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By R. W. Lawrence, A. Bruynesteyn

"Pre-oxidation of refractory pyritic concentrates by biological leaching to enhance the recovery of gold and silver in cyan ideation has been investigated. The results of laboratory tests on three concentrates are presented. In all cases substantial increases in precious metal recoveries were obtained following the pre-treatment. For one concentrate, gold recovery of 81% was achieved following an 87% oxidation of pyrite, compared with 24% recovery by direct cyanidation of non-oxidized concentrate. Gold and silver recoveries from the other concentrates were increased from the range 60-78% to over 90% and from 80-86% to over 98% respectively. Operating parameters are discussed and methods of maintaining high oxidation rates are evaluated. Methods of employing this pre-oxidation technique in commercial practice are described.IntroductionMany of the gold and silver deposits now being developed contain precious metals finely disseminated in sulphide minerals such as pyrite. These ore s often present considerable resistance to metal recovery. The ease with which gold may be extracted is usually related to grain size and its manner of distribution within the host mineral. In many cases, a significant percentage of the gold may occur in submicroscopic form, or in solid solution with pyrite, so that even very fine grinding fail s to liberate the metal for recovery by cyanide leaching. Such ores are often termed refractory. Even in cases where liberation by fine grinding is practicable, high cyanide and lime consumption may be experienced due to the presence of specific sulphide minerals, and poor metal recovery may result.Pre-oxidation methods for refractory ore s and concentrates are commonly used to improve precious metal recoveries. Roasting, for example, as a pre-treatment to cyanidation, removes harmful constituents by oxidation or volatilization, and liberates gold from pyrite. In some cases, however, this method of pre-oxidation can result in poorer metal recovery, particularly of silver, due to fusion and the formation of clinker, and the formation of compounds which consume cyanide in the subsequent metal recovery stage. Difficulties in compliance with environmental pollution regulations may also be encountered."

Jan 1, 1983

By Heather Budney

Objectives 1. Evaluate the effectiveness of ON?s EA processes using criteria from the EA and policy sciences literature. 2. Recommend improvements to the EA processes and draw lessons from the ON case for the consideration of other jurisdictions. Evaluation Process 1. Chose criteria ? 14 primary criteria (Wood 2003) ? Subcriteria from Wood (2003) and Lasswell (1971) 2. Gathered information ? 6 key informant interviews ? Published literature, policies, legislation 3. Assessed criteria and formed Recommendations

May 1, 2008

By D. Paul Bishop, Kevin P. Plucknett, Hung-wei Liu

"Spark plasma sintering (SPS) process has been evaluated for producing the commercially pure (CP) Ti, TiAl and a TiAl-B4C composite. Comparisons were made between the materials in terms of the sintered density, resultant hardness and microstructures. In the present work, the titanium aluminide powders (Ti-48Al, producing a mixture of y-TiAl/a2-Ti3Al) were synthesised „in-house? using a simple reaction-sintering and mechanical attrition approach. This allowed various size distributions to be generated. The powders were then blended with a fine boron carbide (B4C) powder (up to 6 wt.%), and the resulting mixtures were consolidated using spark plasma sintering (SPS) under vacuum in graphite dies. An applied stress of 50 MPa was used for all SPS runs. The SPS parameters were varied in terms of the ultimate sintering temperature (up to 1300°C) and hold time (up to 10 minutes) for each material. It is demonstrated that high densities can be achieved this approach (exceeding 95% of theoretical, with optimised samples close to full density). Microstructural characterisation was conducted using optical microscopy, scanning electron microscopy, and X-ray diffraction. The B4C additions were seen to partially react with the TiAl to form reinforcements, such as TiCx and TiBx. Preliminary mechanical property assessment will also be briefly discussed.INTRODUCTION Titanium- and titanium aluminide-based alloys possess many unique properties, such as excellent corrosion resistance and high temperature strength, respectively (Cardarelli, 2001; Leyens & Peters, 2003). Compared to many other competing materials (e.g. stainless steel or Ni-based alloys), Ti- and TiAl-based alloys also have relatively low densities (~4.5 and ~3.9-4.1 g/cm3, respectively), which is critical for performance in aviation and automobile applications. However, the manufacturing cost is high, due to the expensive raw Ti material and difficulties in machining. TiAl-based alloys are particularly difficult to produce because of their limited ductility (Lütjering & Williams, 2007). To overcome those problems, powder metallurgy (PM) technologies have shown great potential as near-net shape processes for Ti- and TiAl-based alloys. The general PM process largely avoids laborious post-machining and minimises material use. In industrial production, the PM approach has been successfully utilised to manufacture aluminium- and iron-based alloys (Huo & Heath, 2008)."

