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By Herbert D. Drechsler

"THE FOLLOWING are some comments on the article, ""International Trade in Minerals and Economic Development"", by M. Sengupta, published in the October 1976 issue of the CIM Bulletin.Sengupta says in the introduction that ""The mechanism through which this growth (economic development) has occurred is basic ally straight forward"". His statement is quite misleading and perhaps it is better to quote Gerald Meier:""Development economists must operate in an imperfect second-best world, away from the simplified premises of neoclassical economics. Their subject matter is therefore not yet a coherent or self-contained discipline. Denied recourse to a set of general principles, perhaps the student's most sensible introduction to economic development is through a study of 'leading issues' that are at the time a major preoccupation of the development economist and development practitioner"" .Sengupta quotes an authority who wrote 18 years ago. Academic and operating development economists today know full well that existing theory is quite deficient. Sociologists, political scientists and engineers in this field also know that economic, social, political and technical development involves all academic disciplines.Sengupta indicates that tariffs in developed countries prevent less developed countries from supplying refined metal, or manufactured and semi-manufactured products. He lists Zambia, Chile and Zaire as examples of copper concentrate exporters, as inadequately shown in Table 1. He is wrong."

Jan 1, 1977

By Oberlando Gonzalez, Claudia Serna, Andrea Alzate, Esperanza López, Maria Holuszko

This paper presents a systematic approach on gold recovery from electronic waste (e-waste) using ammonium persulfate. This process was developed as a response to the lack of hydrometallurgical systems capable of separating gold from its metallic substrate without material grinding, with minimum formation of pollutants, and achieving a lower reaction time. Computer memory boards, electronic processors and electronic pins and contacts were analyzed to determinate base metals (Ni, Fe, Cu) and gold (Au) using microwave plasma atomic emission spectroscopy (MP-AES). An aqueous commercial grade ammonium persulfate with oxygen and pressure was used to produce the persulfate anion (S2O82-) and the oxidative sulfate ion (SO42-), which partially oxidized and leached the base metals breaking the Au-Ni-Fe-Cu bonds and allowing gold to be recovered in its original non-leaching state. The influence of the oxidative parameters was evaluated using full factorial (FF) and central composite designs (CCD) with response surface methodology (RSM) and first and second order models were developed. Using RSM allowed to obtain a faster recovery of gold, minimizing the agent consumption. The findings presented suggest that optimized quantities of ammonium persulfate, oxygen, pressure, temperature and liquid solid ratio could be used for selective oxidization of the base metals and to extract more than 96% of gold from e-waste.

Jan 1, 2017

By Elhachmi Es-Sadiqi

"For over 40 years, CANMET has focused its research on value-added products and energy efficiency in the metals industry. The Efficient Metal Production Program is currently managed by Dr. Elhachmi Es-Sadiqi, and the Canadian steel industry is its main client — both directly and through international organizations such as the American Iron and Steel Institute (AISI) and the International Lead and Zinc Research Organization. AISI membership includes Canadian steel companies IPSCO, Dofasco, Stelco, Algoma Steel and Sidbec Dosco.Canada’s steel industry makes important contributions to the economy. The industry comprises 14 companies and employs 33 600 people in locations such as Sydney, Nova Scotia; Tracy, Quebec; Selkirk, Manitoba; Saskatoon, Saskatchewan; and Sault Ste. Marie, Ontario. With annual production at about 16 million tonnes, sales in 1995 totalled $11 billion, $3.8 billion of which was exported.Canada’s steel industry supplies the transportation, oil and gas, appliance, packaging and construction industries. It is at the forefront of new technology use and has a substantial support network to provide raw materials, equipment and service. Three main segments of the industry include flat-rolled products (e.g., plate and sheet steels), long products (e.g., concrete reinforcing bar and structural steel), and specialty and alloy steels (e.g., stainless steel and tool steels, in both long and flat products)."

