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By B. H. Kim

It is hypothesized that the standard approach adopted to characterize the ground and to determine the rock strength properties at depth are flawed and generally tend to underestimate the rock strength and possibly the stiffness, particularly when the rock mass is characterized as massive to moderately jointed or blocky to very blocky. It is therefore necessary to conclusively established that the hypothesis, that the rock strength in highly confined rocks is greater than generally anticipated, is actually valid and generally applicable, and then to develop new procedures to establish rock parameters that can be reliably used for the design of deep excavation.

May 1, 2009

By Ross Gallinger

In 1997 a group of Canadian mining companies met to review the Mine Environment Neutral Drainage (MEND) program and to consider future activities. They concluded (i) that Canadian industry and NRCan should fund a small secretariat in Ottawa to support technology transfer in Canada and (ii) that it was important for industry to continue the momentum of MEND on an international scale. The need for INAP (International Network for Acid Prevention) was strongly endorsed by company, university, consultant and government experts from Australia, Canada and the U.S. who were convened in Vancouver in February 1998. The initial focus was the development of a solid knowledge base covering the collective experience of INAP's members to promote the dissemination of successful practices, the identification of knowledge gaps and the formulation of effective research proposals. The sharing of information on past successes and failures alone was viewed as sufficient justification for the formation of INAP. INAP was officially launched in October 1998, and is now an effective, industry based initiative to globally coordinate research and development in the management of sulfide mine waste. Significant improvements in the management of sulfidic mine materials through knowledge sharing, research and development of technology by INAP will reduce liability associated with acid drainage. This paper will explore the international efforts and activities of INAP.

May 1, 2002

By Jacques Deraisme

The technology of percussion drilling is well mastered. The lower cost of percussion drilling allows more holes to be drilled for the same budget. However significant differences are often observed between percussion and diamond drill assay data. This is due to the increased level of contamination associated with the percussion drilling process. Statistical studies on twinned drillholes show that diamond and percussion assays cannot simply be merged in a traditional kriging approach. The question then arises on how to use both types of data to produce reliable resource estimates. To take into account the lower reliability of the percussion assays, a noise characterized by a variance is added to these data. The methodology consists of two steps: 1. Cokriging of the equivalent diamond value at the percussion assay locations. 2. Block kriging using diamond assays and equivalent diamond values, calculated previously, adding to these data a noise, whose variance is the cokriging variance of step 1. This particular way of achieving kriging is called kriging with variance of measurement error. The paper illustrates this innovative methodology with an application on an iron deposit. The results of this method is compared to block kriging using only diamond assays and the gain in precision is quantified. An extension of that approach to multi-element cokriging is also presented.

Oct 1, 2009

By Maarten van de Vijfeijken, Marco Rufli

"By using the latest generation of medium voltage frequency converters, new possibilities have arisen to improve the grinding process. Beside all the direct and indirect advantages, several dedicated functions have now been implemented for ring geared grinding mills in the minerals industry. The advanced operational functions ensure a smooth, safe and reliable operation with minimum stress for the mechanical equipment and therefore highest availability of the mill. Several papers have already been presented concerning the benefits of using this state of the art technology for mill drives (Ravani von Ow and Bomvisinho, 2010; Ravani von Ow and Gerhard, 2010). However this paper will not only show and explain the operational benefit of these functions, but will focus on the experiences gained with this kind of sophisticated ring geared mill drive system. Several measurements of different operating conditions (starting, frozen charge remover, controlled roll back, backlash, etc.) made on an installed and commissioned 2 x 5 MW dual pinion ring geared mill drive system will be shown and discussed. Also the accuracy of the load sharing between the two 5 MW motors during starting, normal operation and stopping will be demonstrated using real measurements from an operating system. Finally the inherent features of these drive systems are briefly discussed.INTRODUCTIONLooking at the demands of grinding mills, we can split them into operational, maintenance and protective demands. For smooth and safe operation, it is important that critical situations are avoided as much as possible. Maintenance functionality must be quick and easy to execute, while protection of the system is important during all operating conditions. ABB has considered all these demands during development of their dedicated mill functions. By adding an additional controller (mill controller), not only a lot of application related functionality and protection is included, but also the interface between the mill drive system and the customer’s distributed control system (DCS) is simplified."