Jan 1, 2017

By Jean-Christophe Ehrström, Fanny Mas

"A specific test set-up has been developed to study at the lab-scale the high-temperature behavior of aluminium alloys in conditions close to those experienced by thick plates during hot-rolling. A particular attention is paid to reproducing both the stress triaxiality and strain fields that exist in plate during rolling. In addition to standard ductility measurements by means of secondary tensile tests (STT), multi-step plane strain compression (PSC) tests have been performed to mimic hot-rolling pass schedules. Tool and sample geometries were adapted to allow low h/a ratios (h= average specimen thickness, a= tool width) and thus guarantee depressive stress conditions at the center of the specimen during most of the test. Such conditions resulting in porosity opening can then be used to investigate the impact of rolling conditions on damage evolution. The mechanical testing was combined with post-mortem high-resolution ultrasonic scans allowing to detect small amounts of damage and quantify its evolution as a function of processing parameters such as strain and temperature. The test set-up was validated on two 2050-type AlCuLi alloys with different susceptibilities to high temperature embrittlement.INTRODUCTION Aluminium thick plates are widely used in the aerospace industry, mainly as semi-products to be machined for internal structure parts of wings (spars, ribs) and fuselage (frame). The conversion route of such products always involves a hot-rolling step, the conditions of which (temperature, speed, pass schedule) have to be optimized to maximize both mechanical properties and final plate quality. This goal cannot always be efficiently achieved by full-scale industrial trials as (a) cost limits the number of possible test conditions and (b) it is often difficult to change one parameter alone. That is why there is a need for laboratory-scale tests able to mimic the rolling process in terms of temperature, strain rate, stress triaxiality and deformation. Most laboratory hot-rolling mills do not adequately simulate industrial processing routes, especially in terms of heat loss, deformation speed and rolling geometry (maximum roll gap vs. work roll diameter). Concerning thick plate, it is of interest to achieve both similar deformation and L/h ratio (L=arc of contact, h=mean gauge) per pass as the industrial schedule because they are simultaneously involved in damage evolution and void closure during hot forming processes (Saby, 2014)."

Jan 1, 2018

By K. Thuro, H. Käsling, F. Menschik

"With increasing data volume, due to enhancing requirements for ground investigation programs for large construction projects, the demand for more efficient filing systems is more and more growing. Depending on the project we also have to use flexible systems to cope with varying data out of different lab and field tests.The chair for Engineering Geology at TUM is developing a web-based database solution to handle all project relevant data in a more appropriate way. We aim to optimize our data management to achieve a fast and easy way of collecting, documenting and analyzing our gained data. The second objective is to provide an easy access to our data for project partners across broadly distributed locations.This Database system consists of a PHP web interface and a MySQL database core. The current setup allows an online access via Internet (www). We are able to grant and constrain access to all data or only arrays of data with our user management system to guarantee the safety of project data and respect all rights and proprietorship. The database system is of modular design and consists of the following three base modules: module of general project data, module of laboratory data and user management module. At the current stage we are able to save and work with all usually generated specific values from unconfined compressive strength tests, brazilian tensile strength tests, point load tests, CERCHAR and LCPC abrasivity tests and ultrasonic tests. The user is able to perform a simple statistical analysis within our database (e.g. average calculation of one sample) and export data as csv or xls files for further analysis.For specific questions within projects we are able to deploy and integrate further modules in our database system. At this moment, we are developing an add on to use this database for different drill test analyses. One of the tools correlates drilling performance and drill head wear measured in the field with rock mechanical properties, and extrapolates the data to estimate the performance and wear in new projects. Today we are managing 90 projects with 550 samples and almost 1350 lab tests with the base module.In our contribution we aim to demonstrate an efficient way of data structuring using a relational database for laboratory and field testing data."

