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By Stephen B. Hearn

The SLon Vertical Ring and Pulsating High Gradient Magnetic Separator was developed to overcome multiple disadvantages associated with traditional horizontal type Wet High Intensity Magnetic Separators (WHIMS) which have been in service for many decades for recovering iron ore and other minerals. Proven successful, with hundreds of units now upgrading low-grade iron ores and maximizing recovery of fines throughout China, the technology is now being tested in the Western world. This paper will discuss the drawbacks of traditional WHIMS, explain the operation of the SLon, and illustrate its practical use in processing hematite ores.

May 1, 2007

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By R. D. Brown

This article summarizes some of the principal features of the taxation of industrial mineral mining in Canada. Where the rules applicable to such operations differ from those pertaining to the production and processing of precious and base meta s (non-industrial minerals), the two sets of rules are compared. If a conclusion could be drawn from such an over-all comparison, it may be that the total tax burden on an industrial mineral mine can be considerably more onerous than on both base meta mining operations and manufacturing profits.

Jan 1, 1979

By Suzie Nantel

Crystalline igneous rocks, known commercially as granite, are exploited in Quebec f rom more than twenty-five quarries for building, ornamental and monumental purpose$. Quebec is the main Canadian producer of construction granite, accounting for nearly 90 per cent of total production. Jn the last three years, this industry has experienced an important growth due to improved marketing and use of modern equipment in rock-cutting and polishing. Jn /983 a 35 per cent sales increase is forecast. The main rock varieties extracted are the following: porphyritic pinkish grey granite and green charnockite from Riviere-dPierre, mahogany brown granite and black anorthositic rock f rom the Lac Saint-Jean area, fine-grained pink granite from Guenette, coarse-grained brown quartz monzonitefrom SaintA lexis-des-Monts. All these rock types occur in the Grenville tectonic province whereas a medium-grained, light grey granite, Devonian in age, is extensively being quarried in the southern part of the Appalachians. In the Superior province a greenish black diabase and a deep red granite are extracted. Search for new varieties and deposits is actively being carried out by prospectors and by the minis/ere de /'Energie et des Ressources du Quebec following growing demand for granitic and gabbroic rocks as dimension stone.

Jan 1, 1984

By William E. Stanley

The paper examines the problems that arise in undertaking socio-economic impact studies to meet the requirements of environmental-impact legislation governing new mine development or expansion. An approach to undertaking socioeconomic impact studies is outlined, responses to specific problems are discussed and ways in which the mining company can use these studies to meet its general objectives are explored. The paper concludes by examining how a socio-economic study, as required by legislation, can be used to assist the mining company in achieving some general objectives it will have in developing a mine.

Jan 1, 1979

By Derrick Hunter, Pat Feighan, Keith Chrystall, David Wells

"Equipment which may be remotely operated, has some degree of on-board intelligence, and which for periods of time may operate autonomously, is referred to as telerobotic. Recent advances in electronics, computers and hydraulic equipment have dramatically reduced the cost and simplified the process of converting standard industrial equipment to telerobotic control. The benefits of telerobotic equipment include improved safety by removing the operator from dangerous situations, reduced maintenance costs and increased productivity. This technology has been proven in various military, nuclear, and police applications.The surface mining industry has expressed an interest in automation and is characterized by a willingness to use remotely operated equipment, however, the majority of telerobotic equipment currently in use is experimental or prototypical. Potential applications of telerobotic equipment for surface mining include remote operation of equipment near dangerous high walls and other unsafe areas, utilization of robotic trucks for routine hauling operations, and control of jointed equipment. In addition, component technologies of telerobotic systems are relevant to various forms of condition monitoring, operator feedback systems, and vehicle positioning.Attention must now be directed toward resolving more complex problems associated with enhancing feedback to the operator, improving the man/machine interface, and ultimately, improving efficiency. Removal of the human operator from the work site introduces significant complications in replacing the sensory inputs that an operator normally uses to efficiently run his machinery. These can be difficult to define and even more difficult to replicate remotely and may include restrictions pertaining to vision, hearing, and touch.In cooperation with Defence Research Establishment Suffield and the Alberta Research Council, Robotech Industries Ltd. is pursuing the development of additional technologies to further enhance an operator’s ability to control remote telerobotic equipment. These developments include a head-mounted display, additional control station displays and improvements to coordinated motion control software. Prototypes of these developments are expected to be completed and tested by the fourth quarter of 1997."

