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By Bahjat Khoshaba, Bern Klein, Haixing Yan, Libin Tong, Andrew Bamber

"When a conductive or magnetic particle was put into an electromagnetic field introduced by an electromagnetic sensor, the particle can influence the electromagnetic field which can be used to characterize this particle. The electromagnetic technology based on eddy current theory was explored to investigate its potential in both the separation of minerals and the pre-concentration of a base metal ore. Samples tested in the study included the minerals obtained from Ward’s Science and the low grade copper ore particles obtained from Mount Polley Mine. The effects of mineral type, sensor frequency, particle size, particle position on the sensor surface, and particle lift-off on the magnitude and phase of the electromagnetic spectra were investigated. The electromagnetic spectra of various minerals show that it is possible to separate chalcopyrite or magnetite from tested minerals, simply based on the magnitude of the spectra. The spectra of the ore particles were determined by the mineral in the particles with the strongest signal. The effect of the pre-concentration of the low grade copper ore is determined by the association of chalcopyrite with magnetite. Direct sorting is the mechanism in the separation of mineral particles, while indirect sorting is the mechanism for low grade ores.INTRODUCTIONSensor-based sorting technologies include radiometric, X-ray transmission, X-ray fluorescence, near infrared, photometric, inductive, microwave heating and so on. Sorting not only discards barren rocks away from the concentrator but also recovers metal bearing that would be lose to the waste dump. The benefits of pre-concentration using sensor-based sorting are achieved on reduced energy consumption for comminution and reduced water usage on a volume per weight of metal basis (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). Amongst others, high frequency electromagnetic sensors were developed for ore sorting at MineSense Technologies Ltd. and are subject of this paper. Improving the understanding of ore heterogeneity is the basis for developing a successful semi-bulk or bulk sorting systems by incorporating the sensors in the material handling equipment (MineSense Technologies Ltd., 2016). The present study focuses on the bulk sorting potential and bulk sorting mechanisms of the electromagnetic technology in the pre-concentration of minerals or ores."

Jan 1, 2016

By C. M. Diaz, P. J. Mackey

Since its inception, in 1987, the Copper-Cobre series of conferences has established itself as the prime world forum for discussing advances in copper process metallurgy, in particular copper sulfide smelting, copper recovery by leaching and electrowinning and copper electrorefining. All copper producing countries have actively participated in the pyrometallurgy symposia held in the framework of these conferences. In 1999 and 2003, the close to 100 pyrometallurgy papers that were presented had to be accommodated in two volumes. In the present paper, the authors firstly provide a brief historical sketch of the Copper-Cobre conferences and then focus on providing a retrospective look at the dramatic changes that have taken place in copper smelting in the last few decades, primarily as discussed in the Copper-Cobre and precursor conferences pyrometallurgy proceedings. Topics include: the development of autogenous, increasingly more intensive, environmentally sound and energy efficient smelting processes; significant improvements in Peirce-Smith converting practice and at the same time the commercialization of alternative continuous converting routes; the consequent expansion and modernization of smelters; the increasing compliance with strict government environmental regulations in most copper producing regions of the world; the realignment of the copper smelting industry throughout the world; and trends in copper smelting R&D. A look at the future closes these reflections on the contribution of the Copper-Cobre conferences to the advancement of copper smelting technology.

