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By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By Stephen Hardcastle

Supplying ventilation in underground metal mines can be one of the most energy demanding services required to support production activities. Consequently, as energy, in the form of electricity or combustible fuels can be expensive and their unit cost is expected to increase, there is significant interest in reducing the overall demands of a mine?s ventilation system through such initiatives as controlling ventilation based upon demand and exploring other power alternatives to the current usage of the diesel engine in mobile mine vehicles. However, determining the benefit of any energy saving technology is complex and not universal applicable across the industry, consequently they have not been widely adopted. For these technologies to succeed they must be strategically applied based upon sound business cases. The intent of this paper is to provide information on some of the prospective control strategies and their potential impact on the power consumption related to supplying ventilation.

May 1, 2007

By H. Wotruba, K. Neubert

Dual-energy X-ray transmission (DE-XRT) imaging is known from safety luggage inspections at airports. The use of DE-XRT technology for sorting applications in the primary raw materials industry has been the subject of numerous investigations. Beside other metal ores, X-ray transmission sorting is already used for the preconcentration of tungsten ore, gold ore and coal. The applicability of DE-XRT sorting is limited to ore types where differences in metal concentrations are measurable, based on an interpretation of X-ray images. Metal contents in particles occur in large varieties in terms of concentration, grain sizes, spatial distribution and mineralogy and therefore influence the X-ray absorption. As a result, each ore has to be tested individually for its suitability for DE-XRT sorting. The objective of current research at the Department of Mineral Processing (AMR) at RWTH Aachen University is to assess parameters influencing the detectability of rare earth oxides. Two approaches were followed: (1) Practical test work, based on artificial ore samples of defined compositions and (2) Computer-based simulation of absorption features of identical particle compositions. In total, more than 300 artificial samples of various compositions and metal grades were produced and X-ray images from DE-XRT sorting were analyzed. Results from the DE-XRT sensor were put into correlation with metal grades and particle sizes, to analyze influences and limits on the detectability of rare earth oxides. In addition, a new approach was tested in which the X-ray absorption of particles of various compositions was determined based on a Monte Carlo (MCNP) simulation. During the simulation, similar compositions, as used for the artificial samples, were tested and the X-ray absorption behavior during DE-XRT sorting was determined. A comparison of results from both approaches is used to assess the applicability of the MCNP-simulation for the prediction of the X-ray attenuation behavior during DE-XRT sorting.

Jan 1, 2016

By F. Lindroos

A cornerstone in the LKAB Green Pellet concept is to produce pellets with a small footprint in terms of energy con-sumption, CO2 emission and emission of other elements harmful to the environment, like dust, sulphur dioxides, nitrogen oxides, chloride and fluorine. The concept also encompasses our determination to make pellet products that contribute to low environmental impact and low energy consumption in our customer?s processes. The presentation will focus on the pelletizing process. It will describe both how we have attempted to decrease the generation of unwanted components in the process gas, and how we have tested or evaluated equipment for external gas cleaning. We will discuss and give examples from recent and on-going efforts and outline some of the future challenges we see, to meet our own environmental standards and also the tough demands imposed by EU and national legislation, while striving to boost production.

May 1, 2011

By W. T. Robson

LAKE Shore Mines, Limited, with property at Kirkland. Lake, Ontario, was incorporated m 1914 and commenced product10n m March, 1918, with an initial capacity of about 60 tons per day. Since that time a gradual expansion has taken place until a present capacity of approximately 2,300 tons per day has been reached, giving a total annual gold production valued at approximately $16,000,000. At the time of incorporation of the Company, the Lake Shore property consisted of four mineral claims and four fractions, totalling 171.05 acres. In 1934, four claims belonging to the Minaker Kirkland Gold Mines, Limited, were acquired and a controlling interest purchased in the Kirkland Hudson Bay Gold Mines, Limited. Both these properties adjoin the Lake Shore claims on the south. From the accompanying compilation of the world's largest gold mines for 1934 (1), it will be seen that, while Lake Shore holds sixth position in respect to the number of ounces produced, there are twenty-five gold mines which treat a greater tonnage of ore. This is an indication of probably the most unusual feature of the Kirkland Lake deposits, namely, the high aver-age tenor of the ores. coupled with the comparatively large tonnages available.