Jan 1, 1996

By Z. S. Shao, X. Z. Li

"Sub-critical crack growth plays an important role in long-term creep failure in brittle rock. Based on micromechanics established by using relationship between micromechanical wing crack growth model and macroscopic strain, and comparing theoretical model with testing results, a method, which applies the theory to real rock, is suggested in this paper. Using this method, properties of creep, damage and progressive failure in brittle rock are investigated. Effects of stress state on creep failure time and steady-state creep rate are analyzed and graphically presented. The results are helpful to support structure design and service life evaluation of underground structures with high geostatic stresses. INTRODUCTIONDuring the long-term operation in underground space with brittle surrounding rock, due to chemical action between pore water and rock, the failure of rock often occurs at stresses below its short-term failure strength, which brings serious effect on the long-term stability of underground structure. Thus, the long-term strength of brittle rock attracted wide interests of scholars around the world. The static fatigue limit was predicted by exponential function that is derived from abundant experiment data of stress level and failure time(Schmidtke & Lajtai, 1985), and similar result by relationship between stress state and failure time was also suggested (Lau & Chandler, 2004; Aubertin et al., 2000; Sangha & Dhir, 1972). According to relationship between steady creep rate and stress state during creep, a critical stress that transforms steady-state creep to accelerated creep was studied and the long-term strength was suggested (Tsai et al., 2008; Ma & Daemen, 2006; Lajtai et al., 1991). Based on the results of experiment in compression, the long-term strength of rock was defined by stress at volume strain reversal. When applied stresses are larger than the long-term strength, the microcracks in the rock will grow constantly, damage of rock will increase and failure of rock will occur finally (Chandler, 2013; Bieniawski, 1967; Brace et al., 1966)."

Jan 1, 2015

By J. L. Thornton

Introduction The importance of coal in our economy is well established, but it may not .be so generally realized how important a part it plays in our daily life. Select a product - any product - and, if it is made in America, bituminous coal has touched it first. Everywhere we will find coal, derivatives of coal, or functions made possible by coal. Apart from the well known major uses of coal for domestic purposes, coking, utilities, railways, and manufacture of steel and cement, there are over 200,000 products derived from coal, from lipstick colours to nylon products and perfumes. An item of interest is the recent action of the Canadian Government in voting $90,000 for development of coal deposits in Yukon Territory to make coal available to the settlers in that area. The value of this move, in case of some emergency, is very evident. Coal in its several stages of formation as peat, lignite, sub-bituminous, bituminous, semi-bituminous, semi-anthracite, and anthracite, has been used for centuries. Coal, as such, was not very well known to the ancients. First reference to "magic stone', or coal, was in 371 BC by Theophrastus, a pupil of Aristotle. This substance was said to burn like wood coal or charcoal and was used by the smiths. The first record we have in modern times was in 852 AD, when sea coal was gathered by the cowled monks of Durham, in Britain, and even at that time a major problem was transportation. Our first record of coal in this continent was near Richmond, Virginia, in 1700. Commercial mining was not under way, however, until 1750. The anthracite fields (presumably in Pennsylvania) were opened in 1793. Even so, there was no extensive mining until about the year 1820. The famous Pocahontas coalfields were opened in 1883. The earliest record of coal mining in Canada is about 1746.

Jan 1, 1950

By C. K. Baxter, A. Odeshi, M. Mohammadi, E. D. Cyr

"Metal additive manufacturing has been a revolutionary step in designing new complex shapes with faster and cleaner building capacity in comparison to subtractive manufacturing processes. The ability to print lightweight alloys such as aluminum has made metal 3D printing attractive to different industrial sector from aerospace to energy and bioengineering. Of particular interest in this study, are the mechanical and microstructural properties of AlSi10Mg-200°C alloys. In this project, samples were 3D-printed in horizontal direction using an EOS M290 machine by Direct Metal Laser Sintering (DMLS) technique. Uniaxial tensile tests and high strain-rate impact e tests were carried out to investigate the mechanical properties and to study the repeatability of the process. A constitutive model is developed to predict the results of the mechanical tests at varying strain rates to better understand the high strain-rate behaviour of these alloys. Using optical microscopy, features such as scan tracks and melt pools within the AlSi10Mg-200°C samples were observed, and the microstructure was observed to be homogenous. The previously listed tests were compared to the results obtained for similar cast alloy counterpart, i.e. A360.0.INTRODUCTION A relatively new way of manufacturing parts is on the increase as rapid prototyping becomes increasingly popular throughout the world. Additive manufacturing is a process which, given a 3D model, uses metallic material in powder form to build a part layer by layer until completion (Gu, Meiners, Wissenbach, & Poprawe, 2013). This way of rapid prototyping is very attractive in comparison to other possibilities because of its ability to accommodate complex design and geometries. Conventional manufacturing methods have limitations when it comes to complex geometries, but additive manufacturing allows for increased design flexibilities while maintaining a light and stable final product (Murr et al., 2012). It also allows for a reasonable cost, especially for small batch sizes that would otherwise be extremely expensive."