Jan 1, 2011

By J. G. Price

"The paper reviews state-of-the art welding processes and consumables for structural and pressure equipment applications in offshore environments, particularly the Arctic. Optimum selection of consumables will be discussed with regard to the facility to meet tentative toughness requirements in weldments. Finally, the development of welding procedure specifications will be considered in relation to the prevention of hot or cold cracking and lamellar tearing.Welding RequirementsGeneralThe exploitation of Canadian frontier oil and gas reserves will require a fleet of various types of offshore structures. These will include fixed jacket types and semi-submersibles for the East Coast with huge man-made islands and icebreakers for the Arctic regions. Both these regions will also require supply and drill ships plus subsea pipelines and cargo tankers for transportation. Clearly the welding of these items will plays large part in the over-all integrity and safety of exploration and production operations.The required development in structural steels and pressure vessel steels, for current and future offshore structures, to improve properties, particularly toughness for lower temperature service, has also prompted welding researchers to develop process and consumable combinations to match the parent plate specifications. This development has had to consider particular aspects of weldability such as a low susceptibility to cold cracking and preventing low HAZ toughness. Current research has centred on attempts to increase HAZ toughness with higher heat input welding of newly developed structural steels.The installation of Arctic region pipelines has provided a sound base for future, more complex fabrications in the most severe service temperatures in the Canadian frontier although few of the installations have been designed to the lowest possible exposed temperature of -62°C."

Jan 1, 1987

By Ivan C. Machado

Jaguar Mining Inc. is implementing a 1.1 Mtpy, 7-year LOM gold project in the Iron Quadrangle (?Quadrilátero Ferrífero?), Brazil. Construction is on schedule and startup is programmed for Q2 2010. Mill feed grade averages 4.43 g/t and LOM gold production is estimated at 800,000 oz. The project entails two sulfide underground mines and three oxide/transition open pit mines. A state-of-the-art flotation/gravity concentration/CIP Plant has been designed based on testwork carried out by internationally recognized Canadian, U.S., and Brazilian laboratories. The mass recovery of the flotation section is only ca 10%, while its gold recovery is about 90%. Therefore, the CIP-ADR Plant will treat only 10% of the solids mass contained in the mill feed, while 90% will be fully cyanide-free material that will be partially used to feed a Backfill Plant. The leached tailings will be conveyed to a rather small tailings dam, whose 20- m3/h supernatant solution will be treated by a new electrolytic technology. The plant design contemplates a High Density Thickener for the cyanide-free rejects exceeding the backfill demand and a Regrinding Section before the Leaching Circuit. The estimated overall metallurgical recovery sits around 92%. This paper focus on the use of modern technologies to reduce costs, risks, and liabilities.

May 1, 2010

By Clifford S. Gibson

THE Workmen's Compensation Ace defines Silicosis as "a fibrocic condition of the lungs caused by the inhalation of silica dust sufficient co produce a lessened capacity for work". This fibrocic condition muse exhibit a specific appearance in the X-ray picture of the chest-an appearance which is not characteristic of several lung conditions which can cause lessened capacity for work and which are not due co silicosis. The layman is sufficiently familiar with this subject co know chat, as far as our knowledge goes, quartz is one of the principal objectionable factors in the production of this condition. He should also know that silicosis respects neither geographical nor industrial boundaries. It is as much a factor in some industrial processes (e.g. foundry work, sandblasting) as it is in mines handling ores containing quartz. Its development co a recognizable stage is usually a matter of many years. As yet, its cure is unknown. Its prevention is possible in varying degrees. The layman should also know that the development of fibrosis may be accelerated by breathing in, or living in, any atmosphere containing dust. Few normal adults, particularly those above a certain age, have clear lungs, and fibrosis in varying degrees is noted in the farmer, the steel worker, the clerk, and many others in varied occupations. It is not restricted to miners. Medical and industrial journals, and at times the press, are crammed with data pertaining to this subject, much of which is misinformation. This is particularly true of certain !laces where the preventive and compensation measures for the good o those earning their livelihood in an industry in which silicosis may be contracted are not so far advanced as in our own Province. A great many of these publishings are alarming to the layman. They leave him with the impression that he is taking his life in his hands if he elects to work underground, particularly in a gold mine-that he has at once sold his heritage of health and chat sooner or later he will succumb to the ravages of this ailment. Nothing could be farther from the truth. Actually, under present conditions in Ontario mines, a very small percentage of the men employed ever become impaired by silicosis to the extent chat they must withdraw from the industry. I propose to tell you briefly something of this subject as it affects our mines.

