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By C. Chapman, M. G. Reading, M. P. Amsden

Ecstall Mining Limited, a subsidiary of Texasgulf Incorporated, operates the Kidd Creek mine, a 10,000- tpd base metal producer, near Timmins, Ontario. Two different ore types are mined and milled copper-zinc and silver-lead-zinc. At the highly automated Ecstall concentrator, the ores are processed by selective flotation in three individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous onstream X-ray analysis. Recently this system was further automated by adding computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery 0.8% and zinc recovery 1.6%, and reduced reagent costs by 12%. Although not anticipated, copper and zinc concentrate grades were improved modestly as well.

Jan 1, 1973

By P. S. Arthur, G. R. F. Alvear

Development of a new smelting process is risky. Many novel processes in the metals industry failed to fulfil the initial expectations of their inventors. Large sums of capital have been invested in technologies that either didn't provide a satisfactory return on investment, or didn't perform at all, and had to be replaced. One of the keys to success in process development is incremental scale up of the technology, with potential problems being identified and rectified as early as possible. In this way the cost of any rectification that is required can be minimized. The ISASMELTTM process was developed to maturity by Mount Isa Mines through the 1980's and 1990's using incremental scale up. Commercialization only occurred once the process had been proven on laboratory, pilot and demonstration scale over many years. As a result ISASMELTTM technology now operates successfully at numerous plants around the world. The methodical approach to development of the technology has allowed owners to modernise their existing operations or create new businesses with significantly reduced technical risk.

Jan 1, 2011

By Mohamed Hamoud

Relative permeability curves represent an important element of special core analyses, but challenges remain in obtaining valid results and the extrapolation and use of existing permeability results is problematic. This situation is compounded in cases where core properties are altered from changes in effective stress. During the production of oil and gas reservoirs, the effective stress changes as a result of changes in pore pressure or temperature. Therefore, changes in rock properties such as porosity and permeability will occur and will consequently influence reservoir performance calculations. An experimental program was carried out to understand the behavior of dense, reconstituted sand samples at low effective stress states. Drained triaxial compression tests were set up to study the effect of stress alteration on relative permeability data through porous media. Initially, a saturation stage was performed followed by isotropic loading to bring the core sample to reservoir fluid and stress conditions. Then, while axial (deviatoric stress) loading was applied to the sample, a series of absolute and relative permeability tests was performed under steady state flow at different levels of strain during pre and post peak shearing stress. The stress-strain behavior results from the study revealed that the absolute permeability decreased during isotropic loading (compaction) and increased during shearing (dilation). However, the shape of relative permeability curve changed from contraction to dilation and showed higher initial kro and the lower initial kro respectively. The goal of this project was to understand the behavior of both absolute and relative permeability at different stresses. It is expected that geomechanical processes will be adopted for special core analyses to support the current integration of geomechanics into reservoir engineering. This will be required if, during SAGD, conventional and/or unconventional reservoir simulation, reservoir engineers implement a proper set of relative permeability data at each in situ state of stress, instead of constant curves throughout the field?s life.

Jun 1, 2012

By M. I. Kalashnikova, Y. M. Shneerson, E. E. Zhmarin, Y. V. Degtiarev, E. M. Vigdorchik

Separation of a magnetic fraction from nickel concentrate following matte flotation, and its treatment in a separate circuit enable reduces precious metals losses. The magnetic fraction is treated in two stages of oxidative leaching: atmospheric and pressure leaching. A study of the atmospheric stage, using mathematical modelling, is described in this paper. The mathematical model and experimental data were used to carry out industrial process calculations. The model enabled extrapolation of the results of batch laboratory test to industrial-scale continuous processing and the selection of optimal process conditions and large-scale equipment. In December 2004, commercial oxidative leaching tests were performed on the magnetic fraction at the Severonickel Plant (Monchegorsk, Russia). A comparative analysis of the mathematical modelling results and the actual process parameters is presented.

