Search Documents

By V. Prostakova, M. Shevchenko

The copper smelting gas / slag / matte / metal / solids system with the Cu-Fe-Ca-Si-O-S major elements has been a long-term focus of the present overall research program using integrated experimental and modelling approach for the phase equilibria characterisation and development of a thermodynamic database. A systematic investigation of phase equilibria of slag systems in equilibrium with Cu metal is providing information for systems where copper coexists in slag with lead, zinc, and aluminium oxides as major components. Experimental studies involve high-temperature equilibration of synthetic samples; rapid quenching; and measurement of the compositions of equilibrium phases using electron probe X-ray microanalysis (EPMA). Particularly important feature of the present study a wide range of temperatures (660-1670°C) being characterised that reveals major inconsistencies in the existing thermodynamic description of the multicomponent system, and allows to establish the thermodynamic properties from phase equilibria in a reliable way. FactSage-based thermodynamic modelling is integrated with experimental research. Initial thermodynamic assessments are used to identify priorities for experiments, planned to provide specific data for thermodynamic optimisation. Significant improvement in the accuracy of the phase equilibria description is achieved, in particular in the PbO-Cu2O-SiO2, ZnO-Cu2O-SiO2, and Cu2O-CaO- Al2O3 systems in equilibrium with metallic Cu. INTRODUCTION Slags high in lead and copper are generated in primary metal production in the smelting of lead sulfide concentrates and in pyrometallurgical metal recycling systems. The compositions of these slags are varied due to increased fraction of recycled materials in the feed as well as introduction of previously unused chemical elements to modern technology. Therefore, their processing becomes chemically more complex; in that way they contain a large number of different metals. These slags form complex non-ideal solutions (with possible formation of several immiscible slags) that can coexist with stoichiometric solids, solid solutions, mattes and molten metal depending on the bulk composition and process conditions. Predicting the outcomes of smelting and refining processes is becoming increasingly difficult. To assist in the optimisation of these metallurgical processing operations, a comprehensive research program is underway to develop accurate thermodynamic databases for these non-ferrous process systems.

Jan 1, 2019

By MacDonald W. L. F. C. A.

IN accordance with the usual approach to a participation in a panel discussion, this paper is, in some respects, intentionally controversial. I would suggest, how-ever that there is more than a grain of truth in many of the comments made. Before dealing with a particular problem. It is appropriate to set out a few of the more significant objective of an: accounting system: (1) The provision of historical data <•concerning past events, for the information of shareholders, tax authorities, etc. This data can also be used as a tool to predict the future. (2) The provision of a record to safeguard the company's assets and to form the basis of any claim for insurance or other damages. (3) The provision of an accounting framework in making an economic study of a proposed course of future action such as the development of an orebody or the outlay of a substantial sum for new equipment. ( 4) The

Jan 1, 1962

By D. J. Houlahan

ABSTRACT Sorting has the potential to massively improve the pro?tability of mining base metal, hard-rock ores. However, several barriers to the increased application of sorting have been identi?ed, including a lack of mineral-speci?c sensors available to the industry. This paper presents the outcomes of acollaborative project to develop an induction-balance sensor speci?cally for low-grade copper and nickelores. A review of the basic principles of induction-balance sensing and of the sensor-rock interaction is presented. Early development and testing of the sensor on ores from the Thompson nickel belt in northern Manitoba is discussed. Shortcomings of the prototype identi?ed in early testing have now been over-come, leading to improvements in design and construction, as well as sensor accuracy. The improve dsensor has now been tested on additional ores from the Sudbury Basin, with good results. A discussion of potential applications is presented and recommendations for future development are made.

