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By Patrick F. R. Murphy

An ultra-low profile LHD has been developed by EJC Mining Equipment of Burlington, Ontario for narrow-reef mining applications. This paper discusses the challenges encountered during the evolution of the machine's design and subsequent field testing. Continuing research and development focuses on optimizing machine performance and controllability, reducing emissions, and enhancing maintainability. Details will be given on field trial experience and ongoing test work being carried out at the manufacturing facility.

May 1, 2004

By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By A. D. Mufch, G. P. Mitchell

"THE HARDY MINE of Falconbridge Nickel Mines Limited is located in Lot 9, Concession 1, Levack Township, Sudbury District, Ontario, 20 miles northwest of the city of Sudbury, and a mile west of the town of Levack. The ore deposit is one of the many nickel-copper sulphide bodies found on, or near, the lower contact of the well-known Sudbury norite-micropegmatite irruptive, and is one of a family of ore deposits which occur on the northwest rim of the irruptive.The property was acquired by purchase in 1935. In the same year a magnetometer survey along the footwall contact of the norite, which is covered by about 150 feet of glacial sands and clays, first indicated the location of the orebody. Drilling from 1935 to 1942 outlined the extent of the ore. Shaft sinking was commenced in the fall of 1951, and the mine is now approaching full production at a rate of about 300,000 tons per year.There are several major differences between the geology of the Levack area and the Falcon bridge area, which lies at the opposite extremity of the irruptive, 28 miles to the east. The purpose of this paper is to describe the essential features of the geology of the Levack area as seen in the Hardy mine, and to supplement the recent papers on other properties in the Sudbury area by Davidson (1), Lochhead (2), and Yates (3).General GeologyA recent review of the regional geology and an extensive bibliography of the Sudbury area can be found in the two papers by H. C. Cooke (4, 5). Some of the recent related references are: Jas. E. Thomson (6), E. M. Abraham (7), Franc. R. Joubin (8), W. G. Q. Johnstone (9)."

Jan 1, 1949

By L. J. Bryson, C. A. Biley

"Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) produces Ni and Cu cathode from slow cooled converter matte after Platinum Group Metals (PGMs) are magnetically separated for further processing. In 2010, execution of the RBMR expansion project was commenced to increase the production capacity to 33 ktpa Ni. The expansion, which is currently still in a ramp-up stage, brought about several fundamental changes to the circuit chemistry, including the installation of a dedicated Pressure Iron Removal (PIR) autoclave. This provided an independent outlet for iron from the refinery, which previously deported to the residue from the leach circuit and was toll refined. At the same time as changes in the circuit associated with the RBMR expansion were being made, the plant experienced a significant increase in iron and copper units per nickel unit in the feed. The decoupling of the leaching and iron removal process steps has had significant advantages for the robustness and control of the overall circuit, in particular pertaining to the preparation of a nickel electrolyte of sufficient purity to produce LME grade nickel. This paper details the primary changes to the RBMR circuit chemistry with a particular focus on iron deportment and the benefits derived from the installation of the PIR autoclave.INTRODUCTIONAnglo American Platinum mines and refines Platinum Group Metals (PGMs) through a complex processing pipeline in its South African operations. Mined ore is first treated through several mineral processing stages, geared to the recovery of base metals and associated PGMs, followed by smelting and refining operations that aim to separate base metals from PGMs and recover the value components to purified, saleable products. The focus of this paper is the Rustenburg Base Metals Refiners (RBMR) complex which receives a PGM-containing converter matte, then physically separates PGMs and base metals, and recovers nickel and copper to cathode by utilising leaching, precipitation and electrowinning processes.With new mining operations coming online and the continued increase in PGM ore arisings, it was necessary to undertake an expansion project at the Base Metal Refinery (BMR) to increase production capacity from 21 ktpa to 33 ktpa Ni. Complicating the expansion project was the requirement of continued production through all stages of design, construction and implementation and, due to stringent capital constraints, the utilisation of all existing equipment installed during a previous expansion in 1981. Against this backdrop, the expanded BMR flow sheet involved significant changes to the chemistry, especially iron management. These changes in iron management allowed for the separation of iron and copper residues and significantly increased the robustness of the plant to changes in feed mineralogy as well as the potential to increase production duties of the existing equipment."

