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By C. Nikolic

A process utilizing ozone for the precipitation of cobalt from nickel sulphate liquors containing ammonium sulphate has been developed. Best results were obtained using nickel carbonate to maintain solution pH at 5.0 to 5.5. Work was performed both in column and stirred-tank reactors. Variables studied included neutralizer type and concentration, NH4+ concentration, temperature, Ni++ and Co++ concentration, per cent O3 in the O2 carrier gas, O3 input rate and agitation. The over-all rate of cobalt rejection increased sharply with increasing agitation and ozone concentration in the gas phase, reflecting relatively slow transfer of ozone from the gas to the liquid phase.

Jan 1, 1978

By A. Rodriguez-Prado, P. Kuschk, R. L. Legge, W. C. Lennox

Using constructed wetlands to chemically reduce hexavalent chromium Cr(VI) to Cr(III) from industrial and mining wastewater has proven to be feasible and efficient. Applying first-order kinetics to describe the process is simple, but in some cases a more accurate model is required to reflect the process. This paper studies the feasibility of using non–first-order kinetics to describe the reduction process. Results indicate that half- and second-order kinetics adequately described Cr(VI) reduction in laboratory wetland mesocosms. The organic carbon content played a relevant role, whether it was built up by plant growth or spiked into the feed water.

Jan 1, 2014

By P. G. Dunn, J. Fitzgerald

ABSTRACT The scheduling of underground mining activities is a complex task that must simultaneously satisfy a large number of constraints. A schedule optimization tool (SOT) for underground mine planning is described, and its use for investigating strategic decisions is illustrated through a case study. The maincomponents of the SOT include (a) a genetic algorithm that searches for optimal schedules, (b) guidance for the application of heuristic rules, and (c) sliding, which implements just-in-time development. Findings indicated that preliminary scheduling performed before invoking the SOT, intended to provide a good starting point for the search, did not ultimately lead to higher value schedules.

Jan 1, 2010

By Peter Silveston, Earl Shannon

Process-oriented experiments on the use of coal as an adsorbent for certain soluble components of sewage are described. The capacity of Canadian coals for these components was less than 0.1 per cent by weight for the highest concentration at which these components could be expected to be found in domestic sewage. This is much less than values reported in the past. A pronounced selectivity between components was observed. Experiments on bacteria removal in beds of coal, regeneration of spent coal to restore adsorption capacity and COD contributions of coal are reported in the paper. The simple application of coal as an adsorbent does not seem promising.

Jan 1, 1970

By G. M. Ritcey, B. H. Lucas

In the conventional alkaline leaching of concentrate containing nickel, copper and cobalt, copper is usually removed from the system, prior to nickel reduction, by sulphide precipitation. A new process is described for the selective extraction of copper and separation from cobalt and nickel, using liquid-liquid extraction. General Mills LIX-63 dissolved in a kerosene diluent is the extractant. Trace amounts of co-extracted cobalt and nickel are easily removed by a scrub treatment, and copper is recovered from the extract by sulphuric acid stripping, thus providing a solution amenable to the oroduction of electrolytic copper. Estimated processing costs are included together with a proposed flowsheet.

Jan 1, 1972

By R. L. Every, A. G. Fonseca

"Sulphur deposition on the internal wall of a pipeline is caused by the temperature effect on the solubility of sulphur in the carrier fluid and is not due to particulate sulphur present. Deposition can be completely eliminated by proper insulation of the pipeline to prevent ""cold-spots"" and the resultant temperature gradient necessary for sulphur to precipitate from solution. Friction head losses for sulphur-condensate slurry systems are quite acceptable from a technical and economic standpoint and, in fact, are less than many present commercial slurry systems. Slurry transportation of sulphur in a hydrocarbon pipeline is a viable possibility and promises to have economic advantage over currently accepted transportation modes."

Jan 1, 1972

By Zhang. L.

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of formic acid on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. XRD and XPS technologies had been used to investigate the crystal structure and electron effect. We think formic acid decomposition on PtSb favors the reactive intermediate route and is not very much affected by the CO intermediate as compared to Pt.