Jan 1, 2010

By D. Groenveld, M. Rozou

"Recent trends move towards automation, smart sensors, internet of things, powerful DCS, and more data. Are those trends already utilized in a real time production environment? Today operators still have to monitor several complex processes at the same time and predict their behavior based on an overwhelming amount of data available.The fact of the operator being overloaded and humans being unable to process multivariable problems shows the need of a tool merging essential data and providing consistent, sound decisions for long-term profitability.This paper shows a successful execution of ABB’s process improvement services in Aitik (Boliden SA), a copper mine located in Sweden. Soft sensors, fuzzy rule blocks and model predictive control were seamlessly integrated in the control system of the grinding area, resulting in proper control of mill loads and particle size without violation of any constraints.INTRODUCTIONDepending on the ore characteristics and the targeted plant capacity, the design of the grinding circuit may vary significantly. Typically, the circuit consists of several mills (rod, ball, SAG, AG) in series and/or parallel with a number of classifiers and sumps at appropriate locations. The goal of the grinding section is to reduce the ore particle size to a level that enables efficient separation between gangue and precious metals in the subsiding processing step. The trade-off between quality and quantity has to be made. It is also crucial to execute this process step at the lowest possible energy and grinding media consumption.An optimal grinding process controller must manage to maintain a given fresh feed level while keeping the product size within a given range without violating any constraints such as power, torque or load limits. To accomplish the aforementioned, it is necessary to manipulate the ore feed rate, water feed rate and the mill speed. The most significant disturbances adding another degree of complexity to this control problem are ore hardness and the amount of circulating load."

Jan 1, 2016

By A. Takala, B Nielson, J. Schunicht

"Pre-concentration in minerals processing presents clear advantages in energy efficiency, water efficiency, reduction of consumables and minimization of capital and operating costs. Outotec’s sorting solutions are powered by Tomra Sorting in order to achieve pre-concentration of concentrator feed in a variety of mineral processing applications. Sensor based sorting combines advanced sensors with rapid computational evaluation and mechanical separation of valuable material from waste and/or gangue. Modern sensor based sorting machines typically use fine air jets to propel individual rocks, thus optimizing recovery and minimizing “mis-sorting”.Gold is generally present in such low concentrations that sensors suitable for ore sorting cannot directly detect it. Therefore, in order to sort gold ore, properties of associated host rock are used. Free and sulphidic gold is often hosted on the quartz-host rock contact zone. Laser scattering effect can be used to detect the surfaces of quartz and composite quartz-host rock particles for subsequent sorting with very high recovery of 95 to 99%. In addition, ore often preferentially fractures along the quartz-host rock contact zone in the crushing circuit. This behavior helps because it liberates more quartz for detection.The feasibility of sorting is investigated for four gold projects in Northern Europe with similar mineralogy. This includes geometallurgical evaluation, amenability testing, small scale “mini-bulk” factory testing in full scale sensor based sorting. The results of the various tests are presented and basic feasibility demonstrated with information on flow sheet development. In addition, the amenability process is evaluated and recommendations made for future projects."

Jan 1, 2017

By J. R. Hart, V. C. Smith, V. P. Babarovich-Hansen, J. H. Schubert

"An introduction and case study of Mintek's latest generation of Milling Circuit controller, the MillStarTM with IES (Interpreting Expert System) is presented. This paper also describes as a case study its installation on a Southern African base metals concentrator plant which has demonstrated improved operation, greatly reduced variation in product quality, as well as increased capacity and availability of the circuit.In this case study, the MillStarTMw as installed along with several other enhancements, including hydrocyclone underflow monitoring, product particle size estimation and flotation circuit stabilisation. MillStarTM utilised the particle size measurement to control grind to within 2% of setpoint, all the while ensuring sump level control, density control as well as mill power optimisation. Mintek' s expertise in the modelling of tumbling mills allowed the development of a specialised optimising controller that ensured the mill was kept in the most efficient operating region.MillStarTM augments the automatic control with useful user interface features, such as on-line trends of any logged variables, historic data warehousing and retrieval and production summary reports.A novel feature that distinguishes the MillStarTMi s the IES (Interpreting Expert System). This is a feature of the software that works with the automatic control code to generate explanations for control actions made by the controller. Often complex control systems are mysterious in nature, reducing trust and eventually resulting in them being switched off. The IES method of exposing the heart of the controller has proved popular and is seen to have potential as a training tool. 314"