Jan 1, 2007

By Frank Otten, Jochen Greinacher

"In July 2017, Deilmann-Haniel signed a contract with IOO Slavkaliy to sink two 750 metre (m) deep freeze shafts for the Nezhinsky Potash mine in Belarus. This is the second shaft project where this technology is employed after two over 1,000 m deep shafts for a potash project in Saskatchewan, Canada, have been sunk by the application of the Herrenknecht Shaft Boring Roadheader (SBR) technology. Developed to sink shafts for green field projects in soft to medium hard rock, in frozen or unfrozen geology, the machine technology utilizes a roadheader-type cutterhead on a telescopic boom to mechanically excavate the rock, and a pneumatic mucking system to convey the muck from the face into the buckets. This leads to a manless face during the sinking cycle and thus a significant improvement in terms of workplace safety. For the Nezhinsky project, the SBR design was significantly modified in close cooperation between Deilmann-Haniel and Herrenknecht, based on the available experience and the special requirements of the project. Such modifications have been for example the adaptation of the Pneumatic Mucking System to cope with wet material as well as dry as originally planned or the shaft lining moving from shotcrete application to jump for and tubbing installation for which a step-change hands-off tubbing erector for the placement of segments was designed. Further modifications to optimize the machine technology for the requirements during shaft sinking were applied on the two machines for the Slavkaliy project as well as several revisions to match the special project requirements. The SBR is suitable for soft and medium hard rock up to 100 MPa UCS. The main design limits are maximum weight of the machine with 400 tonnes and length or height of 50 m due to the depth of the pre-sink. The Pneumatic Mucking System was changed in all components, sheaves and rope arrangement were redesigned and the concept of the hoist system was also re-engineered. The SBR in Belarus is configured for a daily sinking rate of three metres and all systems behind the cutting boom are not the bottle neck of the whole system. The works on site started in November 2017 including freeze hole drilling, construction works, site setup, installation of hoists winches, permanent headgears and other components required for sinking. The SBRs arrived on site in June/July 2018 and were preassembled on surface and then lowered into the 50 m pre-sink. SBR #1 started full face sinking in mid-December 2018, and SBR #2 in late January 2019. By the end of February 2019, the machines were at 150 m and 100 m depth respectively, and achieved up to 3.6 m/day concrete lined shaft. The SBR and the sinking system, the experiences, problems, technical solutions and performances of this challenging project will be presented in this paper."

Jan 1, 2019

By V. Labiouse, F. Orellana

"Hollow cylinder samples can be tested for both the characterization of rock properties and the physical modelling at reduced scale of engineering applications. Particularly, this type of experimental setup can be used to simulate different stress conditions around underground openings, as already developed in the petroleum engineering field e.g. to study the instabilities around deep wellbores during either drilling or the oil production phase. Some authors have also used this technique to successfully characterize the damaged zone around underground openings in the tunneling engineering field looking for an efficient design of their support.This article presents a new hollow cylinder testing device developed at the Rock Mechanics Laboratory of the Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland. It allows a full and independent control of the confining pressure and pore water pressure conditions at both the inner and outer boundaries of Thick-Walled Hollow Cylindrical samples. In order to mimicking a tunnel excavation in a porous rock mass, after initial recovery of the in-situ stress and pore water pressure, the hollow cylinders are subjected to a decrease in the internal confining pressure. Moreover, X-Ray Computed Tomography scans of the specimens are performed through the testing cell before and after the mechanical unloading to monitor the displacements undergone and the sample damage. The equipment, testing procedure and data analysis techniques are briefly presented in the paper.The good performance of the apparatus has already been checked on weak rock specimens, among others on Boom and Opalinus Clay samples. In many configurations, the mechanical unloading is found to induce a Damaged Zone (DZ) around the central hole. Its geometry and extent show a great similarity with in-situ observations around tunnels driven in the Boom and Opalinus Clay formations. Such similarities contribute to increase confidence in the understanding and modelling of the ongoing processes."

Jan 1, 2015

By M. Krasowska

Dynamics of collision and kinetics of the bubble attachment to hydrophobic solid plates (Teflon) of different surface roughness were investigated. The experiments were carried out in such a way that probability of the collision and probability that the detachment will not occur were equal always 100%. Thus, it was possible to determine effect of the surface roughness on the bubble attachment (three phase contact formation, TPC) only. A high-speed camera (1182 Hz) was used to record the velocity variations, bouncing and time of attachment of the bubble colliding with Teflon plates having different surface roughness (5 different plates). Roughness of the plate surfaces was modified in a mechanical way using different abrasive papers. It was found that the roughness had a crucial influence on the time-scale of the TPC formation and attachment of the bubble colliding with the Teflon plates. Despite high hydrophobicity of all plates (contact angles 1100 -115º) it was observed that at the smoothest surfaces (called "Teflon I" and "Teflon II" and having surface roughness below 1 um) there was no attachment during the bubble first collisions. Prior to the attachment four or more "approach?bouncing" cycles of the colliding bubble were observed there and simultaneously the bubble shape varied rapidly within time intervals below 0.85 ms. Time of contact of the colliding bubble with the Teflon plates was very short; 2-3 ms. These results indicate that during that short time of the collision the liquid layer separating the colliding bubble and the solid surface did not reach a critical thickness of its rupture.

