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By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016

By Chris M. Healey

"Abstract- The Jasper Gold mine in northern Saskatchewan produced a total mill feed of 140 127 tonnes at an average grade of 19.0 g/t Au. Both diamond drilling and chip samples from under­ ground workings returned extremely high values, up to 12 851 g/t (375 oz/I) Au over 0.10 meter from a chip sample. In the presence of such extremely high grades, the accurate estimation of reserves is a major problem.ln the first part of this study, production data from the mine were used to evaluate the results of a variety of reserve estimation techniques in this environment. In two out of three cases studied, indicator kriging with assays cut to 342.9 g/t (10 oz/I) gave extremely good results. In the third case, however , indicator kriging gave unacceptable results. Instead, lognormal kriging of uncut data gave the best results.Secondly, from the same database, a number of drill-hole spacings were simulated, and reserves estimated from the simulations. As may be expected, the results of this analysis show increasingly better results with tighter drill-hole spacing. However, even with a 5 m by 5 m spacing the variation from actual grade was quite large. This is not a systematic under- or over-estimation of grade, rather a random scatter of results .The results of this study show very clearly the problems of deriving good estimates of reserves when extremely high-grade samples are encountered. There is a high degree of randomness to this database, so reserve estimation in this situation will remain a high-risk operation."

Jan 1, 1993

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By N. Morrison, I. Holl, R. Welyhorsky, A. Hempstock

ABSTRACT: The Victor diamond mine is located in the James Bay lowlands, 90 km west of the First Nations village of Attawapiskat. The project was the first of its kind in northern Ontario. The process plant was designed to produce a 95 to 98% by weight diamond concentrate through three stages of comminution, dense medium separation, and proprietary X-ray technology for final recovery. The plant was commissioned over a period of six months, commencing prior to substantial completion of construction. Through effective planning of the commissioning phase, the Victor mine start-up was safely completed nine months ahead of schedule.

Jan 1, 2011

By Fan Delian, Ye Jie, Lui Tiebing

The lower and the upper parts of the Doushantuo Fonnation, Hubei Province, China, contain silicate-type K-rich beds (illite and feldspar), and intraclastic phosphorites, as well as Ag-V and V deposits in a "Black Shale Series". The K-rich beds fonned in an anoxic basin whereas the phosphorites fonned in a more oxic and higher energy depositional environment. The Black Shale Series occurs in the lower and upper parts of the Doushantuo Fonnation; that in the upper part consists of black illite shale and dark gray dolostone, and contains Se-rich Ag and V deposits. These deposits are of more industrial significance than the previously discovered Ni-Mo polyelement sulfide deposits which occur in the Lower Cambrian Black Shales Series of South China. Studies of lithotype, sedimentary sequence, and geochemistry of the Doushantuo Fonnation have led to more attention being focused on the uppennost Black Shale Series and its Ag-V and V deposits. There are three ore types: black, Ag-V-rich, illite shale; black, V-rich, illite shale; and dark gray, Ag-Vrich, fmely crystalline dolostone. The first two ore types contain 3070 to 5% Corg and the last, 1.25%. The Ag-bearing minerals are naumannite, argyrodite, aguilarite, acanthite, and native silver that occur as inclusions in pyrite associated with barite. Vanadium substitutes for AI in illite and is also related to organic-matter contents. Because (1) the pre-Sinian Kongling Group contains one to three times greater than the Clark Ag value; (2) black, illite shale has a negative Ce anomaly; and (3) there are large occurrences of black, K-rich, tuffaceous, fme siltstone, the sources of Ag are thought to include subaerial and submarine volcanic materials. It is proposed that Ag, V, and Se were absorbed by clay particles and organic matter during syngenetic deposition in an anoxic environment; Ag subsequently was reconcentrated into sulfides and selenides, whereas V was incorporated structurally into illite during early and late diagenesis. These types of Black Shale Series-hosted Ag-V and V deposits are, therefore, considered to be sedimentary-diagenetic in origin.