Jan 1, 1937

By Hans Lundberg

PREFACE THE successful conclusion of all geophysical work depends on the operator's skill and sound judgment, as well as on his knowledge of geology and geophysics. We have been fortunate enough to have as co-workers a number of very good men. Some results of their work are summarized in this paper, and it is a pleasure to acknowledge their cheerful spirit of co-operation and the enthusiasm and loyalty with which they have assisted in the building of a geophysical organization to serve the Canadian mining industry HISTORY Geophysical prospecting is commonly, but quite erroneously, regarded as something new. The name is modern, but the principle of applying physical laws to reveal the presence of hidden ore is several hundred years old. Already, at the beginning of our civilization, the need was strongly felt for methods that could indicate the presence of ore in regions where the ore-bodies were completely masked or hidden from the eye. Particularly in countries where the rocks have been eroded during periods of glaciation and later covered by a thick mantle of glacial debris, all kinds of mysterious schemes were invented to locate the hidden ore. Often magic was resorted to (for example, the divining rod), but methods based on sound principles were also developed. Such features as topography, colour and taste of surface waters, and the growth and occurrence of trees and plants, were used to reveal certain types of ore deposits. For finding bodies of iron ore, the compass was very early in use. The fact that objects of iron attract a compass needle was utilized in prospecting long bef01:e the time of Columbus, and a systematic search for bodies of iron ore by this method was organized as early as the year 1600. There are still in existence documents, dated a little over 300 years ago, which show that the Swedish Chancellor of that day, Axel Oxenstiorna, ordered dozens of sun-dial compasses from instrument makers in Germany. The Swedish Government at that time employed a great number of prospectors to search systematically for iron ore. This Government undertaking must have been quite successful, as a number of iron ore-bodies were found in areas covered by heavy overburden. These prospectors were simply Government 'geo-physicists', although they were not known by this fancy name.

Jan 1, 1937

By P. K. Kaiser, C. D. Martin, F. Amann

"This article focuses on the uniaxial compressive strength (UCS) of homogeneous and heterogeneous rocks. Critical factors impacting the UCS of rocks are reviewed and then separate assessments of UCS data from homogeneous and heterogeneous rocks are presented. The variability (coefficient of variation) of UCS test results for homogeneous rocks is found to be generally <25% while for heterogeneous rocks the variability is >35%. Failure mode variation is found to be the cause of the variability of UCS test results in heterogeneous rocks. Empirical engineering design methods that use UCS as an input parameter are discussed and suggestions are provided for selecting appropriate UCS values.INTRODUCTIONThe UCS is one of the most commonly used rock engineering parameters whether for rock mass classification or for strength determination. The mean UCS and its variability are often assumed to represent a reliable rock material property. For the reasons discussed in this article, UCS is rarely representative of the intact rock UCS. The UCS test simply records the collapse load during uniaxial loading of a cylindrical specimen. As suggested by many, the UCS is an index rather than a unique engineering parameter. The UCS is thus a proxy for rock strength which depends on the loading rate (e.g., Bieniawski 1967), specimen geometry (e.g., Hudson et al., 1971), specimen size (e.g., Bieniawski 1968), and many other factors. Furthermore, the UCS is not the same as the Hoek-Brown strength criterion parameter sci.There are differences in opinion on what is commonly considered to be ‘intact rock’. When sampling ‘intact’ pieces of core from drillholes crossing blocks of rock bound by block forming discontinuities, samples will be ‘intact’ but some samples will be veined, others will be damaged, and others will be neither. According to Hoek (1983), intact rock pieces are “the unfractured blocks occurring between structural discontinuities in a typical rock mass” and the sci parameter for intact rock is determined using the fitting procedure proposed by Hoek and Brown (1997) based on the data requirements outlined by Hoek (1983). Studies (e.g., Bewick and Kaiser 2014; Kaiser and Kim 2014) have shown that independently determined UCS and sci values for the same rock type are not equivalent. Thus, UCS data cannot be used as a replacement for sci."

