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By X. -G. Chen, E. M. Elgallad

Direct chill (DC) cast ingot plates of 2xxx alloys have been increasingly used for large mold applications in the plastics and automotive industries. A novel heat treatment practice for Al-3%Cu-1%Mg DC cast ingot plates has been developed, involving solution treatment, furnace cooling to the desired aging temperature and holding for appropriate time at the aging temperature. The mechanical properties of the plates were studied for different combinations of aging temperature and time, using hardness measurements and tensile testing. The evolution of the strengthening precipitates was investigated under different cooling rates corresponding to cold water quenching, still-air cooling and furnace cooling, using electrical conductivity measurements. The results showed that by applying the novel heat treatment, the cast ingot plates could provide a wide range of combinations of strength and ductility satisfying the design specifications of large molds. This, in turn, offers a practical solution for the fabrication of extremely large DC cast plates combining between good mechanical properties and low levels of residual stress using the shortest possible heat treating cycle.

Jan 1, 2015

By Frederick W. Breaks, Andrew G. Tindle, Julie B. Selway

"Abstract - Rare-element pegmatites may host several economic commodities, such as tantalum (Taoxide minerals), tin (cassiterite), lithium (ceramic-grade spodumene and petalite), and cesium (pollucite). Key geological features that are common to pegmatites in the Superior province of Ontario and Manitoba, Canada, and in other large tantalum deposits worldwide, can be used in exploration.An exploration project for rare-element pegmatites should begin with an examination of a regional geology map. Rare-element pegmatites occur along large regional-scale faults in greenschist and amphibolite facies metamorphic terranes. They are typically hosted by mafic metavolcanic or metasedimentary rocks, and are located near peraluminous granite plutons (A/CNK > 1.0). Once a peraluminous granite pluton has been identified, then the next step is to determine if the pluton is barren or fertile. Fertile granites have elevated rare element contents, Mg/Li ratio < 10, and Nb/Ta ratio < 8. They commonly contain blocky K-feldspar and green muscovite. Key fractionation indicators can be plotted on a map of the fertile granite pluton to determine the fractionation direction: presence of tourmaline, beryl, and ferrocolumbite; Mn content in garnet; Rb content in bulk K-feldspar; and Mg/Li and Nb/Ta ratios in bulk granite samples. Pegmatite dikes with the most economic potential for Li-Cs-Ta deposits occur the greatest distance (up to 10 km) from the parent granite.Metasomatized host rocks are an indication of a nearby rare-element pegmatite. Metasomatic aureoles can be identified by their geochemistry: elevated Li, Rb, Cs, B, and F contents; and by their mineralogy: presence of tourmaline, (Rb, Cs)-enriched biotite, holmquistite, muscovite, and rarely garnet.Once a pegmatite dike has been located, the next step is to assess its potential to contain Ta mineralization. Pegmatites with the highest degree of fractionation (and thus the most economic potential for Li-Cs-Ta) contain blocky K-feldspar with >3,000 ppm Rb, K/Rb < 30, and >100 ppm Cs; and coarsegrained green muscovite with >2,000 ppm Li, >10,000 ppm Rb, >500 ppm Cs, and >65 ppm Ta. Pegmatites with Ta mineralization usually contain Li-rich minerals (e.g., spodumene, petalite, lepidolite, elbaite, amblygonite, and lithiophilite) and may contain Cs-rich minerals (e.g., pollucite, Cs-rich beryl). The ore minerals of Ta are commonly manganotantalite, manganocolumbite, wodginite, and microlite; Ta-rich cassiterite is also commonly present. Tantalum mineralization tends to occur in albitic aplite, mica-rich (lepidolite, cleavelandite ± lepidolite), and spodumene/petalite pegmatite zones."

Jan 1, 2005

By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By M. H. Fathi

The aim of this work was to prepare the metallic coatings on 316L stainless steel dental implant and evaluate the corrosion characteristics and thus the biocompatibility of the uncoated and metallic coated dental implants and comparison of the effect of the type of coatings on biocompatibility. Three types of metallic coatings including Tantalum, Niobium, and Titanium coatings were made using physical vapor deposition process on 316L stainless steel dental implant. Structural characterization techniques including; X-ray Diffraction, Scanning Electron Microscopy and Energy Dispersive X-ray Analysis were utilized to investigate the microstructure and morphology of the coatings. Electrochemical potentiodynamic tests were performed in two types of physiological solutions at 37±1 °C in order to determine and compare the corrosion characteristics. All three types of metallic coatings had a positive effect on improvement of the corrosion behavior so that the coatings could increase the corrosion resistance of 316L stainless steel and this trend was independent to the type of physiological environment. Biocompatible metallic coatings could decrease the corrosion current density that is a distinct advantage for prevention of ion release. This can improve the biocompatibility of the implant and, consequently prevention of tissue damages, inflammation and irritation and obtained desirable histopathological response.