Jan 1, 1936

By D. P. Tripathy

A supply chain encompasses all the activities associated with the flow and transformation of goods from the raw materials stage(extraction), through to the end user. Supply chain management (SCM) is the integration of these activities through improved supply chain relationship, to achieve a sustainable competitive advantage and it rests on its ability to provide the right goods and services when and where needed. The supply chain is the vital component of any company?s value chain which links the operating processes to its supplier and customer. The globalization of business promises to offer new and unique challenges for the supply chain competencies of most firms. Challenges will also increase in the environmental aspects of supply chain often referred to as ?Green Issues?. The supply chain of mining industry comprises of the flow of material and information from the mine site, to processing and loading for transport, to the customer. However, due to recent changing environmental requirements affecting mining and mineral processing operations, increasing attention is given to developing environmental management (EM) strategies for the mineral supply chain. This paper focuses on: ? Environmental factors leading to the development of an extended environmental supply chain, ? Additional challenges presented by the extension, ? Performance measures appropriate for the extended supply chain, ? Developing a general procedure towards achieving and maintaining the green supply chain.

May 1, 2006

By H. Zhu, Q. Jiang

The leaching kinetics of iron during the atmospheric direct leaching (ADL) of marmatite concentrate was studied under the following conditions: reaction temperature of 343-383 K, slurry pressure of 0.3-0.7 MPa, particle size of (-74 ?m, +63 ?m), (-63 ?m, +44 ?m), (100%-44 ?m). The statistical effects of reaction temperature, total pressure and particle size of concentrate on the extraction and the leaching rate of iron were analyzed. The results show that reaction temperature is a significant factor while slurry pressure and particle size are not statistically meaningful with respect to the extraction or the leaching rate. The extraction of iron fits better to the mixed-controlled shrinking core model and the apparent activation energy was calculated to be 37.66 kJ/mol. The leaching of iron is mixed controlled by the interfacial chemical reaction and diffusion across the product layer.

Jan 1, 2014

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By Jun Wang, Bo Zhang, Wenqing Qin, Guanzhou Qiu, Xiaozhen Ma, Key Lab of Biohydrometallurgy of Ministry of Education, Fen Jiao, Central South University, Yansheng Zhang

"Arsenic contained in minerals sulphides such as enargite and tennantite can represent not only a significant penalty element in base metals production, but also a disadvantage to the environment through producing the toxic emissions to the atmosphere. The achieving separation of arsenic bearing minerals either at an early stage in floatation or from the floatation concentration is significantly beneficial to the economic. However, there was no feasible commercial method of separation at the flotation stage because of its similar flotation properties with many other copper sulphides. In this work, the selective floatation of enargite from copper sulphide concentrate containing maily covllite, chalcoctie, bornite and enargite was investigated. A low arsenic concentrate with As 0.2%, Cu 22% and a high arsenic bulk concentrate with As 7.65%,Cu 33.65% were obtained. It was indicated that Ca(ClO)2 is the effective depressor and the optimum floatation condition was obtained. Most enargite could be floated at pH 11 and controlling the pulp potential at 290 mV SHE. Furthermore, the arsenic removal from the high arsenic bulk concentrate by hydrometallurgy methods was study. The results showed that the reaction temperature and the concentrations of NaOH were the most important variables affecting the rate of arsenic removal. A low arsenic concentrate with As 0.24%, Cu 37.80% was obtained in the optimum leaching condition.INTRODUCTIONArsenic is mainly produced as a by-product of base metals smelting, in particular copper concentrate. China has imposed an upper limit of 0.50% arsenic for concentrates entering (Long et al., 2012). Arsenic amount of copper concentrate within 0.40% has also been imposed in China, and above which will be introduced about 50 RMB penalties per ton for each 0.10% increasing by smelters now. Therefore, it is necessary to remove arsenic from the copper concentrate.In copper concentrate, arsenic is mainly in the form of arsenopyrite (FeAsS), enargite (Cu3AsS4) or tennantite (Cu12As4S13). There are two types of arsenic in the separation of copper and arsenic: arsenopyrite and arsenic bearing copper mineral. It is easier to separate arsenopyrite from the copper sulphide by flotation in comparsion with the separation of enargite or tennantite from non-arsenic copper minerals (Pineda et al., 2015). The main difficulty in the separation of arsenic copper mineral from non-arsenic copper sulphides is their extremely similar floatability, which depends on the fact that tennantite and enargite contain high copper content (Pineda et al., 2015)."

