Search Documents

By T. Kerr, C. Mattich, J. Wilson

"In refractory gold concentrates, gold is occluded in sulphide minerals preventing efficient cyanide leaching. Hence, roasting is used to oxidize sulphur and organic carbon, the latter being necessary to minimize recovery loss through the preg-robbing effect. In 2009, Outotec commissioned the circulating fluidized bed roaster at Syama gold mine in Mali. Since 2013 Resolute and Outotec have been implementing improvements to the roaster performance with the capacity increasing from 8000 t/month in 2013 to above 13,000 t/month in 2016, while achieving a residual sulphide sulphur and organic carbon contents of below 0.1 wt.% and 0.4 wt.%, respectively. Thus a gold recovery in the CIL of above 90% is attained. In 2016, Outotec audited the Syama roaster. The analysis resulted in the Low Carbon Roaster (LCR) upgrade concept which (i) allows re-processing of calcine dust from the spray cooler and ESP after pelletization and (ii) allows the roasting of a further fine-organic carbon rich feed, i.e. de-slime circuit tailings. The LCR upgrade aims to reduce organic carbon to <0.2 wt.% and increase roaster-leaching gold recovery by >3%. Project development included extensive testwork. The LCR process is expected to become operational during FY 2019.INTRODUCTION Double refractory sulphide ores exhibit the characteristics of gold locked within pyrite grains, in the presence of preg-robbing natural (organic) carbon. Hence, to achieve high recovery during subsequent processing steps, i.e. cyanide leaching, oxidation of sulphide sulphur is required, producing a porous calcine by way of a roasting step. This allows for the gold contained within the pyrite grains to be accessible during cyanide leaching. Furthermore, it is necessary to oxidize the organic carbon. Oxidizing the organic carbon is essential as gold recovery loss occurs as a result of gold-cyanide complexes being adsorbed on organic carbon, this phenomenon is termed as preg-robbing (Miller et al., 2016). The gold absorbed on the organic carbon is lost, reporting to the tailings stream. Hence, the aforementioned oxidation of sulphide sulphur and organic carbon is the process goal. Nonetheless, the latter must occur at a controlled temperature which is concentrate/ ore specific, since the pores of the produced calcine should not sinter, as this makes the gold contained in the calcine less accessible during leaching, leading to gold recovery loss. The tight temperature control requirement is a decisive factor in the choice of a Circulating Fluidized Bed (CFB) as the roasting reactor, due to the excellent mixing characteristics of the CFB which results in temperature homogeneity of (+/-10°C). Roasting of double refractory ores, as described above, can be included in the flowsheet after comminution and grinding, a process termed as whole ore roasting, or by including a flotation circuit termed as concentrate roasting. Roasting the flotation concentrate results in less solid flow, increased sulphide sulphur grade and organic carbon content resulting in a higher heating value and higher gold content. A typical composition of the Syama ore and concentrate is given in Table 1. Ore average values presented correspond to the period 2015, while concentrate values are typical for the flotation performance throughout the period 2012–2015."

Jan 1, 2017

By M. G. Manzone

Approximately two-thirds of the annual 210,000 tons at copper refined by AMAX Inc. at the United States Metals Refining Company in Carteret, New Jersey, comes from a wide variety of copper scrap ranging from low-grade smelter scrap to wirebar-grade material. The equipment and methods used to effect such large-scale metal recycling in an urban area and the measures taken to collect and recover metal values from smelter and refinery byproducts while protecting the environment from pollution are described and discussed.

Jan 1, 1977

By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By M. Pearson, L. Zunti

Pressure vessels in hydrometallurgy and many chemical process industries throughout the world require the use of specific lining systems to protect the parent vessel materials from corrosion and/or abrasion. Typically, these lining systems are required for processes that are corrosive and operate at elevated temperatures. Two basic lining system types arc: 1) refractory linings in conjunction with an impervious corrosion resistant membrane, and 2) metal-clad vessels consisting of titanium or other corrosion resistant metal bonded to a carbon steel shell. Operating conditions play a key role in selecting the type of lining system to be utilized for a specific application. Lining systems in turn have an impact on the process vessel size, which ultimately affects the capital cost of the vessel. The capital costs for each type of lining system must be considered for each application, as well as maintenance concerns, quality control, and delivery. It is clear that operating conditions play a key role in the final selection of lining systems utilized for specific projects based on initial capital cost, life-cycle maintenance costs, and overall service life. This paper will examine the fundamentals of each lining system, their inherent technical strengths and weaknesses, and present relative cost comparisons for each lining system as they apply to specific operating conditions and vessel sizes.