Jan 1, 2015

By C. G. Williams

IN preparing this paper on Canadian mine taxation, there has been no attempt to detail the requirements of the various taxing bodies; but rather to consider the matter from the standpoint of its underlying principles and give a general idea of the methods adopted. I have added an Appendix setting forth the principal features of the various Acts, which should be used for general reference only, since new rulings alter minor details from time to time. In current legislation, many important points are left to the discretion of the Ministers and their deputies. We are, indeed, fortunate in having in Canada an able and conscientious body of permanent officials, who bring a sense of justice and courtesy to their work which is most commendable, and which has done much to simplify the working out of general problems. The production of metals may rightly be deemed a form of manufacture, but differs from the average manufacturing business in three important respects: (1) In its early stages, it is wholly speculative, since it is impossible to make any definite appraisal of value or possibilities. (2) The principal asset of any mine, i.e., the ore in the ground, is a wasting asset, and is irreplaceable. (3) Any additional burden by way of taxation cannot be passed on to the public but must be borne entirely by the producer. Having regard to the first of these differences, it is apparent that, since the risk of loss is great, the reward in case of success must be correspondingly great. This fact seems to be constantly overlooked by those who regard the all too few outstanding successes in Canadian mining history as fit prey for predatory legislation. As an illustration of the speculative nature of early mining development, let us consider the Province of Ontario-and I take this illustration simply because I am more familiar with conditions there, and not because I believe it differs greatly from any other province. From 1907 to 1933, 165,243 claims were staked and recorded, from which 43 mines were developed which paid one or more dividends. There was, of course, some duplication through re-staking; also, on some claims very little work was done, and most mines have more than one claim. But, since staking and recording cost real money and effort, each of these claims must have been considered to have had merit.

Jan 1, 1935

By A. D. Yell

"Recovery of water is always a major factor in the Beneficiation process. As Preparation Plants become larger the recovery of water for reuse, is a critical cost consideration. Tema Isenmann Inc in conjunction with our sister Company Multotec Manufacturing, has over the years, developed numerous different Screen Panels, Sieve Bends and Static Screens for dewatering. This paper will focus on a new innovation, the TeePee™ Panel which has double the open area of conventional Screen Panels. This results in efficient dewatering (reduced filter cake moistures) which allows for the use of smaller Vibrating Screens or increased capacity on existing Vibrating Screens. A major factor in the efficiency of any Screen Panel, including TeePee™ Panels, is the performance of the Vibrating Screen. If the Vibrating Screen does not have the required gravitational force or screen area to drain it will not dewater efficiently. Therefore a holistic approach has to be taken where the Vibrating Screen needs to operate at an optimal level, in conjunction with the correct Screen Panels, to achieve efficient dewatering. Key performance areas for Vibrating Screens are therefore detailed in this paper with an emphasis on important dewatering criteria. Case studies of different dewatering applications are included, where the use of TeePee™ Panels, has shown a marked improvement over conventional flat Screen Panels in reduction of filter cake moisture content.INTRODUCTION Dewatering can be done in a number of different ways and is largely dependent on the ore type, the particle size distribution and to what extent one needs to dewater will determine the method used. There are a number of different dewatering methods that can be used for particles above 200 micron, including Screen Bowl Centrifuges, Filter Presses, Static Screens, Static Sieve Bends and Vibrating Screens. This paper will focus primarily on Vibrating Dewatering Screens showing improved drainage and a reduction in the filter cake moisture content. KEY PERFORMANCE CRITERIAL FOR VIBRATING DEWATERING SCREENS For clarification the critical key performance criteria for Vibrating Dewatering Screens are set out in this paper. Dewatering Screens Vibrating Dewatering Screens are normally linear motion, either horizontal or inclined at 5 to 7° upwards with a vertical or back sloped plate at 45° to the rest of the screen deck. The back plate will often have screen panels in them to increase the dewatering capability, as shown in Figure 2 below."