Jan 1, 2015

By Y. Thibault, L. Morin, R. Cameron, D. Gould

"There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite tailings in the Sudbury area alone, with an average nickel grade ~0.8% (plus cobalt). Pyrrhotite is a highly reactive sulphide mineral that has the potential to generate acidity; consequently, it is stored in large tailings ponds that require perpetual treatment to avoid the production of acidic drainage. Re-processing this material using bioleaching technologies has the potential to recover valuable metals, while reducing the toxicity, reactivity, and acid generating potential of the remaining residues. CanmetMINING is currently developing a stirred-tank bioleaching process to recovery nickel and cobalt from pyrrhotite-rich tailings. Stirred-tank experiments have been conducted with one tailings sample over a range of pH and temperature conditions, resulting in 80 to 90% and 70 to 80% leaching of nickel and cobalt respectively in 10 days.INTRODUCTION Sulphide tailings may represent a significant financial liability for mining companies as these wastes may produce acidic drainage under some disposal conditions. As a result, the companies must post financial bonds large enough to ensure there are sufficient funds for perpetual management of these wastes. At the same time, there are billions of dollars in metals incorporated into these mining wastes waiting to become valorized. Many sulphide tailings are amendable to bacterial oxidation for metal extraction. Re-processing of tailings using bacterial leaching has the potential to recover valuable metals from waste; and reduce the toxicity, the reactivity, and the acid generating potential of the remaining residue. By reprocessing these wastes there is an opportunity to significantly reduce liabilities and financial assurance bonds, while recovering metal values. There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite-rich tailings in the Sudbury area alone with an average nickel grade ~0.8% (Peek et al., 2011) plus cobalt and copper. Pyrrhotite is separated from pentlandite concentrates by magnetic separation and flotation. It is already finely ground and has often been segregated from other tailings material, making „mining? relatively inexpensive. This represents roughly (> $100/ton) in contained value, with negligible mining costs. This paper reports on the development of a stirred-tank bioleaching process for recovering nickel and cobalt from pyrrhoitite-rich tailings, which is currently underway at Canmet MINING."

Jan 1, 2017

By Subrata Dutta

Sindesar Khurd Mine is situated in Rajasthan, India, and operated by Hindustan Zinc Ltd, under Vedanta Group. The base metal mine is high in reserves of Lead, Zinc and silver and has been producing since 2007 with initial production of 0.3 mtpa. Recently the mine has gained prominence as a base metal underground mine in introduction of latest mining techniques and achieving high production at lowest costs. The promising Lead-Zinc reserves of Sindesar Khurd Mine (SKM) and high-tech exploration adopted by Hindustan Zinc Ltd (HZL), (Vedanta Group), raising the reserves and resources from a meager 9 Mt (1997) to 81 Mt (2012), has prompted HZL management to ramp up the mine production from 0.3 mtpa (2006-07) to 2 mtpa by 2013-14 with ambitious plans to reach 3.5mtpa subsequently (presently largest underground metal mine in India). The complete trackless system underground mine, recently equipped with latest leaky feeder communication system (unique in India), utilize modern drilling, mucking and hauling equipment aided with various utility/service vehicles. Excavation optimization and quality recovery maximization from the open and post filled stoping methods, continual expert analysis and feedback from International consultants like AMC (Australia) and SRK (UK), and involvement of renowned bodies in management excellence, have lead the mine towards highest productivity and lowest mine operating cost, earning the mine a prominent place in the global base metal industry. The paper deals with how the various challenges in mine planning and designing, mine development, operator skill, equipment introduction and maintenance, expertise availability, provide training and exposure to officials, prompt and effective communication/service, control of ground vibrations, maintain ventilation standards etc are faced in attaining high operational excellence and thus attain a record mine output/man shift (OMS) of 14 ton/man shift with targets to reach 20 ton/man /shift. Scientific designing using 2D/3D numerical mine-modeling techniques, faster stope sequencing with introduction of paste filling ( first time in India),latest leaky feeder communication system, control ground vibration to stringent standards using electronic delay system, faster raising techniques using raise borers to enhance development and ventilation, cavity scanners to monitor large stope voids, fast shaft sinking at 100 m/month(Chinese expertise) and maintaining adequate ventilation with close software monitoring are some of the highlights discussed in the paper towards achieving the targets.