Jan 1, 2016

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By M. A. Bergougnou, I. Inculet, K. I. Burgess

This paper describes the electrostatic methods of separating various minerals, reviews the principles of fluidization and outlines the technique of electrostatic sorting in fluidized beds. The application of the method to the benefication of coal is emphasized.

Jan 1, 1970

By P. Cicmanec

Mining activities in the territory of Slovakia have a long history. Mining techniques have developed rapidly in the last centuries. This paper deals not only with mining history, but also with underground brown coal mining, magnesite mining and other mining activities at present and sustainable developments of the mining industry in the Slovak Republic. This paper looks forward in the context of mineral raw materials in Europe (Global Europe, 2012).

Aug 1, 2013

By Steven W. Wilson, Brigitte Lacouture, Nichola A. McKay

"The Aqqaluk deposit is a lead-zinc ore body that lies immediately north of the Main Pit at Teck Cominco’s Red Dog Mine in Alaska. It is scheduled to begin production in 2011 or 2012. A project team was formed in late 2004 to plan and implement an ore characterisation and metallurgical evaluation on the Aqqaluk ore. The main objective of this program was to facilitate the transition from Main Pit to Aqqaluk ore in the Red Dog concentrator. The program will develop a detailed, spatially-oriented characterisation of the Aqqaluk deposit attributes including lithology, ore geochemistry, bulk mineralogy, ore texture, as well as evaluating the metallurgical characteristics of ore hardness, process water geochemistry, bench-scale floatability and mineral liberation in ground feed, concentrate and tails. Developing correlations between the metallurgical response and the ore characterisation data is key to the emerging science of geometallurgy. This on-going program is a technical due diligence study that aims to reduce the risk associated with processing a new ore and to provide predictive information for mining and stockpile preparation.The test work to date has focused on characterising the five ore zones currently identified in the Aqqaluk deposit, namely: Siliceous (sub-divided to High Zn:Fe and Low Zn:Fe), Vein, Median Plate and Baritic ores. It identified a number of challenges associated with surface oxidation, or weathering, of the core samples and outlined a program for future sample collection and storage. Metallurgical testing evaluated ore hardness by a variety of methods. Preliminary floatability studies have been completed and some initial links have been established between the ore characteristics and the flotation response. Soluble mineral weathering products, the relative abundance of pyrite and marcasite and the iron content in the sphalerite grains have all shown a correlation to mineral recovery.As new core is received, both the ore characterisation and the metallurgical testing will be continued with a view to strengthen the existing correlations and develop new links."