Jan 1, 2017

By M. L. Smith

"In the Phosporia formation of SE Idaho, ore quality varies by depth, seam and distance along strike; phosphorus recovery is sensitive to these variations. Plant ore feed can be blended over time to minimize this fluctuation by using a combination of mine production and inventory stockpile scheduling. Mixed-integer and goal programming has been used to optimize short-term mine production, but the seasonal nature of mine haulage requires the use of stockpiles both at the mill and the mine. The contents of the stockpiles can also be optimized as part of the production scheduling problem, but introducing inventory control introduces a nonlinear term into the formulation. A solution using a piecewise linear formulation is modelled and solved using AMPL/Cplex, and solution strategies are discussed for similar large-scale problems. IntroductionIdaho’s minable deposits of phosphate rock are found in the Meade Peak member of the Phosphoria Formation; two separate zones of this formation are mined with a combined thickness of 30 ft to 60 ft. A generalized stratigraphic section of the Phosphoria section is shown in Figure 1, illustrating the degree of complexity encountered when scheduling mine production. Alteration of the formation results in higher grade ore zones near the surface and variable in P2O5 levels between seams and along strike. This variability is seen as well in other quality characteristics critical to the production of acid and elemental phosphorus. Further, plant recovery and nodule quality are sensitive to variations in ore feed; variability in SiO2, carbonates, moisture, organics (carbon), P2O5 and other constituents of the ore can strongly affect plant recovery. Because ore quality characteristics can vary as a function of the alteration zone (or seam) being mined as well as the depth and distance along the strike of the formation, scheduling of mine production can have a highly significant effect on recovery in the plant. As illustrated in Figure 1, there are nine seams containing 20% to 35% P2O5. Phosphoric acid and elemental phosphorus production requires an ore content of 30% and 25% P2O5, respectively. Variability between numerous beds that are mined and quality variation within a seam due to alteration greatly complicates production scheduling with the result that erratic mill feed characteristics greatly decrease recovery."

Jan 1, 1999

By G. J. Kipouros, W. Judge

"The prevalent metal extraction processes for most reactive metals are fused salt electrolysis and metallothermic reduction. The feed material for both of these processes is the anhydrous chloride of the metal under consideration. Dehydration of the feed material is then a critical step in the production of most reactive metals and requires rigorous thermodynamic analysis. Thermodynamic data for most of the reactive metal chloride hydrates have not been measured. Improper dehydration of the metal chloride may lead to a prohibitive amount of hydroxychloride, oxychloride, and oxide. To prevent hydrolysis a certain pressure of hydrogen chloride is required. An estimation and prediction model is presented for the vapour pressures of reactive metal chloride hydrates in an attempt to deduce the conditions necessary for dehydration to proceed without hydrolysis. Thermodynamic data including heat capacities, standard entropies, and standard enthalpies are estimated/predicted for all conceivable intermediate hydrate compounds. Estimations are based on published data as well as trends proven in similar systems. The thermodynamic estimations and predictions are presented for the magnesium, neodymium, praseodymium, and dysprosium chloride hydrates. INTRODUCTIONThe high reactivity of metals such as the alkalis, alkaline earths, and lanthanides prevents their reduction by traditional pyro- or hydrometallurgy. In their elemental form, these metals are raw materials in the manufacture of intermediate products such as alloys and electronic components. Currently the only two viable metal production methods are fused salt electrolysis and metallothermic reduction. Various feed materials have been proposed for these processes. Using the chloride of the metal as a feed material offers advantages in separation and purity of the final product, as well as lower energy input. Chlorides, however, are hygroscopic and must be dehydrated before use. Improper dehydration will lead to a prohibitive amount of oxychloride which will lower efficiencies and contaminate the final product.Optimum conditions for proper dehydration of MgCl2•6H2O to produce pure MgCl2 without hydrolysis have been calculated from existent thermodynamic data and have been reported previously (Kipouros, 1987; 2001). Calculations were also performed for the case of production of pure anhydrous NdCl3 from NdCl3•6H2O (Roy, 1997)] and the mechanism of dehydration was elucidated. Some thermodynamic studies on the dehydration of chlorides of the rare earths have also been conducted (Sundstrom, 1997; Hong, 1997; Aschcroft, 1968; Haeseler, 1965; Ukraintseya, 1989)."