Jan 1, 2000

By Jacob Masliyah, Zhiang Zhou, Dharamdat Christendat, Tshitende Kasongo, Kevin Hyland, Zhenghe Xu, Ted Kizior, Douglas Cox

"A novel on-line visualization system, previously developed at Syncrude Canada Ltd., has been modified to characterize rising bubbles, particles and particle-bubble aggregates in a flotation process. With this system, the bubble size and rise velocity in a laboratory flotation cell can be determined. The technique allows the loading of solids on bubbles to be visualized, thereby providing an in-depth understanding of sub-processes of flotation. A step-by-step data processing procedure is presented. The applicability of the developed system to mineral flotation and bitumen extraction is discussed. Under batch flotation conditions in a laboratory Denver cell, three main bubble-particle attachment patterns are observed. They are: i) single particles attached to single bubbles, ii) particle aggregates loaded on single bubbles; and iii) a group of particles aggregated with a group of bubbles. The results demonstrate that the on-line visualization system is a powerful tool for understanding and diagnosing flotation processes.INTRODUCTIONAir (Gas) bubbles are an indispensable component in a flotation system. Both industrial practice and theoretical analysis indicate (Yoon, 1993; Diaz-penafiel and Dobby, 1994) that the size and population of bubbles are two important process parameters in modeling flotation. More recent investigations (Finch, et al., 1999; Gorain, et al., 1997) suggest that for a given flotation system, bubble surface area flux, defined as the air liquid interfacial area per unit time and unit cross-sectional area of flotation cell, showed a better correlation with the flotation rate constant. As a result, the bubble surface area flux is now being considered as a key parameter to account for the combined effect of bubble size and population in evaluating the performance of flotation machines and modeling flotation processes. However, the success of using bubble surface area flux in flotation process modeling largely depends on how accurate it can be determined or estimated (Finch, et al., 1999)."

Jan 1, 2000

By Thorndycraftm R. B.

"PURPOSEThe purpose of this presentation to the Canadian Mineral Processors is to review gold heap leaching systems currently in use and discuss their applicability to Canadian ores. The author's experience with the development and operation of heap leaching spans the past four years at. Pinson, and visits to many ether heap leaches in the western United States.INTRODUCTIONBy way of introduction to the heap leaching system, I will describe in slight detail the method used at Pinson Mining in northern Nevada. This will be followed by a discussion of optional methods in use at other operations visited.The Pinson orebody is a finely disseminated, well-oxidized hydrothermal deposit. Gold particles are finer than 20- microns. The orezone hostrocks are metamorphosed and silici¬fied limestone and shale. Sulfides and carbonaceous materials are negligible.The Pinson open-pit mine has operated since June 1980. It produces 1500 tpd of C.I.P. mill feed averaging .10 oz gold per ton, and 1500 tpd of heap leach material averaging .025 oz gold per ton. Cutoff grades are 0.04 for mill feed, and 0.01 for heap leaching. Stripping ratio is 9 tons of waste and leach grade to 1 ton of mill feed.The project is located in northern Nevada at 4900 feet above sea level.,Winters are fairly severe, with freezing conditions affecting operations from early December through April. Although officially designated as ""high-mountain desert"" country, snow and/or freezing rain occur almost every week of the winter.To date, all Pinson production-scale heap leaching has treated run-90,000 tons of ore are stacked on 300 foot square clay leach pads. Cyanide leach solution is applied through ""wobbler"" sprinklers at .0025 gpm/sq ft for 60 to 90 days. The pregnant solution flows from the heap by gravity to plastic-lined ditches, into a collection sump and then through buried piping to the 2.2 million gallon pregnant solution pond."

