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By H. O. Olsen

"GeneralTHE IRON ORE at Marmora is a replacement deposit of Precambrian limestone and is overlain with Palaeozoic limestone. It is a low-grade magnetite deposit and the ore will require concentration be-fore it can be used economically for the production of iron and steel.Present plans estimate an annual production of 500,000 tons of concentrate in the form of pellets. This will require mining approximately two million tons of ore and\ waste annually. Shipment of pellets from Marmora to a ship-loading dock at Picton will be made by rail on a year-'round basis. Shipments from Picton to the Lackawanna plant of the Bethlehem Steel Company at Buffalo, N.Y., will be carried on during the Lake shipping season.LocationThe mine, located a mile southeast of Marmora village in Hastings county, Ontario, is 31 miles north of Belleville and 3•7 miles east of Peterborough. Marmora is 130 miles from Toronto and 150 miles from Ottawa. Highway No. 7 passes half a mile north of the mine and Highway No. 14 half a mile west of the mine. The Canadian National railways' branch line between Trenton and Bancroft passes through the property just east of the open pit.HistoryThe Ontario Department of Mines conducted an airborne magnetic survey of the district during 1948 and 1949. Maps of this survey were released to the public early in 1950. Bethlehem representatives carried out ground surveys in the Marmora area shortly thereafter and in June, 1950, commenced diamond drilling."

Jan 1, 1955

By W. R. Tyson

IT HAS BEEN KNOWN for many years that alloy steels can become brittle when tempered in the range of 350-600°C, or cooled slowly after heating to higher temperatures. The metallurgical literature reveals that blacksmiths were aware as early as 1883 that water quenching was necessary after heat treatment above 600°C to avoid brittleness. It has also been known for years that the problem is associated with trace impurities; a paper in the Journal of the Iron and Steel Institute of 1894 refers to the brittle, faceted fractures that occur in steels containing arsenic, phosphorus or sulphur. However, definitive investigation of the mechanism of embrittlement has been possible only within the last decade with the introduction of new experimental techniques to investigate surfaces, especially Auger electron spectroscopy. It is now possible to study in detail the chemistry of surfaces with a resolution of an atomic layer or two, and enormous progress has been made recently in studying the segregation of impurities to grain boundaries by exposing the boundaries by fracture inside the microscope. A clear picture of the processes occurring and their interpretation is now emerging, as was particularly clear at the recent 1977 ASM Materials Science Seminar on Interfacial Segregation held in Chicago in October. Recent research in this area has pointed the way for commercial exploitation of this new knowledge and experimental technology. It is the purpose of this article to trace progress in understanding temper embrittlement and to indicate other areas where control of interfacial segregation and its effects can be important in metallurgical applications.

Jan 1, 1978

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016

Cansolv® S02 Scrubbing Technology was described in a paper in Copper/Cobre 03. Four years on, the technology is operating at a full scale production facility.Hindustan Zinc Limited expanded their capacity by installing the AUSMELT process. The process proceeds through smelting, slag reduction, slag cleaning and holding stages sequentially in the same vessel, resulting in widely varying off gas characteristics. The off gas is suitable for treatment is a conventional acid plant for a modest proportion of the day, but at other times produces off gas too high in S02 to be discharged to atmosphere. Cansolv® S02 Scrubbing Technology was identified as a means of effectively removing the S02 down to low levels from the off gas during all stages of the pyrometallurgical process. Furthermore, the Cansolv® S02 Scrubbing System Technology produces high purity S02 that allowed for the captured S02 to be directed to an existing acid plant, avoiding the capital cost of new acid making capacity.

Jan 1, 2007

By Arthur R. Rattew

In conjunction with the research study of the Coronation Mine recommended by the National Advisory Committee on Research in the Geo-logical Sciences and coordinated by the Geological Survey of Canada, Canadian Aero Service Limited per-formed a detailed, low-altitude air-borne survey over a block of ground encompassing the .Coronation Mine. The in-phase/out-of-phase air-borne electromagnetic data are com-pared with "horizontal-loop" ground data with reference to: size and nature of conductors detected; criteria in selection of targets for drilling. In-formation provided by Hudson Bay Mining and Smelting Company on their drilling of the numerous conductors in the area is employed in this comparison. The merits of combining a sensitive airborne magnetometer with an air-borne electromagnetic unit are discussed. The magnetic data are considered very important in assessing conductors as prospects for commercial sulphida deposits in this area of numerous electromagnetic anomalies. The "Coronation" survey illustrates

Jan 1, 1962

By V. J. Southey

HOLLINGER mining operations have required development by 24 vertical shafts having a total length of 28,160 feet. Seventeen of these are sunk from surface and seven are interior shafts. Four surface shafts and three interior shafts are now active and, excepting the recently completed new main ore-hoisting shaft, the remainder are either abandoned, or are used for passes or for ventilation. The new shaft bottoms 60 feet below the 3,050 level, but there is much work to be done before it is placed in service. The term 'shaft practice' is intended to include shaft construction and a general treatment o typical equipment. It is a large subject for an organization the size of Hollinger and this paper is intended only to present the salient features. The writer wishes to thank the management for permission to publish this information and to acknowledge the advice and criticism o A. G. Irving, chief engineer, and the willing co-operation of other members of the Hollinger staff.