Jan 1, 2012

By C. G. McLachlan

Professor H.E.T. Haultain: To me from time to time the urge comes to say the agreeable thing as well as the disagreeable in commenting on the work of others. It is a prerogative of age. I don&apos;t apologize. To myself I justify my action as based on a long experience of the matters with which I deal, and I like to tell myself that I have a certain responsibility in such matters on account of my detached position. This Noranda article is a very fine contribution concerning Canadian milling, and I am surprised that no word of commendation or thanks has appeared concerning it in the BULLETIN. There is altogether too much written in these days by men rushing into print, concerning laboratory work, that has not been tied into, nor has resulted in application in the field. The authors of this paper have not rushed into print. The preparation of this paper was evidently an uncongenial task. If the authors had been that way inclined, it could have spread over several lengthy papers. It is an important article because it represents an enormous amount of work in the laboratory and the mill, extending over a period of sixteen years, and resulting in fine metallurgical and economic results with a very difficult and involved problem. It is a fine article because it is so well prepared and presented. It deals with an unusual ore condition, but there is much in it of use to every cyanide millman. It leaves very little room for criticism, though there may be differences of opinion in regard to some of the chemistry phases with which I am not conversant. I am struck by the enormous amount of persistent, painstaking, conscientious research work involved, and in the careful, sincere way in which the methods and difficulties have been described. Persistence and sincerity are the key note of the effort. It should have a good educational effect on the rising generation of millmen, and it should continue for long as a work of reference, and a spur to others. There has been an important by-product, the training and development of the young men engaged in the work. Three of them became superintendents of important mills. One was sought for important work in Africa, another has joined a large research organization in the United States.

Jan 1, 1946

By E. M. Watkin

"Although Canada has achieved one of the highest living standards in the world, people and organizations have, over the past decade, begun to question the cost and means of this achievement. Concern has been expressed about the degree of environmental disturbance arising from industrial activities which have greatly contributed to our increased living standards. These industries include hardrock mining, pit and quarry operations, hydro-electric schemes, various agricultural enterprises and urban land developments.In the construction and operation of the above industries many environmental problems arise because the natural vegetative land cover is destroyed or drastically disturbed. Disturbance may occur to such a degree that revegetation is di ffi cult, often it appears impossible. Portions of the environment around such industries remain aesthetically unacceptable and appear to offer little or no potential for future resource use in wildlife, recreation or agriculture.The general public cannot dissociate itself from the activities of the aforementioned industries. It has, over many years, accepted the benefits and conveniences arising from those activities. Despite this, the increasing level of public concern imposes upon industry a need to alleviate or repair past, present and future environmental disturbance. Therefore it is incumbent upon industry to modify present technology or develop new techniques which would allow the disturbed environment to be easily and rapidly repaired."

Jan 1, 1975

By Ted Nuorivaara

The use of polymer-surfactant mixtures as foam stabilization agents is a topic that has drawn the attention of several fields but has so far not be thoroughly studied in the context of mineral froth flotation. The present work showcases a study on the impact on flotation performance of cellulose surfactant derivatives and their mixtures with commercial frothers. Bubble size and foam property measurements were run in a two-phase system along with laboratory-scale flotation experiments conducted using a porphyry copper ore from a mine in Finland. A comparative analysis on recovery, grade and flotation kinetics is presented on the products obtained using: i) a partially hydroxylated cellulose derivative (i.e. hydroxypropyl methyl cellulose; HPMC), ii) a commercial polyglycol-ester frother (Nasfroth240; NF240), and iii) mixtures of these two. The results show that using frothers with a total concentration of 30 ppm, the HPMC-NF240 mixtures provide advantages in terms of Cu recovery, (i.e., up to 95%), compared to the use of either NF240 (ca. 76%) or HPMC alone (ca. 1%). Interestingly, only a small proportion of HPMC mixed with NF240 was sufficient to produce a measurable increase in recovery. This improved performance was attributed to a synergistic effect of the polymer-surfactant mixture which further reduced the bubble sizes in a two-phase system compared to that of NF240. The present work offers a further step into understanding the phenomena taking place when a short chained surfactant is either substituted or mixed with a cellulose derivative, offering potential ways of exploiting this behavior for the enrichment of minerals. INTRODUCTION Froth flotation has been the predominant technology used to beneficiate sulfidic copper minerals such as chalcopyrite ever since it was invented in the late 19th century. The reason for the domination of flotation technology lies behind its versatility in selective separation as well as relatively cheap operational costs (Wills & Finch 2015). Even though flotation of sulfidic copper minerals is moderately well understood based on the broad research work done around the subject (e.g., Albijanic et al., 2015, Bournival et al., 2017, Wang et al., 2015, Mikhlin et al., 2015, to cite only a few), the modern era presents new challenges to the primary raw material industry, including questions regarding sustainability of mining operations accompanied by a need to improve the process efficiencies due to declining ore grades (Edraki et al., 2014).

Jan 1, 2019

By R. Alarcón Sch., R. Abel F.

