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By N. M. Stubina, P. J. Lind

Barrick Gold is in the process of building several new mines and implementing new processes at existing mines for which metallurgical technology is of key importance. The roles of the company's Strategic Technology Solutions team and the Barrick Technology Centre are discussed within the context of their responsibilities within Barrick's Operations Support group. The paper will present an overview of the development of the technology centre from the former Placer Dome Research Centre to its current form supporting strategic technology, capital projects, and operating sites. Novel approaches to research and development will be presented as well as an overview of some of the technologies developed from bench-scale to pilot-scale, and beyond.

Jan 1, 2011

By J. G. Strasser

"There has been considerable output over the last three decades from the social sciences concerning man and his working environment. In the mining industry at large, however, authoritarian, hierarchical control systems remain the norm, and it can be argued that something less than optimum effectiveness in terms of both productivity and worker satisfaction has resulted.Recently (/975), Campbell Chibougamau Mines Ltd. devised a most interesting organization and incentive system that links the underground production of a standard ton of mined output at controlled grade to an incentive payment scheme. A parallel scheme in the mill complex is based on maximizing recovery of copper and gold from available feed. A key part of both minsystems is the formation of groups who have considerable autonomy, particularly when compared to the still prevalent traditional mining industry relationships between the worker and supervisory levels.This paper traces the development of Campbell Chibougamau's system . Attention is drawn to qualitative and quantitative measures of the success of the method through the commentary of those miners involved in the scheme, and by reference to the favourable records on productivity, absenteeism, safety, turnover and grievance activity.IntroductionPyramidal or hierarchical management control systems, coupled to piece-work incentive schemes, predominate throughout Canada's underground mining industry. Although specific details of such systems vary from site to site, they , are generally understood and accepted as fact by the majority of the work force.Normally, a front-line supervisor (shift boss) directs a number of workmen and assigns them to tasks and working locations commensurate with their abilities, knowledge, training and skills. This front -line supervisor may direct or supervise from as few as 12 to as many as 75 or more workmen. He issues orders according to his assigned production objectives and ensures that these directions are fulfilled in accordance with standard mine practice . Several shift bosses are usually directed by a mine foreman or mine captain. The mine captains report to a general foreman or directly to the mine superintendent or his assistant, depending on the size and scope of the operation."

Jan 1, 1981

By I. E. Wahn, E. A. Boutin

"The Manibridge Mill is unique in its treatment of relatively high grade nickel-copper ore because in the mill design are included one 10' diam. x 10' Maxwell cell, and three 12' diam. x 12' tank cells. These large cells are used as rougher-scavenger cells. Three 8' diam. x 8' tank cells as well are used for cleaning and recleaning of the tank cell concentrate.Flexibility of flow is the main criterion in the tank cell circuit. Targets from these cells are a high grade nickel-copper product with a minimum of talcose gangue.The operation of the tank cells has been encouraging and they have performed well with both low and high grade heads, yielding a high grade concentrate product.Manibridge Tank CellsDescription:The tank cells at Manibridge consist of one 10' x 10' Maxwell cell, three 12' x 12' tank cells, and three 8' x 8' tank cells. The four large cells are currently being used as rougher scavenger cells. The three small cells are used as cleaner cells.Both sets of tank cells consist of Denver steel tank and Super Agitator Mechanisms with steel beam super-structures. The agitator mechanism has a totally enclosed ball bearing spindle housing with a cold rolled steel shaft, and a stanclard standpipe with adjustable collar.The air rings for the tanks were fabricated by Nelson Machinery. Both large and small cells have injection rings with equally spaced air holes in the bottom centre line of the ring.Air is supplied to the tank cells by a Dresser Clark low pressure air blower.The following is a table of pertinent data on the tank cells:"

