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By D. M. Muir

Many plants produce iron(II)/(III) waste liquors which must be treated by neutralisation and precipitation to remove the iron. Iron can be precipitated as crystalline goethite or jarosite by controlled oxidation at low pH and as magnetite by controlled oxidation at high pH, but only at elevated temperatures (>70°C). This study focuses on the characterisation and settling properties of the iron oxides produced at ambient temperatures using various neutralising agents in order to improve the performance of thickeners. It was found that two-stage addition of caustic to FeC12 solutions produced a fast settling material characterised by Mossbauer spectroscopy and XRD as maghemite and magnetite. However, lime and magnesia additions resulted in more ferrihydrite formation and much lower settling rates because of the enhanced oxidation of Fe(II) by air. Settling rates decreased significantly as the proportion of Fe(III) to Fe(II) in the liquor increased. The mechanism of iron oxide precipitation is discussed together with some reasons for the different behaviour of the neutralising agents.

Jan 1, 2006

By József L. Margitfalvi

Different Au/MgO catalysts modified with Mn, and Fe were prepared by precipitation-deposition. The catalysts were characterized by XRD, FTIR, Temperature Programmed Reduction (TPR) and CO chemisorption and were tested in CO oxidation in the temperature range of 243-523 K. The catalytic tests using both Temperature Programmed Oxidation (TPO) technique and time on stream (TOS) experiments revealed the high activity of catalysts prepared. In TPO experiments the modification by Mn significantly increased the activity above 300 K, however in the subambient temperature range the activity decreased considerably. Catalysts modified by iron did not show any decrease in the activity below 300 K, while the activity at high temperature increased significantly. Catalysts modified by Mn, Fe showed higher activity, selectivity and stability in preferential CO oxidation, carried out in the presence of hydrogen than the unmodified Au/MgO catalysts. Results of in situ FTIR spectroscopy on both the base Au/MgO and the iron modified catalyst unambiguously revealed the formation of ionic gold in the presence of CO/O2 mixture. The formation of this species was strongly hindered in catalyst modified by manganese. Results obtained strongly support the need for the formation of "metal ion - metal nanocluster" ensemble sites. These sites are involved in the activation of the CO molecule prior to its reaction with atomic oxygen. It is suggested that at subambient temperature these ensemble sites contain mainly ionic forms of gold, while at higher temperature iron or manganese ions are involved in CO activation.

Oct 1, 2003

By Jeff Stufsky

Debt Financing ?Broad Market Overview ? Recovering due to factors including: ? Increased trust in the system ? Enhanced capitalization of financial institutions ? The need to deploy capital for profit ? Competition: ? Investment-grade bond volumes increasing dramatically, and starting to pressure banks to compete with new capital ? Term Loan B financing from insurance companies and related institutions is returning, also pressuring banks to lend ? Local country financial institution capacity in Latin America has materially increased ? Results: ? Loan capacity increasing generally across instruments, regions, and sectors ? Financial institutions/banks starting again to seek yield as pricing competition heats up ? Tenors increasing with pricing coming down more slowly Underwriting is back in play

May 1, 2010

By I. Stefanou, J. Sulem

"In the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface. Multiphysics couplings play a major role in earthquake nucleation and seismic slip. The effect of shear heating and thermal pressurization may be of prime importance in the control of the stability of shear deformation inside the slipping zone. Other mechanisms in relation with thermal decomposition of minerals affect the pore pressure and the temperature evolution of the system, and can play a significant role in the extreme strain localization observed in field. The actual width of the localized zone is a key parameter for understanding fault weakening mechanisms. On the basis of field observations, laboratory experiments and recent advanced modeling, these phenomena are analyzed and discussed in order to bring some new insights in the understanding of earthquakes nucleation.INTRODUCTIONIn the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface (Scholz, 1998; Sykes, 1978). The conceptual model of spring slider system is commonly used to represent the interaction between an elastic crustal block and a fault zone. Stick-slip instability is possible if the softening rate of the shear resistance of the fault zone is high enough as compared to the stiffness of the crustal block. Therefore, weakening mechanisms that can explain how the frictional resistance of a fault decreases with slip and/or slip rate is of prime importance to understand how an earthquake nucleates. In recent years, several drilling programs in active faults (e.g. the Nojima fault in Japan, Boullier, 2011; the Aigion Fault in Greece, Cornet et al. 2004, the Chelungpu fault in Taiwan, Ma et al. 2006, and the San Andreas fault in the U.S.A. Ellsworth et al. 2000) as well as high velocity friction experiments (e.g. Tanikawa et al 2012a; Tanikawa et al. 2012b) have highlighted the physico-chemical processes involved in the nucleation of seismic slip (see for the example the review paper of Niemeijer et al. 2012)."