Jan 1, 1992

"The Ernest Henry Mining (EHM) ore body is an iron oxide copper gold deposit with an average grade of 1.1 percent copper, 0.5 g/tonne gold and 22 percent magnetite. At the end of 2009, EHM converted the ball mill media charge from forged steel to high chrome media. At high pH values (above 10.5), forged media is passivated, so as the pH of the system drops the media corrosion rate increases and floods the system with corrosion products, affecting flotation. As the high chrome media is much more inert, pH has less of an effect on copper flotation response. Given this, the pH in the roughers was dropped from 10.6 to 9.6 and it was found that there was a slight increase in copper recovery and no statistical change in either the rougher or final copper concentrate grades for copper and gold. With the reduction in pH, there was a noticeable reduction in lime usage from 0.85 kg of lime per tonne of ore processed to 0.55 kg/t. This reduction in lime is equivalent to approximately $700,000 per annum at current production rates.INTRODUCTION The Xstrata Copper Ernest Henry Mine (EHM) is situated 38 km north east of Cloncurry, Australia. The mine began as an open-cut operation in 1998 and transitioned to a multi-sourced operation in December of 2011, utilising ore from the newly completed underground mine in addition to ore mined from the Mount Margaret Mining operations. EHM produces a combined copper gold concentrate containing 25 000 t of copper and 35 000 oz of gold annually, utilising a three stage grinding circuit along with a four stage flotation circuit. In addition to this EHM also produces 1 000 000 t of magnetite concentrate annually via a further grinding and three stage magnetic separation circuit. Based on metallurgical test work performed by Magotteaux between 2002 and 2008, the step to change from forged steel media to 18 percent chrome media was taken in 2009 in a bid to alter the pulp chemistry to improve the flotation performance in the plant (Greet, Kinal, Twomey, & Peatey, 2010). This plant trial resulted in: • Increased dissolved oxygen levels within the pulp, • A ball mill discharge Eh shift of 25 mV to more oxidising pulp potentials, and • An EDTA extractable iron percentage reduction. These improvements in the pulp chemistry resulted in an increase of 1.7 ± 0.6 percent in copper recovery and an increase of 2.9 ± 1.7 percent in gold recovery. As the plant trial using high chrome media was successful, the use of the media was adopted as the standard for the ball mill. This implementation opened the door for further process improvements around the flotation circuit."

Jan 1, 2014

By Edouard Masengo

A long dyke will be constructed in a lake with rockfill placed by end dumping method. Its crest will be at elevation 521.5 m compared to the nominal lake level at 520 m. In the first portion, its height will vary from 1.5 m on a 35.1 m thick tailings layer to 18.3 m on about 0.5 m of tailings. In the second portion, the dyke will be built on native silty clay and will vary from 18.3 to 15.2 m in height. The tailings consist in stratified layers of fine-grained soils showing lateral and vertical segregation. The tailings are compressible and may develop excess pore water pressure on loading. The tailings overlie a thin layer of relatively soft native silty clay. The till beneath the silty clay is considered incompressible compared to the material above. After construction, as the tailings and silty clay consolidate, pore water pressures will dissipate and dyke stability will improve. Since dyke stability will increase with time, the primary concern is its stability during construction. As a result of construction activities, three potential modes of failure were identified and recommendations were provided regarding the measures that should be undertaken to increase dyke stability during construction.

May 1, 2003

By D. Bois, P. Keating, J. Lemieux, M. A. Vallée, M. Allard, R. S. Smith, L. Z. Cheng, M. Chouteau, D. K. Fountain

"Abstract - MEGATEMII airborne electromagnetic data collected over the Iso and New Insco massive sulfide deposits have been modeled using three modeling packages. The EMQ package is a quick inversion tool which indicates that the Iso body is a dipping, plate-like body. The New Insco body is inferred to have a geometry somewhere between a dipping plate and a sphere. The Maxwell package was used to refine the properties of the plate-like body at Iso. The EMIGMA package was able to identify which parts of the New Insco orebody were more conductive. It was observed that the most conductive parts correspond to copper-rich zones and the next most conductive to pyrite-rich zones. The EMIGMA package was also used to show that a thick-prism model might be more appropriate for the New Insco orebody. Gravity modeling constrained by the known geology was successful in identifying the denser sulfide zones. The densest zones appear to be pyrite rich. Magnetic modeling identified diabase dikes. Over New Insco, a small magnetic anomaly was attributed to pyrrhotite-rich sulfides. There was only a weak magnetic anomaly over the Iso body, consistent with the nonmagnetic sulfides logged in the holes drilled at that location. Sommaire - Les données MEGATEMII recueillies au-dessus des dépôts d’Iso et de New Insco ont été interprétées en utilisant trois outils de modélisation différents. L’outil EMQ a été utilisé comme un outil d’inversion rapide suggérant que le dépôt Iso peut être considéré comme une plaque inclinée, et que le dépôt de New Insco se situe quelque part entre une plaque et une sphère. L’outil Maxwell a été utilisé pour raffiner les propriétés du dépôt Iso. L’outil EMIGMA nous a permis d’identifier les différences de conductivité à l’intérieur du dépôt Iso. Il a été observé que la partie la plus conductrice correspond à la zone riche en cuivre, suivie par la zone riche en pyrite. L’outil EMIGMA a aussi permis de montrer qu’un modèle de prisme épais pourrait être plus approprié pour décrire le dépôt New Insco. La modélisation des données gravimétriques, contrainte par la géologie connue, définit bien la zone de sulfures massifs. La zone de pyrite semble être la plus dense. La modélisation des données magnétiques identifie bien les dykes de diabase. Au-dessus du dépôt New Insco, on observe une faible anomalie magnétique correspondant aux sulfures non magnétiques observés dans les carottes de forages à cet endroit."