Jan 1, 1939

By R. E. Eyre

ALTHOUGH the idea of roasting zinc concentrates in suspension had intrigued investigators for a number of years, no commercial application of a process appeared successful until the development of the "Cominco" process. The efficiency and high capacity of this process may be judged by the fact that nearly all other electrolytic plants and many zinc retort plants in the world use this method. A furnace of the Cominco type can roast without special preparatory treatment and without supplementary fuel, mineral sulphides such as zinc sulphides and iron sulphides containing varying amounts of moisture at any desired rate ranging from one-half up to full capacity. The full capacity of a unit is in general about three times that of a multiple hearth furnace of the same size. The latest type of "Cominco" furnace can be built for capacities from 25 to 500 tons per day. The quality of the calcine is subject to positive control and may be

Jan 1, 1961

Lonmin RoM ball mills are treating two types of feed ore produced by conventional mining and mechanised mining methods. It was reported that reduction in mill throughput was observed when treating the mechanised mining ore. Detailed grinding surveys were conducted for troubleshooting. Ore samples were collected for breakage characterisation using a JKRBT based on different particle density components. XRD analysis was conducted to investigate the association of minerals with density components. The plant surveys and the breakage characterisation tests all suggested that the two mining methods did not significantly affect either the ore breakage properties or the RoM mill performance. Instead, the mill discharge open area exerted a remarkable influence on mill throughput. The RoM ball mill operated at Lonmin K4 Concentrator has been proven to be a versatile mill that performed stably with variations in feed size distribution and feed ore changes by different mining techniques. The reasons are elucidated by the multi-component breakage characterisation and the plant surveys data.

Jan 1, 2012

By G. V. Poropat

Roughness of a discontinuity may be an important factor influencing shear strength of the discontinuity. Traditionally, determining the roughness of a discontinuity surface and providing a numerical measure of the roughness has required considerable effort or specialised equipment. The development of new 3D imaging tools that are easy to use has provided effective fast and accurate means of creating 3D surface models from which roughness measurements can be readily obtained. These new techniques are versatile enabling a user to measure roughness along any desired profile and at any resolution up to the limit of the spatial subtense of a measurement on the discontinuity surface. This paper primarily reviews extensions to the use of 3D imaging that enable the measurement of roughness. Additionally we provide some examples of the measurements and examine some of the issues associated with extracting measures from the spatial data that will support estimation of shear strength.

May 1, 2009

By G. H. Montgomery

THE PROPERTY of Aunor Gold Mines, Limited, consists of eleven claims, located in Deloro township, approximately three miles southeast of the town of Timmins. Production began in 1940 and currently the mine is operating at a rate of 485 tons per day. GEOLOGY AND MINE DEVELOPMENT The ore zone at Aunor occurs in altered lavas bounded on either side by soft talc-chlorite schist, locally known as 'soapstone'. The zone has a strike of N.80°E, dips 60° North, and varies in width from 0 to 250 feet. Within this zone the main orebody has a westerly plunge, away from the No. 1 shaft area (Figure 1). The mine is developed by a vertical three-compartment shaft from surface to the 3,082-foot horizon. Working levels are spaced at 125- foot intervals from the 625-foot to the 1,625-foot horizon, from which to tl1e 2,125-foot level the interval is 250 feet.

Jan 1, 1957

By M. Kuyumcu

After German reunification the mining industry in former East Germany was profoundly restructured. Beside privatization of profitable companies the public sector took over responsibility for the mining operations to be shut down. Therefore state-owned companies cope with technical, ecological, and social challenges. The rehabilitation and reclamation has to rededicate former mining areas to new use and provided new jobs as well. In the lignite mining districts there are around 100,000 ha of mining area, a mining caused disturbance to the groundwater balance and to the system of surface water bodies of approx. 390,000 ha. They are called the largest landscape construction site in Europe. In addition to the results and diverse experience achieved over the past 23 years, a description will follow of our new challenges and of an outlook on remaining tasks. This article will describe the financing, as well as aspects of the jobcreation policy arising from lignite industry remediation.

Aug 1, 2013

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By N. K. Jaber

The "Pidgeon Process" for the extraction of magnesium from dolomite ore utilizing ferrosilicon as the reducing agent has been studied extensively by active metallurgists such Mr L,M, Pidgeon the father of this process, Most of the work sited so far has focused on heating the (FeSi/MgO,CaO) briquette mix under vacuum in stainless steel retorts by external fuel hydrocarbon heating, In this work Electrical Induction Heating was employed as the heating method whereby the briquette mix was placed in a steel crucible around which an Induction Heating copper coil was wound and placed inside in a stainless steel vacuum tank, It was observed that by virtue of the fast Induction Heating method utilized in the silicothermic extraction process higher reduction temperatures were reached in shorter periods of time due to fast heat transport into the ore charge mix, This facilitated shorter metal reduction times as compared to the conventional fuel heating methods.