Jan 1, 2007

By N. Parnian

"Carryover of caustic soda (NaOH) in the steam path caused catastrophic failure of superheater 304H stainless steel tubes in a steam generator and led to an unexpected shutdown after just five months of continuous service of petrochemical following the start of production. The cause of the failure was studied, with a focus on the formation of sigma phase in the weld joint and effect of caustic embrittlement on stress corrosion cracking (SCC). The cracks were examined at the seam weld, heat affected zone (HAZ), and Ubend areas. Hardness was measured for the base metal, HAZ, and weld metal, and microstructures were examined using optical microscopy and scanning electron microscopy (SEM). Crack initiation is attributed to gouging on the precipitated carbide at the HAZ and also the formation of sigma phase in the weld metal, as shown by energy dispersive X-ray (EDX) analysis. In addition, cracking was propagated by caustic embrittlement because of residual stresses and hammering. Finally, the characteristic feature of fracture was illustrated by SEM fractography, and consists mostly of intergranular SCC and some quasicleavage transgranular. INTRODUCTIONThree key factors are needed for the initiation and propagation of intergranular stress corrosion cracking (IGSCC): a susceptible material, a corrosive environment, and sufficient stress. Although austenitic stainless steels are susceptible to sensitization and IGSCC, they are widely used in boiler and superheater tubes because of their high corrosion resistance, high oxidation resistance, acceptable mechanical characteristics at elevated temperatures, and low cost.Sodium hydroxide is injected to neutralize acidic constituents in the steam path, but caustic can concentrate in boiler tubes and attack the surface metal (known as gouging) even traces of caustic in the steam can deposit on surfaces and cause local concentrations of several percent (ASM handbook, 1992). Not only sensitized grains but also sigma phase formed in the weld metal can initiate caustic cracking. In this research, the cause of the failure of 304H stainless steel superheater tubes in a methanol petrochemical plant in Iran was studied with a focus on the effects of caustic embrittlement on IGSCC."

Jan 1, 2012

By Sanat Talmaki

Construction and mining worksites pose unique challenges to workers and equipment operators due to their dynamic and unstructured nature. Narrow haul roads, crowded work spaces and presence of workers and equipment in close proximity, combined with large blind spots and overall poor visibility afforded to operators lead to collisions and run-over-type accidents between equipment, workers, and other entities that may be present on the jobsite. Operations that involve machine-infrastructure interaction, particularly in the case of concealed infrastructure such as excavation and drilling lead to unintended strikes between the equipment?s end-effect or and the infrastructure. Such accident-prone scenarios can be avoided by providing operators with real-time feedback and warnings using 3D visualization and proximity monitoring of the entities present in the equipment?s vicinity. Thus the jobsite in the real world is abstracted and represented in a 3D virtual world. However, this requires the ability to create a seamless link between real-world sensors present on the equipment and/or the jobsite and the virtual environment. This paper describes a non-restrictive acquisition allocation framework that allows position and orientation sensor streams from construction and mining job sites to be used for updating 3D virtual scenes in real-time for providing vital collision avoidance warnings to equipment operators.

Aug 1, 2013

By Alex Rown

"THE SYDNEY COAL FIELD has long been afflicted by high costs and low productivities. However, a distinct possibility now exists that improvements can be made in costs, productivities and revenues. If these hopes materialize, the Sydney coal field will once again be regarded as a valuable asset in our national inventory of energy and metallurgical coals. The economic possibilities for the Sydney collieries depend on performance at the pits and in the market place. Because this audience is already well informed about colliery planning, I would like to start with an assessment of the modern coal market insofar as it may relate to the Sydney field. Since 1950 we have seen a vast growth in the population and industrial empires of the western world which has resulted in an enormous and escalating demand for energy. If the energy supply pattern of the first 50 years of this century had been followed, this would have led to an immense demand for coal."