Jan 1, 2015

By Nobuyoshi Yabuki

Building Information Modeling is a prevailing methodology in the building industry and half (by length) of the world's shield tunnels are in Japan. Accordingly, for shield tunnels from 2005 to 2007, we developed a product model called IFC-ShieldTunnel, which is based on Industry Foundation Classes (IFC), in order to meet the future demand for such a product model. IFC-ShieldTunnel was developed by adding new elements that are specific to shield tunnels and that are not included in the original IFC. The added elements include shafts, segments (A, B, and K types), waterproofing elements, segment joint elements, and ring joint elements. Furthermore, soil layers and void elements were created. Recently, we updated the product model by re-organizing the entities and correcting errors. We deployed the updated IFCShieldTunnel model in the construction of an actual shield tunnel in Tokyo for about a year from August 2010 in order to check its feasibility. In the verification process, first, segments were modeled using Autodesk Revit Structure 2011 and property data were assigned to each segment element. Next, a mapping between the original attributes of the entities of IFC and properties of IFC-ShieldTunnel segments was developed. Using this mapping and IFC?s IfcBuildingElementProxy function, we were able to convert the IFC data from Revit Structure 2011 to IFC-ShieldTunnel automatically. Segment data were also converted from Revit Structure to Google SketchUp by IFC-ShieldTunnel. Furthermore, the construction scheduling and cost data were converted from Revit Structure to EXCEL for 4D and 5D analyses of construction. We interviewed engineers who used IFC-ShieldTunnel and received positive comments about the utilization of the product model. Overall, our test demonstrated the feasibility of IFC-ShieldTunnel. In future work, we plan to apply IFC-ShieldTunnel to more projects and test its practicality.

Aug 1, 2013

By J. E. Dutrizac, R. J. C. MacDonald, J. B. O'Reilly

"Sometime around 3000 B.C., primitive metallurgists working in the mountainous regions of Asia Minor bordering on the Black Sea (Pontus) produced a soft, easily fused metal today known as lead. It appears certain that the first metal was made by reductive smelting of galena, but whether this recovery arose by the accidental inclusion of galena in the stones of a fire hearth or whether it occurred as a consequence of simple pyrometallurgical experiments on a series of interesting ""stones"" will likely never be known with certainty. The properties of galena, high metallic lustre, great density and facile cleavage, must have excited the ancients, and such ""stones"" would have been the object of primitive testing111 - Shortly after the discovery of lead, the ancients found that the controlled oxidation of this metal at elevated temperatures yielded smaller amounts of a more interesting material, silver. Again, it is uncertain if the production of silver by primitive cupellation techniques was the result of a fireside accident or the consequence of a deliberate experiment, but the important fact is that silver was produced shortly after the discovery of lead. The techniques for making lead and silver spread gradually throughout the entire civilized world, likely as a result of both technology diffusion and independent rediscovery. The physical properties of lead could not have been overly attractive to the ancients, but silver was a different matter altogether. The gleaming white lustre and relative immunity to oxidation quickly assigned silver to the precious materials category, a status it still enjoys. In early times, argentiferous galena was inevitably processed only for its silver values; lead was generally an unwanted byproduct and was frequently discarded as litharge (PbO) during the cupellation process. The silver was eagerly sought, however, and resulted in considerable mining activity culminating in the famous Athenian silver mines at Laurium at the southern end of the Athenian peninsula."

Jan 1, 1999

By J. G. Henning, T. R. Yu, J. E. Croxall

"Test work was carried out to investigate the thermal response of loose and solid rock under varying environmental conditions. The primary interest was to develop a technique that could be used to increase the thermal variation between loose and solid rock for better detectability of loose rock underground with a thermal imaging infrared scanner.A variety of thermal enhancement methods were evaluated both in the laboratory and in the mine environment. Air temperature variation created by the exhaust from diesel driven, mobile mining machinery was studied in detail. When sufficient hot exhaust was supplied to the air, unsteady thermal conditions became more pronounced on the rock surf ace. This allowed a greater percentage of loose rock to be detected by a high-resolution infrared scanner within minutes.The degree of thermal enhancement of loose rock was found to be dependent directly on the thermal conductivity of rock, looseness, air temperature change, and inversely on the size of loose, airflow rate and distance downwind from the heat source. It was also found that an air temperature rise of at least r c, or rock temperature differential of1°C was necessary for minimal thermal enhancement required f or infrared detection."