Aug 1, 2013

By D. A. Trotter, G. J. Goddard

"This paper describes a method of deciding on various design parameters for a sublevel caving layout. Layout design curves are obtained from the output of a computer optimization program. The program uses mathematical relationships derived from the theory of gravity flow of material to optimize the large number of interdependent design variables which are involved.IntroductionIn the design of an efficient sublevel caving mining system, a large number of interrelated variables need to be considered. Although many papers discuss individual variables, very little exists in the literature to show how these variables interact to achieve optimum results. This can lead to trial and error in sublevel caving design, which can prove costly, particularly because sublevel caving is a mining method which requires integration with sublevels above and below. With no pillars being left, experimental stopes cannot be isolated for study. Unfortunately, the complexity of layout design and the costs associated with trial and error have caused many planning engineers to choose more tried and tested mining methods.Sublevel caving works best to extract low-value ore surrounded by incompetent rock. All phases of the mining method can be highly mechanized, allowing low operating costs and high production rates. Good safety records are achieved, as workers are always in 'good' ground and the method is regular, making it comparable to an industrial process."

Jan 1, 1981

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

In this project, low grade copper ore samples were obtained from two mining sites in the US, and they were chalcopyrite-rich (sample A) and conichalcite-rich (sample B) ore. Copper grades were 0.6% and 0.4% for the two samples, A and B, respectively. Leaching experiments were conducted by bottle roll tests for 24 hours, and various lixiviant systems were applied. Methanesulfonic acid (MSA) and glycine were used as alternative lixiviants to sulfuric acid. Oxidants including ferric ion and hydrogen peroxide were tested. The results showed the copper extraction of sample A increased after adding 1 g/L ferric ion in sulfuric acid and MSA solution, from 20% to 36%, but further increase was not observed with higher ferric ion concentration. The copper recovery increased significantly with H2O2 concentration, and over 80% copper recovery was obtained with 10% H2O2. For sample B, the copper dissolution kinetics were relatively fast and reached the maximum value in five hours. Around 60% copper were extracted in sulfuric acid and MSA solution. Copper recovery slightly increased after adding ferric ion and H2O2. Glycine is a weaker lixiviant for both samples, the copper extractions were 36% and 4% respectively. INTRODUCTION Chalcopyrite is the most abundant copper sulfide mineral on earth, and it is one of the most refractory copper minerals regarding chemical processing. The declining copper grade and depletion of copper oxide deposits stimulate the development of hydrometallurgical process to extract copper from chalcopyrite. The dissolution of chalcopyrite by ferric ion is normally illustrated as Equation (1) and (2) (Dutrizac & MacDonald, 1974): CuFeS2 + 4Fe3+ → Cu2+ + 5Fe2+ + 2S0 (1) CuFeS2 + 4Fe3+ + 3O2 + 2H2O → Cu2+ + 5Fe2+ + 2H2SO4 (2) However, slow kinetics are usually observed from chalcopyrite leaching at ambient temperature and pressure. Researchers attribute the slow kinetics to passivation during chalcopyrite dissolution, and different passivation products are also proposed (Klauber, 2008). In recent years, many efforts have made to develop new methods to extract copper from chalcopyrite, such as utilizing bacteria or stronger oxidant (Zhao et al., 2015; Ruiz-Sánchez & Lapidus, 2017).

Jan 1, 2019

By H. C. L. Reemeyer

One of the fundamental trade-offs for copper concentrators is between grinding circuit product size and copper recovery. The capital and operating cost savings and throughput increases for a coarser grind should be evaluated against potential recovery reductions. Other benefits of coarser grinds, such as GHG emissions reductions and favourable effects on tailings and water management should also be considered. This paper assesses the formation of laboratory and pilot test programs, design of process flowsheets, equipment selection, and evaluation methods to determine the most appropriate and economical grind size for a given deposit. The paper will include an evaluation of case studies. INTRODUCTION The majority of the world’s mined copper comes from sulphide deposits, which are mostly processed using crushing, grinding, flotation and dewatering flowsheets to produce copper-bearing concentrates for smelting. Ores must be ground to a sufficiently fine size to achieve an acceptable level of liberation to allow both high recovery of copper and valuable by-product minerals while efficiently rejecting gangue to tailings. Therefore, a key design parameter in process plant design is the grind size of the flotation feed. Copper concentrators use a variety of grind size targets that depend on various factors, including ore mineralogy and the grain sizes of valuable and gangue minerals; the sensitivity of valuable mineral recoveries in the rougher flotation stages to grind size, ore hardness; electricity costs; and mining vs. processing throughput constraints. Typically, copper and by-product recovery increase as grind size is reduced, which can improve revenue, but finer grinds increase power and grinding media operating costs and may have implications for tailings management. This paper explores the trade-offs that should be assessed in determining the optimum grind size, and to answer the question if coarser grinds are worthwhile. METALLURGICAL AND FLOWSHEET FACTORS Recovery-by-size behaviour of sulphide-bearing particles In base metals sulphide flotation, it is typical that flotation recoveries vary by particle size. Metal sulphide particles rendered hydrophobic by collector in intermediate size ranges (e.g. 10 to 100 um) usually show very high recoveries, often approaching 100%. Recovery usually falls away in finer size fractions (<10 um) as fine particles have little inertia and can move around bubbles without colliding and attaching to them. Coarser particles (>100 um) are susceptible to particle-bubble detachment and dropback (Jameson, 2019).