Jan 1, 2006

By Kathy S. Kalenchuk

Damages have been observed in shafts, backfill infrastructure and the slick line at the Leeville Mine. Shaft damage (shearing and spalling of the concrete liner) is attributed to mine-induced rock mass deformations concentrated where regional faults intersect the shafts. Aggregate bin, mixer station and conveyor drive damage (shotcrete shearing, heave of concrete floor slabs and bending of a vertical steel beams) is attributed to rock mass squeezing induced by elevated magnitudes of the vertically orientated major principal stresses. Separation of the slick line has occurred do to extension of the stressshadowed rock mass immediately above the mined out areas. Three-dimensional numerical models have been developed and calibrated to simulated rock mass deformations with magnitudes similar to those believed to have produced the observed damages. By stepping through the mine sequence, models reproduce deformations at the same mining stage as when damage has occurred. Calibrated models have been used to forward project further damage over the remaining mine life.

Jun 1, 2012

By S. Southall, F. McCaffrey, F. Stober, M. Darini

Electrode Columns are commonly used in electric furnaces to deliver current and regulate furnace power to the smelting or melting process. Hatch has developed an innovative patent-pending system for lowering ("slipping") and/or raising ("back-slipping") the electrodes through an electrode column, without requiring the release of any clamping devices. All clamping forces are applied by springs. Unlike systems employing hydraulically applied clamping forces, (e.g., water bladders) the spring system is failsafe. Its inherent simplicity virtually eliminates the need for maintenance. The Hatch system is particularly applicable to Soderberg electrodes, and comprises two axially movable slipping clamps and a stationary power clamp, each of which apply a distributed, radial clamping force to the electrode. The magnitudes of the slipping sleeves' clamping forces and sequencing of their axial movements are selected such that the slipping clamps, in conjunction with the weight of the electrode, provide slipping or back slipping without release of any clamping force.

Jan 1, 2005

By A. M. Brown, P. V. Straznicky

Dimpling as a means of flush countersinking rivets is an old process predominantly used in secondary structures. The introduction of GLARE as an aerospace material has renewed interest in dimpling and its possible application in primary structures. The dimpling process is able to prevent the creation of a machined knife-edge in the thin aluminum plies of the GLARE sheets. In addition, dimpling eliminates the need to use reduced height rivets, such as the NAS 1097 rivet style. This investigation expands on an earlier study into dimpling of GLARE by Rans and Straznicky. In order to tailor the dimpling process to GLARE, FEM simulations were developed. After verification, a study was performed to find the best parameters for dimpling GLARE3-2/l. Coupon fatigue tests were carried out and the dimpled joints demonstrated increased fatigue lives over the conventional machine countersunk joints. Future wide panel fatigue tests are planned to confirm the usefulness of dimpling thin GLARE laminates.

Jan 1, 2006

By H. Vendette, N. R. Dando, A. Moras

The thorough analysis of results obtained from different testing campaigns performed on an alumina dry-scrubber pilot installation treating aluminum potline offgases, suggests a clear relationship between the emissions of gaseous fluoride and the fluoride saturation level of the alumina. The integration of this relationship into the development of a new generation of alumina dry scrubber represents an intriguing challenge regarding the design of more efficient air pollution control equipment. An innovative scheme challenging conventional industry practices was proposed. From theoretical simulations, the reduction in fluoride emissions can potentially be reduced by as much as 50% in the summer season. To validate this innovative approach, Solios in partnership with Alcoa Primary Metals, modified one of the Aluminerie de Deschambault's systems by adding new temporary equipment on the operating units and subjecting it to several test campaigns. This article presents the first results obtained in testing this new and innovative approach on alumina dry scrubbers used to capture fluoride emissions coming from aluminum electrolysis potlines.

Jan 1, 2006

By Young Hyun Paik, Hyung Sup Choi, Yeun Sik Kim

The basic studies on the surface properties and flotation characteristics of ilmenite were made by electrophoretic, adsorption, contact-angle and floatability measurements. The isoelectric point of ilmenite is found to be at pH 5.6. By combining the results of electrokinetic studies and adsorption measurements, a clearer picture of the ilmenite-solution interface was observed. These findings were correlated with the floatability of ilmenite obtained by Hallimond tube tests. The general flotation characteristics of ilmenite are compared with those obtained for magnetite and rutile. It is indicated that the above three minerals, namely, ilmenite, magnetite and rutile, have very similar surface properties and flotation characteristics. Therefore, it is difficult to make an effective separation of these minerals by flotation. However, it is found that sodium orthophosphate acts as a selective depressant for magnetite in anionic flotation. Therefore, close pH control of the pulp in the presence of the phosphate ion enhances the possibility for a successful separation of these minerals.

Jan 1, 1967