Jan 1, 2004

By James R. Hunter, Sandra K. Zacharias, Ursula M. Franklin

Archaeometallurgical remains can be a valuable source of information about past technological activities and, by inference, the societies that undertook them. Material traces of former metal-producing or metal-working centres can include raw materials, products, or metallurgical installations such as mines, furnaces or forges. Of these remains, the most common is slag, often left undisturbed since its original production. Physical and chemical analyses of archaeological slag and metal can often reveal the processes and materials involved in their formation. Mineral composition and softening temperature of a slag, for instance, can indicate the conditions of the metallurgical operation, such as temperature and atmosphere and, thus, help identify metallurgical processes which took place at a site(1). The present report illustrates the value of such analysis. Metal-working remains from Sainte-Marie among the Hurons, near Midland, Ontario, on the south side of Georgian Bay have been analyzed in order to determine the techniques and processes used by the 17th-century blacksmith who worked at the mission headquarters from 1642 to 1649. Samples were selected from a very large collection of blacksmith refuse which was excavated from the site by archaeologist Kenneth Kidd in 1941-42(2).

Jan 1, 1999

By Ben C. McLellan, Philip J. Bangerter, Andrew Murphy, Glen D. Corder, Damien Giurco

Sustainability now forms a critical part of metallurgical plant design. In addition to compliance with requirements and corporate principles, design engineers must also consider how community and societal responses to the metallurgical industry affect the way they design and build plants. Three broad areas to consider are: the design engineer’s contribution to sustainability through the design process and the relationship to the social license to operate (SLO)—the unwritten license communities give companies to safely and responsibly operate the plant and equitably share benefits; the realization of sustainability goals through methodologies emerging in the design activities; and the integration of design frameworks into a contemporary project design context and its investment objectives. This chapter explores sustainability in metallurgical plant design in the context of SLO, design tools and frameworks, and community and societal influences.

Jan 1, 2015

By B. Haneman, J. A. Gorst, W. Slabbert

"The Bayer process involves the digestion of bauxite in caustic liquors at high temperature and pressure. Typically the digestion section of the plant involves the heating of liquors up to the digestion temperature followed by flashing of the digestion product to atmospheric pressure with the flashed steam used to pre-heat the incoming cold slurry. Despite the heat recovery, the digestion process is a high consumer of energy. The application of tube digestion technology in such plants has resulted in significant improvements in refinery energy efficiency with associated benefits of process simplification and refinery flow sheet capital cost reduction. This paper reviews the potential application of this technology to other metals within the non-ferrous industry.THE BAYER PROCESSA typical Bayer flow sheet is shown in Figure 1. The raw feed material bauxite (containing aluminium hydroxide as gibbsite Al(OH)3 and boehmite AlO(OH)) is digested in caustic liquors (caustic soda is the solvent) at high temperature and pressure. This process extracts the alumina and silica and any carbon present on the ore. The slurry is then flashed down to atmospheric condition allowing for heat recovery from the flashed vapour and producing slurry supersaturated in alumina.Following the digestion process the mud is removed via thickening and then pressure filtration to remove fine particulate and produce a clarified liquor with dissolved alumina in solution. The resulting pregnant liquor is then cooled allowing the alumina in solution to precipitate as aluminium trihydrate Al(OH)3. The precipitated hydrate is then filtered and washed and classified into fine and coarse fractions. The fine material is returned to the precipitation process as seed while the coarse fraction is calcined at high temperature to produce alumina. The filtrate from the filtration process (spent liquor) is then heated by the incoming pregnant liquor before being fed to an evaporation process which produced the strong caustic liquor required in the digestion process. Finally, the mud from the thickening process is washed to recover caustic and then fed to tailings ponds. The washer overflow is then mixed with the digester product to increase super-saturation."

