertainty in the process design. The need to properly describe and understand the commissioning and start-up time is examined using these curves and the importance on project success is highlighted. A number of case histories of recent mining and metallurgical projects are also reviewed. Finally, the paper reviews how to better assess the level of start-up uncertainty associated with a project and makes suggestions for decreasing the commissioning time due to technological risk.INTRODUCTIOThe start-up of a new mining and metallurgical facility, a much anticipated event, is a critical step in the life of such a project. Achieving a successful start-up and reaching the design capacity on-time requires careful planning, a thorough understanding of the key technological and engineering components involved and a well-trained and adequatelystaffed start-up crew. In this paper, some of the aspects related to start-up of a mining/metallurgical project will be explored, and in particular, the impact of the technology component will be examined. In order to illustrate this, a number of case histories based on recent mining and metallurgical projects will be discussed. Ways of assessing and understanding the uncertainty associated with technological issues related to start-up of a mining and metallurgical plant will also be examined.The history on mining and metallurgy is full of success stories of great mines and mills that are now considered “company makers” (well known examples of such successes include the Horne mine for Noranda which had a 1 year start-up in 1926-27, the Dome mine for Placer Dome, the Grasberg deposit for FMI in Indonesia). Less well documented are specific studies relating to plant start-ups and what constitutes a success or a failure, however there are a few notable references in the literature and these will be reviewed."

Jan 1, 2003

By R. L. Armstrong, C. I. Godwin, V. M. Kruan

"The Scheelite Dome tungsten-bearing skarn property, central Yukon Territory, is in metasediments in contact with a quartz monzonite intrusion. Contact metamorphism to biotite-muscovite- andalusite hornfels and calc-silicate hornfels is superimposed on low-grade regionally metamorphosed rocks represented by quartz-mica pelitic schist and muscovite-biotite pelitic schist.Metasediments are likely Precambrian in age, even though Rb-Sr whole-rock analyses indicate an early Paleozoic age (511±41 Ma); this apparently too young radiometric age is due to partial loss of radiogenic strontium during regional metamorphism. The minimum age of the quartz monzonite intrusion is Cretaceous at 90.4±2.6 Ma (K-Ar on biotite) and its initial 87Sr/86Sr ratio is 0.7121. The high initial ratio of the intrusion is due to the addition of radiogenic strontium from the metasedimentary country rocks and perhaps an underlying older basement.Scheelite-pyrrhotite-chalcopyrite mineralization occurs in diopside-zoisite skarn pods within the calc-silicate hornfels near the quartz monzonite intrusion. The source for lithophile tungsten is probably the same as for the granitic magma, namely Precambrian sialic basement.IntroductionThe Scheelite Dome tungsten skarn property is within the Mc-Questen map-area (NTS: 115P/16),28 km northwest of Mayo, Y.T., at latitude 63°47' north and longitude 136°15' west. The property can be reached by helicopter or by four-wheel- drive vehicle from Mayo.This paper summarizes the geology of the Scheelite Dome property, which has been described in a general way by Little (1959) and Cathro (1969). Geological mapping and sampling were done by the first author (nee Steffler) during June 1979. Field work was supplemented with detailed work at the Department of Geological Sciences of The University of British Columbia during 1979 and 1980 (Steffler, 1980). Whole-rock chemical analyses were done by Cominco Ltd."

Jan 1, 1982

By A. Sargeant

This paper evaluates the application of post consumer glass as a cementing agent in underground mine backfills. The underlying theory indicates that glass is pozzolanic and, when used in a finely divided form, behaves as an activator to generate binding products, thus contributing to the development of backfill strength. The objective of this study was to evaluate the strength performance of backfills when Normal Portland Cement is replaced with various percentages of post consumer glass. The study evaluated the performance of backfills prepared using tailings from three mines. Each backfill was prepared using unique recipes, and were evaluated at cure times of 7, 14, 28, 56, 112 and 224 days. Laboratory work involved visual, physical and chemical material characterization followed by strength evaluations. Results of strength assessment revealed that backfill prepared with glass is reactive and can contribute to the strength of backfill. The results also indicated that the reactivity of glass may be affected by the incorporation of slag within the recipe, the availability of lime and the level of hydration of the binders. The study concluded that, at 15 % glass replacement of NPC, backfill prepared with mine tailings, NPC and glass can achieve improved or equivalent strength performance compared to backfill prepared tailings and NPC alone.

