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By C. J. R. Braithwaite, Giancarlo Rizzi

"Abstract-The Navan zinc-lead ore deposit (70 million tonnes) is hosted principally (97%) by the Meath Formation (Lower Carboniferous, Courceyan, Navan Group), comprising a lower, mainly carbonate mudstone unit, the Stackallan Member, and an upper grainstone-dominated unit. The Stackallan Member, about 60 m thick, comprises about 35 peritidal cycles including an oolitic grainstone interval. Grainstones forming the upper part of the formation, about 150 m thick, comprise at least six shallowing-upward ramp cycles. Emergence horizons are indicated by subaerial dissolution surfaces, in situ breccias, and a single palaeosol.Most dolomitization at Navan is confined to the Meath Formation. The linear dolomite body, trending NE-SW, has a flattened, laterally limited, tabular geometry in cross-section, suggesting that dolomitizing fluids initially rose vertically, cross-cutting stratigraphic and sedimentological boundaries, although fluid flow was subsequently controlled by these features. Three stages of dolomitization are indicated by textural relationships, cathodoluminescence (CL), oxygen isotopes, and fluid inclusion data. Stage 1 crystals, with generally dully luminescing cores and up to six overlying subsidiary zones, are the main replacive phase. Crystal surfaces are commonly corroded and overlain by bright stage 2 rhombs (which also form new nuclei lining molds and fractures). Three subsets of zones are present in stage 2 crystals: bright, non-luminescent, and dull; these are locally separated by additional corrosion surfaces. Stage 3 comprises relatively large baroque crystals, generally dully luminescent but with up to seven sub-zones. Isotopic and fluid inclusion data suggest growth of successive stages from waters which became progressively hotter (60°-160°C).The distribution of the ores follows the dolomite trend. Ores were precipitated between Stages 1 and 2 of dolomite growth, following Stage 2, and also during the nucleation and growth of Stage 3 crystals. Dolomitization and mineralization appear to have been temporally and genetically related. The cyclic sedimentation of the host rocks, which accentuates lithological and petrographical contrasts between depositional units, controlled dolomitization. The relationship between dolomitization and mineralization, which is closely associated with faults, provides powerful exploration criteria. The recognition of these features in limestones elsewhere in the Irish ore field may point toward unrecognized zinc-lead prospects."

Jan 1, 1997

By D. Kim

Kennecott operates one of the largest and most modern copper refineries in the world at Magna, Utah, USA. The inputs to the refinery are anodes produced at Kennecott Smelter, which has extremely high contents of lead and bismuth. In order to minimize undesired effects in the electrolytic refining process, unwanted impurities, especially bismuth, must be controlled. This paper describes the process development of practicing state-of-the-art quality control and presents the pilot test results of using the MRT Technology for Bi production.

Jan 1, 2007

By Dave Bulled, Khiratt Husain

"The use of High Pressure Grinding Rolls is gaining significant interest as a replacement for SAG milling in the comminution of hard rock ores because of the potential for reduced costs in terms of energy and grinding ball consumption. Estimation of expected energy consumption for fullscale operations has conventionally involved the testing of a few fairly large samples in pilot scale HPGRs. This paper describes the development of a small-scale batch test method for determining a work index for HPGR of a large number of samples that can be used to show the variability of the ore as an integral part of a geometallurgical approach to circuit design and production forecasting.The test equipment that was developed comprises a hydraulic press with adjustable pressure operating on small batches of ore in a locked cycle test procedure. A work index measurement was determined that links the specific energy consumed in the test to the breakage achieved such that the index can be used to predict comminution energy requirements.The measurements were calibrated against laboratory scale HPGR equipment to develop a model for design and forecasting that includes crushers, HPGRs and ball mills in a complete comminution circuit.INTRODUCTIONEstimation of the expected energy consumption for full-scale HPGR operations has conventionally involved the testing of a few fairly large samples in laboratory and pilot scale machines (Danilkewich, 2006). With the financial input of five mining corporations, SGS Lakefield Research has developed a small scale test capable of providing relevant information on the variability of energy consumption and size reduction from drill core samples. It is our intention that the values measured in the test will be scaled up, through benchmark comparison with pilot sized and full sized HPGR units, to allow plant design and throughput forecast on a block by block basis of the mine plan using a new CEET program. CEET® (an acronym for Comminution Economic Evaluation Tool) is an advanced grinding design and performance predicting tool that uses energy relationships to model the performance of SAG / Ball mill circuits."