Jan 1, 1984

By Terry Keough

Contents for discussion ?Current liner technology ?Innovation of magnetic products ?Development of magnetic wear liners ?Installation and change out method ?Uses and capabilities ?Internal wear liners ?Summary Vulcanized rubber ?Many of you are familiar with using vulcanized rubber to provide wear protection on mining equipment. For years, this was the standard for most mining equipment, and mines spent a lot of money fabricating and lining steel equipment.

May 1, 2010

By D. A. Whitley, R. P. Carone

"Shaft sinking by blind shaft drilling offers the mining industry a different approach to shaft construction. Benefits of blind drilling include less construction time and fewer safety problems while being economically competitive with conventional sinking methods under certain conditions in soft water-bearing formations.Technology and equipment are available today to drill blind shafts up to 20 feet in diameter and over 3,000 feet deep. This is an extension of proven techniques developed by private industry. To drill a 20-foot-diameter hole requires a specially manufactured hydraulic drill unit with a rated hoist of 2 million pounds and 500,000 ft/lb of torque.This brief paper will discuss the following aspects of blind shaft drilling:• benefits;• equipment f or drilling;• circulation methods;• circulation rates;• shaft alignment; and• progress rates to be expected.IntroductionShaft sinking by blind shaft drilling offers the mining industry an improved alternative method for shaft construction. The drilling of 20-foot -diameter shafts to depth s in excess of 3,000 feet can be done by utilizing equipment specifically designed and manufactured for this purpose. This equipment is a distant cousin, at best, to standard oil well drilling rigs. The actual configuration of these drilling machines will be discussed in a following section.To most people, the drilling of mine shafts may seem to be a new or at least recent technology. However, as early as the I920s, German and Dutch miners were drilling 24-foot diameter shafts for coal mines. What led ""miners to resort to drilling were ground conditions that still plague conventional shaft sinkers today: soft , water-bearing formations. The major drawback to these early attempts was a low penetration rate due to poor bit cleaning. This, however, was not the end of early shaft drilling activity. From 1936 to 1950, a number of mine shafts were drilled by the calyx or coring method. This method employs a bit with a large bore down the center. As it drills, it cuts a core. When 5 to 10 feet have been drilled, the core is removed. The disadvantages of this method were the time and work involved in breaking the core free, and it was inadequate in soft water-bearing ground."

Jan 1, 1981

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By T. H. Etsell, P. Kerr, Qi Liu

"The objective of this investigation was to study the reaction mechanisms during the reduction of iron oxides in the presence of calcium chloride and carbon black as a simplified iron segregation process. The gas phase was analyzed by mass spectroscopy and the solid reaction products were analyzed by scanning electron microscopy. Mass spectroscopy, combined with thermogravimetric analysis and differential scanning calorimetry, revealed the presence of several gases at elevated temperatures over time, and the scanning electron microscope in combination with energy dispersive X-ray analysis illustrated the growth of a metallic iron phase on or near the carbon substrate. The results correlated well with similar copper and nickel segregation processes, but also introduced new insights that challenge the simplicity of the current models. The formation and transport of gaseous iron species to the carbon substrate in the presence of steam and hydrogen were evident during the reduction process that was studied; however, there is more happening at a mineralogical level, based on evidence of a liquid phase resulting in substantial growth due to an apparent fluxing effect created by the calcium chloride.These results help to better explain the chemical reactions and, in turn, the thermodynamics and kinetics of iron segregation processes related to the beneficiation of low grade complex iron ores. The results are also applicable to the production of metallic iron and concentrated titanium dioxide from ilmenite ores. The benefit of this process is that it allows ores in which the iron minerals are intimately associated with gangue minerals to be processed in circumstances where conventional mineral processing techniques are unsuitable or incapable of upgrading the material."