May 1, 2007

By M. P. Rennick, D. M. Burton

Abstract -The Murray Brook massive sulfide deposit, which was the first geochemical discovery in the Bathurst camp, is one of the largest sulfide deposits in the area. The massive sulfides are hosted by quartzose metasedimentary rocks in the lower part of the Ordovician Tetagouche Group. This thick succession of sedimentary rocks is overlain conformably by felsic volcanic rocks, and is structurally overlain by mafic volcanic rocks. The massive-sulfide body is polydeformed, but primary metal zoning is still discernable and may permit future exploitation of discrete lead-zinc and copper zones. Although it was discovered in 1956, the deposit was not developed unti11989, when Murray Brook Resources commenced processing of gossan containing precious metals. Recovery of gold, silver, and mercury is accomplished by indoor vat leaching on a year-round basis.

Jan 1, 1992

By C. G. Williams

This paper describes the planning, development and operation of the Highvale Mine to supply coal to both the existing Sundance and the approved Keephills thermal power plants of Calgary Power Ltd. Reference is also made to the company 's Whitewood Mine, which feeds the Wabamun thermal plant .

Jan 1, 1979

By Anil K. Beersing

Effective drainage systems are required for reclamation of mine-disturbed areas to control surface water runoff and avoid excessive erosion. For the conventional structural design approach, armouring material necessary to satisfy the design criteria should not move during the design flood event since displacement would uncover the erodible underlying materials. This paper discusses an alternative geomorphic approach for designing drainage channels and watershed landscape. The approach is based on quantitative studies of geomorphic processes operating in a watershed. A design based on the geomorphic approach replicates the configuration, channel regime, sediment volume and hydrology of natural and mature drainage systems. Movement of some armouring material is acceptable in such an approach because the channels are allowed to mature by natural degradation and aggradation, with erosion rates comparable to the natural environment. The key advantages of a geomorphic approach over a purely structural approach include reduced sizes of armouring material, geomorphologically sustainable landscapes, ?walk-away? or maintenance-free design and reduced liability in the future. The geomorphic approach is illustrated using the example of a coal mining operation in northwest U.S.A. The paper discusses field data collection, design criteria, typical design details, and construction methods.

Apr 1, 2005

By Jiuhua Xu, Shuiku Jia, Weiren Sun

"Abstract -The Jinqingding gold deposit, situated in the east Jiaodong Peninsula of Shandong province, is typical of the pyrite-quartz vein gold deposits in the Muping-Rushan gold belt of China . The gold deposit is controlled by a great NNE fracture zone and is composed of several lenticular orebodies within the fracture zone occurring in the Kunyushan granite massif. The Kunyushan granite massif was formed by the replacement of the Archean Jiaodong group.The main minerals associated with gold are pyrite, chalcopyrite, galena and sphalerite; the gangue minerals are dominated by quartz, sericite, microcline and calcite. The mineralizing event can be divided into four stages: (1) pyrite-quartz; (2) quartz-pyrite; (3) siderite-polymetallic sulfides; and (4) calcite-quartz. Gold occurs mainly as native gold and electrum in stage 1 and stage II. There are some evident differences between pyrite from major stages of gold mineralization and that from minor stages; these include differences in crystal forms, size and composition of fluid inclusions.Wallrock alterations consist of sericitization, silicification, pyritization and potash-feldspar alteration. Five alteration zones can be distinguished from unaltered granite (zone 0) to vein lodes (zone IV). Au and Ag increase rapidly from zone 0 to zone IV, Cu increases continuously, while Pb and Zn increase slowly. R-type geological factor analysis indicates that the Au, Ag, Cu, Pb and Zn bear a close relationship to wallrock alteration."