Jan 1, 2016

By W. Holyk

"Although lead, zinc, copper, and iron sulphides have been known for many years in the Bathurst region, the existence of large massive deposits was not known until the discovery of the Brunswick orebody in 1952. This was followed by the discoveries of the Anacon orebody in 1953 and the American Metals orebodies in 1954. There is no question as to the great importance of these large massive sulphide deposits, and no doubt that other sulphide deposits are to be found. The problem, of course, is where and how to find them.The discovery of the Brunswick and Anacon orebodies is attributed to geophysical work. The original discovery of the American Metals deposit is generally attributed to a regional airborne electromagnetic survey.It is generally stated that the Bathurst area is a geophysical camp, and this is essentially true, but in this highly competitive search for orebodies it is obviously impossible for an individual company to cover the entire area by a comprehensive geophysical survey. Some means other than geophysics must be used to narrow the target. The quickest, cheapest, and simplest method is geological investigations.It has been stated that nothing can be accomplished by geology in the Bathurst region, since the camp is largely covered with overburden. This is true only insofar as detailed work on certain properties is concerned. It is not true of the larger regional picture. Outcrops are scarce, but angular float is abundant, and precedent shows that angular float has moved but a short distance from its source.GeologyAeromagnetic maps published by the Department of Mines and Technical Surveys are the best guides to the geology and structure of the area. These maps supply factual information concerning the underlying rocks. When coupled with field investigations, they are very useful in the interpretation of regional geology and the selection of favourable areas. The discussion of the geology is accordingly centred upon the aeromagnetic maps. The following is essentially a working theory, based on geological facts as best reconciled with all other available information,"

Jan 1, 1949

By K. Lillkung, J. Kourunen, M. Latva-Kokko

"Carbon-in-leach (CIL) and carbon-in-pulp (CIP) processes utilize activated carbon to adsorb solubilized gold for recovery. Due to carbon attrition and non-ideal carbon management, however, some of the gold is lost in carbon fines and to the solution. The carbon attrition mechanism inside CIL/CIP reactors is mainly abrasion-related. This is critical to gold loss since gold loading takes place predominantly in the outer shell of the carbon particles. Thus fine carbon dust has a relatively high gold content and such a small particle size that it cannot be captured with safety screens. The attrition rate depends on ore and carbon characteristics, but it is always proportional to the mixing power intensity. This rate can be minimized by continuous suspension level measurement and control of agitation speed. In addition, a novel tank bottom structure can significantly reduce the required mixing power input compared to a flat bottom tank. A major challenge in carbon management is infrequent and inaccurate measurement of carbon concentration in the reactors. In order to reduce soluble gold losses by means of improved carbon management, Outotec has been developing a continuous in-situ measurement for carbon concentration that is tolerant to changes in slurry density.INTRODUCTION Cyanide leaching has been utilized since the late 19th century as a standard technology for hydrometallurgical gold production. Since then, gold and silver recovery rates have increased due to technological development, but very similar recovery methods are still being used. The original recovery method was to use zinc precipitation – similar to the Merrill-Crowe process, which is still common for feed materials with low throughput and high silver content. However, in most cases, activated carbon recovery is preferred due to its improved efficiency. The carbon-in-pulp process (CIP) and its modification, carbon-in-leach (CIL), have a lower residual soluble gold level and are not similarly affected by soluble base metals. The main alternative for the use of carbon is ion exchange resins. The principle of resin processes is similar to the CIL/CIP processes, with a different type of adsorbent material. Carbon processes are usually preferred over resin processes due to the significantly higher cost of resin material and the possibility to use simpler, well-established technology with carbon processes."