Jan 1, 1974

By J. E. Nesset, F. Rosenblum, J. A. Finch

"The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to highly reactive and potentially hazardous to both humans and infrastructure. It is essential that there be a reliable test methodology that can measure and categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral mixtures making it difficult to predict their self-heating behaviour a-priori based on mineralogy or with a simple “snapshot” test. Furthermore, self-heating behaviour will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to measure and reliably predict the latent self-heating hazard of a sulphide material. Several of the methods were tested and compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.INTRODUCTION Sulphides as well as other materials (coal, wood chips, hay, powdered milk, to name a few) that are stockpiled in an air atmosphere may undergo oxidation reactions which can result in the evolution of heat (Beever, 1984) (Hudak, 2002) (Blanchard, 2007). If the rate of heat generated exceeds the rate of heat dissipation, the stockpile temperature will rise, potentially leading to “hot spots” in the most reactive areas, and possibly even fires. The heat generation rate, the “self-heating” rate, depends on many factors such as the type and composition of material, particle size, moisture content, oxygen availability, ambient temperature and humidity, and of prime importance, the extend of prior oxidation, or more specifically, the presence of oxidation products. The desire of operators that mine, process or transport sulphide-bearing materials with a potential for self-heating is to have an accepted and reliable method for evaluating and quantifying the potential hazard of their material. The challenges are how to best measure the self-heating properties of given samples, and based on results, predict the behaviour of the bulk material over time and in-situ. Generally, when evaluating a given material one derives the self-heating characteristics of that sample at the time and under the conditions of testing, which will be referred to as a “snapshot test”. If that material is invariable, i.e. it will not change its response over time, then it may be considered to be a “predictive test”. However, if as a result of continuing oxidation or other changes, the material becomes more or less reactive with time, then a “snapshot test” is unreliable with respect to predictive ability."

Jan 1, 2014

By G. M. Ritcey, K. E. Haque, S. H. Lucas

"Laboratory-scale hydrochloric acid leach tests were conducted on an Elliot Lake uranium ore. Hydrochloric acid leaches without an oxidant or with molecular oxygen (i.e., air or pure oxygen gas) as an oxidant favoured uranium and radium extractions. Conditions for maximum uranium, thorium and radium extractions with hydrochloric acid in the presence of sodium chlorate were determined. The highest extractions of uranium (96%), thorium (81%) and radium (91%) were obtained using a mixture of 44.0 kg HCI and 2.5 kg NaCIOJ per tonne of ore at 75°C with 18 hours ' retention.Flowsheets for two-stage leaching are proposed. The residues obtained from the second-stage leach contain uranium (0.002%), thorium (0.006%) and radium (15 to 20 pCi/g). Tailings of this nature are considered suitable for mine backfill, and, if pyrite is removed, suitable for surfacedisposal.IntroductionThe nuclear energy industry forecasts an increasing demand for uranium. This increasing demand requires not only largescale mining and processing of conventional and complex uranium ores, but also leads to the consideration of new and nonconventional sources of uranium, e.g., black shales, phosphate rocks, granite, sea water and fossil-fuel ash.Sulphuric acid leaching is the most widely used process to extract uranium from the ore(l). The leach liquor is separated from the solids (tailings), purified, concentrated in various intermediate stages, and finally a semi-purified product, yellow cake (80-85070 U30 8) , is precipitated. The tailings, which constitute nearly 98% of the total bulk of most ores, are usually discarded in surface disposal areas.The Elliot Lake region of Ontario is one of the major uranium producing areas in Canada. The principal uranium minerals are brannerite and uraninite, present as microscopic grains in the matrix of quartz-pebble conglomerates. The average grade is between 0.10 and 0.15% UPs. Up to 6.5% pyrite is also present in the conglomerates. Because pyrite is less reactive toward sulphuric acid leaching, almost all the pyrite goes into the tailings and eventually into' the disposal sites."

Jan 1, 1980

By Pierre Gratton, Gordon Peeling

The Mining Association of Canada launched the Towards Sustainable Mining initiative in 2004. TSM’s goal is to improve the mining industry’s performance by aligning its actions with the priorities and values of Canadians. The initiative currently includes performance indicators for four areas: tailings management, energy use and greenhouse gas management, external outreach and corporate crisis management planning. Over the past year, the association has been designing a performance assessment and verification system for these performance areas, as its members prepare to move to external verification of their performance in 2006. The presentation will describe the initiative and its evolution, as well as the challenges faced in developing a verification system applicable to an entire sector.