Jan 1, 1990

By CIM Standing Committee

The CIM Definition Standards on Mineral Resources and Reserves (CIM Definition Standards) establish definitions and guidance on the definitions for Mineral Resources, Mineral Reserves, and mining studies used in Canada. The Mineral Resource, Mineral Reserve, and mining study definitions are incorporated, by reference, into National Instrument 43-101 – Standards of Disclosure for Mineral Projects (NI 43-101). The CIM Definition Standards can be viewed at mrmr.cim.org. Readers should be aware that reports written by persons issuing technical reports that disclose information about exploration or other mining properties to the public in Canada are governed by a number of securities regulations.

May 10, 2014

One Data Set for the Lifecycle Complete data captured at the logging stage benefits the entire life cycle Exploration Technical Studies Production and Milling Visible Light Spectrum Hyperspectral, put simply, is the interaction of light with matter based on the nature and chemical structure of the specimen. SpectrumWe develop the library to match the liberation size fraction Analyses every 1mm2 1 meter of NQ core = 35 000 analysis data Crystal size detection : 0.1 micron

May 1, 2013

By J. G. Speight

Laboratory studies indicate that autogenous heating of low-rank coal can be prevented by a prior treatment which involves immersing the coal for short (5-15 min.) periods in an inert liquid at temperatures between ~ 350° and 400°C. Such "carbonization" effectively reduces the accessible pore volume of the coal to levels at which heat generation through subsequent sorption of moisture and oxygen is too slow to cause significant temperature rises in a stockpile. In addition, this treatment also irreversibly removes most of the moisture held in the raw coal and raises its calorific value by as much as 10-12%.

Jan 1, 1973

By D. A. Nelson, Wedding. R. E.

"A planned production increase of 1.25 million tonnes per year at Domtar's salt mine in Goderich, Ontario required an increase in the underground mine ventilation system from 320,000 to 700,000 scfm, The design of the expanded facility included the addition of a 22-foot-diameter shaft to augment the existing production and service shafts.A preliminary review of the ventilation requirement s indicated that in order to pr ovide good economic design for the expanded system, a comprehensive ventilation survey of the existing system was required. The survey was completed in the latter part of 1980, and subsequent engineering design and equipment selection proceeded throughout 1981.This paper presents the methods used to carry out the survey. Particular attention is given to the numerous challenges presented in determining air flows in the large 45-ftwide by 43-ft-high airways. Emphasis is placed on practical field survey techniques.A mathematical model of the ventilation system using a computer program is described, and the application of this program to provide design data and assist in equipment selection is discussed. Economic sizing of airways and fan selection are analyzed considering horsepower and operating costs.IntroductionThe Goderich Mine of Sifto Salt Division, Domtar Inc., is located on the eastern shore of Lake Huron in the town of Goderich, Ontario, and has been operating since November 1959. The salt is extracted by a modified room-and-pillar method, and the workings advance at a rate of 1.5 miles per year by undercutting, drilling and blasting. The surface mine area consists of a 12-acre site in the Goderich harbour, at the mouth of the Maitland River, and the underground property consists of approximately 2,700 acres lying mainly under Lake Huron."

Jan 1, 1983

By R. D. Brown

On November 16, 1978, Finance Minister Chretien delivered his second formal budget in the House of Commons. Over-all, the provisions of the budget should provide moderate stimulus to the Canadian economy. With respect to the mining industry, the budget offers some welcome changes in the form of' improved write-offs for development expenses and social assets; higher investment tax credits; and a reduction in federal sales tax. On the other hand, income bond financing of new mineral ventures may be restricted.