Jan 1, 1998

By D. A. Livingstone

"INTRODUCTORY REMARKS BY PANEL CHAIRMAN - D. A. LIVINGSTONEThe mining industry has progressed significantly from the dusty mines and mills of decades past to the modern processing complexes of today, and improved technology has made great strides in eliminating debilitating lung discuss. More recently, the public's environmental awareness is also working to enforce more stringent regulations and controls in tl1e matter of dust in working places.There are numerous excellent texts and handbooks outlining the principles of collection of dust produced in the various unit operations entailed in the crushing, screening and the transport of ore. However, it is painfully obvious that dust emanating from belt return idlers and scrapers, take-up pulleys, skirting, larger and deeper chutes, clean-up operations, etc., which I choose to refer to as fugitive dust, presents some seemingly unmanageable difficulties, or at least difficulties inordinately costly to correct. Possibly static electricity is adding to the difficulties. In my view, these problems are magnified in many of our B. C. operations where ore from open pit mines in cold climates is frequently crushed in unheated buildings, thereby precluding the simple and obvious use of water sprays for dust suppression.It is hoped that the presentations and discussion which follow will emphasize some of these unusual problerr.s and suggest corrective measures, either tried or planned."

Jan 1, 1976

By H. Nakano

The codeposition behavior of impurities such as Ag, Bi, Fe, Ni, Pb and Sb with Cu was investigated galvanostatically at 5-3000 A/m2 using a Pt cathode at 60 °C in acidic copper (I) chloride (cuprous chloride) solution at pH1-2 containing 1.0 mol/L of Cu+ and 4.9 mol/L of Cl-. The impurities were classified into two groups: Group I (Ag, Bi) which codeposits with Cu as a metal, and Group II (Fe, Ni, Pb, Sb) which is slightly involved in the deposited Cu in nonmetal form from the electrolyte. Silver and Bi in Group I behaved as more noble metals than Cu, and significantly codeposited with Cu, showing typical features of regular-type codeposition. When Cu was deposited dendritically, the Ag and Bi content in the deposit increased with increased duration of electrolysis as a result of decreased net current density caused by increased cathode area. The current efficiency for Cu deposition in impurity-free solution was 95-100% over 100-1000 A/m2, but it abruptly decreased at above 1000 A/m2 when the limiting current density of Cu was attained. Although Fe, Ni, Pb and Sb in Group II were involved to 0.01-0.02 mass% in the deposit, they had no influence on the current efficiency or morphology of Cu.

Jan 1, 2007

By J. O. Marsden

Over the past eight years, Phelps Dodge (a division of Freeport-McMoRan Copper and Gold, Inc.) has developed a suite of proprietary hydrometallurgical processes for the treatment of copper concentrates as an alternative to conventional smelting and refining technology. The technical viability of two processes has been commercially demonstrated in a large scale plant at Bagdad, Arizona, designed to process approximately 52,500 metric tons per year of concentrate containing 30.5% copper. The first process utilizes high temperature (225°C) pressure leaching, followed by countercurrent solid-liquid separation, and then blending of the copper-bearing solution with low grade stockpile leach solution for subsequent treatment by SXlEW for copper recovery. The second process uses super-fine grinding, medium temperature (l60°C) pressure leaching, followed by solid-liquid separation, and treatment of high grade copper-bearing solution by direct electrowinning to recover the bulk of the copper values. The latter process will be utilized at Morenci in a commercial facility designed to treat mixed chalcopyrite-chalcocite-covellite concentrates. This facility is scheduled to start up in 2007. Other flowsheet options have been developed by Phelps Dodge for application to a variety of concentrate materials in specific situations. Examples of various flow sheet options are presented in this paper, and the advantages and disadvantages associated with each are discussed in detail.

Jan 1, 2007

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb/Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb/Zn ore was traced to a pH effect. In the pH range 9.5-11 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH) 2 is suggested, the Fe++ions being derived from superficial oxidation of pyrite in the ore.INTRODUCTIONGalena and sphalerite commonly occur together. The usual practice is to float galena first followed by the flotation of sphalerite after activation with copper (II) sulphate. If ores contain pyrite it is depressed by maintaining an alkaline pH (9- 10) and using NaCN as depressant.In flotation tests with a Pb/Zn ore from Polaris selective flotation of galena could not be achieved consistently as a considerable amount of sphalerite, even though unactivated, floated. A systematic study was carried out to determine the cause of this problem. This led to the unexpected finding that sphalerite floated in the alkaline pH range 9.5-11.0 without preactivation with Cuso 4 . This paper describes the results of this study and discusses a possible mechanism of the flotation of sphalerite."