Jan 1, 2006

By S. V. Burr

"A 28-year study of cross folds leads to the conclusion that the northwest-southeast folds recognized in many areas of North America are part of a regional pattern. Detailed examination of over 650 geological maps and reports of Ontario indicates that this folding can be traced across the province. Evidence is presented that this fold pattern played an important part in determining the pattern and scale of intrusion, that its recognition in the field can aid in defining stratigraphy, folding and faulting, and that it may have played an important role in channeling hydrothermal or magmatic mineralization. IntroductionThe concept of regional cross folding in Ontario is not new. W.H. Gross (1955) discussed regional cross folds in the Archean of Northwestern Ontario, and A.M. Goodwin (1961) referred to regional cross folds in the Archean of Ontario and Quebec. However, the interpretation in this paper is new.The writer saw a cross fold for the first time, underground, at Little Long Lac Gold Mines in Geraldton, Ontario, in 1951. This recalled the ""transverse folds"" on E.R. Faribault's classical maps of Nova Scotia, published by the Geological Survey around the turn of the century; M.E. Hurst's cross fold(s) at Timmins, Ontario (Figure I); and the cross folds mapped by A.W. Jolliffe in the Yellowknife area of the Northwest Territories. All these mapped cross folds had one thing in common with the fold at Little Long Lac: A northwest-southeast axial trend. Were such cross folds of purely local extent, or might they be indicative of a widespread regional fold pattern? If so, has such folding any significance for mineral exploration or potential?By 1959, based on a study of about 1000 Canadian geological maps and reports, including 291 in Ontario, the writer reached the conclusion that cross folding trending northwest-southeast is so widespread as to constitute a pattern of folding, and that such cross folding should produce changes in plunge along pre-existing greenstone fold belts."

Jan 1, 1980

By J. H. Baek, D. W. Lee, B. K. Kim

Nanostructured Cu-Al203 composite powders were synthesized by thermochemical process for an electrode application. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from copper and aluminum nitrates, 2) heat treatments to evaporate volatile components in the precursor powder and synthesis of nanostructured CuO+Al2O3, and 3) CuO reduction by hydrogen into Cu. The suggested procedures stimulated the formation of the gamma-Al2O3. The mean particle size of the final composite powders was 20nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/Al2O3 composite by the conventional internal oxidation process.

Jan 1, 2004

By J. A. McLennan

Geological uncertainty is an unavoidable characteristic of all mining projects since only limited information is available from sampling. Mine planning and development decisions with significant economic consequences are made when the geological heterogeneity is inherently uncertain. Geostatistical simulation is preferred over kriging because the methodology provides alternative property realizations that can be combined into a model of geological uncertainty. Geological uncertainty can be transferred into production uncertainty, which can help characterize the economic risk of the project. This paper presents a case study for the Pogo property, being prepared for development near Fairbanks, Alaska. The exact dimensions, grades and production predictions have been modified; however, the methodology is illustrative. The geostatistical methodology consists of (1) assembling the relevant drillhole data and establishing a suitable coordinate system, (2) calculating the target distribution, (3) creating a model of spatial correlation, (4) generating multiple realizations at a small scale and (5) linearly averaging all the realizations to the chosen selective mining unit (SMU) support size. The geostatistical model is then used to calculate production uncertainty.

May 1, 2004

Peñasquito is Mexico's largest gold producer, consisting of two open pits - Peñasco and Chile Colorado - containing gold, silver, lead and zinc. Over the next three years, mining activities in the pit are expected to be focused on lower grade ore in the upper parts of the Peñasco pit while stripping is emphasized to ensure an economically optimal pit shell design to maximize the net asset value of the operation. By 2019, Peñasquito’s gold production is expected to benefit from an improvement in mined grades as it recommences mining higher grades at the bottom of the Peñasco pit and significantly enhanced metallurgical recoveries with the planned completion of the Pyrite Leach Project ("PLP").