Jan 1, 1972

By John E. Udd

"For decades, writers have expressed concern about impending shortages of professionals for Canada&apos;s minerals industry. Even under the present difficult economic circumstances, it is anticipated that the supply which will be available will not be adequate to meet the requirements in certain key areas including mining and petroleum engineering. It is evident that, unless further initiatives are taken, shortages will exist for some time.In this paper, the writer reviews information which relates to both the demand for, and the supply of, persons with advanced-level education in minerals-related disciplines. In particular, a summary is made of the information regarding supply which has been collected by the CIM General Committee on Education for many years.In concluding, the writer expresses some personal opinions regarding imbalances between demand and supply and offers some recommendations for future actions.IntroductionLast year, in a paper which was presented at the Annual General Meeting of the CIM in Calgary, the writer presented a review of the situation regarding professionally educated manpower for the minerals industry, and concluded that indications were that the gap between demand and supply was widening and that the situation could be expected to continue. Since that time, the deterioration of the nation&apos;s economy has caused an appreciable reduction in demand. Simultaneously, a further annual survey by the CIM has shown that the numbers graduating in certain specializations, notably geology and some of the technologies, are rising very rapidly. One of the great concerns of educators at present is that adequate opportunities may not exist for all of those who are now graduating.The danger of the present situation, then, is that a momentary lack of opportunities may cause potential students to choose alternative careers . Because of the lead-time which is involved, it is very possible that this could result in greater shortages during a period of economic recovery or expansion. Action must be taken to ensure that adequate numbers will be attracted to the industry, and this applies particularly to those who have already made the career decision and who are enrolled in minerals-related programs."

Jan 1, 1982

By R. P. Hackl, P. G. West-Sells

Carbonaceous gold ores are particularly attractive for leaching by ammonium thiosulfate as the gold thiosulfate complex is not significantly adsorbed by the organic carbon present in the ore. A technically and economically feasible process for treating these ores with ammonium thiosulfate has been developed. In this process, gold is extracted by leaching the ore with ammonium thiosulfate, the solution is separated from the ore by counter - current decantation, the gold is recovered by precipitation with ammonium sulfide, and finally the gold containing product is upgraded by reacting the elemental sulfur present in the precipitate with ammonium sulfite. The precipitation filtrate is recycled back to the grinding step to close the solution balance. Reagent consumption is not excessive. Besides precipitating gold, the precipitation step removes most deleterious solution impurities and converts a portion of the polythionates back to thiosulfate. This paper discusses the optimization of the leaching, precipitation, and upgrading steps. The results of a 10 kg/h pilot plant campaign are also discussed.

Jan 1, 2005

By L. Shasko, M. Hurlbert

As climate change is increasingly perceived as a problem, and fossil fuel based power production options are increasingly limited through regulatory restrictions and public distaste, future options become constricted. Reflexivity and social learning elicited through qualitative and mixed research methods offer important insight into what future power production pathways might be. Given factors of cost, baseload requirements, and energy density, options such as nuclear may be increasingly accepted. This paper explores this literature and possible methods of pursuing the reluctant acceptance of nuclear energy.

Jan 1, 2020

By J. M. B. Scarborough

This paper deals with measures taken to maintain effective operation of heavy-duty equipment in open-pit mining. at Pine Point, N.W.T., during periods of extreme cold weather. The points covered include equipment modifications designed to improve cold-weather performance, effective lubrication of machinery that is vulnerable to extreme cold and operating procedures designed to prevent equipment damage.

Jan 1, 1966

By J. L. Luo, D. G. Ivey, A. H. Adeleke

Double-edge-notched flat tensile samples of X70 steel were used for both slow strain-rate testing (SSRT) and cyclic loading testing with the notch located in the zone of interest, i.e., the weld metal (WM), base metal (BM) and heat affected zone (HAZ). By using both optical and scanning electron microscopy, the stress corrosion cracking (SCC) behaviour with respect to crack morphology and various forms of microstructure was investigated. In all the samples considered, the mode of failure was predominantly transgranular with cleavage facets around the edges of the fracture surface. The BM, with a bainitic microstructure, had the highest resistance to SCC when compared with the mixed microstructures of acicular ferrite-primary ferrite and acicular ferrite-grain boundary ferrite observed in the WM and HAZ, respectively. The effect of microstructure on stress corrosion cracking behaviour is discussed based on experimental observations.

Jan 1, 2005

By J. B. Boniwell

The INPUT electromagnetic prospecting system was originally developed by Dr. A. R. Barringer in an effort to increase the sensitivity and penetration of airborne EM methods. Although brought to an operational state some several years ago, it is only through relatively re-cent modifications and testing that some of the potential of the system has been fully realised. This is brought into perspective by some recent results over known ore deposits and geologic environments.