Jan 1, 2012

By C. I. Walker

Field tests at a number of large mineral processing operations have been undertaken to better understand the wear life impact of different aspects of pump design, materials of construction and maintenance procedures. Data are presented for wear rates, and typical result variability is explored. To improve the availability of pumping equipment in a milling circuit it is not only important to improve the wear life, but also reduce the variability in the wear life of components so that the incidence of premature failure is lessened. Localised gouging wear due to flow separation and turbulent eddy formation is often the point at which part-holing occurs. A number of improvements to the design of pump impeller and throatbush (suction side liners) to reduce the localised gouging wear are outlined. Also, results are presented on the use of composite materials (mix of metal, rubber and ceramic) for throatbush materials to protect specific areas against wear.

Jan 1, 2012

By Richard W. Hutchinson, Robert W. Hodder

"Pyritic massive sulphide deposits lie conformably above submarine volcanic rocks, and beneath siliceous and manganiferous iron formations. The massive bodies are often zoned, with a barren pyritic top grading downward into pyrite with sphalerite, and occasionally galena, and a chalcopyrite-rich base. They are frequently brecciated, like the lavas beneath them, which contain pyrite and chalcopyrite as coatings on joints and fractures and as dispersed grains. The lavas also exhibit propylitic, argillic and silicic alteration. These sulphide deposits appear to have formed on sea bottom from fluids escaping through the lavas during periods of exhalative and sometimes explosive volcanism. The process may be comparable to the present deposition of base metals from hot brines in the Red Sea. Some porphyry copper deposits resemble the altered, sulphide-impregnated lavas which lie beneath bodies of pyritic massive sulphide. In porphyry copper deposits, pyrite and chalcopyrite occur as veinlets and dispersed grains in intensely fractured tuffs, flows, sub-volcanic intrusions or other host rocks, characterized by propylitic, argillic and silicic alteration. Metal zoning is present; sphalerite and galena often occur in manganiferous veins peripheral to a shell of pyritic veinlets which encloses the mineable zone of chalcopyrite-bearing veinlets. This sulphide distribution appears to have formed from hydrothermal fluids escaping, either passively or violently, from solidifying magma. The fluids may be comparable to hot brines encountered by drilling in the Salton Sea area of California.There are also important differences between massive sulphide and porphyry copper deposits. The former usually occur in differentiated, mafic-to-felsic subaqueous volcanic rocks, whereas porphyry copper deposits are often associated with shallow plutons and subaerial volcanic rocks of intermediate to felsic composition. Calcic-sodic metasomatism accompanies the massive sulphides, whereas potassic metasomatism characterizes the porphyry cop.per deposits. Further, ages of massive sulphides range from Archean (Keewatin) to Tertiary, but porphyry coppers are Triassic to Tertiary in age. These similarities and differences suggest that massive sulphide and porphyry copper deposits are related tectonically and metallogenetically. The former were generated during early stages of crustal evolution, particularly in Archean time, and were repeatedly derived during early stages of younger, individual tectonic cycles. In contrast, the porphyry coppers developed during the later stages of crustal evolution - later in terms of both absolute age and relative age within younger individual tectonic cycles. They appear in younger rocks generally, and specifically in rocks involved in events of the middle and late tectonic stages of orogenic belts. The massive sulphide deposits are of early-magmatic eugeosynclinal affiliation, whereas the porphyry deposits formed in late-magmatic, predominantly subvolcanic settings at the edge of continental plates, where contemporaneous exhalative volcanism was mainly a subaerial phenomenon. Transitional types of deposits exist and are found on continental margins with flanking eugeosynclinal sequences."