Jan 1, 1979

By D. McConchie

BauxsolTM, prepared by treating bauxite refinery residues with Mg2+ and Ca2+, has an excellent ability to remove arsenic from acidic waters. The addition of BauxsolTM to sulphidic waste rock at the Gilt Edge Mine, South Dakota, reduced As concentrations in leachate water from 35 mg/L to < 0.005 mg/L; the concentrations have remained below 0.005 mg/L for the five years since the treatment was initiated. However, ordinary BauxsolTM does not effectively remove As from near-neutral water and it needs to be acid-treated or blended with small amounts of reagents, such as jarosite or ferrous sulphate, to increase the proportion of positively charged binding sites on the particles. The use of a jarosite/BauxsolTM blend can effectively treat ponded water, and As(V) concentrations can easily be reduced from over 1 mg/L to < 0.001 mg/L; As(III) has to be oxidised to As(V) for effective removal. Metal contaminants in the jarosite are trapped by the BauxsolTM and only very small amounts of the As, or other elements bound during treatment, are liberated using a TCLP leaching test. The exhausted treatment reagents meet the criteria for classification as an inert solid and do not need to be disposed of in a secure repository.

Jan 1, 2006

By D. McFadgen

"THE Dominion Steel & Coal Corporation, through its subsidiaries, the Old Sydney Collieries and the Dominion Coal Company Limited, produces 4% million tons of coal annually from eight submarine collieries situated on the eastern coast of Cape Breton Island. The present workings have a frontage of 20 miles and extend 31/2 miles under the Atlantic ocean on gradients varying from 4 deg. to 24 deg. To date, some of the workings have reached .a depth of cover up to 2,800 feet.The pitching seams, the annual seaward advance, the resulting depth of cover and the rdatively soft roof and floor have necessitated the adoption of extensive longwall mining, with room-and-pillar mining con-fined to areas above the 1,000 foot cover line, where 60 per cent of the -coal is left standing in pillars to support the ocean floor. Longwall mining accounts for 87 per cent of the total production with the remaining outputs obtained from room-and-pillar work and the narrow work development. Seventy-four per cent of the longwall production and 41 per -cent of the room and development production is completely mechanized.Although 2 tons of water is pumped from the collieries for each ton of coal mined, the working sections are relatively dry as the heavy make of water is essentially surface drain-age from the land crop areas. The dry workings and the long haulage distances, which in many cases exceed 4 miles, have resulted in a continuing programme to combat the dust hazard, both at the working face and along the mine roadways."

Jan 1, 1960

By Dirige. A. P. E.

A study was conducted for an operating mine to determine the appropriateness of its tailings material to be used for the preparation of a low modulus, high density backfill. The research was initiated due to issues arising from increased observations of compressive failure of backfill placed in stopes and inconsistent backfill behaviour (i.e. increased backfill brittleness and modulus). Backfill materials investigated were classified tailings and de-slimed tailings. Characterization of the physical properties of the classified and de-slimed tailings materials was conducted to assess the effect that these material properties would have on the strength and deformation behaviour of high density backfill products made using them. Such behaviour was investigated to determine whether differences in tailings physical properties would influence the strength and modulus character of the backfill materials. Uniaxial (UCS) and consolidated-undrained triaxial compression strength tests were conducted to determine strength performance and deformation behaviour of backfill. This paper presents the results of the backfill material characterization study and how different particle size distributions affected the strength performance and deformation behaviour of the different backfill mixes. It also demonstrates how stress-strain curves generated from material strength tests were used to evaluate variation in high density backfill mix response when such materials were subjected to unconfined and confined (triaxial) compression loading.

Aug 1, 2013

By W. J. Asselstine

Introduction This paper is prepared from data gathered for a similar paper to be submitted to the United States Bureau of Mines, for publication as one of their information circulars. It covers the history and development of the present milling practice at Premier. The authors wish to acknowledge the assistance and suggestions given during the preparation of this paper by D. L. Pitt, Manager of the Premier Gold Mining Company, Limited; also their indebtedness to various members of the Engineering Staff and of the Accounting Department who have assisted materially in gathering the data used. Location The Premier mine and mill are situated in northern British Columbia, approximately fifteen miles north of the head of Portland canal, in the Salmon River section, about half a mile east of the Alaska-British Columbia boundary line where it crosses die Salmon river. The mill is located on a rather steep hillside on the horizon of the main haulage level of the mine, and is within a hundred feet of the mouth of the tunnel. Both the mine and mill are connected with tidewater at Stewart, B.C., by an aerial tramway (1) eleven and one-half miles in length, which delivers both ore and concentrate to the bunkers at the dock for shipment to the smelters. All mine and mill supplies are transported from Stewart dock to Premier over this tramway, except heavy machinery. Heavy pieces have to be hauled either by truck in summer or sleighs in winter over a good road which runs from Stewart dock to Premier.