Jan 1, 2019

By E. M. Hillary, D. F. Sangster

"Abstract - As a contribution to the World Minerals Geoscience Database Project, an index-level database comprising information on 142 SEDEX Pb-Zn deposits and occurrences was constructed in Microsoft Access 95 format. Although consisting of only basic information, the compilation, with full referencing of all data, is possibly the largest non-corporate SEDEX Pb-Zn database in the world. It thus provides an opportunity to make geoscience queries of SEDEX Pb-Zn deposits on a scale not previously available. This report provides a summary of the results of a few such queries both as a contribution to a better understanding of SEDEX lead-zinc deposits and as a demonstration of what even such a simple database can offer.During the compilation process, it became apparent that SEDEX Pb-Zn deposits could be assigned to one of the following three sub-types: Type 1 (53.5% of total) in which sulfide minerals are the only exhalative components; Type 2 (33.1%) in which the exhalative components are sulfides plus chert, siderite/ankerite, and/or barite; Type 3 (13.4%) which contains any components of Types 1 and 2 plus abundant iron-oxide minerals (commonly magnetite) and/or is associated with iron oxide-rich sedimentary rocks.Highlights of systematic queries of the database reveal that:1. a majority (84%) of the world’s SEDEX Pb-Zn deposits are not underlain by a discordant footwall feeder zone or vent complex;2. 63.6% of deposits occur in Proterozoic strata followed by a second peak in the Devonian (16.8%). Of those in the Proterozoic, 83% of Type 3 deposits occur in the Gondwanaland supercontinent, whereas only 42% of Type 2 and 39% of Type 1 are located in this large paleo-landmass;3. median (Pb+Zn) grades in Types 1 and 2 fall between 9% and 10% with a majority clustering within this range. Type 3 grades, however, range from ~1% to ~20% (Pb+Zn) with a median of 5%; 4. median size of Type 3 deposits is ~33 Mt, whereas Type 1 and 2 median sizes are ~7 Mt and ~8 Mt, respectively.The report concludes with a brief discussion of how an index-level database such as this can be used in conjunction with other, similar databases to reveal interesting and instructive relationships for guiding both research and exploration."