Jan 1, 1987

By S. Koski, J. Vanderbeek, J. Enriquez

"The Cerro Verde copper-molybdenum porphyry mine, majority owned and operated by Freeport- McMoRan Copper & Gold, is located 30 km southwest of Arequipa Peru. The concentrator, which produces copper and molybdenum concentrates, started operating in late 2006 with a 108,000 tpd design capacity, processing primary sulfide ore (mainly chalcopyrite and molybdenite). Plant capacity was recently increased to 120,000 tpd. The comminution circuit consists of one 60” x 113"" primary crusher, four MP-1000 secondary crushers in closed circuit with dry screens, four 2.4m x 1.6m High Pressure Grinding Rolls (HPGRs) in closed circuit with wet screens, and four 7.3m x 11m gearless ball mills in closed circuit with cyclones. The HPGR circuit is fed by the Secondary Crushing circuit product at a T80 of 35 millimeters, and the HPGR circuit product feeds the Ball Mill circuit at a T80 of 3000 microns.This paper describes operating experiences with HPGRs during these first four years highlighting improvements in operating practices and presentation of data regarding operational efficiencies, also discussed are the primary benefits provided by HPGRs such as production of micro fractured particles, reduced ore Bond Work Index, and reduced power consumption. Cerro Verde represents the first installation of HPGRs in both the copper industry and large scale hard rock mining."

Jan 1, 2012

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By A. Tohn, L. May, Adham. K.

The path from process conception to commercial implementation poses significant technical, economic, and sometimes political challenges for every project team. Solving the technical challenges typically distinguishes successful projects from those that fail. Here, the authors provide an outline for technical success based on lessons learned from years of experience in process design and R&D. Challenges faced by new technology developers, with regard to design and definition, are described. Experience-based methods to avoid missteps are shared. Special emphasis is placed on the selection of viable unit operations, definition of known and unknown parameters, experimental screening of options, and piloting for scalable design information. Use of computational models to define, assist, and interpret the pilot operations and results are described. Furthermore, the value of active collaboration amongst the design, research, and owner team is demonstrated.

Jan 1, 2011

By R. Marleau, R. Assad, J. Dugas

"A study of the geological features of known occurrences of mineralization in Gaspe is the basis for a classification. Nickel, chromite, asbestos and some copper are pre-or syn-Taconic, whereas the most important deposits are tied to granitic post-Taconic stocks. Most occurrences are clearly related to igneous rocks: nickel, chromium and asbestos to Ordovician serpentinite; copper to volcanic rocks of different ages; and copper, zinc and lead to acidic intrusions with apparent zoning. Some lead-zinc deposits lying between the Grande Greve and York Lake formations are stratigraphically controlled. Some occurrences are tied to faults; e.g., the nickel-copper mineralization along the North Grand Pabos fault. Northerly-trending transverse structures appear to coincide with the Gaspe Copper, Mount McGerrigle (Tabletop) granite and Lemieux dome areas of mineralization. JEAN DUGAS, after graduating"

Jan 1, 1969

"The outlook for Eastern Canada is decreased coal production and for Western Canada increased production. The market for Western coal is expected to reach 40 million tons per year in metallurgical and thermal-power markets.Technical developments in Eastern Canada include successful methane drainage experiments, modifications to the shearer-loader to improve cutting rates, mechanized mining of a tail-gate stable and mechanical stowage of level brushing. In Western Canada, the most modern equipment is used in mining, beneficiating and shipping coal. Underground hydraulic experiments were started in 1969. The importance of reclamation was recognized and plans have been made to re-vegetate disturbed areas and mine dumps.The Mining Research Centre closed the field office in Nova Scotia and is preparing to open a new field office in Calgary, Alberta."

Jan 1, 1970

By Mike Fontaine

The success of a project is defined by meeting the financial performance objectives of the business case within a stipulated timeframe. Early in design, little information is normally available; the uncertainty introduces risk to the project outcome. Using a range of risk management tools and techniques, a project can be developed from front end loading phases 1 through 3 (FEL1–FEL3), and project implementation (FEL4) and then into operations with an optimized probability of success. For every project element, the risk management framework embodies: establishing a context; assessing risk (identify, analyze, and evaluate); and treating risk. Embedded within design activities, this process mitigates or eliminates risks. Monitoring and control, as well as extensive communication and consultation with stakeholders, is integral to the risk management process.