Jan 1, 1972

By C. G. Williams

IN preparing this paper on Canadian mine taxation, there has been no attempt to detail the requirements of the various taxing bodies; but rather to consider the matter from the standpoint of its underlying principles and give a general idea of the methods adopted. I have added an Appendix setting forth the principal features of the various Acts, which should be used for general reference only, since new rulings alter minor details from time to time. In current legislation, many important points are left to the discretion of the Ministers and their deputies. We are, indeed, fortunate in having in Canada an able and conscientious body of permanent officials, who bring a sense of justice and courtesy to their work which is most commendable, and which has done much to simplify the working out of general problems. The production of metals may rightly be deemed a form of manufacture, but differs from the average manufacturing business in three important respects: (1) In its early stages, it is wholly speculative, since it is impossible to make any definite appraisal of value or possibilities. (2) The principal asset of any mine, i.e., the ore in the ground, is a wasting asset, and is irreplaceable. (3) Any additional burden by way of taxation cannot be passed on to the public but must be borne entirely by the producer. Having regard to the first of these differences, it is apparent that, since the risk of loss is great, the reward in case of success must be correspondingly great. This fact seems to be constantly overlooked by those who regard the all too few outstanding successes in Canadian mining history as fit prey for predatory legislation. As an illustration of the speculative nature of early mining development, let us consider the Province of Ontario-and I take this illustration simply because I am more familiar with conditions there, and not because I believe it differs greatly from any other province. From 1907 to 1933, 165,243 claims were staked and recorded, from which 43 mines were developed which paid one or more dividends. There was, of course, some duplication through re-staking; also, on some claims very little work was done, and most mines have more than one claim. But, since staking and recording cost real money and effort, each of these claims must have been considered to have had merit.

Jan 1, 1935

By Y. Zedan

In this study, the statistical design of experiments (DOE) was applied to study and regulate the properties of near-eutectic Al-11%Si alloys. Develop regression equations for such response variables as hardness, yield stress, ultimate tensile stress, percent elongation, total cutting force, cutting power, and tool life together with other factors which, include the percentage composition of the alloying elements, and the requisite modification (Sr) level. These equations may be analyzed quantitatively to acquire an understating of the effects which the main variables and their interactions may have on the mechanical behaviour and the machinability of the alloy under investigation. The results reveal that increasing the levels of Cu and Fe content results in an increase in hardness, yield stress, and ultimate tensile strength in both modified and non-modified alloys. On the other hand, both Cu and Fe appear to affect the percentage elongation adversely, whereas the Sr-level has a positive effect on this parameter. It was found that Sr-levels have the most significant effect on the cutting forces and cutting power followed by the content in Fe and Cu. The results also reveal that the interaction coefficients of these variables have a significant effect on tool life compared to the main independent variables. This fact may be attributed to the formation of complex insoluble phases between Cu, Fe, Si, and Al as investigated using Scanning Electron Microscopy (SEM) attached to an EDX analysis system. The accuracy of the regression equations in predicting the expected properties has been verified by carrying out random experiments in the range of variation of these variables.

Jan 1, 2011

By Staff, G. M. Hogg

"The eastern portion of the Late Precambrian geosynclinal structure known as the Labrador Trough comprises a 16,000-square-mile sulphide-bearing belt of good potential as a base metal exploration area. Hollinger and Hanna mining interests have carried on exploration in the region since 1953, with encouraging results. This program has been considerable in terms of both effort and expenditure, and has resulted in an apparently successful primary evaluation of the entire belt.Much detailed work remains to be done in the area. Exploration to date has been largely of a reconnaissance nature, employing various methods in common use in Canada today. In the course of this work, several deposits of promise, containing near-economic quantities of copper, zinc, nickel and other metals, have been located. A broad classification of these deposits is proposed.Exploration in the sulphide belt was started on the basis of partial control of the area under mineral exploration concessions. This was necessary to justify operations in an area of difficult access and high operating costs. The results of this now-terminated arrangement are regarded as being of benefit to those directly concerned as well as to the mineral industry in general."

Jan 1, 1966

By M. C. Makepeace

"It is the objective of designed experiments to obtain more information for less material and process cost than can be obtained by traditional experimentation. In this paper, the fundamental concepts on which the statistical design of experiments is based are briefly re-viewed according to the following outline: The Experiment The Design The Analysis Two simple 2"" factorial experiments are presented as examples."