Jan 1, 1994

By Carl Bertrand, Patrice Nadeau, Claude Bazin

"Rio Tinto Fer et Titane processes the ore extracted from the Lac Tio orebody to concentrate the hemo-ilmenite (FeO.TiO2-Fe2O3) mineral that is subsequently smelted to produce pig iron and titanium oxide slag. The ore is crushed, heat treated (roasted) and concentrated using dry magnetic separators. This paper describes a model to predict the magnetic susceptibility of the roasted ore and its behaviour in the magnetic separation plant. The model uses a classification of the ore as a function of the size and magnetic susceptibility of the particles. A subsequent division into mineral species allows the simulation of the magnetic separation process. The model is used to assess various operating options when process disturbances occur.INTRODUCTIONOre processing operations consist of ore size reduction followed by the recovery of valuable species in a concentrate that is subsequently sold for its minerals or metal content. The concentration processes are based on the physical and/or chemical properties of the minerals contained in the ore. Flotation is typically used to recover minerals of base metals such as copper, zinc, lead or nickel. Iron ore and other dense minerals are typically concentrated by gravity separation processes. Magnetic separation uses the magnetic properties of the minerals to concentrate magnetite and other minerals, to clean coal concentrate and to recycle ferrosilicon for dense separation processes (Brophy, 1985).Magnetic separators can be divided into low and high intensity separators and high gradient magnetic separators (Gillet, 2008). Most of the low gradient magnetic separators are built as rotary drums that are operated in wet or dry conditions. Dry magnetic drum separators are used by Rio Tinto Fer et Titane in Sorel-Tracy, Canada to concentrate hemo-ilmenite from the ore extracted at the Lac Tio Lake mine near Havre St-Pierre, Canada. The analysis of production data suggests that process improvement could be achieved by identifying key variables for the control of the magnetic separation circuit and/or by modification to the circuit flowsheet. The use of a process model was considered to be an effective approach to conduct a preliminary analysis of the circuit with a view toward process optimization. However, the literature contains few detailed studies dealing with the modelling of magnetic separation processes."

Jan 1, 2011

By Alan Reed

"Afton Mines Ltd. (N.P.L.) operates an 8500-tpd open-pit copper-gold mine near Kamloops, R.C. The pit is currently 480 feet deep and will reach an ultimate depth of 800 feet. The east, south and west walls of the pit are composed of Triassic andesites (Nicola Volcanic Formation) and contemporaneous sub-volcanic intrusions of micro-syenite, microdiorite, diorite and picrite-basalt (Iron Mask Pluton). The north wall of the pit consists of Tertiary sandstones, shales and mudstones (Tranquille formation) and dacitic dykes, sills, flows and tuff s (Kamloops Volcanic Formation).The Afton copper-gold orebody (30 million tons of open-pit ore with a grade of 1.0 per cent copper, 0.016 oz/ton gold and 0.12 oz/ton silver) occurs within the Triassic Iron Mask Pluton adjacent to its faulted contact with Tertiary rocks. The Triassic-Tertiary contact is a complex fault system dipping 65 degrees southward and causing the Triassic rocks to overlie the Tertiary rocks. The detailed trace of this contact is very intricate due to the mutual interference of three principal fault systems.The dominant geological structures in both Triassic and Tertiary rocks are faults striking WNW and dipping 65 degrees southward, i.e. sub-parallel to the orebody (strike faults). Cross faults and oblique faults are abundant and highly significant in some sectors of the pit. The Tertiary sedimentary rocks show an early series of northwesterly plunging folds deformed by a later series of northeasterly striking folds. Major lithological and structural boundaries divide the pit into 8 structural domain s within which the pitwall slope stability is controlled by the local geological structures and lithology.Assay data from production blasthole samples and exploration diamond drillhole samples show a log-normal frequency distribution, with a fairly low relative variance. Variograms computed from production blasthole samples show good continuity with elliptical horizontal zones of influence which are truncated by the major faults that bound the ore zone."

Jan 1, 1983

By Sepulvedam Jaime E., Levi Guzmán Rivera

"Grinding media consumption rates and their dependence on key operating conditions in semiautogenous grinding mills is analyzed on the basis of a detailed mathematical model recently developed by Moly-Cop´s specialists which describes and takes into account the three primary media consumption mechanisms, namely: abrasion/corrosion, surface spalling and impact ball breakage. The influence of key mill operating conditions – such as ball filling, discharge grate opening, mill speed, lifter profile, and ball quality – on their corresponding grinding media consumption rates is explored via a variety of model simulations, discussing in every case the independent contribution of each of the indicated consumption mechanisms to the estimated total ball consumption rate.INTRODUCTIONA thorough understanding of the independent contribution of each grinding media wear mechanism is extremely important, especially in semi-autogenous grinding (SAG) operations where macrowear (spalling) and ball breakage cannot be ignored or neglected. The high impact conditions imposed in modern SAG milling environments has created serious challenges for grinding media manufacturers since their products must be able to perform with minimal breakage and surface spalling.GRINDING MEDIA WEAR MECHANISMFor SAG milling operations, at least 3 different mechanisms have been identified as the main contributors to the observed overall grinding media consumption, here referred to as: abrasion / corrosion, ball breakage and surface spalling.Wear by Abrasion/CorrosionThe abrasive/corrosive wear mechanism has been discussed in depth in previous publications (Benavente Hector, 2007; Guzman Levi, 2014; Sepulveda and Morrow, 2014). The most widely accepted approach to mathematically characterize the consumption (wear) kinetics of grinding media in rotary tumbling mills is known as the Linear Wear Theory (Prentice, 1943; Norquist, 1950; Sepulveda, 2004) which claims that—at each instant 't' after a grinding body enters the mill load—the rate at which the body loses weight is directly proportional to its surface area exposed."