Jan 1, 2006

By G. Morin, F. Chiesa, B. Duchesne

The Quality index is a useful tool allowing to assess the metallurgical quality of aluminium AlSiMg foundry alloys (A356/357). Its value is calculated from the ultimate tensile strength and elongation; it increases with the metallurgical quality of the casting, i.e. with finer dendrites, lower microporosity and inclusion count and lower iron content. This Quality index does not depend on the degree of temper applied during the heat treatment (aging time and temperature). After defining the Quality index, it will be explained how it can be predicted from the knowledge of the local solidification conditions obtained from modelling. The paper will then present four case studies of castings for which the prediction of the Quality index by modelling was made. These case studies from different authors will involve the three most common casting processes used for producing high integrity aluminium castings, namely: sand casting, permanent mould casting and investment casting (lost wax). In all cases, the accuracy of the prediction will be assessed by comparing the predicted Quality index distributions to the experimental values based on the published measured values of the local tensile properties.

Jan 1, 2006

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By J. Dubinski

This paper describes the key circumstances of the underground coal gasification (UCG) process, which is planned to be carried out in the Polish hard coal mine ?Wieczorek?. The construction and field tests of a UCG pilot plant have key issues that need to be addressed to realize the research project goal: the elaboration of a highly effective technology of fuel and electricity production. The project will conduct several monthly tests of gasification in the pilot geo-reactor, which will be constructed based on the results of laboratory tests. The realization of the process requires numerous appropriately prepared actions adjusted to natural conditions in the hard coal deposit. Based on scientific principles, it is necessary to elaborate the procedures related to the location of the UCG installation (including its legal and safety aspects), and to perform a technical risk analysis. In addition, it is necessary to determine the required mining, geological, technical, economic and organizational circumstances, while at the same time considering the real but constantly changing process conditions.

Aug 1, 2013

By A. Saki, P. Gebski, W. Ying

Industrial smelting furnaces are subjected to significant structural changes and deterioration caused by the conditions under which they operate. The current methods for the structural assessment of furnaces include visual inspections, analysis of thermal data, acousto ultrasonic-echo (AU-E) of the refractory lining and surveying of the key structural elements. Acoustic Emission (AE) non-destructive testing (NDT) technique has proven its capabilities for continuous monitoring of industrial installations and structures. Recently, Hatch Ltd. has been successful in applying acoustic emission for monitoring furnace tapblocks, and expanding the scope of the acoustic emission monitoring to the structural integrity of the entire furnace. The capability of detecting emissions related to the fracture development in the furnace shell, movement of the refractory, electrode arcing, combined with efficient source location algorithms makes an acoustic emission system a comprehensive tool for the real-time furnace integrity monitoring. In this paper the concept of such state of the art system for structural integrity assessment is presented. The initial results of the acoustic emission monitoring together with data analysis techniques are discussed.

Jan 1, 2011

By J. J. Benitez

MIBC (methyl-isobuthyl carbinol) was previously shown to enhance significantly sylvite flotation when used at the stage of preparation of amine dispersions. In this paper Atomic Force Microscopy (AFM) is used to study the effect of MIBC on deposition of octadecylamine (ODA) on the surface of mica. The AFM images indicate that amino terminated, and therefore hydrophilic, deposits of ODA are observed on the mica surface in the ODA dispersions free of MIBC. In the presence of MIBC a methyl terminated (hydrophobic) monolayer is obtained on the mica surface. The transition between the monolayer and bilayer phases is due to the presence of MIBC. Experiments carried out in distilled water reproduced the results obtained from the brine. Working in pure water instead of brine simplifies the preparation conditions and the analysis by AFM.