Jan 1, 2017

By Bryn Harris, Liming Huang, Andre Laplante

"This paper reviews flowsheets generally used in gold rooms to upgrade primary gravity concentrates particularly those of Knelsons. It is concluded that even for small operations, which treat between 250 and lo00 kg of concentrates per day, there is a strong economic incentive to include in the flowsheet magnetic removal of tramp iron, at least two shaking tables, screening of either table feed or table tails at 150-212 um, and scavenging of table tails with a small centrifuge. Headroom, rather than floor space, is often inadequate in most gold room designs, and limits gravity flow and flowsheet flexibility. Experimental data are presented to demonstrate the effectiveness of a small Knelson Concentrator to scavenge significant amounts of gold (up to 91 %) from fine table tails.RésuméCet article examine les schémas d’évolution généralement utilisés pour traiter les concentres gravimétriques d‘or, en particulier ceux produits par concentrateur Knelson. Nous en venons à la conclusion que même pour un petit circuit d’une capacité de 250 A 1000 kg/jour pourrait bénéficier des opérations unitaires suivantes : concentrateur magnétique pour extraire la feraille, au moins deux tables A secousses, criblage de l’alimentation ou du rejet d’une ou des tables i une maille de 150-212 um, et épuisages des rejets fins de table avec un centrifuge de petite capacité. C’est l’espace vertical du lieu où se fait cette concentration qui représente la contrainte la plus importante, plutôt que sa surface, puisqu’il faut maximiser l’écoulement par gravite des pulpes et s’offrir une certaine flexibilité quant à l’agencement final des opérations unitaires. Nous présentons également des données expérimentales pour démontrer l’efficacit6 d‘un Knelson de laboratoire pour récupérer jusqu’ à 91 % de l’or contenu dans les rejets fins de table."

Jan 1, 1999

By Vincent Roy

Numerous on going activities at the Daniel-Johnson Dam : ? Surveillance / monitoring ; ? Structural investigations & evaluation ; ? Injection work ; ? Crack mapping ; ? Instrumentation management (drawings & inventory) ; ? Drainage system state ; ? Foundation evaluation

Aug 1, 2013

By A. Yousefpour, M. Hojjati, G. Chouinard

In recent years, high performance thermoplastic composites such as PEEK and PEKK have been developed for aerospace applications. These materials offer, among the other properties, high toughness and damage tolerances. These are semi-crystalline materials and their processing can lead to different crystallinity that in turn have some impact on the final properties. The effect of cooling rate on degree of crystallinity of PEEK is studied to identify the processing window for manufacturing. Samples were heated at the constant heating rate of 20°C/min up to 375°C (above melting point) and held for 10 minute. The enthalpy of the crystallization was measured at different constant cooling rates of 0.5, 1, 2, 5, 10, 20, 30, and 40°C/min. After cooling, the samples were heated at constant heating rate of 2°C/min using modulated DSC. At temperature between 90°C to 375°C, two endotherm peaks were observed. Results suggest that endotherm peaks are related to a melting and recrystallization phenomenon of one crystal morphology. However, the second endotherm peak could be associated with another crystal structure or morphology.

Jan 1, 2006

By Par G. Jönsson, Joachim von Scheele, D. S. Sarma, Mukul Goyal

Dust from flue gas cleaning systems at iron and steel production is frequently considered as a waste problem, but it is actually a potential raw material source. By using a technology like the oxyfuel based OXYFINES technique, it can be melted into a suitable form. The product from this processing, however, needs to meet the requirements of a recyclable raw material, here particularly a top-charged blast furnace feed. The present work has been focused on characterization of the product produced from these dusts by OXYFINES technology. The investigation has been carried out on samples of processed dusts from a European integrated steel mill. It was done by means of chemical analysis, density measurement, light optical microscopy, X-ray diffraction, scanning electron microscopy combined with energy dispersive spectroscopy, and micro indention hardness measurement. Special attention was paid to the presence of zinc, an element that might be harmful while recycling the material (e.g., in a blast furnace). The results show that the product contains four different regions with different morphologies and properties in the material, which are discussed in detail. The overall conclusion is that by processing the dusts in this way, a raw material suitable for recycling in a blast furnace can be obtained.