For many years, copper cathode quality has been a priority for end consumers, since it affects the variety of products that can be obtained from them. From the beginning, physical and chemical quality of the wire bars was controlled, as this product was used to obtain wire rod and other forms of copper by wire drawing. At that time, all the electro refined cathodes were melted and casted as wire bars. Subsequently, in the 80’s, with the introduction of continuous casting furnaces, it was possible to directly produce wire rod from cathodes. From then on, cathodes quality standards were consistently increased, by the introduction of uniform criteria, among which we can identify ASTM and British Standards as well. Also, producers began to use more demanding internal standards than the existing specifications, in order to differentiate their cathodes as high quality products among customers. Today the physical aspect of cathodes, including nodules, cracks, sulfates, or others, is the first element used by end customers to assess their quality. This paper aims to show a brief vision of the evolution of quality specifications for products used to manufacture copper wire. INTRODUCTION From the beginning of refined copper production for industrial purposes, mandatory minimum quality conditions were established. These quality conditions were used as the main element to determine prices and discounts of the respective sales contracts. Reviewing the copper development history, we can appreciate that its quality requirements had been constantly evolved, so that currently refined copper has an extremely high quality standard, that allows its direct use in the production of ultra-thin cables and other products applied in the industry. In each stage, refined copper production has fostered the development of technology used in their treatment. Similarly, cathode processing technology has been evolving to minimize treatment costs in order to generate a wire rod for several uses, ranging from power cables to super conductors. In this sense, to the already known type of fusion processes of the Southwire or Asarco type (capacities over 80 kt / year), wire rod production processes of the Upcast or Rautomead type (capacities between 20-50k t / year) have been added. They immediately deliver oxygen-free wire rods. In both cases, we can conclude that the clients' requirement had evolved from a chemical criteria focus, to considering more subjective aspects, such as visual control as the first stage of inspection.

Jan 1, 2019

By H. Y. Sun, Q. Y. Tan, X. P. Niu, L. Li, Y. Jia, R. M. Ruan

During bioleaching processes of sulfide minerals, the sulfide minerals act as the natural habitats for acidophiles, of which, most are autotrophic iron and sulfur oxidizing microbes. These microbes acquire energy by oxidation of sulfide minerals, and play crucial role in bioleaching processes. In the industrial bioleaching heaps, microbial community and their activity are highly related to engineering configurations, while the optimized industrial operation can help to fast dissolution of aim minerals and acid/iron balance under optimized microbial condition. Microbial community succession and activity formation, the function of microbes to mineral dissolution, the mechanisms to promotion and inhibition of sulfide minerals oxidation, and the industrial instances for microbial community regulation were reviewed. For these instances, promoted microbial activity helped to fast pyrite oxidation for sulfuric acid generation, which realized zero sulfur acid addition to the irrigation solution in the initiation of a bioleaching heaps. High microbial activity by optimized operation parameters improved Cu leaching efficiency during the heap bioleaching process. And also by inhibition of microbial activity, especially the iron oxidizing microbes, the excessive pyrite oxidation can be inhibited, which helped to the acid/iron balance during heap bioleaching. INTRODUCTION Around the world, high grade copper ore are exploited, while barely new high-grade deposits are succeeded, the copper grade of ore deposit is constantly decreasing. The increasing copper demands worldwide requests to process these low-grade ore deposits. Processing of low-grade ores are not economical by usual extraction processes. Heap leaching is a cheaper process for recovery of low-grade ores, and has been applied to extract valuable metals from sulfide minerals worldwide, such as copper, gold, uranium and nickel (Gericke et al., 2009). Heap leaching process has greatly decreased the economic grade and expanded the recoverable ore reserve worldwide (Brierley, 2008). It is usually carried out in the open environments, and could process huge amount of ore (usually in millions of tonnes in one reactor) in the heap reactor (Gericke et al., 2009). For copper sulfide, especially the secondary copper sulfides, heap (dump) bioleaching is successfully applied. Heap bioleaching process is cost saving, and sometimes can be achieved without adding chemical into heaps, by microbial fixing of the atmospheric N2 and CO2, and generating oxidant Fe3+ and sulfuric acid in heaps from oxidation of sulfide minerals. Also heap bioleaching is environment friendly by cycling use of the leaching solution, and without exhaust emission.