Jan 1, 2005

By M. M. C. Lima, L. C. S. Solimani, M. A. Quintela

Galvanized steel scrap is recycled to B OF converters where zinc escapes from the bath and is captured by the gas control system, appearing in BOF sludge. As BOF sludge contain high iron content, it could be recycled, but due to its zinc content, it is disposed in landfills. In this study techniques were evaluated for zinc layer removal from scrap by sulfuric acid leaching. The effects of coating weight, temperature, time and sulfuric acid concentration were evaluated for three different galvanized scrap. The results showed that the behavior of each galvanized scrap was different. Nevertheless zinc removal efficiency was more than 80% with low dissolved iron in the leached solution.

Jan 1, 2011

By N. Shi, T. G. Joseph

ABSTRACT One-twentieth-scale field trials for conventional and concept dipper designs were compared to mid- and ultra-class-sized conventional dipper performance. Digging effort was used as the performance indicator for comparison. It was shown that linear relationships exist between dipper capacity, suspended hoist load, and peak hoist load. A ratio of conventional and concept dipper performance at the 1/20th scale was then evaluated to allow prediction of the performance of an ultra-class concept design using an independent ultra-class conventional dipper dataset. The outcome indicated a peak hoist requirement of 15.5% less to achieve the same production as the conventional design.

Jan 1, 2011

By Roger Francis

There is increasing use of acid leach extraction methods at elevated temperatures and pressures by the mining industry. In many locations there are limited supplies of fresh water, and waters with higher chloride contents must be used, making conditions more corrosive. The fluids downstream of the main autoclave are hot, acidic, oxidizing and contain chlorides and present a challenge to the mining community to ensure reliable operation. Zeron 100 is a high strength superduplex stainless stee, that offers high corrosion resistance at a cost effective price. The paper presents a combination of laboratory data and service experience, particularly in the aggressive fluids found in downstream processing.

Jan 1, 2010

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By M. Sokoto, H. Hata, K. Nishina, K. Haiki

Fluoride ions in zinc electrolyte cause corrosion to aluminum cathode plates at zinc electrowinning process, so we have developed an iron compound as a fluoride ion adsorbent used in zinc sulfate solution. The iron compound is synthesized from FeC13 solution with a small amount of sulfate ion by neutralizing reaction with Na2CO3 solution. The fluoride ions adsorbed on the surface of the iron compound are desorbed in alkaline solution and the iron compound can be reuse as a fluoride ion adsorbent. Moreover, if adsorption capacity of the iron compound decreases, it can be dissolved in HCl solution and re-synthesized.

Jan 1, 2008

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

By Therese Schneck

The presence of xenon isotopes from in-situ spontaneous fission of short-lived Pu244 has been confirmed in Hadean detrital zircons from Western Australia. Hadean and meteoritic zircons can retain secondary overgrowths developed after primary cristalization at 3.97-3.94 Gyr. On the moon, the metal grain in sample 66095,78 is mantled by troilite, schreibersite and cohenite. High chlorine content FeCl2 is deposited around metallic FeNi. The magnitude of Pollonium-210 to Radon-222 on the Aristarchus plateau spectrum indicates a past greater activity. The Earth Moon system from Nb/Ta systematics is consistent with a Moon iron core delayed to 3,9 Gyr.

Aug 1, 2010

By B. Karnath, K. Guha, S. Tandon

At Jhagadia Copper Ltd (India), Copper is produced through secondary route using Top Blown Rotary Converter (Kaldo Furnace). The basic raw material being treated includes Matte-slag Reverts, Copper Cakes, dross & Cement, Oxide Ore, Low S bearing Concentrates & various metallics along with high grade copper scraps. The plant has capability to refine & produce Blister grade copper from Kaldo furnace as well as PS Converter . Blister is fire refined in Anode furnace & electro refined in Refinery to produce cathode copper. Our product , Copper Cathode , has already been established in the market as its quality is better than 'LME Gr'. The paper deals with the experiences encountered during commissioning & stabilization of the plant.

Jan 1, 2007

The Rabbit Lake In-Pit Tailings Management Facility contains frozen layers of tailings due to subaerial deposition during the coldest periods of winter. Thawing is required to ensure full consolidation of the tailings and to regain disposal space presently occupied by ice. Electric resistance heating has been used to heat soil for bitumen extraction and remediation of volatile contaminants. A preliminary evaluation of the application of electric resistance heating to thaw about 0.3 cubic metres of frozen tailings was conducted using tailings frozen at about -2 oC. Visible thawing of the tailings mass was observed after 25 hours, demonstrating the feasibility of this approach.