Jan 1, 2005

By L. Tong

"The oxidation of Quebracho was evaluated by acid-butanol assay, which indicates depolymerization of Quebracho. Anthocyanidin, an oxidation product of Quebracho, is stable at 95?C for up to 2 h. The ionization, complexation, and oxidation properties of Quebracho were discussed. Complexation of metal-Quebracho occurs at ambient temperature. The formation of complex precipitates is influenced by the acidity of the solution. Temperature is another important parameter that influences the oxidation and the complexation of Quebracho. Quebracho-ferric complex precipitate forms at 90?C, 0.1 mol/L H2SO4. The formation of Quebracho-metal complex in the leach solution is a possible reason for the consumption of Quebracho. Quebracho molecules adsorption on the mineral surface is reduced by consumption of Quebracho, resulting in poor sulfur dispersing effect in the leaching process. INTRODUCTIONQuebracho is used as a sulfur dispersing agent (SDA) in the pressure leaching of zinc concentrate as stated in U.S. Patent No. 3,867,268 (1975). It prevents the zinc sulfide particles from being coated with molten sulfur, thus preventing the inhibition of the zinc leaching reaction. Recently, the sulfur dispersing effect of Quebracho was investigated in the oxygen pressure leaching of nickel concentrate. The oxygen pressure leaching of pentlandite can be represented by reactions 1-3."

Jan 1, 2012

By R. Gutray, J. E. Grainger

This paper deals with the use of a cement-deslimed mill tailings mixture for a scraping floor in cut-and-fill stopes at Madsen Red Lake Gold Mines Limited. It describes the mixing and placing procedures and the precautions used with respect to the floor while mining in the stopes. Details of the mix are presented, and advantages and disadvantages discussed. The paper concludes with a brief outline of the costs.

Jan 1, 1966

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011

By D. O. Tansey

This paper will describe the mechanisms involved in delay blasting and how they are applied with the use of D.S.B. It will examine the control of potential damage resulting from detonations, and show how good fragmentation and efficient recovery of this material blasted can be achieved.

Jan 1, 1979

By M. Korchynsky

"The key words which characterize vanadium are: unlimited availability, versatility of applications and price stability. The supply of vanadium is assured by diversified sources, distributed all over the globe. The inexhaustible raw materials base is complemented by a strong vanadium industry. Both the fully integrated vanadium producers and converters of vanadium oxide or vanadium-containing slags or residues guarantee an adequate supply, commensurate with the steady growing demand.The major share of the world's vanadium output is being consumed by the steel industry. As an additive to steel, the versatility of vanadium is particularly impressive. A few hundreds of one per cent of vanadium convert plain carbon steel into high-strength, low-alloy steel with more than double strength. On the other extreme, high-speed steels made via the powder metallurgy route show superior performance with vanadium additions as high as 6 or 8 percent. Vanadium is used as a cost-effective alloying addition in steels for high-temperature service, fully alloyed heat-treatable steels, new dual-phase steels for automotive components, rail steels, etc., to mention only a few applications. Vanadium is also an established essential addition for titanium alloys. The chemical industry is relying on vanadium compounds as important catalysts.In spite of a wide diversity of applications and continual growth in consumption, vanadium has exhibited, over the past several decades, a remarkable price stability, free of conjunctural fluctuations. Because of its availability and versatility, it will continue to be one of the key metallic elements for future technologies.Key Features of VanadiumIn attempting to single out the key features of the metallic element vanadium, three descriptive characteristics come to mind: availability, versatility and price stability."

Jan 1, 1982

By T. Velea

The most widespread methods for producing metallic copper are smelting of copper sulphide concentrates (which generates various types of polluting substances) and the hydrometallurgical route which consists of leaching in sulphate and chloride media (usually employing high temperature, high-pressure and special equipments). This paper presents a process, called VEPE, which consists of oxidizing copper sulphide concentrates in weak alkaline media (Na2C03 orland NaOH solutions), under low pressure and with air sparging. The oxidized concentrate contains less than 0.4% S. Copper is recovered from the oxidized concentrate by the standard leaching-solvent extraction-electrowinning route, with a total efficiency of 98% extraction. The proposed technology could represent a good opportunity to recover copper from sulphide concentrates in a clean, simple and profitable way.

Jan 1, 2007

By R. J. Johnston

"INTRODUCTIONPoint Mines is located about 65 miles east of Hay River on the South Shore of the Great Slave Lake. It is connected to the Northern Alberta Railway System by the Great Slave Lake Division of CN Railways at Roma Junction, Alberta.The operation started in the fall of 1965 with a capacity of 5000 t.p.d. An addition was put into operation late in 1968 to bring the capacity up to 8000 t.p.d. The present milling rate is 11,000 t.p.d.The location of Pine Point Mines is such that long end cold winters are to be expected end temperatures of lower than -200F are encountered from late October to late March, with extended periods of -300F being common in January and February.It was recognized by Cominco engineers during the initial design period that since freezing would be encountered with open pit ore somewhere in the crushing circuit, the problem was to reduce it as much as possible. Other mines, working under similar conditions, found that the fine ore bins feeding the grinding circuit were the main problem area. The decision was reached, therefore, to have heated fine ore bins and to make sure thst the ore was sufficiently warm to prevent freezing.CRUSHING PLANT FLOWSHEETThe crushing plant has a standard open flow circuit (flowsheet). Ore from the stockpile is loaded into R-50 Euclid trucks by Caterpillar 992 Front End Loader with 11 cu. yd. bucket and dumped into a 42 x 65 C.A.C. Superior Crusher driven by a 300 HP motor. The crusher is set at a nominal 5 inches. The ore falls through into a 100-ton surge bin. There are high level and low level nuclear gauges to allow the primary operator to optimize for optimum orientation."