Jan 1, 2018

By A. Ehsani

"Seas and oceans constitute about 70% of the earth’s surface. They contain an enormous stock of various mineral resources such as sedimentary (marine placers), massive sulfide ore deposits, manganese nodules and cobalt-rich ferromanganese crusts. Sea and ocean floor ore deposits could well contribute to the meeting of ever-rising demand for raw materials in the metal industry. In this regard, more research and development in science and technology appear to be required to ensure maximum benefit from the mineral resources of seas and oceans. Since the 1960s, a variety of mineral and metallurgical processes have been studied and developed to deal with marine ores and to extract metals such as gold, nickel, copper, cobalt, manganese, tin, platinum group metals (PGM), zirconium, thorium, etc.In marine environments, there are many parameters which can affect the selection of the mineral and metallurgical processes. These include the extent and grade of the deposit, mineralogical and chemical properties of the deposit, and physical properties of minerals present with particular reference to particle size distribution and mineral liberation size.In this paper, we briefly review the latest trends in processing and extraction of marine mineral resources. Mineral processing technology is mostly applied for recovery of precious metals i.e. gold and PGM, in particular, from marine placers. In general, pre-treatment (sizing, classification, dewatering), gravity concentration techniques (shaking tables, spirals, jigs, etc.,), flotation, magnetic, and electrostatic separation are the options for enrichment of marine placer ore deposits. In the case of massive sulfides, manganese nodules/cobalt-rich crusts, hydrometallurgical and pyrometallurgical methods (as proven technological methods) can be exploited for extraction of metals from concentrates after physical separation or directly from marine ores. The hydrometallurgical treatments involve acid (e.g., sulfurichydrochloric) and alkaline (e.g., ammonia) leaching with different reducing agents and pre-treatments such as roasting. Alternatively, pyrometallurgical treatments involve mostly smelting, chlorination and segregation processes."

Jan 1, 2016

By T. A. Chepushtanova, I. U. Motovilov, V. A. Luganov, G. D. Guseynova

"Kazakhstan has significant reserves of oxidized nickel ore with low nickel content. Processing of such ores is effective via pyrometallurgical technologies such as smelting to ferronickel or matte with consecutive extraction of metals from melting products. There are also many options for direct hydrometallurgical processing. However, they do not provide high nickel recovery.We studied extraction of nickel and cobalt by using combined technology of low-grade ore processing from the Shevchenko Kazakhstan deposit, which includes smelting to poor matte followed by hydrometallurgical processing of the matte. The nickel content in the initial ore was 0.75–0.9%. Pyrite concentrate of Sokolov-Sarybai Kazakhstan deposit containing 0.17% cobalt and 0.06% nickel had been used as a sulphidizer at smelting.As a result of the study, we were able to extract up to 98% of the nickel and up to 80% of the available cobalt. Obtained matte contained 3.1% nickel, 0.29% cobalt, 71.6% iron and 24.3% sulfur. Matte leaching was carried out by hydrochloric acid. The iron content in the pregnant solution was 170–185 g/dm3. Nickel and cobalt precipitation from the pregnant solution was carried out by hydrogen sulfide. Initial matte or cast iron was used as neutralizers during the process. Practically complete precipitation of nickel was achieved at 3–5% excess of neutralizer at 333–343°K in 4 hours; up to 95% of cobalt precipitation was achieved in 50% excess of neutralizer at 363°K in 8 hours. The purified solution contained 200–600 mg/dm3 of nickel, 80-100 mg/dm3of cobalt and 175–185 g/dm3 of iron. The purified solution allows to obtain iron oxides by high-temperature hydrolysis, and to regenerate hydrochloric acid.As a result of non-ferrous metals precipitation we obtained sulfide concentrate with concentration of Ni up to 25% and concentration of Co up to 5.5%. The technology is recommended for semi-industrial testing."