Jan 1, 1998

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017

By K. Morin, C. -Y. Hon, G. Lachapelle

"Air-sampling results suggest drill operators working inside environmental drilling cabs at an open-pit gold mine in Nunavut, Canada, are at risk of exposure to asbestos and silica (quartz). The authors installed RESPA® CF Vortex HyperFLOW® units, which showed promising results under laboratory conditions. The goal was to evaluate the effectiveness of these units under actual working conditions. Personal and area air sampling was conducted in drilling cabs with and without the unit and a Wilcoxon rank-sum test was performed to compare the results. Particulate concentrations were significantly lower in drill cabs with a unit installed than in those without.RÉSUMÉ Selon les résultats d’une campagne d’échantillonnage de l’air, les foreurs travaillant dans des cabines de forage environnemental dans une mine d’or à ciel ouvert du Nunavut, au Canada, risquent d’être exposés à l’amiante et la silice (sous forme de quartz). Les auteurs ont installé des unités RESPA® CF Vortex HyperFLOW®, lesquelles of frent des résultats prometteurs en laboratoire. L’objectif est d’évaluer l’efficacité de ces unités dans des conditions de travail réelles. Des échantillons de l’air inhalé par le personnel et dans les aires de travail ont été évalués dans des cabines de foreuses équipées ou non de cette unité ; un test de Wilcoxon (également appelé test de la somme des rangs de Wilcoxon) a été mené afin de comparer les résultats. Les concentrations particulaires étaient considérablement plus faibles dans les cabines de foreuses équipées d’une unité que dans celles en étant dépourvues.INTRODUCTIONGenerally, mining operations are associated with a variety of occupational hazards. In an open-pit gold mine in Nunavut, Canada, drill operators are routinely exposed to asbestos (primarily amosite) and silica (quartz)—two naturally occurring substances in the ore that is to be drilled (Table 1). Inhalation is the primary route of exposure for these two hazards, which are associated with respiratory health effects such as asbestosis and silicosis, respectively. In addition, asbestos and silica are classified as human carcinogens by the International Agency for Research in Cancer (2001, 2011). Given the toxicity of these two agents, it is imperative that precautions be taken to minimize the risk of exposure of the mine’s workforce. To address this matter, the mine has an exposure-control plan, which includes the provision of personal protective equipment, personal hygiene facilities, training, and a medical surveillance program. Furthermore, the mine performs occupational exposure assessments or air sampling on a regular basis because the morphology of the ore changes rapidly with respect to asbestos and silica content."

Jan 1, 2017

"Some of the tools developed for the processing of nickel laterite ore by resin-in-pulp (RIP) may be applicable to the remediation of metalliferous mine drainage (MMD). In both cases, recovery of metal value and production of a stable waste stream appropriate for long term storage is desired. MMD typically has the additional challenge of management of toxic low-value metals. Seen in this light, innovations in RIP reactor configuration, selective elution strategies and novel synthetic ion exchange resins become useful tools for taking on the MMD challenge in a way that maximizes both environmental and economic benefit. INTRODUCTIONAcid mine drainage (AMD) is a common problem in any country with significant past mining activity. When sulphide containing minerals, tailings or slag are exposed to water, oxygen and sulphur oxidizing bacteria, AMD will result. Abundant and reactive iron sulphide minerals leach first, providing acidity and the ferrous/ferric couple that can enhance the oxidation kinetics of other minerals. If this runoff contacts encounters acid consuming carbonates or silicates, the acidity may be neutralized, but certain heavy metals remain in solution and can continue to be an environmental hazard (Gray, 1997). For this reason, the remainder of this paper will refer to the broader term metalliferous mine drainage (MMD) rather than acid mine drainage. In either case, such drainage, containing high heavy metal concentrations and often significant acidity, is toxic to aquatic life and can lead to significant damage to ecosystems and to public watercourses. MMD is a problem most commonly associated with now defunct sulphide mineral mines, but similarly toxic streams can result from many types of waste, such as poorly stabilized leach tailings, slag heaps, and coal flotation tailings (Johnson and Hallberg, 2005; Lee et al., 2002; Sainz et al., 2002; Schüring et al., 1997). In any case, the management and remediation of MMD is an important ongoing problem for the resource industry, particularly for the many mines in Canada closed before the advent of more stringent environmental standards. MMD remediation represents a significant long term expense for the resource industry. Multi-disciplinary efforts to understand and mitigate this problem range from creation of artificial wetlands (Poulin and Lawrence, 1996; Sheoran and Sheoran, 2006) to sophisticated biochemical reactors and precipitation processes (Hatami, 2010). Certain remediation technologies such as ion exchange offer methods to make a saleable product by recovering valuable dissolved metals. This paper will show how these technologies can help defray the cost of remediation, and offer potential to turn a dangerous waste stream into a useful product."