Jan 1, 2008

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By B. N. Church, A. R. Pettipas

"The second vertical derivative method of processing aeromagnetic data from low level helicopter surveys yields results correiatable with the known geology and may be utilized to indicate possible targets for future exploration in the Silver Queen and Equity Silver mines areas, near Houston in central British Columbia . The principal zones of alteration associated with mineralization, known from detailed mapping, are further delineated and extended in a way not possible by a cursory examination of the original magnetic data.IntroductionThe second derivative method of processing aeromagnetic data is a long established procedure used to enhance the short wavelength content of the magnetic fields. Some recent exam pies of the use of the second derivative technique have been published by Chandler (p. 385), Sun Yunsheng et al. (p. 424) and Yarger (p. 223) in Hinze, 1985. According to theory, the ""second vertical derivative"" is closely related to the rate of curvature of magnetic (or gravity) fields and is particularly useful in resolving and sharpening local anomalies. The contours on second derivative maps may coincide with important features such as lithological boundaries, faults and mineralized zones.In the Houston area, central British Columbia, aeromagnetic data supplied by local mining companies provide a ready base for analyses. Examples are data sets for the Silver Queen and Equity Silver mines centred 35 km and 34 km south and southeast, respectively, from Houston (Fig. 1), (Cochrane, 1970 and Church, 1985)."

Jan 1, 1990

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By A. Kapoor, L. Morin, S. Mortazavi, P. Béedard, Gould. W. D., A. Kuiper

The degradation of thiocyanate in a simulated gold mill effluent was studied using a laboratory scale rotating biological contactor (RBC). Complete SCN- removal was obtained at temperatures of 8 and 12°C, and a hydraulic retention time of approximately 3.3 h. The NH4+ produced by thiocyanate hydrolysis was oxidized by nitrifying bacteria to NO2 and NO3-. The HS- produced by thiocyanate hydrolysis was chemically and biologically oxidized to elemental S, which was subsequently biologically oxidized to sulfate. Incomplete sulfur oxidation occurred in the RBC, particularly at 8°C and elemental sulfur deposition was observed on the RBC disks. The RBC feed exhibited toxicity to rainbow trout but the RBC was effective in removing the acute toxicity of thiocyanate.

Jan 1, 2005

By J. E. Sepulveda, R. Morrow

"In full scale mineral grinding operations, the steel balls normally utilized as auxiliary grinding media get to be consumed at different specific rates, as determined by 3 basic mechanisms: abrasion/corrosion (wear), impact ball breakage and impact surface spalling, the latter relating to the removal of rather small pieces of steel coming off the exposed surface of the balls due to repetitive impact with other balls in the charge or the surrounding mill liners. In conventional ball milling applications, the clearly predominant mechanism is gradual wear by abrasion/corrosion. In the case of SAG mills, where the make-up balls may be as large as 6”f diameter, breakage and spalling mechanisms are significant contributors to total ball consumption, although not to the extent of overriding wear mechanisms.Ball wear has been well characterized by the Linear Wear Theory, as presented at the last CMP 2014. Impact breakage has been customarily monitored, at the ball manufacturing site, via Drop Ball Tests (DBT) consisting of repeatedly dropping balls from a standard height and accounting for the number of broken balls and the weight loss (spalling) of the remaining unbroken balls. When properly conducted, DBT’s should provide meaningful indications of the breakage and spalling resistance of large diameter balls. The current publication is focused on the interpretation and projection of DBT results to full industrial scale, taking into account all 3 mechanisms of grinding media consumption in SAG mills.INTRODUCTIONA thorough, quantitative understanding of the independent contribution of all active grinding media consumption mechanisms is of the highest practical relevance, particularly in semiautogenous (SAG) milling operations where ball breakage and spalling can not be ignored or neglected, as it has been normally acceptable for conventional ball milling processes. The high severity impact conditions currently imposed in typical SAG mill environments create serious challenges to the manufacturers and suppliers of large diameter (5”–6”) SAG balls, whose products must be capable of surviving such harsh operational conditions with minimum breakage or spalling."

Jan 1, 2015

By Niels Verbaan, Ron Molnar, David Dreisinger

"An acidic chloride leach solution was generated from the treatment of an ore containing the following value elements: silver, gold, indium, gallium, copper, zinc and lead. Iron was also co-extracted into solution as a ferric chloride species. Iron extraction was a significant component of the overall acid consumption of the leaching process. The recovery of iron by solvent extraction and water stripping was investigated. Tri-butyl-phosphate (TBP) was very effective at recovering iron from the leachate. The water strip solution could be decomposed to produce ferric oxide (hematite) and hydrochloric acid for recycle via hydrothermal hydrolysis or pyrohydrolysis.INTRODUCTION The Malku Khota deposit is situated in the eastern part of the Bolivian Altiplano at elevations between approximately 3,800 and 4,580 meters above sea level (Figure 1). The project is located 98 km east-southeast of Oruro, and 85 km south of Cochabamba in a relatively remote area."

