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By A-A. Bogno, Ch. -A. Gandin, A. Maitre, H. Henein

Most metallic materials are produced from their liquid state. In order to control the properties of industrial products, it is very important to understand their solidification path and the resulting microstructures which can be significantly affected by melt undercooling. High undercooling results in rapid solidification and a refined microstructure with minimal microsegregation. This paper reports on the analysis of rapidly solidified Al-Cu droplets obtained by a single fluid atomization process, Impulse Atomization. A quantitative analysis by Rietveld refinement method of the Neutrons Diffraction data was carried out to determine the fraction of the intermetallic Al2Cu. Knowing the fraction of Al2Cu, the eutectic fractions and corresponding dendritic and eutectic undercoolings were estimated using the metastable extensions of solidus and liquidus lines of the Al-Cu system calculated by Thermo-Calc. In addition to this work, a model of microsegregation coupled with ThermoCalc software via TQ (application programming interface of ThermoCalc) and the Wang-Beckerman model for dendritic growth velocities has been developed for binary alloys. This has led to the development of a phenomenological relationship between primary phase undercooling and initial growth velocity. A comparison of estimated primary undercoolings using a coarsening model with the adiabatic undercoolings for each alloy composition has confirmed that solidification occurs under adiabatic conditions during recalescence.

Jan 1, 2014

By Roger St. C. Smart, Paul Weber, Joan E. Thomas, William M. Skinner, Warwick Stewart, Stuart Miller

For mine sites affected by acid rock drainage (ARD) or with a potential future ARD issue, the prime consideration is not only the classification of different waste rock as potentially acid forming or non acid forming but also the peak acid (and metal) release rates and expected ARD duration during which effective ARD management and acid neutralisation capacity (ANC) are required. Methods for assessment of this ANC (e.g., Sobek tests) are already available but can be unreliable in ARD containing significant proportions of framboidal pyrite or iron carbonates. The measurement of negative ANC values and the release of S to solution showed that significant sulfide oxidation may occur prior to and during testing in samples containing reactive (particularly framboidal) pyrite resulting in serious underestimation of the original ANC. A simple methodology with dissolution in Ar-purged water before ANC testing, removing ferrous salts, and sulfate assay after ANC testing corrects these effects. Results also showed that a significant lag period (up to 432 h) may be needed for complete hydrolysis of Fe associated with the standard Sobek ANC testing of, for instance, siderite. Hence, the ANC of iron carbonates is usually significantly overestimated. By filtering and the addition of H202 until there was no subsequent pH drop (due to Fe hydrolysis reactions), followed by back titration to pH 7.0, the ANC for siderite was similar to the ANC determined after 432 h lag by the Modified Sobek ANC test and to the mineralogical carbonate ANCcarb determined by calculation based on electron probe micro-analysis. A chemical ANC calculation, based on neutralising cations released to solution, has provided a method to quantify the short-term ANC of carbonates and silicates in simple mixed mineral assemblages and waste rock samples. Results showed that silicate ANC can be more important in short-term neutralisation than carbonate ANC in low carbonate samples. In the longer-term, decreasing sulfate and metal loads with increasing pH values suggests that eventually sulfide acidity generation rates will match the longer-term inherent acid neutralisation rates of the sample derived from silicates. A kinetic ANC measurement for silicates, after steady state dissolution is reached, that indicates the number of hydrogen ions neutralised/m2/yr has been developed. These values can be used in estimates of the net acid production profile from wastes with low (and decreasing) pyrite content after the short-term ANC is exhausted.