Jan 1, 2012

By P. Dent

"Rare earth permanent magnets (REPM) have become virtually indispensible in hundreds of applications including aerospace, automotive, electronics, energy, medical and military. An understanding of REPMs is important since they are key drivers of demand for the overall rare earth sector. Rare earth permanent magnets stand out due to their superior magnetic properties of high induction and coercive force. We will discuss the past, current and future of the permanent magnet market and supply chain. We will summarize present and potential new nanocomposite and lower content or non rare earth magnet technologies and customer options which may mitigate rare earth usage.INTRODUCTIONRare earth permanent magnets are ubiquitous and often unseen critical components in many civilian, green energy and military technologies. They have become imbedded in applications such as hybrid electric vehicles, computer hard drives, direct-drive high power wind generators, audio speakers, motors, energy conversion systems, most weapons systems and hundreds of other uses. Several rare earth elements including neodymium, samarium, dysprosium, praseodymium, terbium and gadolinium are essential ingredients in production of the highest performance magnets available in the world today. They have enabled vast miniaturization and the significant increase in power density in hundreds of applications.China has become the dominant source of rare earth elements over the last two decades. Today, nearly 100 percent of the world’s rare earth metals and more than 95 percent of the rare earth oxides come from China. China’s near worldwide monopoly on the production of downstream materials such as rare earth oxides, metals and magnets severely impacts the supply chain in this growing global market. The past decade has seen an unmistakable trend toward increased dominance in raw material production and manufacturing by China, and a steep decline in U.S. production capabilities, most notably in the neodymium iron boron (Nd-Fe-B) market where there is currently no domestic production. This Chinese dominance is further demonstrated with over 65 percent of hard ferrite and roughly half of aluminum nickel cobalt (Alnico) and samarium cobalt (Sm-Co) production in that nation (Figure 1). In addition, China has imposed export quotas and export taxes of up to 25 percent for rare earth elements, arguably in violation of their covenants made with their protocol of accession to the Word Trade Organization. These export quotas have been decreasing steadily over the last several years in spite of rising global demand and were slashed by 72 percent in July 2010 (Bradsher, 2010) causing many recent news stories."

Jan 1, 2012

By J. J. Taute, O. S. Tinkler, G. Zárate, K. C. Sole, J. Steeples

Global practice in copper solvent extraction is reviewed, based on individual plant operating data for 2018. The survey respondents account for almost 40% of global copper cathode production by solvent extraction and electrowinning. Regional trends in operating conditions, as related to the prevailing ore mineralogy, leaching processes, and life of mine are evaluated. The adoption and expansion of this technology in the African Copperbelt and Asia are assessed, together with the associated challenges of specific orebody characteristics. Trends in feed and electrolyte compositions and flow rates, and extractant and diluent selection, together with their impact on copper recovery are reviewed. The evolution of equipment design and associated ancillary processes are discussed, and new projects identified. INTRODUCTION Continuing from similar surveys carried out in 1997, 1999, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Robinson, Sandoval, & Cook, 2003; Robinson, Moats, Davenport, Karcas, Demetrio, & Domic, 2007; Sole, Zarate, Steeples, Tinkler, & Robinson, 2013), global operating practice in copper solvent extraction (SX) in 2018 is reviewed. Contributing operations include established sites in the USA (8), Chile (9), Peru (2), Spain (1), Mexico (2), and Australia (2), as well as newer operations in Africa (7) and Asia (3). This survey represents 2018 copper cathode production of 1.91 Mt, or about 43% of world production by solvent extraction combined with electrowinning (SX–EW). Trends in operating conditions and performance, as well as equipment design and process technology choices are analysed. The significant expansion in production in the African Copper Belt is also discussed. There are currently about 130 operations worldwide producing some 4.6 Mt copper by SX–EW; of these, about half produced more than 10 000 t/a. Figure 1 shows global copper production by country. As it has for several decades, Chile remains dominant, with 36% of global production of cathode copper. Since 2005, the Democratic Republic of Congo (DRC) has increased production year on year, and now represents 23% of the global total (International Copper Study Group, 2017; Statistica, 2018). Copper production in Asia has grown significantly in the past decade, particularly since the ramp-up of Wanbao in Myanmar. There used to be numerous small copper SX plants in China (Schlesinger, King, Sole, & Davenport, 2011), although most of these have now shut down and Chinese production is lower than it was five years ago. The most important trend, however, is the rise of Chinese-owned mining companies, particularly in Central Africa, but also around the world more generally.