Jan 1, 2007

By Stanley Davidson

"This description of the structural geology of the Beattie mine has been condensed from a more comprehensive paper published previously (4).The property is in western Quebec, a short distance east of the Ontario boundary on the extension of the so-called Porcupine belt into Quebec.According to the geological surveys of the Dominion and Provincial Governments the regional structure in the vicinity of the mine is an easterly pitching, overturned syncline with several thousand feet of Timiskaming sediments in the centre surrounded by Keewatin volcanics (1, 2, 3).The mine lies on the north limb of the syncline, and the Keewatin series in this locality is, with few exceptions, overturned, dipping steeply north and facing south.The mineralization is closely related in space, and possibly genetically, to a body of syenite porphyry intruded into the Keewatin series along the north limb of the syncline. No ore has been found very far from the syenite or related lath-porphyry dykes, and the largest orebodies are composite, consisting of bleached and brecciated volcanics ( primarily tuffs) adjacent to altered syenite porphyry, both silicified and mineralized with very fine pyrite and arsenopyrite. In addition there are important ore shoots following a fracture zone within the syenite."

Jan 1, 1954

By A. Piche, J. Nantel

"This paper describes the recent developments in Canada toward the establishment of a Canadian Centre for Mining Automation and Robotics, at McGill University and École Polytechnique in Montreal. The role of the Mining Association of Canada (MA C) and of the National Advisory Committee on Mining Automation will also be reviewed. IntroductionIn order to remain competitive, the mining industry must increase its productivity and reduce its costs. In the last two decades, this objective has been achieved through mechanization. From now on, any further improvement in productivity will be gained through increasingly more automated mining equipment.Recent international developments following the Versailles Economic Summit in June 1982, having given rise in Canada, to a renewed interest in applications of robotics and automation to mining.The mineral industry in Canada is at a crossroads. Competition in emerging from everywhere: lower grade ore bodies, increasing distances between viable mines and markets, third world massive production of certain commodities, substitution of "" space age"" materials (ceramics, plastics, composites, etc.) for metals.On the positive side, it is generally believed that present mineral commodities, i.e. base metal, gold, iron, industrial mineral s, etc ., will continue to be in high demand for centuries to come despite substitution. New applications for conventional metals will be found and the enhancement of certain properties of these conventional metals mean continued demand. For some mineral commodities, there will never exist an y substitute."

Jan 1, 1988

By L. Jiang

This report investigated the dynamic recrystallization (DRX) phenomenon in magnesium alloy AZ31 billets to understand the deformation mechanisms and microstructure evolution during extrusion and other metal forming processes, Compression tests of coarse-grained as-cast magnesium alloy billets containing lamellar Mg17Al12 eutectic phase and (Al, Mn) particles suggest that temperatures higher than 300°C, strains greater than 0,25 and strain rates above 0,l/s lead to the formation of fine DRX grains in the deformed samples. Microstructural observations also indicate particle-stimulated DRX nucleation (PSN) during hot deformation of the AZ31 alloy, facilitated by the presence of Mg17Al12 and (Al, Mn) particles, While the Mg17Al12 is dissolved into the matrix at about 350°C, (Al, Mn) particles may remain effective for PSN at temperatures up to at least 400°C, This study suggests that alloy design with a proper distribution of second-phase particles can provide the desired microstructure for improved properties and formability in wrought magnesium alloys.