Jan 1, 2004

By R. Stauber, B. Friedrich, S. Hilgendorf, G. Homm, C. Gellermann

Due to recent regulations limiting tolerated lead concentrations in copper alloys, new recycling strategies have to be considered. This study investigates the suitability of technical approaches in order to recycle leaded copper alloys exemplified by CuZn39Pb2 and produce an alloy in compliance with future lead regulations in the European Union. Three pyrometallurgical methods are considered to achieve this goal, namely vacuum distillation, intermetallic precipitation and fractional crystallisation. The impact of essential process parameters i.e. pressure, temperature, time, atmosphere and quantity of additives are identified using thermochemical and kinetic modelling. An experimental implementation reveals a general suitability of all three refining processes. However, the individual efficiency of the different methods strongly differs. Thus, a detailed assessment is carried out in order to provide an evaluation on the efficiencies of these methods from a technological, economical and environmental point of view. Taking a possible industrial realisation into account, the authors recommend the approach of vacuum distillation, although the energy demanded is comparatively high due to the enthalpy of evaporation for zinc, or rather, lead. However, required lead concentrations can be reached quickly without introducing an external element to the material. The prediction of selectivity and evaporation speed, which are immanent variables for a successful implementation, can be validated experimentally. INTRODUCTION In 2016 approximately 1 million tonnes of leaded copper alloy semi-finished goods with an average lead content of 2.1 Ma% have been produced in the European Union (EU). The global production in the same period exceeded 5.5 million tonnes, while the lead concentration has stayed constant at around 2.4 Ma% for the last 50 years. Up to 80 % of the current production volume is covered with end-of-life scraps, which are used for direct re-melting, depending on the alloy composition. Lead has been a popular alloying element in copper alloys in general, and in particular in brass due to its positive impact on various mechanical, physical and chemical properties, especially machinability. Health and environmental concerns were drivers for many governments to implement limitations on lead. In order to further utilise the resource potential of leaded copper scrap, it is inevitable to develop methods to efficiently eliminate lead from circulation as far as possible. (Glöser, Soulier, & Tercero Espinoza, 2013; Soulier, Glöser-Chahoud, Goldmann & Tercero Espinoza, 2018)

Jan 1, 2019

By J. Kalynchuk, R. Poulin, R. Pakalnis, D. Peterson

"A market survey of all underground mines in Canada (Fig. 1) was completed to determine the ex1ent to which cable bolts are being used as ground support. One hundred and nine questionnaires were distributed with 65% of them being returned completed. As a result, the quantity, types and locations of cable bolt installations have been determined. In addition, the grout pumps used, time required and cost of installations have been addressed. The popularity of other support types used in underground mines is summarized.IntroductionRock reinforcement consists of installing support within the rock mass (internal) or within the excavation (external). Within the past twenty-five years several new types of ground support have been introduced within the mining industry. Cable bolts were first introduced to the Canadian mining industry in the 19605 (Gramoli, 1975).Cable bolts have gained increased acceptance as a method of ground support during the past decade. The cable bolt is comprised of one central wire surrounded by six slightly smaller outside wires and typically having an over-all diameter of 15.2 nun to 15.9 nun (0.6 in. to 0.625 in.). The cable wires are made from high-strength steel with an ultimate strength of 26 tonnes (58 000 Ibs) (Goris, 1990). Current cable bolting practice consists of cement grouting one or more steel cables within a drill hole in order to reinforce the surrounding rock mass. Cable bolts are a form of internal support and are generally used in open stoping and cut-and-fill mining methods (Fig. 2).They can be either tensioned (active support) or untensioned (passive support) and may be of any length, though for underground mining applications, they are generally less than 20 m (65.5 ft) and are untensioned. A major advantage compared to previously used ground support is that the cables are flexible and can be coiled to approximately 1 m (3.3 ft) diameter coils allowing relatively long support to be installed in areas with limited head room (1.8 m).With the advent of bulk mining methods which require comparatively large stopes, it has necessitated the use of relatively long support tendons to stabilize the large spans being created. As a result, the use of cable bolts for ground support in mines has increased significantly within the past decade."