Jan 1, 2015

By Chris Twigge-Molecey, John Peacey

To meet the business objectives of a metallurgical project, there is often a need for new and untried technology or equipment, whose very novelty can present serious risks to meeting those objectives. The key risk management approach is a rigorous stepwise progression from theoretical evaluations and laboratory tests to pilot plant trials. These must be followed by demonstration-scale trials before final construction of a commercial scale plant, paying particular attention to the magnitude of the scale-up between phases. Success depends on following a well-defined program, not eliminating any steps, and ensuring adequate resources are available to the development team. Chapter 6 discusses the nature of technology risks to metallurgical plant projects, and the rigorous management practices needed to identify, analyze, evaluate, and avoid or mitigate them.

Jan 1, 2015

By R. Minto, W. G. Davenport

The slag removed from the reverberatory furnaces of copper smelters contains significant copper values. A serious financial loss is involved, as further recovery operations are not normally carried out. This paper describes the factors affecting physical transport of matte into slag by gas bubbles, and the subsequent entrapment and flotation of matte drops. Three distinct patterns of transport behaviour have been identified from studies of a number of liquid/liquid systems, including liquid metal and liquid matte systems. A theoretical approach is proposed to explain these behaviour patterns, and to predict transport and entrapment behaviour in matte/slag systems. The concepts of "Film Coefficient" (ø) and "Flotation Coefficient" (?) are introduced. The effects of smelting process variables on the physical loss of copper matte in slag are also discussed.

Jan 1, 1972

By J. R. Rau

While refuge chambers are common place in most underground mining projects, there are different philosophies as to what life support systems are to be considered and how these systems are to be applied. Case studies in the underground mining industry have examples of emergencies where the external compressed air and power supply to the refuge chamber were compromised due to proximity of services to the fire location. In 2005, The Department of Industry and Resources, Western Australia, drafted guidelines that listed specific requirements for refuge chambers which included a secondary life support system that would operate independently of external sources. The objective of this document is to examine what critical life support systems are essential for safe entrapment in the event of an emergency and to examine considerations for their application.

Aug 1, 2013

By P. Hale

"The trend to drives of more than 10,000 hp on large-capacity ball and autogenous mills for increased operating efficiency has been limited by factors in the conventional drive system. A solution to this problem, using modern developments in static converter technology, is the concept of driving the mill directly without gearing using a low-speed, low-frequency synchronous motor with a cyclo-converter power supply.This paper presents various practical arrangements of mill and low-speed motors giving the specific advantages of each system. The means of controlling inrush currents on starting and of spotting by the use of variable-frequency control are outlined in general form. Several gearless ball mill drives are scheduled for start-up in European cement plants and further orders have been placed."

Jan 1, 1970

By P. Gautier

Current feedstock in the aluminum hot forging processes can be used in the cast or extruded forms. The microstructural variation between as-cast and extruded materials could result in different mechanical properties and corrosion resistance for hot-forged products. Corrosion performances were examined for forged parts produced by two AA6082 feedstocks at different conditions using the following corrosion tests: open circuit potential, anodic polarization, salt spray exposure and corrosion fatigue. With the help of optical and scanning electron microscopes, metallographical investigations were carried out on cast-forged and extruded-forged materials before and after corrosion. The corrosion behavior of both materials was compared in both as-forged and aged tempers. Results show that there is no significant difference in the corrosion performance for final cast-forged and extruded-forged products.

Jan 1, 2011

By C. Riveros, H. Henein

Bulk Metallic Glasses have a high potential as advanced engineering materials due to their various properties including strength and corrosion resistance, to name a few. This paper investigates amorphous phase formation and rapid solidification characteristics of impulse atomized Co-based alloys in order to understand and control the application properties of the final products. Amorphous fraction and kinetic crystallization properties of the atomized Co-based alloy powders were quantified by means of Differential Scanning Calorimetry. In addition, different but complementary characterization tools were used to analyze microstructures of the powders. These include optical microscopy, X-ray diffraction and micro-hardness tests. While the amorphous fraction within the powders is promoted by high cooling rate and smaller powder size as expected, hardness is found to decrease with the fraction of amorphous phase.

Jan 1, 2015

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015