Jan 1, 2017

By J. C. Escobedo, J. M. Almanza, A. Flores, Cortés. D. A.

Secondary aluminum dross, which has been exposed for several years to atmospheric conditions, was characterized using chemical analysis, X-ray diffraction, optical and scanning electronic microscopy, and energy-dispersive spectroscopy. Based on the characterization, a method to purify the solids is presented. This method starts with the washing of the dross in boiling water to eliminate the soluble compounds like Na and K, followed by the physical separation of the metallic aluminum by milling and screening. Finally, an acid lixiviation process is applied using three different acid solutions, HCl, HNO3, and H2SO4. The best results were obtained using HCl. The main insoluble components of the dross after lixiviation were Al, SiO2, and Al2O3. MgAl2O4, AlN, Si, and Na2Al22O3·2H20 species were also found. Based on the alumina content, the solid product could be suitable as a raw material in the manufacture of castable refractories or metal matrix composites.

Jan 1, 2005

By M. Kalin

"SUMMARYWaste management in general, and the water treatment of mine and mill effluents, has become an ever increasing burden for mining operations. A reduction in these expenditures would undoubtedly be desirable if this could in fact be achieved within effluent guidelines and monitoring requirements.A brief summary is presented of the research which has as its aim the development of methods which would reduce such costs and lead to solutions for environmentally acceptable close-out conditions for acid generating mine waters. The basic concepts of Ecological Engineering and Biological Polishing are presented, together with an indication of the present state of these research efforts. Details are provided of the progress of various experiments which aim to promote reducing conditions, organic matter production and the establishment of biological filters which remove metals from the water which are then retained within the waste management areas. These conditions should lead to a curtailment of acid drainage and an improvement in effluent quality.A description is provided of the first pilot demonstration using this approach to achieve a walk-away condition for the close-out of a massive sulphide tailings resulting from 10 years of operating a copper/zinc concentrator in Northern Ontario.1.0 INTRODUCTION1.1 Waste management and close-outIt is recognized that the achievement of a cost-effective and competitive mining operation, from the commencement of exploration for ore bodies through to the day-to-day efficient operation of the mine, requires a certain expertise and sophistication. However, the environmental effects of these activities are considered peripheral issues and their importance as an integral part of the planning and development of the mine/mill, is not always appreciated."

Jan 1, 1988

By Takayuki Takasugi, Naoya Masahashi, Yasuyuki Kaneno, Satoshi Semboshi, Yusuke Kadoi