Jan 1, 2006

By B. R. Rakishev

When transferring from the railway transport to the combined automobile-conveyor transport by stripping works at coal mines, it was proposed to form at the working zone a concentration horizon for reloading part of the stripping volumes at the railway transport. The procedure is adduced for substantiating parameters of bloc-panels, depending on the step of transferring of reloading points in interrelation with the intensity of the working zone?s development with observing the balanced movement of parts of the stripping zone relative to the temporary concentration level.

Aug 1, 2013

By R. E. Barbosa

Seepage forces generated during tunnel excavation affect the ground response and may cause severe instability problems, including total ground collapse and flooding into the tunnel. This paper presents a new closed-form analytical solution, for stresses and displacements around a cylindrical tunnel excavated in a porous water-bearing elasto-plastic material, which includes the effects of seepage forces. The analysis is carried out in terms of effective stresses and pore water pressures. The solution shows that seepage forces may have a major effect on the effective stresses around the tunnel, on the extent of the plastic zone, on the radial displacements, and on the tunnel support requirements. The conditions for development of a ?flowing ground? condition at the tunnel face have been identified. The paper presents a procedure for the hydromechanical ground-support interaction analysis, to determine the excavation induced inflow and the pressures acting on the lining, throughout the progressive driving of the tunnel, including the effective pressures exerted by the ground and the pressures generated by the water.

May 1, 2009

By Zhiqiang Wang

This paper mainly focuses on the method of ?three-zone? definition (a caving zone, a fissure zone and a curve subsidence zone) for full height cutting in a thick seam. Based on criteria of a caving zone and a water conducting zone, as well as existing research achievements, it is believed that there exists great error for calculation of height of the ?three-zone? area using cutting height and the coefficient of bulk increase. Dynamic factors should be considered, so, based on the theory of key rock strata and combining this with several other factors, such as mining area, this paper presents a new method to determine the overburden ?three-zone? definition. The results are as follows: (1) geometric models of a working face and key stratum are established through the rock displacement angle, with consideration of the influence of mining on the key stratum (the range of key stratum influenced by mining is enlarged as the mining area increases); (2) because there is always a cavity below the key stratum of the thick coal seam with full seam cutting, and the key stratum gradually fracture with face advancing, based on the geometric dimension of strata, the maximum fracturing interval expression has been presented, including the working face advancing range. This can theoretically lead to the location of the key stratum influenced by mining, and its stability before mining, helps to confirm which zone the key stratum and following-up strata belong to, using the criteria of sliding instability or deformation instability; (3) the new method of ?three-zone? definition which is based on the theory of key rock strata is first proposed for full height cutting in thick seam. Finally, combined with practical engineering, and comparing with field data, it is believed that the proposed method is more objective than existing methods.

Aug 1, 2013

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016

By T. Boiselle, C. Gielen, P. Henry, J. M. Bier

"Hydrometal is specialized in the production of zinc sulphate from complex secondary raw materials. Electric Arc Furnace (EAF) dust is one of the more interesting potential sources to produce zinc sulphate. In order to minimize waste quantities generated from EAF dust treatment, our R&D team has developed and patented a new process to recover the Fe contained in the dust as iron oxide product to be used and sold into the pigment market. The process is based on a specific reductive leaching step of the zinc ferrite contained in EAF dust, followed by a purification step to remove impurities (Ni, Cr, Cu...) and finally the controlled precipitation of the iron oxide. The aim of the iron precipitation step is to obtain the right shape and length of crystals in order to guarantee the right color and tinting strength of the pigment. The innovative aspects of the process results in the controlled oxidation of the iron to get the right crystal size and good purity material. The iron product can be valorized as red or yellow pigment often produced by the Penniman-Zoph process.INTRODUCTION A Few Words about HYDROMETAL Hydrometal SA (Engis, Belgium) is a subsidiary of Jean Goldschmidt International SA (JGI) in Brussels. JGI is mainly involved in metal trading activities (Goldschmidt, 1995). In 1985, JGI acquired the leaching circuit of a Belgian electrolytic zinc producer located in Engis, a few kilometers south of Liège, near the river Meuse and it was decided to name this plant: SA HYDROMETAL. Hydrometal is well connected by water, rail and road from its central location in the industrial region of Liege, in the heart of Europe. The company received in 1997 an additional license to process and recycle toxic and hazardous waste. Figure 1 shows a picture of the plant."