Jan 1, 2004

By D. Atkinson

"Porphyry molybdenum-tungsten mineralization on the east flank of Hudson Bay Mountain crops out over 5 km2 and is intersected to depths of 2 km. Features such as a hornblende-biotite aureole, mineralogical zoning and dike, vein and fracture geometries within lithologies of the Middle to Lower Jurassic Hazelton Group and Cretaceous Skeena Group reflect an intrusive complex, the Upper Cretaceous to Early Tertiary Hudson Bay Mountain stock which has been intersected by drill holes. The stock is believed to be the mineralizing agent. A southeast-dipping granodiorite sill has been outlined by drilling within the Hazelton Group. Molybdenite and scheelite veins cut all rock types; however, the granodiorite sill hosts a higher density of fine-grained, banded, quartz-molybdenite and pegmatitic quartz-molybdenite veins reflecting a competency contrast between the intrusive sill and other country rock. Due to the relative abundance of these veins, grade is higher within areas of the sill. Above the 15000£ cross-cut 20.6 million tonnes grading 0.401% MoS2 and 0.041% W03 have been defined. During exploration of the deposit sampling procedures had to be adjusted because of the nugget effect attributed to drill intersections of banded and pegmatitic veins.IntroductionMolybdenite was discovered in outcrop at the foot of Kathlyn Glacier on Hudson Bay Mountain and first reported by the Geological Survey of Canada in 1944. The deposit has several names: Hudson Bay Mountain or Glacier Gulch, both after its location, and Yorke-Hardy after the original staker.The deposit is on the east flank of Hudson Bay Mountain, 9 km northwest of Smithers, west-central British Columbia, within NTS area 93L/14 (54° 49' North, 127° 18' West, Fig. 1). Hudson Bay Mountain, on the southern edge of the Bulkley Valley, is a dominant topographical feature reaching 2590 m elevation. Mineralization is partly overlain by the Kathyln Glacier which is visible from Highway 16. Access to the 3100 m of underground development is from a portal at 1066 m elevation on the east slope of Hudson Bay Mountain."

Jan 1, 1995

By Y. S. Sun, Northeastern University, W. B. Li, P. Gao, Z. Y. Zhang, J. W. Yu

"The boron-bearing iron concentrate was extracted from ludwigite ore by the process of magnetic-gravity separation. In order to fully utilize the refractory ore and meet the boron consumption of China, a novel process for separation of boron from iron in boron-bearing iron concentrate was proposed in this paper. In particular, laboratory scale experiments of improving boron reactivity were performed. Fine boron-bearing iron concentrate briquettes were reduced by bituminous coal completely at 1125 °C for 150 min. The effect of sodium carbonate, which was used as an additive in the roasting process, was investigated. The addition of sodium carbonate decreased the boron reactivity and facilitated the volatilization of boron. The influence of diverse cooling methods of the reduced samples on the boron reactivity was studied. The results indicated that boron reactivity could reach up to 80.76% when the reduced samples were cooled by rapid water quenching. In addition, the magnetic material containing 92.71 % Fe with a recovery of 95.11 % and boron-rich non-magnetic material containing 14.51% B2O3 with a recovery 88.85% could be obtained by low-intensity magnetic separation. The magnetic material and boron-rich non-magnetic material were good raw materials for steel-making and borax production, respectively.INTRODUCTION Ludwigite ore is abundant in Liaoning province of China, with 28.43 Mt B2O3 accounting for 57% of the boron resources of the country (Liu et al., 2006). However, it has not yet been utilized on an industrial scale due to its complex mineralogy and fine mineral dissemination (Wang, Wang, Ding, Ma & Xue, 2012). At present, boron-bearing iron concentrate and boron concentrate can be obtained from ludwigite ore using magnetic-gravity separation. The boron concentrate contains B2O3 12%~16%, which can be used as a high-quality raw material for the boron chemical industry after activated roasting, but the B2O3 content in the iron concentrate reaches up to 4%~6%. In order to further separate boron and iron from boron-bearing iron concentrate, a blast furnace and a solid pre-reduction followed by electric arc furnace melting have been proposed (Liu, Cui & Zhang, 1998; Wang et al., 2012). However, both of these two current routes face the same crucial problem that molten boron-rich slag has to be cooled slowly to obtain the alkali-dissolution activity of boron, which affects the yield of boron resource."

Jan 1, 2016

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By D. K. Fountain

"High metal prices and advanced technology in open-pit mining methods have resulted in considerable interest in the development of large, low-grade mineral deposits. Brenda Mines Limited is presently testing such a deposit of copper-molybdenum mineralization near Penticton, British Columbia.The mineralization of economic interest at Brenda has a total metallic sulphide content of between 1 and 1.5 per cent. This sulphide content approaches the limits of detectability of standard geophysical methods. How-ever, due to a favourable geological environment, it has been possible to utilize the Induced Polarization Method to outline the mineralization at the Brenda property."

Jan 1, 1968