Cu–Ti alloy wires doped with and without a small amount of Ni were fabricated by over-aging and using intense drawing procedures. For both the Cu–Ti alloys with and without Ni doping, the over- aged microstructure was occupied fully with a coarse lamella of Cu solid solution and β-Cu4Ti plates precipitated discontinuously by grain boundary reactions. The full-lamellar microstructure was developed much more rapidly by aging in multi steps at 873 K to 723 K rather than by isothermal aging at 723 K. Ni doping in Cu-Ti alloy was also effective to accelerate the formation of the lamellar microstructure. When drawing the over-aged alloy with inferior hardness but superior electrical conductivity, the strength increased steadily and eventually exceeded that for the wires drawn from the peak-aged alloy. In addition, the electrical conductivity of the wires drawn from the over-aged alloy was always much greater than that from the peak-aged alloy. Eventually, the procedure of over-aging, followed by intense drawing, could enhance both the strength and electrical conductivity of Cu-Ti alloys, whichever they contain a small amount of Ni or not, rather than the conventional peak-aging and drawing process. INTRODUCTION Cu-based alloy wires, which have an excellent combination of strength and electrical conductivity, have attracted extensive attention for highly mechanically stressed electrical devices, such as conductive lead wires and wires in suspension springs. Cu-Be alloys are widely used for such electrical components owing to their combination of strength and electrical conductivity among industrial Cu-based alloys. However, since beryllium is potentially toxic and also a rare element, substitute materials for Cu-Be alloys have been searched for several decades. Age-hardenable Cu–Ti based alloys have been proposed as candidates because their mechanical and physical properties are comparable to those of Cu-Be alloys; however, their electrical conductivity is inferior (Datta & Soffa, 1976; Soffa & Laughlin, 2004). In order to satisfy the requirement of downsizing and streamlining electrical devices, further improvement of the mechanical and electrical properties of Cu–Ti alloy wires is needed. Age-hardenable Cu–Ti alloys, which contain approximately 3 to 6 at.% Ti, are typically prepared using a solid solution treatment above 1100 K and then aging at a moderate temperature of 700 K to 800 K. It has been revealed that the microstructural events during aging progress as follows (Soffa & Laughlin, 2004): (1) compositional modulation of the parent supersaturated Cu solid solution in an initial aging stage (Laughlin & Cahn, 1975), (2) continuous nucleation and growth of fine needle-shaped precipitates of metastable β’-Cu4Ti with a tetragonal structure in a peak-aged stage, and (3) discontinuous precipitation of cellular components laminating the plates of a terminal Cu solid solution and stable β-Cu4Ti with an orthorhombic structure at the grain boundaries in an over-aging stage. It has been also accepted that the highest number density of dispersed fine β’-Cu4Ti needles should contribute to maximal strengthening. On the other hand, decease of the strength in the over-aging stage occurs due to the replacement of the fine β’- Cu4Ti needles with cellular components containing coarse β-Cu4Ti plates, while the electrical conductivity is significantly enhanced due to the depletion of solute Ti in the Cu matrix. This suggests that a combination of strength and electrical conductivity for age-hardenable Cu-Ti alloys is in a trade-off relationship, and that innovative improvement of both properties might be limited to tuning the aging conditions.

Jan 1, 2019

By C Jincheng, L. Liang, L. Wenjun

"Considering overgrinding in a grinding process, the grinding characteristics of comminuted hematite products using a HPGR and a conventional CC were comparatively studied. The major properties including particle size, grinding kinetics and grinding technical efficiency (Et) were investigated. Individual size distributions (ISDs) of -2.0mm in a HPGR product showed a more significant “double-peak” characteristic than a CC product. As a result, HPGR products were finer and had a wider full-size distribution because of the greater proportion of fines. The parameters m and zi in m-th order grinding kinetics were analyzed by the partial-derivative method and the critical time tc(tc = exp (1/ zi)) was obtained. zi mainly affected the breakage rate when t < tc; otherwise, m mainly affected the breakage rate. In these tests, tc was considerably higher than the grinding times, and HPGR products yielded a higher zi-value than the CC product for the same sieve size. This indicated that HPGR products had a higher breakage rate and needed a shorter grinding time for a certain grinding fineness. Et was calculated by simulating the size distributions of batch grinding products. HPGR products gave a lower Et at a decreasing rate than the CC products for -2.0 mm feed and -0.5mm feed, and then showed a slightly higher Et for -2.0+0.5 mm feed. This indicated that overginding in HPGR full-size products was more serious under the condition of coarse grinding, whereas the efficiency was higher and overgrinding weakened significantly in HPGR coarse products because of screening-out fines. Based on the above research, a new process of “ultra-crushing in HPGR – classified grinding” was advanced, reducing ores tonnage into first stage ball mill significantly, improving grinding efficient and weakening overgrinding in the whole grinding process.INTRODUCTIONIn mineral processing, comminution accounts for a substantial portion (approximately 60~70%) of the energy consumed in plants. As an ultra-fine crushing equipment,the application of the HPGR for industrial comminution has been paid close attention because of its low specific energy, low steel consumption, high capacity and high ratio of reduction, among others (Schonert, 1998; Norgate & Weller, 1994; Fuerstenau & Kapur, 1995). HPGRs comprise two counter-rotating rolls that draw feed material into the roll gap. One roll is fixed to the mainframe, while the other movable roll is mounted on slides and positioned by hydraulic rams. The specific pressing force (SPF) (i.e., total force divided by projected roller area) is typically in the range of 3~9 N/mm2 depending on the application, while pressures of up to 1000 N/mm2 have been measured within the operating gap (Maxton , Morley, & Bearman , 2003)."