Jan 1, 1995

By Xiaoqi Sun

"Rare earth elements (REEs) have a series of specific properties making them invaluable in products including lighting, electronics and magnetism. The elements have been used in many commercial products, for example, turbines, electric vehicles, batteries, lighting, computers, cell phones and lasers. Heavy REEs are attracting the interests of scientists from many countries, and these elements have become critical to develop high-tech materials. Ion-adsorbed rare earth deposits were first discovered in China. The minerals are also called weathered crust elution-deposited rare earths. The particular types of deposits are distributed throughout southern China. The ion-adsorbed deposits are rich in medium and heavy REEs, accounting for more than 80% of the world’s total medium and heavy REEs production. However, the separation of heavy REEs from ion-adsorbed deposit is difficult owing to their similar chemical properties. The conventional separating technologies have caused serious pollution. A novel extraction strategy has been developed in this laboratory and is presented herein.INTRODUCTIONThe unique properties of rare earth elements (REEs) render them important in high-strength magnets, lighting phosphors, polishing compounds, and ceramics. Especially for applications that take advantage of the f-orbital electrons, substitutions outside the REE family are often difficult to impossible (Nassar, Du, & Graedel, 2015). Extracting and separating individual elements from mined ore is not easy, requiring lengthy operations to separate them, and this results in high costs and adverse effects on the environment. The low concentration of REE in the earth’s crust makes economic exploitation difficult (de Boer & Lammertsma, 2013) and the sustainability of the REEs separation industry has aroused considerable attention (McLellan, Corder, Golev, & Ali, 2014). To eliminate protons and break the dimmers in organic phosphonic acids or carboxylic acids, the saponification of acidic extractants by acid-base neutralization reactions are widely used in industrial REEs separation (Sun, Luo, & Dai, 2012a). The saponification procedure contributes to increased extractability and selectivity of acidic extractants to a considerable extent. The common industrial saponification mechanisms and technological processes are shown in Figure 1 and include ammonium saponification (saponified by NH3·H2O), sodium saponification (saponified by NaOH), calcium saponification (saponified by Ca(OH)2), and magnesium saponification (saponified by MgO). These inevitably result in wastewaters containing NH4 +, Na+, Ca2+ or Mg2+ because of the cation-exchange extraction mechanisms (Xiao, Long, Huang, Feng, Cui, & Wang, 2013; Song, Fu, Wang, Liu, Zhou, & Li, 2014; Sun & Waters, 2014)."

Jan 1, 2016

By J. M. Goris

"Researchers at the U.S. Bureau of Mines are conducting research on cable-type ground supports to assess their material and support properties and to provide design criteria for implementing cable supports as a workable roof control system under various underground mining conditions. Much of this work involves laboratory assessment of the material and support properties of cable supports using both conventional and birdcage steel cables. Included in this assessment are single and double cables, effects of changes in embedment length on support strengths, water-cement ratios, use of breather tubes, and pumpability and water-bleeding properties of grouts.IntroductionSince cable supports were introduced in the early 1970s, considerable research has been conducted in laboratories and at mine sites to understand their behaviour. The U.S. Bureau of Mines began a laboratory evaluation project in 1985 at the Spokane Research Center (SRC) to study the behaviour of cables supports under uniaxial loads so that the effects of various cable support components, such as grout and breather tubes, could be identified. Other objectives were to compare the behaviour of various types of cables and grouts and to collect meaningful data for numerical analyses. Pull tests were conducted to determine how cables supports reacted under uniaxial loads and how they failed when ultimate loads were exceeded. Such data are essential for the development of numerical models for analyzing rock mass behaviour when the rock is supported with cables.Test ProgramBecause each cable support can be composed of either single or double cables as well as a breather tube, pull tests were designed to include a variety of samples containing these components. A series of samples containing a single conventional cable, a neat cement grout having a water-cement ratio of 0.45, and no chemical additives was selected as a standard (Table I). Then one component in the system, such as the presence of a breather tube, was changed, and results of tests compared to results obtained for the standard samples to determine what influence that component might have on the behaviour of the support system. If significant changes in test data occurred, they could be attributed to that one component. To control the quality of the samples, the physical condition of the cables and tubes were monitored closely, and compressive and tensile strengths as well as flow properties were determined for the grout used in each test series."

Jan 1, 1991

By R. Rosenblum, J. Y. Kim, D. Shink, K. G. Stowe

"A small scale continuous flotation cell was designed and constructed at the Noranda Technology Centre to develop a mobile testing flotation circuit located next to the production circuit. This mobile small scale flotation pilot plant can easily and economically be set up at any circuit in a mill and used to evaluate and predict plant performance against a given flotation condition. The main feature of the cell, beside the provisions of automatic pulp level and feed rate control, is to provide a reduced surface to volume ratio approaching to that of an industrial machine.This paper describes the basic design and the results of various testwork carried out to date including aeration, conditioning, reagents, recirculation, flotation gas, etc. are presented in comparison with the plant production results. INTRODUCTIONStudy of the behaviour of an ore during concentration by flotation process starts, in general, with a series of tests in laboratory cells. Given the discontinuous nature of these tests, the information obtained by such a study is somewhat limited. It has long been recognized that laboratory test results are not always reproducible in pilot plant tests and subsequently, the pilot plant results do not always predict plant performance. The differences are often blamed on batch vs continuous operations, grinding media, size distribution, aging (oxidation), water quality, equipment, operator's skills, etc."