Jan 1, 1967

By M. D. Scott

"Highland Valley Copper recently installed a semi-mobile in-pit crushing and conveyor system designed to feed both the Bethlehem and Lornex concentrators with a feed averaging 120000 tonnes per day. The system installed with a rated capacity of 12000 tonnes per hour is the highest capacity hard rock semi-mobile crushing and conveying system currently in existence.The system is designed in a manner that the crushers can be moved easily as the pit is developed in depth with conveyors extending deeper into the pit, and conveyors being moved radially from a surge pile located at the rim of the ultimate pit as the pit increases in size laterally.The system consists of two 6000 tph, 60 by 89 Krupp semimobile crushers feeding two moveable 4500 hp, 60 in. conveyors, 1.25 km long feeding a 7500 tonne live storage surge pile. Two 96 in. belt feeders installed in reclaim tunnels under the pile feed two parallel 4500 hp, 60 in. conveyors, 1.25 km long on a 12 per cent uphill grade to the two existing Lornex plant feed conveyors. A third 96 in. belt feeder, under the pile, feeds a 60 in. conveyor, loading trucks hauling crushed ore to the Bethlehem mill.A description will be given: (1) of the system&apos;s design features in which climatic extremes, operating, and maintenance characteristics were of primary importance; (2) of the way the system was constructed from components purchased internationally on an extremely tight construction schedule; and (3) of the way the system has operated during the first few months in operation during which time it demonstrated that it has met various design criteria."

Jan 1, 1988

By I. C. Brown, J. F. Henderson

"IntroductionThe Yellowknife greenstone belt lies along the west side of Yellowknife bay on the north shore of Great Slave lake, some 600 miles north of Edmonton, Alberta. The producing gold mines along the belt include the Con-Rycon and Negus which came into production in 1938 and 1939, and the Giant Yellowknife, which followed in 1948. In addition to these, the Akaitcho and Crestaurum mines are potential producers and there are several promising prospects.Early geological work along the belt was done by A. W. Jolliffe who first recognized a number of great faults, the largest of which is the West Bay fault with a horizontal movement of more than 3 miles. In 1943, A. S. Dadson, following an examination of the Giant-Yellowknife property, advanced the hypothesis that Baker Creek valley was underlain by a series of major gold-bearing shear zones. Subsequent diamond drilling in 1944 bore out the correctness of this view and outlined the great ore-bearing shear zones that are now being developed and mined by Giant Yellowknife Gold Mines. Near the south boundary of the Giant property, the shear zones are cut off by the West Bay fault. This prompted Neil Campbell, District Geologist for the Consolidated Mining and Smelting Company, to make a detailed study of the geology along the West Bay fault in the hope of finding the faulted extension of the Giant shear-zone system on the west side of this fault. In this he was entirely successful. By careful geological mapping he matched several faulted diabase dykes on both sides of the fault and, knowing their dip, determined the horizontal and vertical components of movement along the fault. Subsequent •diamond drilling based on Campbell's work located the presumed correlative of the Giant shear-zone system on the Con-Rycon and Negus properties, where it has been named the Campbell zone or system. At the present time, all production at the Negus Mines property is coming from orebodies along the Campbell zone."

Jan 1, 1950

By W. A. Alexander

Introduction In the course of a programme of research on beryllium in progress in these laboratories, knowledge of the recrystallization temperature became necessary. As the information is not available in the literature, the determination of this temperature for metallic beryllium was undertaken. By the reduction of grain size through working and recrystallization and the probable simultaneous induction of preferred orientation, it was hoped to improve the working properties of beryllium at lower temperatures. The recrystallization temperature is usually determined by observing the lowest temperature of annealing at which new crystals are formed in severely cold-worked metal or alloys. This temperature is profoundly influenced by the following factors: the purity of the metal, in the case of an element, or the composition of the alloy; the degree of straining or working; the temperature of straining; the original grain size; and the time held at the annealing temperature. The observed temperature is lowered by higher purity, more severe straining, lower temperature of working, smaller original grain size, and longer time of annealing. Beryllium presents special difficulties in that the percent elongation in tension is effectively zero, so that ordinary squeezing or rolling was not possible. A possible means of straining was suggested by the fact that indentation hardness tests could be made. It was known from earlier work that the metal could be worked at elevated temperatures, so that working at the lowest feasible temperature and quenching might also be a means of producing strain. The purity of the metal is also a point of some uncertainty in the case of beryllium. Losano has prepared 99.96% Be which appears to be the best reported. Distilled metal used in the present work approached this purity. However, by analogy with other metals, residual impurities may have a pronounced effect on the recrystallization. Further purification of beryllium would evidently entail considerable difficulties due to the highly reactive nature of the metal, and was not attempted.