Jan 1, 2016

By A. Ingelson

Conflict over mineral development and its impacts on indigenous peoples occurs in many countries around the world. Canada, Bolivia and Peru have experienced mine development for centuries in areas where indigenous communities have been and continue to be affected by the mining industry. On a global basis the mining industry continues to face the challenge of implementing meaningful consultation programs with indigenous peoples. Many governments around the world have adopted sustainable development as a policy and one important element of sustainable development is minimizing social conflict. John Moffet and Francois Bregha (Moffet & Bregha, 1996), in their analysis of the role of law reform in promoting sustainable development, noted that stakeholder participation can reduce this type of conflict. Social conflict can result in expensive litigation and costly project delays for mine developers. Meaningful consultation with indigenous peoples in areas where mine development is proposed can be a critical factor in securing a social licence to operate. A report released by the United Nations in 2005, outlined the elements of a concept called ?free, prior informed consent? (FPIC) that promotes more sustainable development. FPIC provides that mineral exploration and mining should not proceed unless the mining company has secured the consent of the relevant indigenous group(s). This paper employs a comparative approach to evaluate the extent to which three active mining nations, Canada, Bolivia and Peru, require consultation with indigenous residents and adhere to the principle of FPIC. The comparative approach assists in the identification of those consultation elements in the legal regimes of each country that can minimize social conflict in mineral exploration and mine development and therefore contribute to more sustainable development. First, we examine the legal requirements to consult with and accommodate indigenous communities in Canada, a country with a long history of mineral development over a large geographic area that has entrenched in its Constitution the protection of indigenous peoples? rights. We then turn to an analysis of Bolivia, one of the most indigenously conscious mining jurisdictions that has followed the Canadian lead in entrenching constitutional protection for indigenous peoples. Third, the approach to consultation with indigenous peoples in Peru, a nation that has not adopted the Canadian and Bolivian approaches to constitutional protection of indigenous peoples rights, is considered.

Aug 1, 2013

By J. C. Folinsbee, D. R. Derry

"The Property of Opemiska Copper Mines (Quebec) Ltd. is in Levy Township, Chibougamau district, west of Chibougamau and south of Opemiska Lake. The original find was made in 1929 by the late Leo Springer and associates of Prospectors Airways Ltd., following observation from the air of an area of dark rocks in newly burned-over country. Work on the ground discovered three veins of high-grade chalcopyrite in gabbro (No. l, No. 2, and ""North"") and, after several seasons of trenching and diamond drilling, financed by Ventures Ltd., a shaft was sunk in 1936. This work indicated about 280,000 tons of six per cent copper ore to a depth of 500 feet. During this period, the senior author carried out a reconnaissance geological survey over the whole property and surrounding claims, which showed that the veins were in the gabbro portion of a large composite basic sill that had been folded with the enclosing lavas. Owing to the low price of copper and lack of transport work was suspended and the property remained dormant until 1951.In that year the company was re-financed, the property prepared for production, and further exploratory drilling undertaken. The drilling, based on structural indications, located a new vein of which the only previous evidence had been some irregular stringers. This vein, No. 3, was traced by drilling for a length of 2,000 feet and the indicated reserves were thereby increased to about one million tons. An additional vein, No. 4, was intersected in several holes.With this encouragement, plans for production were confirmed, and operations commenced' at the beginning of 1954 on a scale of about 400 tons a day, concentrates being shipped by truck to St. Felicien and thence by rail to Noranda. In the first year of operation concentrates were re-covered carrying 14,047,210 pounds of copper, 76,714 ounces of silver, and 6,259 ounces of gold. The operation is under the direction of J. P. Millenbach, General Manager, with J. M. Thompson as Assistant General Manager and F. G. Cooke as General Superintendent on the property."