Jan 1, 2006

By Rodrigo Serna-Guerrero, Ted Nuorivaara

"As the demand of raw materials increases in a global scale due to demographic and economical changes, it is necessary to find technological solutions that improve current production processes in an efficient and sustainable manner. The main objective of this preliminary study is to evaluate the properties of foam produced with a cellulose-based molecule as an alterative to commercial frothing agents in flotation operations. There are two potential advantages identified with the use of cellulose-based additives for the proposed application: i) these chemicals can be produced from sustainable sources (i.e., non-edible crops), and ii) cellulose can be functionalized with chemical groups, in order to rationally modify its behaviour. In previous studies dealing with foam stabilization, it has been proposed that some functionalized cellulose species present a self-assembly mechanism at gas-liquid interfaces. Unlike typical surfactant-based frothers, cellulose molecules form networks around the bubbles that act as protective layers to the mechanical stress and to the occurrence of ionic species. This work studied the properties of foams produced in the presence of a partially hydroxylated cellulose molecule (i.e., hydroxypropyl methyl cellulose; HPMC) under various concentrations in a laboratory-scale column. A comparison with a commercial surfactant frother (i.e., Nasfroth 240) is presented, and a rationalization of the behaviour of HPMC in terms of foam properties (i.e., surface tension, bubble size, foam depth) is proposed. INTRODUCTIONThe search for green alternatives to chemicals produced from non-renewable sources has become a topic of major relevance in industry (Choi et al., 2015). As a chemical consuming industry, the mining sector faces now the challenge of adopting new processing technologies and strategies in order to achieve the future demands of sustainability. Evidently, a move towards green chemistry can only take place by identifying substitute molecules offering potential advantages in terms of recovery and grade."

Jan 1, 2016

By M. Rudolph, T. Leißner, TU Bergakademie Freiberg, C. Mämpel, R. Möckel, M. Embrechts, T. Leistner

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until 1991. For long times, gravity separation processes used to be the dominating beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. For fine (< 100 µm) and very fine (< 20 µm) particles these approaches might not represent effective techniques, significant valuable materials could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these tailings disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these tailings disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles. In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods (including conventional froth flotation and oil-assisted flotation). Different size ranges of the material were previously prepared in order to investigate their response to the different techniques. For the study, special emphasis is put on agglomeration flotation, an oil-assisted flotation method. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (including sulphosuccinamates and phosphonic acids) and depressants (including sodium fluorosilicate and oxalic acid) regime, oil dosage, agitation time and pulp density during oil/pulp agitation. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements and zeta potential analysis. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Jan 1, 2016

By J. C. Johnson

Underhand mining with cemented mill tailings for backfill has proven to be a safe and effective alternative to conventional overhand mining for rockburst prone mines. The ability of the cemented sandfill to survive a rockburst shock wave without failing has been observed at mines in the Coeur d?Alene Mining District many times in the last twenty years. To better understand the dynamic loading of this commonly used support material the National Institute for Occupational Safety and Health (NIOSH) performed laboratory experiments using a split Hopkinson Pressure Bar (SHPB) to quantify the maximum stress and energy absorption of cemented mill tailings from the Galena mine. Cylindrically shaped cemented backfill specimens aged 28 days were placed in the split Hopkinson pressure bar testing apparatus and a dynamic load was applied. The measured peak dynamic compressive strength of the cemented sandfill was 10.6 MPa (1540 psi) and is approximately twice the static unconfined compressive strength (UCS) of 5.5 MPa (800 psi). These test data showed about 95% of the initial energy was reflected away from the backfill and only 5% of the energy was absorbed. This may help to explain why backfilled stopes could withstand seismic events up to 3.5 Richter magnitude (Ml). When a compressive rockburst wave impacts a stope a large amount of the stress and energy is reflected away. The reflected wave is a tensile wave which creates tensile cracks and spalling in the entire wall of the stope. The backfill supports the damaged wall rock and holds it in place. Some of the stress and energy of the rockburst is transmitted into the backfill and because the backfill is being dynamically loaded it has a strength that is twice its static value and absorbs a substantial amount of rockburst energy. Although mining in deep underground mines is an extremely hazardous occupation, the use of underhand mining with cemented backfill for static and dynamic ground control increases the safety of the workers.