Jan 1, 1992

By M. Jahazi, M. Brochu

This paper describes the advantages/disadvantages of electron beam freeforming using two different types of filler metal: (1) brazing paste and (2) solid wire. Sound buildups were obtained from both filler metal. The freeforms produced with the brazing paste showed a certain level of porosity, which was reduced by successive melting. In comparison, the solid wire buildup was practically free of pore. When compared with the solid wire filler, the brazing paste produced narrower buildups but a larger scattering of the width.

Jan 1, 2004

By D. M. Fraser

"Brunswick Mining and Smelting Corporation Limited operates two mines; one open pit (No. 6) and one underground (No. 12), approximately 20 miles south-west of Bathurst, New Brunswick. Both are massive sulphide deposits containing copper, lead, zinc and silver. The No. 12 property began operation in 1963 and is presently being mined at a rate of 3600 tons per day underground and is in the completion stages of an expansion to achieve 11,000 tons per day underground by the end of 1930.Originally at Brunswick Mining, acid mine drainage was added to tailings and neutralized by an excess of lime in the tailings. A conventional recycle system was established with a biostabilization pond for the treatment of thiosalts, a liming station and sludge settling area for neutralization of acidic water and a final reclaim pond with a pumping station for reclaim water.We found that not more than one third of the reclaim water could be used as it upset the flotation circuit every time it was used. It was established that the mine water and surface drainage were the cause due to oils and detergents in the water. It was also found that the biostabilization pond method Cf thiosalt treatment was not efficient for year round operation in our climate.In 1974, we reviewed the problems and began a 3 phase program to control effluents from the property:"

Jan 1, 1980

By Tapiwanashe Chenje, David Hewitt, Peter Radziszewski

"Steel media wear is a major cost component in mineral processing. In the case of existing operating mill, steel media wear prediction can be used to help compare the performance of steel media from different suppliers before completing marked ball tests. It can also be used to investigate how ores from different site of a given mine affect steel media wear. In the case of Greenfield cases, steel media wear prediction can be used to estimate the cost of steel media for a given feasibility study.This paper presents a wear testing and prediction methodology that ties together abrasion wear and corrosion wear testing results through the use of a simplified discrete element charge motion model. The experimentation dimension to this methodology takes samples for steel media, mine site ore and water to determine abrasive and corrosive wear parameters of a given media, ore, water set.The test methodology development is illustrated along with a comparison of wear predictions with observed wear rates in some operating mills. A case study is included that illustrates how this methodology was used to estimate steel media wear performance. The paper closes with a discussion on the use of parts of the experimental methodology to investigate other abrasive wear conditions such as liner wear, paste backfill piping and ore breakage as well as avenues for future test development.INTRODUCTIONThe cost of comminution processes represents a significant part of the overall costs of a mining operation. Grinding media/liner wear alone accounts for 15-25% of the total operating cost. The annual steel grinding media consumption is approximately 2.5 mtpa or 0.3% of total world steel production [Smorgon Steel Group, 2005]. Using an estimated grinding media cost of about US$0.75/kg [Halbe and Smolik, 2002], gives a media cost of over US$1.875 billion per annum. Mining continues to shift towards exploitation of lower grade ores as the higher grades get depleted. These low-grade ores require finer grinding for the liberation of the value minerals, and hence it can be assumed that grinding media consumption will also continue to rise.The Bond abrasion test, dating back to 1963, [Weiss, 1985] is still used to estimate the total mill media wear. This is a purely empirical test based on the ore. From Bond abrasion index tests, it is possible to determine a wear rate using the following function:"