Jan 1, 2016

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Abstract- Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been con­ ducted, thereby providing a unique opportunity to examine the geochernical evolution of a sulfide- rich mine-tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% aluminosilicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, SOi-, Cu, Zn and Pb (up to 10 000 mg/L, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively) . In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tinoxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SO42- , Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents . Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massive­ sulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By Neil Schofield

"The Pine Creek gold mineralization is associated with saddle reefs and quartz and quartz sulphide veining within the Enterprise Anticline. The anticlinal structure is complex and the mineralization was considered prior to development to be dominantly strata controlled. Gold grades vary up to 160 gin 1.5 m core samples with coefficients of variation in excess of three.The estimation of ore reserves for such a deposit must account for both the geological complexity and the extreme variability of gold grade.This paper describes the structural and variogram analysis of the gold grades and demonstrates the importance of incorporating the geological model in such an analysis. Variogram interpretation is greatly improved and greater insights into the finer geological structure areprovided. Part 2ofthis work presents the application of multigaussian kriging to reserve estimation for deposits with highly variable grade and which consequently demand highly selective mining operations. IntroductionThe Enterprise Gold Mine is situated some 220 km southeast of Darwin in Australia's tropical north. Gold is believed to have been discovered there in 1869 during the construction of the overland telegraph line.From 1894to 1915, some 75 000 ounces of gold were produced from 121 000 tonnes mined mainly by Chinese leaseholders. From 1906 to 1915, government-sponsored drilling led to the sinking of the Enterprise Shaft to 79 m and several drives were developed. Mining ceased because of war.Since late 1980, Goldfields Exploration Pty. Ltd. had explored on several mining tenements near Pine Creek under joint venture with the title holders, Enterprise Mines NL. This work culminated in the development of the current mine which opened on October 29, 1985.Feasibility studies to determine the economic viability of mining were based on ore reserves generated by project geologists using a sectional polygonal approach tuned to the interpreted geological control of the mineralization.The study motivating this two-part paper covers are-estimation of the recoverable reserve s using the geostatistical approach of multigaussian kriging developed at Stanford University, (Verly, 1984)."

Jan 1, 1988

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been conducted, thereby providing a unique opportunity to examine the geochemical evolution of a sulfide rich mine>tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% alumino silicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, S042-, Cu, Zn and Pb (up to 10 000 mglL, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively). In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tin oxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SOi-, Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents. Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massivesulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By F. C. Lendrum

Introduction The property of Normetal Mining Corporation is in Desmeloizes township, Quebec, twelve miles north of Dupuy on the main line of the Canadian National railway from Quebec city co Cochrane, Ontario. The ore bodies occur within a band of highly sheared and sericitized agglomerate which strikes N.60°W. and clips 82° north. Along a zone 1,000 feet or more in length and of variable width, the agglomerate has been replaced by copper, zinc, and iron sulphides, with copper usually predominant on the hanging-wall side and pyrite replaced in part by sphalerite on the footwall. A northsouth diabase dyke cuts through the ore zone near its east end. The Normetal mill produces a copper concentrate and a zinc concentrate which are shipped, respectively, to Noranda, Que., and Newcastle, Penn., U.S.A., for further treatment. The present paper deals with the milling of ore from what is known as No. 3 orebody. This is a lenticular body of high-zinc ore lying co the east of the diabase dyke, along the line of strike of the main ore zone, which extends westward from the dyke. On its northern side, No. 3 orebody is in contact along most of its length with a narrow band of copper ore which is highly oxidized.

Jan 1, 1948