Jan 1, 1947

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By M. C. Bétournay, J. E. Udd

"The legacy of abandoned mines in Canada creates issues that impact on both the health and safety of Canadians and the environment. Solutions to the problems of abandoned minesites require a detailed understanding of site conditions, the engineering solutions which may be relevant, and planning for effective use of the land. In this paper, the authors outline the basic thrusts that have been developed at CANMET to address this problem. These include: multiprovincial agreements to develop a national database; methods of site rendering; a ten-year research program to develop engineering approaches; the review of a large number of case studies; and outlining the associated risks. Examples of the applications of this research are provided in the areas of: municipal, provincial, and federal co-operative projects; site-specific applications; and international linkages."

Jan 1, 1997

By Richard W. Herzer

Introduction Thermal methods have been predominant in the metallurgy of the base-metals ever since the foundation of the industry thousands of years ago. Development in hydrometallurgy has been confined largely to the past six or seven decades. It was at first necessarily slow, then for a number of years rapid progress was made. At present, the uncertain state of the metal industry has curtailed research on the subject; however, in the next few years one may assuredly look forward to an ever increasing use of wet processes. Leaching methods have attained the dominant position in the case of certain metals, notably zinc. For others, they have made no headway at all. Copper presents a situation all its own. Due to the varied nature of its ores and to the large number of localities in which it is mined, a great number of processes have been developed, each suitable in its own particular field. In the case of this metal, therefore, it is more difficult to arrive at definite conclusions. It is the purpose of this paper, first, to review the outstanding developments of base-metal hydrometallurgy, and, secondly, to consider possible Canadian applications of some of the processes in use. The discussion will be confined to the three metals, zinc, lead, and copper, with particular reference to the last mentioned. Zinc General Note At present, zinc is produced by two principal processes, the older retort process and the electrolytic process. The latter is a development of the last twenty years and, judging by its present progress, bids fair eventually to supplant older methods in a large proportion of cases. It is certain, at least, that in the erection of a new plant, a hydrometallurgical process would be given the most serious consideration

Jan 1, 1934

By A. Berry, N. R. Banerjee, C. S. Finnigan, M. Fayek, N. J. Bridge

Lac Cinquante is a mineralogically simple, vein-hosted uranium deposit in Archean basement rocks (Angikuni greenstone belt) that originally were unconformably overlain by Proterozoic sedimentary and volcanic rocks of the Baker Lake Group (BLG). Basement rocks are mainly pillowed and massive tholeiitic lavas (N-MORB) with interbedded tuff; overlying sedimentary rocks comprise a basal talus/fault breccia that grades upward into fluvial sedimentary rocks and subaerial, trachytic volcanic rocks; granite and porphyry dikes (Hudson and/or Nueltin granitoids) intrude the basement rocks. A typical section through the Main Zone comprises 1) laminated ‘tuff’, 2) altered (carbonate-hematite-chlorite) schistose ‘tuff’, 3) a pitchblende-bearing, breccia-vein, 4) altered ‘tuff’, and 5) laminated ‘tuff’. The vein comprises brecciated chlorite, hematite, and pitchblende with carbonate cementing the breccia. Graphitic ‘tuff’ with sulfide-stringer veinlets locally overlies or underlies the vein. Pitchblende also occurs in the altered rocks and in gash veins that cut basement rocks. U-Pb ages on pitchblende fall into two groups: one at 1828 } 29 Ma reflects primary uranium mineralization, and a second at 1437 } 31 Ma represents resetting. Pb-Pb chemical ages show other resetting events at 1260-1321Ma, 895 Ma, 741-813 Ma, and 660-706 Ma. One possible genetic model for the Lac Cinquante deposit involves leaching of uranium from granitoids and the BLG by basinal brines that migrated to depositional sites where graphitic rocks acted as a reductant. A second model requires that uranium was sole-sourced from the BLG and that granitoid rocks provided heat to drive the hydrothermal system, which leached and ultimately precipitated uranium. The deposit has characteristics similar to vein-type uranium deposits in the Beaverlodge District of Saskatchewan

Jan 1, 2013