Jan 1, 1972

By H. R. Banks

SHORTLY after the commencement of operations at the Sullivan concentrator, the use of a pilot table was instituted in order to present a visual control of various products by showing the amount of galena still present in the tailing from several stages of flotation. Among the products so treated, the final tailing was later included. It was sratifying to note that very little free galena was escaping, but a fine streak o a whitish mineral appeared at the concentrate zone. This mineral was identified as cassiterite. The amount was small and the newly recognized component in an already complex ore was considered primarily as of academic interest. However, the problem of recovering a usable metal was intriguing and, as opportunity presented itself in temporary lulls in research on Sullivan and other ores, the concentration of tin was a useful 'bit of knitting' to go on with. It was recognized from the start that the bulk of the mill tailing would have to be floated and the residue subjected to gravity treatment. Since one of the predominating features of Sullivan concentration operation has been the necessity of fine grinding, the problem of gravity concentration was thereby intensified. Several batch runs were made, and sufficient pulp was treated to produce about one ton of final tin concentrate assaying 67 percent tin. The overall recovery was under 30 percent and the estimated profit at full tonnage was only marginal. Testing was resumed several years later, when the price of tin again appeared attractive, in an attempt to develop a more compact plant with better recovery of tin. The weakness of the original plan of concentration was the large number of tables required to treat a feed so low in tin.

Jan 1, 1941

By M. E. Holuszko

A research program has been carried out at the Mining Department of the University of British Columbia to study the effect of wettability of coal on its handleability and bulk density. The effect of moisture content on the bulk density of coal was found to be more pronounced for hydrophilic coals than for hydrophopbic ones. Altering wettability of coal surface leads to different effects of moisture on bulk density. The samples were studied at different fine fractions content, and it was shown that there was no effect of increased content of fines on the bulk density for hydrophobic coals, while for hydrophilic coals this effect was very significant. It was shown that the moisture content at which the lowest bulk density was reached coincides with the critical moisture content for studied samples, as determined from handleability tests using Durham Cone method. This critical moisture is the moisture content at which a sudden deterioration of coal handleability occurs. Based on the bulk density and handleability tests, the flow theory of moist coal is proposed.

Jan 1, 2006

By Tassos Grammatikopoulos, Gary Pearse, Massoud Aghamirian, Charlotte Forstner, Stephen Mackie

"SGS Minerals Services (Lakefield, Ontario site) has conducted a number of developmental and pilot programs that examined methods for the beneficiation, extraction and recovery of lithium from a variety of spodumene containing hard rock sources. An overview of the beneficiation programs is presented separately by Aghamirian, Mohns, Grammatikopoulos, Imeson & Pearse (2011). The focus of this discussion will be the hydrometallurgical steps involved in producing a high grade lithium carbonate (Li2CO3) sample from the spodumene concentrate. SGS has applied the standard Li2CO3 hydrometallurgical flow sheet to a number of spodumene concentrates and has determined that all of these samples respond in a similar manner to the process and produce a final product having a Li2CO3 grade of >99.5%. The standard process is sufficiently robust to accommodate the observed variability in the concentrates that have been tested. Advantage of one spodumene deposit over another will thus be gained through process optimization and innovation. Optimization at the beneficiation stage and at the hydrometallurgical stage must be considered. Some aspects of the process optimization of the hydrometallurgical flow sheet will be presented.INTRODUCTION The current activity in the exploration, development, and mining of lithium based minerals is due in large part to the key role that this metal plays in the rechargeable battery industry (U.S. Geological Survey, 2011). Lithium battery technologies are widely applied in a range of portable electronic consumer products. The expanding development and production of hybrid and fully electric vehicles has contributed to the increased interest in finding and developing new lithium sources in order to meet the expected demand from the lithium battery industry. Lithium may be sourced from continental brines (sub-surface salars), hard rock minerals (pegmatite, spodumene), hectorite clay deposits, geothermal brines and oilfield brines. Currently the majority of the lithium products are produced from Li brines. The four major lithium producing countries are Chile, Australia, China, and Argentina (U.S. Geological Survey, 2009; Roskill, 2009). These countries accounted for 97.6% of the total lithium produced in 2010."