Jan 1, 2016

By A. Cabañas

"In this paper, geostatistical techniques are applied to forecast the annual copper price in the short and medium terms (from one to five years ahead). These techniques allow the incorporation of monthly and multivariate information in the analysis and provide more accurate results than traditional approaches, especially as far as the one-year forecast is concerned.A second advantage of geostatistics stems from its ability to assess the uncertainty associated with the unknown future prices, thanks to estimation variances or confidence intervals, depending on the technique used. Such an assessment has a crucial importance in decision-making, from both macroeconomic and microeconomic points of view. IntroductionThe copper price traded in the London Metal Exchange is a relevant parameter for defining macroeconomic policies of producing countries like Chile. It is also a key factor for the mining companies, since fluctuations in the sell price affect the expected financial flows. Due to the amount of money involved in decision-making, it is necessary to have accurate forecasts of the future copper prices and to quantify the uncertainty associated with such prices.This paper focuses on the annual copper price estimation in the short and medium terms, i.e., from one to five years into the future. Henceforth, the word “estimation” will be used as a synonym of “forecast,” according to the geostatistical jargon (Matheron, 1989).Two main approaches, based either on statistics or econometrics, are currently used to forecast commodity prices, but both of them are not very accurate when applied to copper. First, the main methods are briefly reviewed, then the geostatistical formalism will be presented. So far, the latter approach hardly has been used to estimate commodity prices, although it may reconcile both statistics and econometrics via (1) the use of a stochastic approach and (2) the handling of ancillary variables related to the copper market. Another advantage of geostatistical techniques is the ability not only to forecast the copper price, but also to measure the uncertainty associated with it."

Jan 1, 2004

By M. P. Hay

"For a model to be successful it must address the concerns and needs of a target audience. Further, the model must demonstrate the same patterns of behaviour as the real system, and need only be complex enough to meet this objective. If the model is too complex it can become unusable to those who need it most.With this in mind, SUPASIM has been developed for the practical metallurgist requiring only laboratory flotation rate data as input. Some 35+ successful plant simulations have been completed since 1985. The approach of SUPASIM is to characterise an ore, organise information in an understandable way and add structure to the complex flotation situation and hence support the metallurgist to interpret the relationship between variables and optimise the flotation process.The paper describes the basis on which the model was developed and sets out to provide an insight into interpreting laboratory flotation kinetics and their physical meaning in a production plant and the influence floatable gangue has on float performance and plant design. A case study illustrates how the ratio of slow floating mineral to gangue can influence circuit design and improve recovery on a plant scale.INTRODUCTIONThere is an enormous amount of useful data in the results of a laboratory scale rate test. Each variable of fraction and rate, for mineral, metal and gangue has a physical meaning in the plant. The link between float kinetics and the plant in respect of recovery, grade, pulp density, pulp flowrate, residence time, number of stages of cleaning and circuit configuration has been established by the author in the process of developing SUPASIM."

Jan 1, 2005

By W. Beres

Many non-commercial operators are currently faced with the need to operate fleets of legacy gas turbine engines. How long such engines can be kept in service safely, without replacing a significant portion of their aging structural components, has become a growing concern to engine life-cycle managers, due to uncertainties in the remaining lives of critical components of these engines. This paper describes the application of the damage tolerance methodology to predict safe inspection intervals (SII) for critical components of gas turbine engines, using components of a turboprop engine for a transport aircraft as examples. High temperature components of this engine are made of advanced aerospace alloys. The methods of predicting three-dimensional fatigue crack growth at the critical location of turbine discs and spacers using both commercial and in-house developed algorithms are presented. Sensitivity analyses are performed to determine the effect of variations in material parameters on the predicted safe inspection intervals. In addition, spin rig tests performed for both turbine discs and spacers are described. Finally, crack growth rates predicted by numerical analyses are compared to those obtained from spin rig testing and the damage tolerance of the turbine components is assessed.