Jan 1, 2016

By D. Nower

"The supply of copper is expected to be at a large deficit in 2012. To recover from these deficits mining companies are required to maximize production and there is no better way to accomplish this than to optimize the use of their mobile mining equipment fleets. To optimize these fleets, each equipment type has to be monitored in its own unique way. Automation would not only improve production, but also minimize the safety risks and eliminate planning errors. The automated vibration monitoring of multiple systems on the shovel can determine the machine’s condition at all times. This reduces unplanned downtime and keeps critical shovels in production. This paper will discuss the details of how shovels can be successfully monitored, continuously. INTRODUCTIONP&H Mining, part of Joy Global, is the world’s largest manufacturer of above-ground mining equipment. Its electric rope shovels, such as Figure 1, with capacities up to 115 tons (104.3 metric tons), are used for high production loading in surface mines; its draglines, such as Figure 2, have bucket capacities to 160 cubic yards (122 cubic meters). P&H also produces blasthole drills, mobile mining crushers and other essential mining equipment. Headquartered in Milwaukee, WI, the company does business on every continent, except Antarctica. ECONOMIC FACTORSDue to the global demands for metals and power, mines are required to operate at full capacity. Mine operations cannot afford any critical assets to shutdown unexpectedly; depending on the ore type and quality, downtime for a single shovel can be as much as $300,000 per hour.Electric rope shovels are one of the most critical assets in open pit mining. They are very large, complex machines with DC or AC motors, multiple reduction gearboxes (some of them complex planetary) and multiple large rolling element bearings. This complexity, combined with the tough 24/7 service, results in too much unplanned shovel downtime, which can affect the entire downstream process."

Jan 1, 2012

By Erwin L. Zodrow

"IntroductionThrough an extensive coal sampling project in the Sydney coalfield of Nova Scotia during 1981 - 1984 involving a majority of the mineable coals (Zodrow, 1985, Fig. 1), a sizeable inventory on trace, minor and major metals was established. In this paper, results of studying the inventory are summarized, concentrating mainly on the relationship that exists between metal variations and thickness of coal channel samples (i.e. trends) and on explaining the trends in geochemical and sedimentological terms. As an over-all conclusion the Everglades peat of Florida is proposed as a modern-day analogue to Upper Carboniferous peat swamp development that took place in the Sydney Basin.Data InventoryFor this study 17 channel samples were cut , 8 cm to 14 cm channel width and 8 cm to 10 cm depth, from 10 successive coals which in stratigraphically descending order are as follows: Point Aconi (3), overrider Lloyd Cove (2), Lloyd Cove (2), Stubbart (2), Harbour (4), Backpit (I), Phalen (,I), Shoemaker (1) and McAulay (I), where bracketed values signify the number of channel samples cut from a seam (Zodrow, 1985, Fig. I). Each channel sample was subdivided by 15 em incremental length yielding a total sample size of 137 for analysis. By appropriate modern techniques these samples were analyzed to determine concentration levels for 32 chemical elements and ash content, the average results of which are presented in Table 1.Tests were also made for Pd, Pt, Ga, Nb, Cd, Cs, Sm and W but their concentration levels in many instances hovered on the lower detection limits that were used and on this accounts are excluded from discussion. Ashing, when necessary for the determination of concentration levels, was done for 12 hours at a temperature not exceeding 450°C. Concentration levels for the elements are reported in reference to whole-coal or whole-coal equivalents and discussed on this basis. In the course of the analyses, lower detection limits received careful attention."

Jan 1, 1986

By A. Dave Mackintosh

The Current demand for potash has pushed world prices to record levels and allowed Saskatchewan producers to operate at maximum capacity. Several years of strong demand has resulted in a permitting rush not seen since the 1960?s. Even though Saskatchewan has a huge potash resource, mining and processing constraints will limit the areas of economic development. Introduction In 1969 M. E. Holter prepared a report ?The Middle Devonian Prairie Evaporite of Saskatchewan?, published by the then Dept. of Mineral Resources. Holter?s report has remained the bible of geologists working in potash ever since. It is astounding that a report written before there was really much potash mining history in the province, is as valid today as when it was first published. This paper re-iterates much of Holter?s report and adds a little mining experience to essentially confirm the importance of his work.

May 1, 2008

By D. L. Millar

The hydraulic air compressor (HAC) is driven only by water, held up by a dam, to create relatively low head (typically 10-20 metres), such that the developed hydropower is used to cause flow in openings deeper underground. Air is entrained in the water at the inlet to the sub-surface openings (an air to water volume ratio of 1:1 is reported to be optimal) and is compressed as it is carried along by the deepening water flow. At depth, and with lower water velocities arising from larger cross sectional area tunnels, air bubbles separate out of the water flow and are collected in a receiver space above the flowing water. Water, free of air, then passes back up a return shaft (up-pipe) and rejoins the river or stream flow. In principle, an HAC can produce any pressure and flow rate required, given large enough shafts and enough water supply with head sufficient to overcome frictional resistance in the sub-surface tunnels. Practically, as air solubility in water increases with pressure, HAC installations with depths greater than 100 metres may lead to higher rates of compressed air loss, without special separation measures. A modern HAC application for mine refrigeration and cooling is presented.