Jan 1, 2016

By K. Norris

"The Campbell mill has undergone numerous changes over the past 43 years. However the rate of change has increased significantly in the last 4 years. A new grinding circuit, carbon-in- pulp circuit, pressure oxidation plant, and column flotation circuit are all new additions. Other changes have occurred in the last 2 years including a large reduction in sodium cyanide consumption, and the introduction of a computer controlled grinding circuit. More improvements are planned in the next 2 years. Some of these improvements include the construction of an effluent treatment plant, and the replacement of filtering and Merrill-Crowe precipitation with carbon-in-leach and electrowinning.Recent changes and improvements to the Campbell mill are a commitment by Campbell mill personnel and Placer Dome Inc. to decrease operating costs, increase gold recovery and gold production, improve industrial hygiene and safety, and meet environmental compliance with current government legislation.INTRODUCTIONThe Campbell Mine has been and continues to be one of Canada's premier gold mines. Campbell Mine is 100% owned and operated by Placer Dome Incorporated. Milling of ore commenced in 1949 at a rate of 300 tons/day producing 58,000 ounces per year of gold. In 1992 Campbell Mine will mill 1340 tons/day of ore at a grade of 0.6 ounces/ton, producing 275,000 ounces of gold at a cash cost of $205.00 Cdn./ounce.This paper discusses some of the changes that have been made to the Campbell mill in the past 4 years. The flowsheet has undergone extensive changes and will continue to change rapidly in the next 2 to 3 years. A simplified flowsheet of the Campbell mill is shown in figure 1."

Jan 1, 1992

By Melanie Grob

Two commonly estimated fractal dimensions, called b and D values, represent statistical characteristics in the distribution of magnitude sizes (b) and spatial hypocenter locations (D) of microseismic events, respectively. We postulate that the values of b and D are related to specific stress regimes. Through different case studies of fluid injection into an oil/gas reservoir or geothermal field, we infer that the measured temporal variation in fractal dimension b is most likely due to significant changes in the local stress regime. The fracture dimension D indicates the spatial clustering of events. The distribution of these events can vary with time because of stress perturbations that (re)activate fractures whose direction favours their movement under a specific stress regime. Thus a combined statistical study of these two dimensions can help infer the variations of local stresses in a reservoir.

Jun 1, 2012

By A. Kobzhanov, S. Saparova, S. Brochot, D. A. Mango

KATCO (an ORANO Mining and Kazatomprom joint venture) is the largest in-situ leach uranium mining operation in the world, exploiting the Muyunkum and Tortkuduk uranium deposits in southern Kazakhstan. After extraction from the deposits, uranium is then transported via a hydraulic network to be purified in three processing plants located near these deposits. Within KATCO, with the support of ORANO Mining and CASPEO, in 2018 and 2019, a large project that had as its main objective to improve the uranium accounting system was implemented. The objective of this paper is to describe this project and all the changes that it entailed. At KATCO plants, a black-box approach was previously used for uranium accounting. However, it is recommended to use all the available measurements and to deploy a data reconciliation model (between well-fields and plant) as the reconciliation uncertainty is overall lower and it provides a more accurate uranium balance. During the deployment of this project, the rules and algorithms to generate the uranium accounting report, the associated flow diagrams (for uranium accounting), the streams, units of operation, stocks, reporting and Key Performance Indicators calculation rules were re-defined.