Jan 1, 2019

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By S. Avalos, J. M. Ortiz, W. Kracht

Semi-autogenous grinding mills are intensive energy consumers. Current models base their energy consumption inference on operational variables and feeding ore characterization. While they provide adequate design guidelines, they are not suitable for real-time energy forecasting dealing with gaps in operational dataset and up/downstream process bottlenecks. This work explores the capability of Gated Recurrent Units to learn the semi-autogenous grinding mill consumption behaviour. Gated Recurrent Units are trained to forecast different time-support consumptions under a time-series operational dataset. The results show high performance on small supports (30 minutes) to capture local variability and long-trends while larger time supports (8 hours) can only capture time-trends but not local variability. The proposed technique seems promising for further research and implementation on real mine cases since the input variables are low-cost and easy to obtain. INTRODUCTION Current changes in the Chilean energy matrix (Román-Collado, Ordoñez, & Mundaca, 2018), from fossil fuels to renewable energies, have impacted different industries and particularly the mining sector. Solar energy incorporation into greenfield/brownfield projects will help reducing costs and will lead to rethink foundational paradigms (production and processing strategies) (Pamparana et al., 2017). Also, integration of new space-time predicting tools together with automated real-time updating models are some of the main challenges in the geometallurgical framework (Ortiz et al., 2015; van den Boogaart & Tolosana-Delgado, 2018). Those contexts encourage and demand the development of tools capable of predicting the energy consumed by mining systems, being comminution the greatest energy consumer with an average close to 50% of the entire mine consumption (Cochilco, 2013). In comminution, the semi-autogenous grinding mill (SAG) represents the largest energy consumer (~10 nominal each SAG). Theoretical and empirical energy consumption models (Jnr & Morrell, 1995; Morrell, 2004; Silva & Casali, 2015) base their inferences mainly on feed/product size distributions, SAG sizing, bearing pressure, feed hardness, water addition and grinding charge level, and commonly assume steady-state and work isolated from up and downstream processes. While those techniques provide adequate design guidelines, they are not suitable to predict hourly, daily or even weekly energy consumptions on interconnected comminution circuits where upstream/downstream bottlenecks lead SAGs to operate below designed regimes. Forecasting energy consumption is required by short-term energy management, medium and long-term planning energy consumption, designing the nominal capacity of renewable energy sources, among other. Also, when models are input-sensitive and some of those input measurements are expensive and/or time consuming, model robustness suffers when real-time predictions are required.

Jan 1, 2019

By L. Vollert

In-situ recovery of metals is presently experiencing a revival not seen since early applications in amenable copper oxide deposits, uranium and generally applications where neither, porosity and permeability, nor process chemistry have been prohibitively difficult. With ever decreasing grades in current mining operations or Greenfields projects and ever increasing capital and operating costs, in-situ recovery is looked to as the processing option that will both unlock these deposits as well as potentially derive revenue from mineralised waste remaining in the ground once traditional mining and processing methods become uneconomical. In-situ recovery is also being looked to as a mining method that minimises the environmental impact sustained in the application of traditional energy and water intensive mining and processing operations where millions of tonnes of ore are mined from the earth, processed on surface and then disposed of in both waste dumps and tailings facilities. The key challenge facing companies like Newcrest is that these low-grade deposits or remnant mines are generally hard rock applications that require costly methods to liberate the valuable minerals. A further challenge includes identifying suitable chemistries that both facilitate the economic recovery of gold and copper and that may be considered environmentally acceptable. This paper presents a desktop study whereby the issues of access creation and chemical extraction are discussed and evaluated with a view to driving future research in the area and unlocking this application as a real processing option. INTRODUCTION Mining companies are increasingly challenged by low grade, deep and complex ore deposits which are no longer economically exploitable by current methods. The large footprint of current open pit operations can present obstacles for permitting and social acceptance. For these reasons in-situ recovery (ISR) technologies are receiving renewed attention as a technology which could be used to exploit these more complex deposits economically and with less environmental impact. The environmental impact may be further reduced if emphasis is placed on use of renewable energy sources rather than traditional grid power, gas turbine or diesel generators are employed to drive the operation. A potential renewable energy driven ISR mine of the future is shown in Figure 1.

Jan 1, 2019

By D. Berkley

"Economic and environmental constraints drive more and more industrial organizations in using energy management as one of the means for addressing these issues. The recent increase in energy price could even make energy management a matter of “survival” in some cases.Experience shows that energy management is successful when the energy is managed like a resource, i.e. continuously, systematically, and in an organized manner, not like an expense, paying the bills once a month. This requires the development and implementation of an energy management program (EMP).This paper outlines some of the barriers, keys to success, components, and approaches to a successful energy management program, plant- or corporation-wide."

Jan 1, 2005