Jan 1, 2015

By Alain Simard, Andre Gobeil, Sylvain Lacroix, Maurice Rive, Denis Racicot, Pierre Verpaelst

"The Abitibi volcano-plutonic belt forms the major portion of the Abitibi lithotectonic subprovince in the Superior Province. The Abitibi belt is composed essentially of"" (1) approximately 2.7 Ga old volcanic and sedimentary rocks; and (2) gabbro, tonalite, granodiorite and syenite intrusions occurring in well-defined prekinematic ( synvolcanic ), synkinematic and post-kinematic plutonic suites. Most of these rocks are metamorphosed to greenschist facies. Regional multi-phase deformation affects the volcano-sedimentary rocks. Deformation was initiated as these rocks were formed, and peaked at the end of the Keno ran orogeny with the emplacement of granitic batholiths.There are 145 former and current mines in the Quebec segment of the belt. To date, more than 420 Mt of ore have been extracted yielding 1,600 tonnesof Au, more than4,000 tonnesof Ag,4,400,000 tonnes of Cu and 5,300,000 tonnes of Zn. Mineral production is concentrated in geologic domains that approximately coincide with the boundaries of lithotectonic domains. We have compared the geology and mineral deposits of different domains to illustrate their distinct metallogenic signature. Certain domains are dominantly gold-producing (Cadillac-Malartic, Val-d'Or, Caopatina), others are base-metal producers (Matagami and Normetal), while others produce both gold and base metals ( Rouyn-Noranda, Chibougamau, Casa-Berardi-Joutel).Gold is extracted from quartz-rich vein deposits (for example, Val-d' Or), sulfide-rich veindeposits(Cadillac or Chibougamau) and from volcanogenic massive sulfide deposits ( Rouyn-Noranda). Base metals are generally mined from volcanogenic massive sulfide( RouynNoranda, Matagami, Normetal), although certain vein deposits yield base metals (Chibougamau) . Certain sectors are dominantly zincrich (Matagami, Normetal)."

Jan 1, 1989

By M. H. Moys, C. Bhondayi, Eric Tshibwabwa

"The relationship between froth bubble size as represented by intra-bubble impact distances (IID) and flotation performance is investigated. Experiments using an artificial ore comprising of limestone as the floatable component and silica as the gangue material were carried out in pseudo-steady-state circuit. A method to measure IIDs developed by Bhondayi and Moys (2014) was then used to measure froth bubble sizes as a function of froth height, superficial gas velocity and feed rate (pulp residence time). Samples for flotation performance evaluation were also taken. Results indicate that as froth height increases, the average IID values increase resulting in a decrease in limestone recovery while the grade increases. Increasing gas rate results in lower IID values that are accompanied by high recovery and low limestone grade. The effect of feed rate on both flotation performance and average IID values depended on froth depth and gas rate. Average IIDs largely remained the same at the two feed rates investigated.INTRODUCTIONIt is regarded as obvious that froth bubble size distribution (FBSD) will have an effect on plant grade and recovery. As the average FBSD decreases, the bubble surface area flux will increase making possible an increase in recovery and a decrease in grade. The opposite trend will be involved if average FBSD is increased. However: no method for measuring FBSD has been available, so these trends have not been studied in any detail. Bhondayi and Moys (2014) developed a novel technique to measure or estimate froth bubble sizes. Although they established a potential to use this method in understanding froth performance, no data have been presented to assess the correlation between the estimates of bubble sizes and actual flotation performance. In this work experiments are done to establish how the change in froth phase bubble sizes affect flotation performance. Flotation performance will be evaluated using recovery and grade. How water recovery to the concentrate changes with changes in bubble sizes will also be evaluated. It is known that water recovery is approximately inversely proportional to the square of the overflowing bubbles sizes. It will be interesting to establish how the rate of change of bubble sizes changes with water recovery."

Jan 1, 2016

By Z. Mubarok

An overview of the problems encountered the electrorefining of copper anodes containing high levels of nickel and antimony is presented. Our investigations have been focusing on the passivation behaviour of the anodes with high contents of Ni, Sb, Sn, and Pb, the formations of kupferglimmer and floating slimes. The results of linear voltammetry, chronopotentiometry and electrolysis test revealed a noticeable lower resistance of the anodes to passivation in comparison to those with lower contents of Ni, Sb, Sn, and Pb. Anode containing kupferglimmer exhibited oxygen gas evolution during the passivation state. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) indicated that tin can replace and/or join antimony in the kupferglimmer structure. Under specified experimental conditions, floating slimes precipitations took place with high Ni, Sb, Sn, and Pb anodes prior to the end of one anode period.