Jan 1, 2020

By W. Dresler

"A major Canadian chromite deposit at Bird River, Manitoba is one of the largest known chromite reserves in North America but it exhibits low chromium contents and low chromium to iron ratios. Commercial beneficiation techniques permit these ores to be upgraded to concentrations which, however, remain inferior to most other ores and concentrates used worldwide f or production of high-carbon ferrochromium. Analyses for reduction of low-grade concentrates by submerged-arc electrofurnace techniques predict chromium contents between 45.9% and 51% for a high-carbon ferrochromium alloy. Relatively high over-all chromium recoveries between 79.5% and 91. 1% can be achieved. Alloy compositions for Cr, Fe, C and Si are determined for various burdens with low-grade concentrates. Consumption data per ton contained chromium are obtained for electric power, coke, concentrate, quartzite and limestone. The data are compared with those of high-carbon ferrochromium producers in South Africa. Economic aspects are discussed and compared with a South African reference study.IntroductionThe present ferrochromium demand in the western world is estimated at approximately 1.7 Mt with a consumption of approximately 0.36 Mt in the U.S.III and 0.03 Mt in Canada&apos;-&apos;, A low estimate of the installed production capacity for ferrochromium in the non -communist world is 2.4 Mt. This production capacity of ferrochromium by far exceeds the demand, which is also evident from the fact that no shortage in supply of ferrochromium to the world markets was encountered in the past. Supply-demand comparisons therefore suggest that in the foreseeable future no new chromite or chromium producers should enter the world markets unless superior chromites or superior technologies are successful in competing with existing producers. Neither one of these conditions exist presently in Ca nada or the U.S., although essentially no ferrochromium is produced and no chromite is mined in these countries at the present time."

Jan 1, 1986

By Jose R. Hernandez-Aguilar, Chris J. Martin, Rob Thorpe

"This study presents an approach to establishing relationships between metallurgical performance and the characteristics of the bubble population (gas dispersion) inside flotation cells. Bubble size Db, superficial gas velocity Jg, and bubble surface area flux Sb (Sb = 6Jg/Db) measurements were obtained along with metallurgical samples in full-size equipment processing different ore types. The gas dispersion was manipulated by changing the operating conditions of the cells (gas flowrate and frother type) and the metallurgical performance (grade-recovery) was determined. In two cases, the Sb had a strong relationship with grade and recovery, hence, Sb could be used as practical operating parameter. In another case, Sb did not correlate with recovery. The reasons were attributed to creating small bubbles using frothers with desired anti-coalescence properties. This illustrated that bubble size was the key parameter for metallurgy rather than Sb.INTRODUCTIONUnravelling the mechanisms that govern the relationships between metallurgical performance and the characteristics of the bubble population (gas dispersion) inside a flotation cell remains a major challenge. Information on this subject is scarce in the literature, particularly, plant-scale data. The report of Jameson and Allum (1984) appears to be the first gas dispersion study conducted in industrial (mechanical) cells. To introduce concepts, some aspects of their work are reviewed here.The prime motivation of that study was to establish whether any particular cell design (among 44 cells surveyed) could produce very small bubbles (< 0.1 mm), which laboratory research suggested would increase the recovery of fine particles. Although one of the outcomes was that the (examined) cells did not seem to produce such small bubbles (Sauter mean1 D32 ˜ 0.9 mm), the analysis highlighted the importance of including other factors. Jameson and Allum indicated that, besides bubble size (Db), other characteristics of the bubble dispersion should be considered, namely: gas holdup ?g – the fraction of cell volume occupied by bubbles, superficial gas velocity Jg – is the gas flowrate divided by the cross-sectional area of the cell and, bubble surface area flux Sb – the rate of production of (new) bubble surface area (m2/s) per m2 of cell cross-sectional area. It should be noted that, whereas Jg, ?g and Db can be measured directly, the Sb is derived: Sb = 6Jg/Db, where Db is usually substituted by the Sauter mean diameter (D32)."