Aug 1, 2010

By M. H. Leite, R. Corthésy, D. E. Gill

"La connaissance des contraintes naturelles qui prévalent dans les massifs rocheux est un prérequis indispensable pour la conception sécuritaire et économique des excavations comme on en retrouve dans les exploitations minières souterraines. Certains chercheurs se sont attardés à colliger les résultats de mesures de ces contraintes et les ont utilisés pour produire des modèles de prédiction basés sur leur traitement statistique. Ces modèles de prédiction sont très populaires auprès des exploitants miniers puisqu’ils permettent, du moins dans les étapes préliminaires de design, d’obtenir de façon s’apéconomique mais approximative, une partie des paramètres dont ils ont besoin. Dans le cadre d’un projet initié en 1994 avec la collaboration de l’IRSST, il a été décidé de produire un modèle de prédiction englobant une partie de la zone périphérique de la faille de Cadillac, soit une zone plus restreinte que le Bouclier Canadien utilisé jusqu’ici comme région pour l’élaboration de tels modèles. Pour produire ce modèle de nouvelles données obtenues avec une technique permettant d’exercer un excellent contrôle de qualité ont été ajoutées à celles déjà disponibles. Une telle régionalisation des données de base permet d’obtenir un modèle où les intensités et les orientations des contraintes principales sont beaucoup moins dispersées que ce que rapportent les modèles publiés jusqu’à ce jour. Enfin, il est démontré que le modèle proposé pour la région étudiée est en toute probabilité plus sécuritaire que les modèles plus généraux publiés à ce jour. Knowledge of the in situ state of stress existing in a rock mass is essential to the safe and economical design of underground mining excavations. Prediction models have been published, based on the statistical treatment of stress measurement results. Such prediction models are very popular among mine operators because they allow them, at least at a preliminary design stage, to economically obtain part of the information needed, even if this information is approximative. In 1994, a research project financed by IRSST was initiated aiming to produce a prediction model that would comprise a peripheral zone around the Cadillac fault. This region is more confined than the Canadian Shield on which the existing prediction models have been based up to now. In order to produce such a model, existing stress measurement results have been used in conjunction with new stress measurements that have been performed based on a technique which allows full control of the quality of the measurements. Restricting the data upon which the model is based to a more specific region gives a model in which the intensities and the orientations of principal stresses are far less scattered than the results published to date. Finally, it is shown that the proposed model is probably safer for the studied region than the models previously published."

Jan 1, 1998

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019

By S. Kelebek, E. Yalcin

"Two composite samples of a gold-bearing ore from North Western Quebec (Barry Township) were tested to assess their grindability, recovery by flotation and Knelson concentrator as well as extraction using cyanidation.Work index values (BWi) for two composites were found to be 10.4 and 11.0 kWh/tonne, respectively. Flotation tests involved feed samples for which the particle size ranged from a P80 value of 205 ?m to 53 ?m, which resulted in gold recoveries of 91.8% to 95.8% (at gold grades of 130 to 140 g/tonne). Cyanidation tests indicated gold extraction levels ranging from 94.2 to 97.5%. Higher, recoveries were obtained at finer grind sizes and higher cyanide strengths. However, the grind size had a bigger impact on gold leaching. Gold grade and recoveries obtained with the Knelson concentrator device were lower than those obtained by flotation. Mass recoveries to concentrate products strongly depended on the fluidization pressure used. High gold recoveries can be obtained generally at low water pressures of 3 to 4 psi. Higher water pressures produced more selectivity at the expense of higher gold losses.It can be concluded that the gold ore samples tested have good characteristics due to moderate levels of energy requirement, high gold recoveries and extraction rates attainable.INTRODUCTIONBench scale testing of ore samples is an important step in the long series of metallurgical and economic studies involved in bringing new ore bodies into production (Coleman, 1980). Through a laboratory testing program, the behaviour of an ore in a particular process on a larger scale can be established. In an exploratory manner, this testing can be helpful for classification of ores in terms of “good ore” or “problematic ore” by providing preliminary information on recoverability of target minerals. Potential problems if any can be assessed by further investigation of products (e.g., middlings) obtained as a result of testing. A detailed bench scale experimental program in the metallurgical laboratory can also provide the background work for flowsheet development. Depending on the simplicity or complexity of the ore to be tested and type of details required from a testing program, the amount of samples required in the mineral processing laboratory can vary from several kg to more than one hundred kg depending on how detailed the metallurgical testing program is."

Jan 1, 2008