Aug 1, 2013

By S. Dessureault, M. Yildirim

More mining companies are now investing in IT, including updating one of the traditional IT process control tools used in the mining industry: real time in-pit truck allocation control and monitoring systems, or fleet management systems (FMS). These systems have been used to maximize the overall mine production by improving equipment utilization and reducing production costs. Most modern operations monitor the in-pit operations using GPS and wireless communications to produce data. Improvements in bandwidth, sensors, and computing power are causing modern systems to become more complex and generate more data. However, human analysis by simple regression or table generation in spreadsheets of the data is becoming impossible. Data mining solves this data management problem. Data mining finds patterns and relationships in very large data sets. This paper describes the application of modern data mining techniques on truck dispatching systems in a real open pit hard-rock copper mine. The analyses conducted included determining how the trucks performed under particular conditions and allocation systems. The long-term benefits of this work are to identify strengths and improvement opportunities in truck assignment systems and establish the skill sets and IT infrastructure needed in undertaking more complex datadriven technology such as a truck dispatcher trainer.

Jan 1, 2007

By A. P. E. Dirige

The stability design of cemented backfills is normally conducted using conventional approaches. Analytical or numerical models, backed by trial-and-error methods, are the primary means used to describe or predict the support performance of backfills during mining. The stability of paste backfill free-standing faces is a major concern due to potential consequences to production, ore dilution and safety. Available analytical or mathematical models are developed based on assumptions of the failure modes that may occur when vertical fill faces are exposed during adjacent mining. Numerical modeling serves to provide an understanding of backfill strength and deformation behaviour. Such approaches offer inherent limitations and generally result in conservative designs. In this paper, centrifuge physical modeling was conducted not only for performance evaluation studies, including stability analysis, but to develop an understanding of the strength and deformation behaviour of paste backfill exposed faces when the adjacent ore zone is removed. The failure mode and mechanics of failure observed in the centrifuge model of a given prototype situation are discussed in detail. Centrifuge model results were compared to numerical modeling and it was concluded that a sliding block failure mechanism that resembles a circular slip appears to be the predominant failure mode.

Aug 1, 2013

By Kristie D. Tarr

Ideally, in situ monitoring would supply the input data for numerical modeling of backfill material property requirements. However, clue to production requirements and costs of conducting field tests, input data are often based on small-scale laboratory tests. The size of test samples is known to play an important role in the laboratory assessment of the behaviour of geotechnical materials, including backfill. There are observed differences between the mechanical properties of laboratory-scale samples and those of in situ materials, and these are generally attributed to the differences in scale. Various scaling factors have been proposed for converting laboratory observations to anticipated in situ conditions for soil and rock materials. With regard to mine backfill, very limited studies exist which have involved the effects of sample size on material properties. The literature indicates that reported backfill strength data are based on a variety of test sample sizes and in some cases, specimen geometries. Carefully determined laboratory scale effects could play an important role in estimating the potential backfill behaviour in the field, especially when developing new backfill systems. Laboratory studies were conducted with sample diameters ranging from 50 to 300 mm. Scale factors relating specimen size to strength were developed wherever possible, and are presented in this paper

May 1, 2008

By R. G. Gillies, C. A. Shook, W. H. W. Husband

"The current state of knowledge concerning pipeline transport of coal in water slurry form is summarized for the four categories: coal-water fuels, conventional fine coal slurries, coarse coals and stabilized mixtures of coarse and fine particles. Surface chemistry is of dominant importance for coal-water fuels and considerable progress in understanding the role of surfactants has been achieved in recent years. Little generalized research on the flow of conventional fine coal slurries has been done in the past 17years, although innumerable conceptual designs and feasibility studies have been undertaken. Coarse coal slurries are fairly well understood but the model which explains their flow requires more data to be established fully. Stabilized flow mixtures should probably obey the same model as coarse coal slurries but experimental results for stabilized mixtures have not yet been incorporated in a comprehensive theory.IntroductionPipeline transportation of coal in a water vehicle has been employed for many years in coal washeries. It has been used less frequently in hydraulic mining and thermal power station fuel supply systems. The suitability of coal for pipeline transport arises from its moderate specific gravity relative to the carrier fluid and the fact that throughputs are often large and steady over long periods of time."

Jan 1, 1990

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012