Jan 1, 2007

By P. W. Jensen

Gold deposits in Interior Alaska are commonly coincident in time and space with reduced, mid-Cretaceous granitoids. The True North deposit of the Fairbanks district is several km from such granitoids, but yields mineralization ages indistinguishable from the Fort Knox granite-hosted deposit. True North, however, resembles sediment-hosted epithermal Au, demonstrating the variability of intrusion-related Au deposits in metamorphic rocks. The True North deposit (14M tons at 1.5 gpt) is hosted within a carbonaceous thrust complex separating eclogite facies from amphibolite facies rocks, located > 5 km from mineralized granite outcrops. The ores contain anomalous Sb, As, and Hg (stibnite is the most common sulfide) with ankerite-sericite alteration in steep NE-striking ?feeder? shears and low angle thrust shears. Nearest hornfelsed rocks are located > 1 km away, and across several high-angle faults. Fluid inclusion data indicates trapping temperatures of ~250C from low-density, low-salinity fluids at P < 0.5 kb. Au was originally present as solid solution in sulfides; minable ores are restricted to the oxidized upper 100 m of the deposit. The considerable differences between this deposit and the temporally equivalent Fort Knox intrusion-hosted deposit indicate no one description adequately characterizes this deposit type.

May 1, 2003

By P. Chu, J. A. Finch, R. Li

"Bubble size plays a key role in flotation. In this paper, we examine the possibility of using passive acoustic sending to determine bubble size. Software was developed based on Short Time Fourier Transformation (STFT) to analyze the frequency of the acoustic signal emitted from the bubble formation event. Bubble size was determined from the Minnaert frequency. The acoustic-determined bubble size responded to reagent dosage, but was less sensitive than that given by imaging. The constraints of the current acoustic approach are discussed.INTRODUCTIONBubble size is an important factor affecting flotation performance. It determines the maximum available surface area for collecting and transporting mineral particles. Of interest for process control (Gorain, Franzidis, & Manlapig, 1995), it can be determined by several techniques, such as image analysis (Grau & Heiskanen, 2002; Hernandez-Aguilar, Gomez, & Finch, 2002); conductivity (Barigou & Greaves, 1992); drift flux analysis using gas rate and gas holdup measurements (Banisi & Finch, 1994); and optical sensors (Randall, Goodall, Fairlamb, Dold, & Connor, 1989). However, all these techniques have drawbacks.Acoustic analysis of the oscillatory behaviour of bubbles to extract bubble size is another possibility (Leighton & Walton, 1987; Pandit, Varley, Thorpe, & Davidson, 1992; Al-Masry, Ali, & Aqeel, 2005; Manasseh & Ooi, 2009; Leighton & White, 2012; Spencer et al., 2012). The fundamental basis is the work of Minnaert (1933) who first correlated the bubble size with its natural frequency, Equation 1:"

Jan 1, 2016

By Jean-Marie Fecteau

The gold mine sector is presently facing low gold prices as well as technological challenges. Its competitiveness and survival will depend on new mining methods and equipment to improve ore extraction. In 1999, Natural Resources Canada has invested new funds over a period of three years at CANMET?s Experimental Mine to establish the Narrow-Vein Mining Project. A team of engineers and researchers specialised in mining, mechanics and electronics engineering are working to meet the critical need of ore-extraction technology. CANMET?s program in mechanisation and automation for narrow vein mining had, prior to 1999, realised several important achievements, many in co-operation with a consortium of mining companies (Soredem). The investment of new funds in this area will contribute to develop technologies to improve the productivity, as well as health and safety conditions of the narrow vein mining industry. Several important impacts of this project will be monitored. Specifically, a database of methods and equipment used in narrow vein mining is being developed. A key thrust is to identify operators? needs with respect to the development and automation of mining methods and equipment. Based on those needs, research and development projects will be created. The main problems identified following meetings with mine operators are described with a few elements of solution and the Web site created for the broadcast of the results is presented.

Oct 1, 2001

By H. Lazreg

This paper presents an evaluation of surface resistivity techniques as a tool for delineating salt-water intrusion in Shippegan, N.B. The study consisted of resistivity profiling, resistivity soundings and a limited number of induced polarization soundings in selected areas in the Province of New Brunwick. The results from resistivity profiling indicate that when seawater intrusion occurs in a sandstone formation the resistivity contrast is sufficiently large to allow a precise delineation of the intrusion. A formula is then derived to convert resistivity values to chloride concentration in the "cone of intrusion". The results from resistivity soundings showed that shaly formations may have resistivities as low as seawater-contaminated sandstone. An indeterminacy has resulted from this resistivity overlap. A limited number of IP soundings were performed in an effort to resolve it. The results showed that IP can be of appreciable help in resistivity interpretation.

Jan 1, 1972

By Sergio Fuentes

During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs. This paper describes improvements in mine design, mine planning and mine management, including methods enabling the Chilean and International mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine.

May 1, 2003