Jan 1, 2016

By P. J. Mehrfert

"Recovery of mineralized coarse particles is notoriously low in conventional concentrators that treat copper porphyry ores. The application of coarse particle flotation techniques has the potential to achieve comparable metallurgical performance at significantly coarser primary grind sizings. ALS Metallurgy has been conducting both internal research and commercial test programs to investigate the potential of Eriez HydroFloatTM technology on copper sulphide ores. Test data indicates that significant improvements in the recovery of copper sulphide bearing particles between 200µm to 850µm can be achieved using Hydrofloat technology compared to conventional flotation techniques. This paper summarizes the results from a selection of test programs that includes recovery by size data from both conventional flotation and HydroFloatTM tests. An explanation of the apparatus and test procedure will be given. Mineralogical analyses of the test products and characteristics that limit metallurgical performance will be discussed.Description of Apparatus and Test ProtocolThe HydroFloatTM laboratory cell is a clear plastic column with an internal diameter of 14 cm. Water and air are introduced to the cell through a circular manifold located in the lower portion of the cell. The cell has a conical bottom which directs slurry to a pinch valve that controls the discharge of tailings. Feed solids are introduced to the upper portion of the cell in slurry form. The cell is operated in a manner such that the manifold water creates a teeter bed zone of suspended solids in the middle portion of the cell. Tailings exit the bottom of the cell at a high pulp density, and most of the introduced water overflows the top of the column and is collected in a launder. Particles with a hydrophobic surface may attach to air bubbles that percolate through the teeter bed, rendering them sufficiently buoyant to be transported to the overflow launder.Three significant features of this arrangement enhance the potential to recover coarse, low grade particles by flotation techniques. Firstly, the hindered settling conditions created by the rising column of water allow coarse particles to become buoyant once attached to a modest sized air bubble. Secondly, the flow conditions within the cell are relatively quiescent compared to a conventional flotation cell that utilizes an agitator. This allows particles that have limited hydrophobic portions of their surface, due to a low content of exposed sulphide mineral, to maintain a somewhat fragile attachment to air bubbles long enough for successful recovery to the overflow. Finally, the absence of a froth phase at the top of the cell allows particles attached to air bubbles to immediately exit the vessel, reducing the potential to drop back into the pulp phase as bubbles burst or coalesce."

Jan 1, 2017

By L. Yacher

Most metallurgical plants already have sophisticated control systems as well as a process-historian that manage thousands of real-time and historical variables. There exists a huge potential for operational improvement through the inference of patterns, correlations and cause-effect relationships within these records. The ability to run online and offline advanced multivariate statistical analyses represents a great potential for the mining industry, in various areas such as cathode quality improvement in an SX/EX plant, the analysis of the correlation between the ore characteristics and the mill throughput, the determination of early failure alerts for major equipment, etc. The background theory is described, as well as some practical experiences of operations in Chile and Peru. Cu2007

Jan 1, 2007

By Barry James

Energy, like labour and materials, is one of the basic production inputs in the industrial minerals industry. This paper discusses the significance of the changing energy situation in Canada as it affects the industry. It is apparent that the importance of energy as a management concern has increased considerably since 1973. The importance placed on energy management today will undoubtedly be an important factor in determining company and industry sector strength and profitability tomorrow.