Jan 1, 2009

By S. J. Haynes

"This paper documents the characteristics of the different quartz veins, and their relation to gold, in the turbiditic Meguma domain of eastern Nova Scotia. Eleven different types have been distinguished in the greenschist facies on the basis of form, internal structure, mineralogy, wallrock alteration and crosscutting relationships to each other and to regional structures. Gold is present as rare visible disseminations in host rock slates and in ore-grade, early-formed veins, that pre-date the formation of upright Acadian folds and intrusions of Devonian granitoids. Four vein types pre-date Acadian folding. Five gold-deficient vein types are associated with Acadian folding (syndeformation); whereas two gold-deficient vein types clearly post-date this deformational event: Previously unreported, wall rock alteration is associated with early crosscutting and semiconcordant auriferous veins. In contrast, early stratiform veins are devoid of wallrock alteration. It is suggested that the auriferous vein arrays formed as submarine exhalitive systems over synsedimentary tensional faults and that the Meguma domain may represent the opening of a basin similar to the modernGuaymas rift .IntroductionThe term ""turbidite-hosted gold deposits"" is introduced to distinguish gold deposits contained within a turbiditic sequence of wackes and shales (or their metamorphosed equivalents) from gold deposits in other types of sediments. Usage and justification for the term is similar to ""carbonate-hosted lead-zinc deposits"" or ""volcanogenic massive sulphides"". A range of different characteristics can be present in individual deposits, some of which may be indicative of specific deposit types in the same manner that volcanogenic massive sulphides can be subdivided into ""Cyprus type"", ""Kuroko type"", ""Besshi type"", etc. Historically, gold deposits hosted by turbiditic flysch were an important class of quartz-vein gold mines in the 19th century. They included the goldfields of Victoria, Australia, Otago, New Zealand and Nova Scotia, Canada. Production from most of these fields had ceased by World War II and interest in this type of deposit waned. However, the recent exploration interest in gold has resulted in both re-assessment of the classical mining camps and the discovery that ""turbidite-hosted"" gold deposits are present in many parts of the world.Mapping of the regional geology and gold deposits of the Megumadomain of Nova Scotia was carried out by E.R. Faribault of the Geological Survey of Canada between 1886 and 1939. Faribault produced a comprehensive series of maps and reports for each gold district, a compendium of which was published by Malcolm (1929)."

Jan 1, 1987

By E. J. Sun

The ADS system was developed to reduce accidents related to haul trucks operating under low visibility conditions in surface mining and construction sites, which is based on the GPS, mesh-wireless networks, and the Google-Earth 3D graphic engine as the graphic interface and mine-mapping server. This system has the capability to pin-point and track vehicles in real time using a 3D interface, which is based on user-based AutoCAD mine maps using the Google-Earth graphics interface. All equipped vehicles are shown in a 3D mine map stored in a local server through a wireless network. When low visibility conditions are present, the system indicates available exit/escape routes for driver safety. The research results indicate that the ADS system potentially increases reliability and reduces uncertainty in open pit mining operations by customizing the local 3D digital mining map, constructing the truck 3D models, tracking vehicles in real time using a 3D interface and indicating available escape routes for driver safety.

Oct 1, 2009

By P. C. Holloway, A. Tshilombo, T. Xue, M. J. Collins, R. Lopetinsky, I. Mihaylov, I. M. Masters

The Voisey’s Bay deposit contains a trace amount of cadmium, which reports to solution during pressure leaching of the nickel concentrate at Vale’s Long Harbour Hydrometallurgy Plant, and must be removed to produce high quality nickel cathode. In 2006, Vale approached Sherritt Technologies to collaborate on the development of a process for removing cadmium to low levels (<1 mg/L) in the nickel raffinate. Following successful bench scale and pilot plant testing at Sherritt’s laboratories, the cadmium removal process was then moved through engineering and construction, culminating in the successful commissioning and startup of a cadmium removal circuit at the Long Harbour Hydrometallurgy Plant in 2017. This paper presents the results of this collaboration and the challenges that were encountered through each stage of development, as well as current results from operation of the commercial cadmium removal circuit. INTRODUCTION Vale’s Long Harbour Processing Plant, with a nameplate capacity of 50,000 t/y nickel, began operation in 2014. In addition to electrolytic nickel rounds, the plant also produces electrolytic cobalt rounds and copper cathode. The Long Harbour Processing Plant uses a unique hydrometallurgical process developed by Vale Base Metals Technology Centre, as shown in Figure 1, to treat a nickel sulphide concentrate produced at the Voisey’s Bay mine and mill located in northern Labrador (VBN concentrate) (Stevens et al., 2009).