Jan 1, 1949

By Jianwen Yang, Yucai Zhou, Yanhong Dong, Daixiong Chen

"The study of combined depressants for flotation separation of lead from copper has been carried out to solve the copper-lead separation problem. Test results show that the depressant of CMC (Carboxyl Methyl Cellulose) or sodium sulfite plays an important role on the selective depression of galena flotation. When the two reagents above are combined, the selective depression effect on galena is further enhanced. When the mass ratio of CMC to sodium sulfite is 1:4, galena was best depressed, with the lowest lead content in the copper concentrateClosed-circuit tests indicate that under a certain pH value of the slurry, with the best ratio of CMC to sodium sulfite as depressants, the copper concentrate with the grade of 28.23% copper and 4.12% lead is obtained, and the copper recovery is 84.87%; the lead concentrate with 68.12% lead and 0.86% copper is obtained, and the lead recovery reaches to 92.20%. An efficient separation of copper and lead is achieved with the combined depressants. INTRODUCTIONComplex copper-lead-zinc sulfide ore is abundant in China. With the rapid increase of mineral consumption, it has become one of the important sources to produce copper-lead-zinc metals. However, it is difficult to achieve effective separation of copper and lead, due to the complicated ore properties, such as fine dissemination, low copper grade, complex symbiotic relationship and similar floatability of copper and lead.Poisonous reagents of bichromate and cyanide are often used as depressants for copper lead separation. They have good separation efficiency, but pose serious pollution issues. As the environmental protection is becoming more and more important, it is a trend to replace traditional toxic reagents with new nontoxic efficient chemicals. Organic depressant FCLS studied by Liu has strong selectivity against galena, and does not depress chalcopyrite. A new type of galena depressant of CLS-01 discovered by Jin-lin Yang shows good results in the separation a mixed copper and lead concentrate. In addition, dextrin, chitosan and some other natural organic compounds (Drzymala, 2003; Huang, 2012; Qin, 2013) have also been studied to separate copper and lead."

Jan 1, 2016

By D. M. Maijer, S. L. Cockcroft, S. Modak, A. B. Phillion

"A comparison between hydrogen-diffusion-based micro-porosity formation and growth behaviour of two important aluminium foundry alloys, B206 (Al-Cu) and A356 (Al-Si-Mg) is presented in this paper. Specifically, the predicted pore size and pore fraction distribution of these two alloys resulting from directional solidification and identical hydrogen concentration are investigated numerically based on a model proposed by Yao et al. (2011. Met. & Mat. Tran. A. 42A, 4137–4148). This model takes into consideration the initial hydrogen content in the melt, the cooling rate, the partitioning of hydrogen between the solid and liquid phases, and the evolution in solid fraction with temperature. Due to different alloy chemistries, the activity of hydrogen in B206 and A356 are quite different, as are the solidification range and the resulting solidification microstructure. Being a primary alloy, B206 has dendritic microstructure and solidifies over nearly 135°C (505–641°C), whereas A356 contains fifty percent eutectic microstructure, and solidifies over 80°C (533–613°C). This allows a very different behaviour of micropores i.e. the effective pore radius in B206 is quite a bit lower as compared to A356, as is the pore number density. The evolution of local hydrogen concentration in liquid metal is analysed and compared for both the alloys.INTRODUCTION Over the past decades, the demand for materials with enhanced strength-to-weight ratios has significantly increased in the aerospace and automobile industries in order to improved fuel efficiency. For many automotive components, particularly shape castings, the trend is towards replacing ferrous alloys with aluminium alloys. The increase in the use of Al is primarily due to its low density, about one-third that of steel, and its relatively good strength that allows for weight reduction without reducing performance. Presently, Al-Si based alloys (e.g. A356) are the most prevalent due to their good mechanical performance in strength-to-weight ratio and excellent castability (Atwood et.al., 2000). However, superior mechanical properties can be achieved using Al-Cu alloys. For example, the alloy B206 offers a higher strength while retaining excellent ductility (Poirier et.al., 1987)."