Jan 1, 1967

By D. M. Rippley

THE St. Lawrence Seaway Project ranks with the greatest engineering undertakings of all time. A summary of major materials going into the construction of this project, shown in Table I, will assist in an appreciation -of this fact. These data relate to Seaway construction only, and it should be remembered that two large-scale power projects are in the construction stage on the St. Lawrence river concurrently with construction of the Seaway. A project of such magnitude as the Seaway would attract widespread interest even if it were being constructed in a remote area. The fact that it is located in a heavily populated and developed section of both Canada and the United States has done much to enhance this interest, and in many ways complicates the problems confronting the engineer in the design and construction phases. Many consider the St. Lawrence Seaway to be a new idea that has developed within the past decade - such is far from the fact, because the St. Lawrence River canal systems have existed for more than a century, and the Seaway Project is but a new, larger, and more efficient version of a continually expanding facility.

Jan 1, 1957

By Ron Light, Doug Applett

"HistoryThe Nanisivik mine began operation in October 1976 as the world's most northerly metal mine and the first permanent industrial project in the Canadian High Arctic. Located 700 km north of the Arctic Circle on Baffin Island's Strathcona Sound, exploration by Texasgulf Inc. between 1957 and 1970 had outlined the ore deposit. In 1974, Nanisivik Mines Ltd. was formed with Mineral Resources International, the Government of Canada, Metallgesellschaft and Billiton being shareholders, and Strathcona Mineral Services Ltd. providing project management. In 1996, Breakwater Resources purchased the mine from Alberta Energy Corporation Limited which had recently acquired the assets of then owners Conwest Exploration Ltd.Ore DepositThe main ore deposit is very flat, approximately 80 m in width and varying in thickness from 3 m to 16 m. The length of the deposit is approximately 3000 m with satellite zones located on the perimeter of the main zone. The economic mineralization is sphalerite with minor galena and silver. The sphalerite and galena are coarse grained and associated with pyrite as the main gangue component with minor inclusions pf dolomite and calcite within the deposit. The deposit being hosted in a permafi·ost environment creates a number of challenges. Dry drilling is employed in room and pillar production drilling. The permafrost aids in the stability of both the pillars and the back."

Jan 1, 2000

By N. Sarmady, Mei Li, N. C. Parson, W. J. Poole

"The mechanical behaviour of AA6082 is a function of the extrusion conditions and in particular, the quench rate after extrusion. It is well known that precipitation of Mg-Si phases on grain boundaries during quenching can negatively affect the ductility of the alloy. In this study, AA6082 alloys containing 0.5 wt. % Mn and 0.15 wt. % Cr were direct chill (DC) cast, homogenized and then extruded to produce 3 mm x 42 mm strips. The microstructure in the as-extruded strips was unrecrystallized due to the Zener-Smith drag from the Mn/Cr dispersoids. It was shown that a solution treatment of 5 minutes at 560°C did not significantly affecting the as-extruded microstructure but if the as-extruded strip was cold rolled prior to heating, recrystallization occurred concurrently with the solution treatment. As such, 3 initial microstructures were produced, i.e. unrecrystallized and recrystallized with a grain size of 9 and 40 µm. After the solution treatment, controlled cooling experiments were conducted using the Gleeble 3500 thermomechanical simulator with cooling rates of 10, 25, 80°C/s as well as water quenched. The mechanical properties (e.g. yield stress, fracture stress and fracture strain) were determined from tensile tests for the different combinations of initial microstructure and cooling rate. The relationship between the quench rate and precipitation of Mg-Si phases on grain boundaries was examined by FEG-SEM. It was found that the yield stress decreased as the cooling rate decreased and that there was complex relationship between the fracture properties and the microstructure.INTRODUCTION As the automotive industry strives to reduce fuel consumption and CO2 emissions with the goal of reducing the environmental impact, there is a need for lighter vehicles. As a result, aluminum alloys are gaining popularity to replace steel parts as structural components. An exemplar of this is the Ford F-150 pickup truck which has an aluminum body and is ˜750 pounds lighter than the previous steel version of the vehicle. The structure includes a mix of aluminum sheet, extrusions and cast alloys. The current research is concerned with the performance of aluminum extrusions in applications such as side rails, crash tubes and other structural parts. These components experience a combination of bending, stretching and folding both during the forming of the part and in service, e.g. crash of a vehicle. There is a need to have detailed information on the influence of processing on final material performance, in particular the cooling rate after extrusion."