Jan 1, 2019

For the last few years, a new and innovative technique has been successfully used to determine refractory and castable thickness in various metallurgical vessels. The acousto ultrasonic-echo (AU-E) technique uses stress waves to detect metal penetration and delaminations within refractory linings. In addition, it is capable of measuring the thickness of refractory layers and build-up material. The inspection and measurements can be carried out while the furnace is in full operation. The present paper discusses the principles of the AU-E technique, and its advantages and limitations. A number of case studies are presented to demonstrate various capabilities of this new Non-Destructive Testing (NDT) technique.

Jan 1, 2005

By Margaret Anne Stephenson

While the concepts of Aboriginal title share a similar jurisprudence in both Australia and Canada resource development regimes on Aboriginal title lands differ significantly. In Australia, the process is the right to negotiate with mining proponents. In Canada, the process is the duty to consult with government regarding mining projects. This paper compares and assesses the processes for ?consultation and negotiation? with Indigenous peoples when development actions (particularly in the context of mining resource development) impact Indigenous property rights and how agreement making can be progressed. This paper will question whether the resource development processes afford Indigenous people?s property rights full respect when mining developments on Indigenous lands are proposed.

Aug 1, 2013

By C. T. Morley

The steadily increasing interest in high pressure grinding rolls (HPGR) as a legitimate alternative comminution technology for hard rock applications has led to a proportional increase in the demand for trade-off studies comparing HPGR with more established approaches, typically SAG-based but including AG and stage-crushing designs. The primary trade-off is between a) the higher capital cost typically incurred with HPGR-based designs and b) the higher operating costs of the more traditional technologies. However, if, through circuit design innovation, the capital cost penalty of HPGR circuits could be eliminated or reversed, then the need for trade-off studies would diminish.

Jan 1, 2012

Pilot plants for pressure hydrometallurgy represent special design and project execution challenges unique to the industry and to the pilot- and demonstration-scale. Pilot plant projects have different objectives and shorter timescales than commercial plant projects. Design considerations and strategies, and project execution methods that meet the special needs of pilot plant projects, are discussed. Specific guidance is given for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical process equipment, and for the selection of materials of construction for pilot-scale equipment. The balance between the need for process similarity with future commercial operations and the realities of pilot-scale equipment is also discussed.

Jan 1, 2004

By Z. Trojanová

Mg micropowders generated by gas atomisation of a magnesium melt with argon were mixed and ball milled with ceramic nanoparticles prepared by laser-induced gas phase reaction. The materials were then hot extruded. Specimens were deformed in tensile as well as compression tests at temperatures between 20 and 300 °C at a constant initial strain rate. The flow stress is significantly influenced by the test temperature. The yield stress decreases with temperature. This decrease and the flat character of the stressstrain curves at elevated temperatures indicate possible contributions of softening processes. The materials studied exhibit high-damping characteristics. The results are analysed and possible mechanisms are discussed.

Jan 1, 2006

By L. H. Bergmann

THE blasting practices described are fairly representative of those employed in the coal mines of Eastern Canada. As such, they may be of interest to Western Canadian coal mine operators. The treatment of the subject is general, no attempt being made to discuss blasting operations at any particular coal mine in detail. All the mines dealt with are mining bituminous coal and are classified under the Coal Mines Regulation Act of the Province of Nova Scotia as &apos;closed light&apos; mines. As such, they are required to use only &apos;permitted&apos; explosives and to apply them in a &apos;permitted&apos; manner, except where authority is given by the Mines Department to do otherwise.

Jan 1, 1945

By H. Hao

This paper outlines the development of a 2-D axisymmetric mathematical model to predict the evolution of temperature during the Direct Chill (DC) casting of AZ31 magnesium billets. Model predictions of temperature have been compared to measurements made on an industrial DC casting machine at Timminco Ltd, in Haley, Ontario. These measurements have been used to fine-tune the thermal boundary conditions employed in the mathematical model, The model, which is based on the commercial finite-element code ABAQUS, has been developed as part of a strategic project aimed at improving the DC casting process for light metals through a reduction in casting related defects and increased productivity.

Jan 1, 2004