May 1, 2007

By A. Dave Mackintosh

Historical closure data has provided a description of the stress distribution patterns occurring around mine openings and enabled the development of a time ? distance plot predicting the location of the stress peak and its migration away from mine openings with time. Data collected from active mining areas during the 1970?s and 1980?s indicated the peak appeared to stabilize approximately 135m (450 ft.) from openings after four years. The region of high load and accompanying poor ground conditions in which the peak was centred was spread over approximately 45m (150 ft.) to 60m (200 ft.). Recent data from new development headings cut adjacent to 25 year old extraction areas suggests load transfer takes place over a much greater distance and time frame than predicted.

May 1, 2001

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract-Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O sig- nature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By J. A. Morgan, W. A. Barclay, J. C. Pedersen, I. C. Campbell, D. S. Bubar, R. P. Taylor

"Abstract - The Lilypad Lakes property is host to a group of Ta-mineralized dikes that occur over an area of at least 10 km2. Field relationships are consistent with a syn- to late syn-tectonic timing for their emplacement (with respect to the major regional D1 episode of deformation), with several of the dikes exhibiting a steeply dipping, open, S- to M- to Z-shaped fold geometry. Individual dikes range up to 30 m wide (Rubellite Dyke, Pollucite Dyke), have strike lengths of up to 750 m (e.g., JJ Dyke), and are continuous to depths of greater than 250 m (e.g., Rubellite Dyke, Pollucite Dyke). Typically, they display sharp intrusive contacts characterized by the development of thin, holmquistite-rich haloes. The Tamineralized dikes are comprised of silica- and alumina-rich, sodic, granitic pegmatites that display extreme levels of geochemical fractionation (K/Rb typically < 10.0, as low as 2.2; Nb/Ta typically < 0.20, as low as 0.03), and enrichments in an economically important group of lithophile elements, most notably Li, Rb, Cs, and Ta. Geochemical assays of individual surface grab and drill core samples have yielded values as high as 1.51 wt.% Li2O, 1.25 wt.% Rb2O, 6.21 wt.% Cs2O, and 0.108 wt.% Ta2O5. Diamond drilling has established the presence of wide (~20 m), potentially ore-grade intersections of Ta mineralization (>0.045 wt.% Ta2O5) in both the Rubellite and the Pollucite Dykes.Three Ta-oxide minerals (microlite, wodginite, manganotantalite) of primary origin predominate in the Ta-mineralized dikes, where they occur as fine, disseminated grains in the albite-rich pegmatite matrix. The sequence of crystallization is typically manganotantalite wodginite microlite, which conforms to a well-established paragenetic sequence for rare-element granitic pegmatites in general. All three of the primary Ta oxides are characterized by a high degree of chemical purity (e.g., average Ta concentrations in microlite from 77-79 wt.% Ta2O5), a compositional feature consistent with the extreme levels of geochemical fractionation characteristic of the host granitic pegmatites, and one that indicates that the Lilypad Lakes pegmatites are likely to produce Ta mineral concentrates of the very highest quality.Locally, a second generation of Ta minerals is present, restricted to small vugs in the pegmatite matrix that are surrounded by fine aggregates of K-rich mica or clay. The secondary Ta minerals are dominated by microlite, which is typically intergrown with fluorite and Fe-sulphides, and is distinguished from its primary counterpart by its lower Ta content (around 70 wt.% Ta2O5) and much higher concentration of uranium (up to 9 wt.% UO2). Also, secondary microlite consistently yields low analytical totals from electron microprobe analysis, suggesting that it is H2O-rich. The presence of this second, vug-related generation of microlite, together with the occurrence of localized networks of crosscutting fractures that host high concentrations of Cs and Rb (in the minerals pollucite and Rb-Kfeldspar), suggests that a late-stage, fluid-dominated metasomatic/hydrothermal event may have been important in certain sections of the dikes, and has effected a redistribution of the economically important elements Ta and Cs."

Jan 1, 2005

By Konstantinos Modis

According to recently established theoretical analysis and under certain conditions, a critical sampling density can be determined for an earth-related space-distributed natural variable. Sampling above this critical limit adds little to the mapping results. The objective of this paper is the application of the above theory to the Sesklo clay quarry in Greece, where Heracles General Cement Company had conducted a sampling campaign to estimate its reserves. The structural analysis of Al2O3 values generated a variogram model, from which the critical sampling density was identified. This critical number was by far lower than the existing sampling density. Clay reserves were then estimated using geostatistics and inverse distance squares in different data schemes with variable densities. The results of the comparisons between the various models revealed that, when the sampling density was greater than its critical value, geostatistics and deterministic interpolation gave similar estimations, which is also in agreement to the theory. The optimal sampling grid finally proposed here, will result to significant cost savings in the next drilling program which is now in plan by the company.