Jan 1, 2006

By Jose A. Jimenez

"Mining operations generate an enormous amount of data that is difficult to organize, analyze and act on. These data require an extremely broad range of experts to investigate and manage the cross-disciplinary information. The data collects in paper files, diverse databases, historians, stand-alone applications, and excel files. This collection of sources represents everything from monthly, weekly, or daily inputs to real-time feeds or sporadic unscheduled entries. With the operational complexities ever increasing and fewer engineers per mine, an efficient operation is becoming more and more challenging. Engineers are typically burdened with data collection, clean up, and administrative efforts leaving very limited time for engineering assessment and/or optimization analysis. Often optimization becomes limited to the analysis of equipment uptime through existing field automation systems. A great portion of the field data is tucked away in historians seldom reaching those engineers who might leverage the data. Few mine operators have the time or budget to re-architect their operations data collection or management practice, so solutions must enable improvements without requiring expensive or time-consuming implementation. This presentation highlights examples where the aforementioned challenges are addressed using a solution framework designed to enable: 1) data integration and connectivity, 2) monitoring and opportunity recognition, and 3) engineering workflow automation. The initiative extends the concepts and success proven in the automation market segment to all disciplines across the mine operations. INTRODUCTIONThe mining industry by its very nature spends a great deal of its capital on equipment maintenance and replacement. In addition, periodic shutdowns due to equipment failure are typically very costly in terms of interrupted operations. Keeping mining equipment running at peak performance and avoiding costly shutdowns can make a huge difference in the overall return from mining operations. Today, information can be make available that can go a long way towards spotting equipment issues and permitting timely intervention to avoid costly unplanned shutdowns. That said, gathering all of the information from numerous points on many different pieces of equipment necessary to enhance overall equipment effectiveness presents its own daunting issues."

Jan 1, 2016

By A. Robles-Vega

Personnel of Mexicana de Cobre, a subsidiary of Southern Copper located in Nacozari, Sonora Mexico have been working in the past few years on the development of a process to treat and manage, in an environmentally accepted practice, the residues and effluents generated during the process. To date, this team has been reviewing existing technologies and also has explored new alternatives. At the end of this phase, a novel, efficient and complete process has been configured which will be able to treat some solid and liquid streams such as Teniente converter dust, Peirce Smith converter dust, a Sb-rich precious metals slag, copper refinery electrolyte bleed, acid plant blowdown and an acid bleed of the precious metals plant. The process will consist of a leaching stage, followed by a very selective copper precipitation using novel technology which has been named as back reactions. After copper precipitation, impurities (As, Sb and Bi) will be precipitated mainly as arsenic trisulfide (As2S3) using H2S(g) which will be generated by means of a new process developed in our company. At the end of the process, small volumes of arsenic trisulfide will be vitrified and then disposed as a stable residue.

Jan 1, 2007

By J. W. Smith, J. Van Dusen, A. Papachristodoulou

"As part of a study to evaluate factors affecting tankroom air quality, the mechanism of aerosol generation from bursting bubbles in electrowinning operations has been investigated. Typically 2 to 3 mg/m2.s are produced in zinc tankrooms. Analysis shows that the rate of production of film drops (geometric mean diameter - 2 urn] increases with decreasing bubble size, and that jet droplets (geometric mean diameter - 20 um) are not produced with gas bubble larger than - 4 mm. Both mechanisms of drop formation and current efficiency are affected by surface active agents, with an over-all reduction in emission of up to 60% to 70% being achievable. A source control system which does not adversely affect electrolyte properties is always preferred, and coalescence of all gas bubbles in to a continuous stream of gas at a single point on the electrolyte surface would eliminate aerosol emissions. This objective was the basis for design of a coalescence device which, in laboratory tests, reduced the emission rate by over 95%.The control device fit s over the electrodes in the electrowinning cell and is partially immersed in the electrolyte. A number of changes in the design which resulted in significant improvement in the performance of the device are reported.Field tests have shown that only about 75% of the aerosol below 10 um can be eliminated by coalescence. The remainder (up to 95% of the total) is controlled by coalescence of droplets, by impaction on the exposed collector surface and gravitational settling.The device does not interfere with operation of the tankroom, handles the effect of surges in power during harvesting, and is simple and inexpensive to maintain. IntroductionDuring the electrowinning of metals (such as zinc and copper) gases are evolved along the electrode surface forming small bubbles. The bubbles travel upwards and burst on the electrolyte free surface generating, in this way, small droplets. Because the electrolyte is often highly acidic or contains toxic materials, the whole process can result in the formation of an aerosol in the atmosphere above the electrowinning cells which poses a serious health hazard to workers in the area, and corrodes equipment."

Jan 1, 1988