Jan 1, 2018

By N. Romani, R. Provost

"Commissioning of a circulating dry scrubber plant was recently completed at an existing facility, in order to treat the sulphur dioxide off-gas emitted from rotary kilns. Proper planning of the different commissioning stages and staffing an integrated team are the most important factors required for a successful plant start-up. A strong operational readiness plan must be in place as early as the start of construction in order to ensure a smooth transition from commissioning to operations. Plant performance can meet or exceed performance criteria within the required timeframe if the proper group dynamic and good communication is established between construction, commissioning and operations teams.INTRODUCTIONCommissioning of a circulating dry scrubber (CDS) plant was recently completed at an existing facility in Quebec, Canada. The CDS plant treats the sulphur dioxide off-gas emitted from rotary kilns in order to meet increasingly stringent environmental requirements. This installation enables the existing facility to reduce their sulphur emissions by over 90%.The CDS ProcessA general overview of the CDS process is presented in Figure 1 below. The combined, de-dusted off-gas from multiple kilns is sent to the CDS, which acts as an entrained fluid bed, where the gas is contacted with a water mist, re-circulated solids and hydrated lime. The SO2 from the gas stream and the available calcium hydroxide (Ca(OH)2) from the hydrated lime dissolve in the water and react to ultimately form calcium sulphites and gypsum. The solid residue (referred to as CDS residue), is the primary byproductof the process.Fresh hydrated lime and CDS residue is captured by the dust collection system and is re-circulated to the CDS via a fluidised transport system. Clean off-gas passes through the dust-collection system and is then sent to the atmosphere by a single exhaust fan.The CDS residue purged from the system is combined with the dust collected from the kiln offgas system and this mixture is wetted in the already exiting agglomeration system, to minimize dust generation during handling, and then sent to disposal."

Jan 1, 2016

By A. G. Pathan

Rock and soil mechanics investigations were carried out in block VIII at Thar Coalfield, Pakistan. Most of the strata were mainly composed of sand, with an average content of 67.68 %. Laboratory studies of rock and soil samples from drill hole GT-01 revealed that the strata in block VIII are very weak with an average uniaxial compressive strength of 3.59 MPa, an average tensile strength of 0.68 MPa, an average Young?s Modulus value of 0.234 GPa, an average cohesion of 129.19 KPa, and an average friction angle of 55.47°. Slope stability analysis, based on a probabilistic approach, was carried out using Slide-V software. Monte Carlo simulations have been applied to investigate the probability of failure in the slopes of an open pit lignite mine in block-VIII. From the slope stability investigation, it was found that the probability of failure is 0 % at a slope angle of 16°.

Aug 1, 2013

By D. Berkley

Off-gas systems often become the limiting factor in production increase and environmental projects. Any upgrade or new off-gas project needs to address control instability issues, instabilities that can result in safety hazards, significant loss of system capacity and/or emissions to the environment [1]. In addition, the design engineer must optimize system configuration and equipment size for the new operating conditions, to have a technically feasible and economically viable project. Dynamic simulations can be used for addressing both the control stability and the design optimization issues. This paper illustrates how the dynamic simulation of transient processes and of their control system can be used in "real life" situations for these purposes, presenting the example of an electric furnace off-gas system design.

Jan 1, 2005

By D. R. Reeves

This paper describes the geophysical Jogging of coal that is being carried out for the National Coal Board in the United Kingdom. An explanation of the technique is given and results are presented showing estimations of seam thickness to within ±0.5 in. and ash content to accuracies of ±2.5 per cent. The basic method of interpretation is outlined and some conclusions regarding the conditions of roof and floor material which may be deduced from the logs are explained. An indication of future developments in this field, including the identification of coal type and moisture content, is given.

Jan 1, 1971