Oct 1, 2009

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By Brendan Parker, Tyron Rees, Steven Hart, Abba Manesh, Ian Mcgaffin

"In September 2009, Newmont began the commissioning of a 3 stage crushing and milling circuit at its Boddington Gold Operation in Western Australia. The Boddington ore has been recognized as one of the hardest and most abrasive ores treated to date and this played a pivotal role in the selection of crushing and HPGR technology for this operation as opposed to the more conventional SABC circuit.This paper will examine the scale up from laboratory to pilot plant and full scale operation of the crushing circuit. There have been many challenges to overcome in the first 18 months of operation; however, the HPGRs have in general met design expectations and performance is expected to improve further with ongoing design changes"

Jan 1, 2012

By M. Mohammadi Zahrani

The morphological modification of primary and eutectic Mg2Si phases by bismuth (Bi) addition in Mg-5wt.% Si in-situ composite was investigated. It was found that with addition of 0.5wt.% Bi, the morphology of primary Mg2Si precipitates was altered from coarse dendritic to polygonal shape, and their mean size was significantly decreased from more than 20 µm to about 8 µm. Moreover, the rod-like eutectic Mg2Si in Bi modified Mg-Si alloy solidified much finer than that of the base alloy. Such improved microstructure of the modified alloy resulted in 10% tensile strength and 20% elongation improvement. The isotropic growth manner of primary Mg2Si particles in modified alloy was attributed to the poisoning of growth in preferred directions by dissolving Bi atoms in Mg2Si lattice. The reduction in size of eutectic Mg2Si was found to be the result of Mg3Bi2 compound formation around eutectic Mg2Si rods.

Oct 1, 2011

By Sarah R. Hindle

Carbon capture and storage has jumped to the forefront of climate change mitigation efforts for its capacity to sequester large amounts of carbon. Mineral carbonation is one prominent option, mimicking and accelerating the natural weathering process of certain silicate minerals. This has the ability to produce stable carbonate minerals that can store carbon on geologic time scales with little to no risk of leakage. Commercialization of this process is ideally suited for integration into the proposed mining operations at the Turnagain Nickel site in Northern BC. This is due to the abundant supply of suitable ultramafic feedstock material, as well as the economic benefit of sharing costs while reducing net emissions and bringing value to otherwise valueless and costly waste rock. While studies have shown this process to be technologically viable on a laboratory scale, assessing the economic and financial viability of such a process on an industrial scale is necessary. An evaluation of the financial feasibility of integrating mineral carbonation into the mining cycle at Turnagain under a proposed cap-and-trade system is presented.

May 1, 2010

By J. Lee, K. B. Min, J. Rutqvist

Shear slip of fractures in fractured rock masses is a critical issue for many geological engineering applications, such as the design of underground nuclear waste repositories, enhanced geothermal systems (EGS), and geosequestration of CO2. This paper presents new development of the TOUGH-UDEC simulator for analysis of coupled thermal-hydraulic-mechanical (THM) processes in fractured porous media. As an alternative to developing a single coupled THM code in discontinuum, two existing wellestablished codes, namely TOUGH2 and UDEC, are coupled to cover coupled THM analysis of multiphase fluid flow, heat transfer, and deformation in fractured porous media. TOUGH2 is widely used for modeling heat transfer and multiphase, multicomponent fluid flow, and UDEC is a well-known discrete element code for rock mechanics, which have been verified and used by many groups all over the world. Although a sequential coupling of two codes is less efficient than having a single code in principal, a big advantage with coupling of TOUGH2 and UDEC is that both codes are well tested and widely applied in their respective fields. When linking two codes, the coupled equations cannot be solved simultaneously; they should be solved sequentially, with coupling parameters passed to each equation at specific intervals. After solving thermal-hydraulic equations through the TOUGH2 model, pressure (P) and temperature (T) information is delivered to UDEC model. Pressure information is directly stored at the center of each UDEC zone and domain, however, temperature information is interpolated from zone-centers to the corners nodes. After solving the mechanical equation through the UDEC model—considering new pressure and temperature—calculated fracture apertures are converted to equivalent permeability and porosity for TOUGH2 flow analysis. The solution was calculated by iteratively following an explicit sequence for numerical efficiency. Verification examples are presented to demonstrate the capabilities of the coupled TOUGH-UDEC simulator.

Jan 1, 2015