Jan 1, 2012

By John Loui Porathur

Highwall Mining has been recently introduced in India. The first Continuous Highwall Mining extraction in India started operating at Ramagundem Opencast Project-II (OC-II) of Singareni Collieries Company Ltd. (SCCL) in December 2010. A new hybrid empirical and numerical modelling approach has been devised to design web pillars for the initial Highwall Mining sites in India, considering the complex geology, such as existence of thick seams and multiple seams in close proximity. This paper gives the scientific elucidation of a comprehensive design methodology adopted for the above mentioned Indian Highwall Mining sites. The design technology includes web pillar design for multiple seams using hybrid empirical and numerical methods, slope stability assessment, ground movement monitoring, and recommendations for conducting blasting operations in the vicinity of Highwall Mining extractions.

Aug 1, 2013

By H. J. McQueen

The irregular history of Mg wrought products is briefly described. The temperature and strain rate dependence of microstructural evolution, flow stress and ductility of Mg alloys in hot working, are described. The flow curves rose rapidly to a peak stress which was lower as temperature T rose and strain rate e declined and above 300°C the curves extended into plateaus until failure. Clearly grains not oriented for slip undergo mechanical twinning in the initial stages (a 0.15) at all temperatures. Basal slip proceeds in suitable grains and in the twins. The stress concentrations at grain and twin boundaries lead to slip on non-basal systems and to the formation of subgrains with greater dynamic recovery (DRV) at higher T or lower e. With increasing strain, misorientation builds up resulting in dynamic recrystallization (DRX) first at twin intersections and later at grain boundaries which have become quite serrated. Even after extensive straining at high temperatures, the new grains are found mainly along the boundaries of the original grains, leaving their centers with only basal slip except when nucleation at twins leads to completion of DRX throughout a grain. Despite similar shear modulus and melting point to Al, hot mechanical forming behavior of Mg alloys differ due to differences in crystal slip systems, twinning, and second phases. Moreover, the influences on forming of alloy additions (solutes, segregation in casting, dispersoids, precipitation) and impurities are not as well catalogued as for Al. Despite the benefits from dynamic recrystallization, varied grain orientation effects, heterogeneous substructures and the resulting stress concentrations result in considerably lower ductility for Mg alloys at the same stress level as for Al materials. Application of these theories to extrusion, rolling and forging and the effects on product properties are surveyed.

Jan 1, 2006

By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By D. Van Tonder

ABSTRACT The comparative economics of ion exchange and direct precipitation have been analyzed by developing indicative CAPEX/OPEX models for typical alkaline leach uranium circuits. An agitated tank ore leach application is considered, comparing resin-in-pulp and direct precipitation as recovery options. Capital and operating cost estimates are derived from rates and factors used in recent studies and projects. The analysis showed the main economic drivers to be the ore grade and resin loading. The resin loading is impacted by the prevalence of competing ions, especially chloride. At resin-in-pulp solution chloride concentrations below 3 g/L and uranium grade below 640 g/t U3O8, resin-in-pulp is more economical, whereas at chloride concentrations above 3 g/L, direct precipitation is more economical.

Jan 1, 2012

By E. Bonsall, J. J. Brummer, A. R. Graham

"A method and device are described for sampling diamond-drill core by cutting a continuous fillet of constant cross section from the cylindrical surface of the core throughout appropriate sample lengths. The apparatus employs a tapered, abrasive-set, cutting wheel, the conical cutting surface of which projects slightly into a rectangular core-guiding trough set parallel to the axis of rotation. The depth of fillet and thus the amount of sample per unit length can be regulated by adjusting the core guides. The freshly cut fillet itself, by engaging in a guide beyond the cutting wheel, acts to prevent rotation of the core during operation of the device.The cuttings which form the sample are normally collected in a tray below the cutting-wheel and appear at about 80 per cent -100 mesh. They require little or no further treatment or comminution before analysis. Speed, economy and convenience of sampling are thus greatly increased as compared with conventional sampling by im-1>act breaking or sawing, followed by crushing, grinding and sub division for assayAssays from fillets (about 1/20 the cross-sectional area of the core) and from 180-degree segments, from the same ninety-three core-samples, representing 431 feet of nickel-copper mineralization, gave the following results:"

Jan 1, 1968