Jan 1, 2017

By K. Huang, L. Pan

"Darcy’s law has been used extensively to model cake filtration. It is a macroscopic model, in which particle size dominates the kinetics and cake moisture. In the present work, a capillary flow model has been developed from first principles to study the effects of microscopic parameters such as capillary radius, boundary layer slip, disjoining pressure, and surface tension that may be important for dewatering ultrafine particles. Laboratory-scale pressure filtration tests show that dewatering kinetics is strongly dependent on capillary radius, which in turn is influenced by surface hydrophobicity, surface charge, and length scales of particles. The model parameters determined from laboratory-scale filtration tests show that use of a hydrophobizing reagent can greatly improve fine particle filtration due to increased slip and decreased capillary pressure. The kinetics of dewatering kaolin clay is fastest at a pH where the layer-structured particles coagulate with a face-to-edge orientation. The capillary flow model developed in the present work may be useful for designing filters and optimizing operating conditions.INTRODUCTIONIn 2014, Canada produced 2.2 million barrels per day of crude oil from the oil sands resources in Alberta, which is expected to grow to 3.2–4.0 million barrels per day by 2030 (CAPP, 2013). One of the challenges to meeting these projections is the tailings management. At present, the industry uses ?77 km2 of the lands to construct tailings ponds. Significant amounts of the tailings disposed to the ponds are silts and clays that are slow to settle and consolidate, creating problems for reclamation. It is, therefore, the objective of the present work to develop a filtration model that may be useful for developing advanced dewatering technologies that can address the tailings management issues.Darcy’s equation is the governing law for filtration. It was derived as an empirical model by H. Darcy in 1856 while he was studying fluid flow in sand filters (Hall, 1956). Since then, many investigators derived it from first principles. It relates superficial fluid velocity to the pressure drop across a porous medium of known permeability. In filtration, the latter can be related empirically to particle size using the Kozney equation (Yoon, 2005)."

Jan 1, 2016

By M. Lindgren

"Hydrometallurgical processing involves process stages, like leaching, that create harsh environment for stainless steels. High acidity, the presence of chlorides and oxidizing ions combined with relatively high temperature create risk for both uniform and localized corrosion. Advanced electrochemical techniques were employed to study uniform and pitting corrosion of two stainless steel grades 316L and 2205. Results obtained with the linear polarization resistance technique combined with the harmonics distortion analysis, electrochemical noise and coupled multielectrode array systems are compared to the results of conventional electrochemical techniques and immersion tests.INTRODUCTIONHydrometallurgical processing has become favoured in metals production in recent years due to energy costs, leaner ore bodies and environmental factors. Because the hydrometallurgical processing route is flexible, various types of secondary raw materials, like flotation tailings, dusts, sludges and slimes can also be treated in addition to conventional mineral concentrates (Sarveswara Rao & Acharya, 2008).Hydrometallurgical processing relies on aqueous chemistry, usually acids, at temperatures around 100°C for the recovery of metals from ores, concentrates, recycled or residual materials. The processing route can typically be divided into three stages: leaching, solution concentration/purification and metal recovery. The processing environment is aggressive, especially in leaching. High acidity, relatively high temperature together with impurities, like chloride ions, place high demands on the corrosion resistance of construction materials. The dominant corrosion mechanism may be uniform corrosion or localized corrosion depending on the process conditions (Ekman & Torsner, 2010). This complicates the prediction of corrosion rates and, consequently, cost effective material selection.Traditional means to evaluate uniform corrosion resistance of stainless steels are immersion tests and the results are published in the form of iso-corrosion diagrams (Outokumpu Stainless, 2010). For the localized corrosion, namely pitting and crevice corrosion, immersion tests can be used but the duration of the test is rather long because an incubation period takes place prior to the occurrence of the actual localized corrosion damage. Electrochemical techniques, traditionally in the form of cyclic polarization scans, have been employed to assess the susceptibility of a material to pitting corrosion (Papavinasam, 2008). They cannot, however, give any indication of the pitting corrosion rate and lack potential for on-line measurements."

Jan 1, 2012