Jan 1, 1933

By G. S. Ospanova

The results of complex processing sulphide copper ore and advantages of recovery of copper by vat and heap leaching, sorption, cementation and electrolytic solutions processing and utilization of waste material after heap leaching of copper for production of building materials were investigated. The combined chemical solvents with the additives of oxidizing agents are developed at the KazNTU. The solvents are inorganic or organic chemical reagents, which form complexes of Cu, Au, Ag, Pt, Ni, Sr, Co etc. Recovery of non-ferrous metals from solutions and purification of industrial waste waters is carried out on the base of using new synthetic and natural sorbents (from local raw materials) which are able to bind ions in both cationic and anionic forms depending on type of ligands and external conditions. Optimum parameters of copper sorption were determined. The developed wasteless technologies of copper extraction from sulphide ores with usage of new non-toxic solvents and accessible sorbents with full recycling of water are tested in pilot scale heap leaching, and are recommended as the ecological, economical and practical alternative to traditional methods.

Jan 1, 2007

By K. S. Coley, G. A. Irons, T. Kaneyasu

"It is very important to reveal the lime dissolution mechanism in steelmaking slag, to promote its dissolution without calcium fluoride, which is now almost forbidden for use in most industrialized countries. In this research, the purpose was focused on the development of an experimental method to measure the mutual diffusivity of Ca2+ under the condition of lime dissolution into slag. By forming diffusion couples using a ""vacuum slag aspirating technique"", the method was established. The following mutual diffusivities of Ca2+, in CaO-SiO2-FeO slag systems, imitating oxygen steelmaking slag, were determined using this method:4.1*10-10 m2/s at 1400°C for 27wt.%CaO-53wt.%SiO2-20wt.%FeO slag,4.3* 10-10 m2/s and at 1400°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag, and 1.3*10-10 m2/s at 1250°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag.It was also verified that, if the basicity and ferrite content of the bulk slag are low, then a calcium silicate film forms on the lime surface, and drastically deters the lime dissolution."

Jan 1, 2004

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By Åke C. Rasmuson, Mahmood Alemrajabi, Kerstin M. Forsberg, Kivanc Korkmaz

"In the present study the recovery of a Panasonic Prismatic Module 6.5 Ah NiMH 7.2 V plastic casing hybrid electric vehicle (HEV) battery was investigated, separately processing the anode and cathode electrodes. The composition of the electrode materials was determined by total dissolution and analysis using ICP-OES. Nickel is the dominant metal in the active materials (65% by mass in the anode and 70% by mass in the cathode). Most of the rare earth elements (La, Ce, Nd, Pr and Y) are located in the anode active material, whereas only a small amount of Y is found in the cathode material. The electrode materials were further characterized by SEM-EDS and powder XRD. The electrodes were leached in sulfuric acid and in hydrochloric acid under different conditions. The dissolution was followed by taking out samples and analyzing the concentration of REE, Co, and Ni using ICP-OES. The results indicate that the dissolution of nickel could be limited by slow dissolution kinetics of nickel oxide. Further, it was found that light rare earths are lost through precipitation during sulfuric acid leaching with increasing extent as the temperature and sulfuric acid concentration increases. The separation of REE from the sulfuric acid leach liquor by precipitation as NaREE(SO4)2.H2O and from the hydrochloric acid leach solution as REE2(C2O4)3.xH2O have been studied by performing experiments using battery leach liquors. INTRODUCTIONIt is well known that the Hybrid Electric Vehicle (HEV) is becoming more common due to economic and environmental reasons. Batteries are widely used in HEVs’ such as automobiles or larger trucks for transportation purposes. The most common type of battery in these vehicles is nickel metal hydride (NiMH), largely due to Toyota's decision to use them in their popular Prius. More than two million hybrid cars worldwide are running with NiMH batteries, such as the Prius, Lexus (Toyota), Civic, Insight (Honda), and Fusion (Ford). Panasonic manufactures HEV prismatic NiMH batteries that have been used by Toyota and GM (among others), while Sanyo manufactures HEV cylindrical cell NiMH batteries, which have been used by Honda and Ford."

Jan 1, 2016