Jan 1, 1978

By Rodney G. Orr, Phil Robertshaw, Roland Loewer, Klau Lehnert-Thiel

This paper documents the 1988 discovery and subsequent evaluation (to 1991) of diamond bearing kimberlites in the Fort à la Corne area, Saskatchewan, by Uranerz Exploration and Mining Limited. Cameco Corporation began participating as a joint venture partner (50%) in mid-1989. The first indications that kimberlite-type intrusions might exist in the area carne from Geological Survey of Canada aeromagnetic maps. Because of the overburden thickness (over 100 m), magnetometer surveys continue to be the main exploration tool in defining pipe locations and sizes. Magnetometer surveys in varying levels of detail have outlined one main cluster and two sub-clusters, the main group being some 10 km by 50 km in size. In excess of 70 individual targets have been interpreted from the magnetics as probably representing kimberlites. The size range of the individual magnetically-defined bodies is between 1 ha and 74 ha. Proof that the magnetic anomalies were kimberlite intrusions carne in 1989 when each of seven test holes, all drilled on different targets, intersected the potential diamond host rock. The majority of the targets tested were diamond-bearing, with the indicator mineral chemistries suggesting that both peridotitic and ecIogitic diamond parageneses could be expected. To date, 18 individual kimberlite bodies have been drill-tested. A total of 39 bulk samples, amounting to 186 t (representing 360 t of theoretical sample recoveries) were processed in 1990 and 1991. One hundred and sixty diamonds were recovered, averaging 0.04 carats in weight, the largest being 0.6 carats. Most of the bulk sample grades are less than 2 carats/loo t; only three bulk samples have higher grades, the best being approximately 10.5 carats/l00 1. The diamonds are predominantly gem-quality stones.

Jan 1, 1992

By Hilden. M.

"As the Cadia mill was the first 40ft diameter SAG mill, commissioned in 1998, its performance, liner and discharge design attracted considerable international attention. Twelve years on, the liner design and the control philosophy are being readdressed to further improve the mill’s performance. A comprehensive series of 3D liner scans, over life of the liner, have been used to calibrate liner mass loss and progressive changes in the liner profile. This data is being used to provide true charge mass and mill filling, plus progressive trajectory profiles over life of liner. This information, along with measures of mill performance over liner life, is being used to select the optimal operating conditions as the liner wears, and hopes to inform future liner design. INTRODUCTIONSince the Cadia mill was the first 40ft diameter SAG mill, its performance, liner and discharge design has attracted considerable international attention, as reported in previous SAG conferences. The mill experienced particular challenges with regard to pebble and slurry discharge, which necessitated a discharge redesign, incorporating a considerably greater pebble port open area and curved pulp lifters (Hart, Valery, Clements, Reed, Song & Dunne, 2001). Packing between lifter bars on the shell liner was found to dramatically reduce mill throughput over the first half of the liner life. In response, the liners were redesigned to a 2/3 spacing so as to open up the space between lifters. Due to ongoing high liner wear issues, the liner was redesigned based on the discrete element modelling (DEM) of Conveyor Dynamics conducted by Nordell and Potapov (2001). This aimed to maintain mill throughput with new liners and provide an extended liner life. This design was kept proprietary for many years, so has not been open to review."

Jan 1, 2012

By Michael K. Watkeys, Charlesworth. E. GUY, Jacobus E. Potgieter, Anhaeusser. Carl R., Roger L. Gibson, Alexander F. M. Kisters

Abstract - Intrusive features of cupriferous noritoids from the deeply eroded Proterozoic granite-gneiss terrane of the Okiep Copper District in South Africa illustrate the emplacement of basic magmas into a mid- to lower-crustal environment. The small, easterly trending intermediate to basic intrusions of the so-called Koperberg Suite display a wide variety of geometries, occurrence and emplacement modes, including dike-, sill- and plug-like bodies. Coeval granulite-facies metamorphism, partial melting and ductile deformation of country rock gneisses during intrusion of the basic magmas led to emplacement and dilation processes of the intrusions which differ significantly from those described for dikes and sills at shallow crustal levels. Regional tectonic stresses are largely negligible due to very low differential stress (?1 - ?3) during deformation and intrusion, which permits emplacement at high angles to the principal compressive stress and which follows favorably inclined structural anisotropies. Dilation of the basic intrusions is largely determined by compositional differences of host rocks and occurs by thermal erosion, i.e., assimilation of wall rock gneisses. Low length-to-width ratios of basic to ultrabasic dikes and predominantly diaper -like outlines of mesocratic bodies are indicative of low viscosity contrasts between the mafic magmas and high-grade metamorphic host-rock gneisses. Buoyancy-controlled ascent of the basic to intermediate intrusions is expressed by a broad compositional zoning of basic bodies with respect to the granite-gneiss stratigraphy. Various intrusion modes within the stratigraphic column of the granite-gneiss sequence reflect a lithological and structural stratification of the seemingly homogeneous granite-gneiss terrane.

Jan 1, 1994

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006