Jan 1, 2019

By D. G. Macintyre

Thick westward prograding clastic wedges were deposited along the margin of ancestral North America from Mid-Proterozoic to Mid-Paleozoic time. Periodic rifting and tectonic subsidence resulted in the formation of starved sub-basins along this otherwise passive continental margin. These sub-basins host important sedimentary exhalative barite-zinc-lead-silver deposits. In northeastern British Columbia, a thick succession of Paleozoic basinal facies clastic rocks is preserved within the northwest-trending Kechika Trough. Within the trough, sedimentary exhalative barite and barite-sulfide deposits occur in starved basin sediments of Middle Ordovician, Early Silurian, and Late Devonian age. The last are the most economically sigrrificant and are hosted by carbonaceous cherty argillites and siliceous shales of the Middle to Late Devonian Gunsteel Formation of the Lower Earn Group. The largest deposit, Cirque, has reserves in excess of 35 million tonnes averaging 100J0 (Pb +Zn) and 47 g/t Ag. Other potentially significant deposits include Driftpile Creek, Bear, Mt. Alcock, Fluke, Pie and Elf. Stratiform barite deposits are also common, particularly near the basin-to-shelf transition zone. The Late Devonian barite-sulfide deposits typically are zoned: interlarninated barite-sphalerite-galena-pyrite occurring near suspected vent areas grades outward into bedded barite. Laminated beds of pyrite typically occur in hangingwall siliceous shales, particularly above the inferred vent zone. The apparent absence of epigenetic stringer sulfide zones and footwall alteration implies that the deposits were formed from ponded brines at relatively low temperature. Away from the main deposits, the favourable stratigraphic interval is marked by the presence of thin beds of nodular and laminated barite and thin laminae of pyrite. Thin tuff beds also occur locally in this stratigraphic interval and are evidence for a Late Devonian volcanic event. A paleogeographic reconstruction of the Kechika Trough in Late Devonian to Mississippian time suggests that the barite-sulfide deposits formed in third-order starved basins between uplifted, northwest-trending horst blocks that were capped by shallow-water carbonate banks. The presence of intraformational breccias suggests that fault movement accompanied barite-sulfide precipitation. This tectonic activity may have allowed the escape of heated, overpressured metalliferous brines from permeable reservoirs within the sedimentary pile. Sedimentary exhalative deposits formed where these brines were exhaled as buoyant plumes onto the seafloor, cooled, and ponded in anoxic seafloor depressions.

Jan 1, 1992

By G. R. C. Pacheco, D. M. Fonseca, R. Neuböck, G. E. Gonçalves, W. Moulin-Silva

Degradation by sulfur gases is an important lining wear mechanism in the copper industry. SO2/SO3 gases infiltrate into the pores of the basic refractory bricks, combine with their raw materials through expansive reactions and significantly modify the bricks’ structure. This study presents a comparison of the corrosion resistance against sulfur attack of different magnesia-based refractories using a simple, low-cost and quantitative method. Recipes containing sintered MgO grains showed lower resistance to corrosion by sulfur oxides compared to basic grades containing fused grains. Chromium corundum grades were used as a reference and showed very good resistance to this corrosion mechanism under the test conditions. The novel test provided relevant results that agree with what is commonly observed during operation and in previous post-mortem studies. This tool could be very useful in selecting refractory grades for the copper industry and predicting their performance. INTRODUCTION Oxidation of matte sulfides during copper production leads to the formation of sulfur oxides, which infiltrate into the pores of the refractory lining and react with the basic oxides below 1000°C to form magnesium and calcium sulfates. This reaction is accompanied by an expressive volume increase, consequent densification of the refractory microstructure and weakening of the brick bond (Malfliet et al., 2013). Thus, corrosion by SO2/SO3 is an important wear mechanism in the non-ferrous industry and the resistance to this compound should be considered when defining refractories for this application. Previous studies on this matter include expensive and complex testing methods involving pressurized SO2 gas cylinders in order to investigate the corrosion resistance of MgO-containing materials by sulfur oxides (Gerle & Podwórny et al., 2016; Fotoyi & Eric, 2011; Fotoyi, 2009; Podwórny & Piotrowski et al., 2008). The current study was based on a test developed by Pacheco & Fonseca (2018) to assess alkali infiltration and aims to provide an evaluation method of the corrosion resistance of refractories by SO2/SO3 in a simple and quantitative manner. This novel test is useful to compare the corrosion resistance of different refractory recipes and properly select the grades that should be employed in the non-ferrous industry. A case study is provided to illustrate the damage caused by sulfur oxides in refractory linings.

Jan 1, 2019