Jan 1, 2004

By L. Xu, A. Vazirnegad, R. Bhaskar

"Respirable dust samples are collected by the U.S. Mine Safety and Health Administration (MSHA) and mine operators as part of the requirements of the Federal Coal Mine Health and Safety Act of 1969. About 1.85 million respirable dust samples collected by MSHA were analyzed for the period 197/ to 1990 f or the states of Alabama, Colorado, Illinois, Kentucky, Ohio, Pennsylvania, Utah, Virginia, and West Virginia. Trends in coal dust exposure of continuous miner operators, helpers, and roof bolters were analyzed. The reported production in each of the nine states was analyzed. The relationship between average dust exposure and coal production was evaluated. In addition, the differences between mine operator and MSHA inspector collected data were examined for each state. The average exposure levels for the three occupations - miner operator, miner helper, and roof bolter were also compared.The data indicate that the dust exposure levels have significantly dropped over the last twenty years, while at the same time production has increased, attesting to the ability of the U.S. mining industry to adapt successfully to the stringent dust control regulations. In terms of coal production, it appears that some states, such as Utah, Illinois, and Kentucky, were able to increase their production significantly relative to others, such as Pennsylvania and Virginia. The relationship between dust concentration and coal production is, at best, tenuous. 11 implies that existing dust control technology has assisted several mine operators to meet dust standards, while, at the same time, enabling mines to produce more coal than before. Comparison of data collected by MSHA and mine operators indicate that MSHA inspectors recorded higher dust levels and lower shift production relative to mine operators."

Jan 1, 1993

By A. H. C. A. Zimmerman

WE have just heard what must be regarded as a thoughtful, constructive and somewhat painful analysis of the financial function of our industry. While thinking about this, it is interesting to reflect on the conditions which have stunted the growth of the financial side of our affairs. Mining must be regarded as a wealthy business. •while immeasurable grub takes and development budgets have been lost, there can be little argument that a productive ore-body nearly always produces the type of wealth that breeds some extravagance. I recognize that this statement can be attacked from many sides, but an historical comparison with a commercial enterprise involving similar investment will demonstrate what I mean. However, these old times are be-ginning to disappear for a variety of reasons. High amongst these are: ( l) Increased costs of exploration. (2) Remoteness of many new finds. (3) Fixed or declining metal prices (particularly when expressed in constant dollars). ( 4) Constant demands for higher wages.

Jan 1, 1962

By Manqiu Xu

"Ore grades are decreasing and ore deposits are becoming more complex. In order to make a sound economical decision about a mining project, metallurgical testwork must be carried out. A few large “representative” samples cannot represent the metallurgy of a large ore body and a large number of samples reflecting variation in ore head grades and in mineralization types must be obtained for proper metallurgical studies, including flowsheet development for a greenfield project. A relationship can be established between the recovery of valuable minerals and ore grade for each mineralization type. This relationship can be used to establish a correlation between values recoverable and values contained in the ore body that can include multiple pay metals. With this information, a sound economical decision can be made about the viability of a large mining development project.INTRODUCTIONThe demand for minerals today is historically high as many countries are being rapidly industrialized. The supply for these minerals is not necessarily running short. However, it is widely accepted that the world today is running short of the easy to mine and easy to process ore deposits. As ore grade is decreasing and ore mineralogy is becoming more complex, metallurgical testing must be fully conducted in order to make a sound economical decision about a mining project. For a high-grade and high-quality deposit, it is hard not to make a good profit even with low metal prices. For a low-grade and hard to process deposit, the profit margin is much lower and is dependent on the throughput and the recovery of valuable minerals. The recovery of valuable minerals is a function of ore grade and mineralogy and it must be experimentally determined for a given processing option.At Vale Base Metals Technology Development, metallurgical testing for an existing operation or brownfield project is termed as Ore Evaluation, while metallurgical testing for a greenfield project is termed as Flowsheet Development (Xu, 2011). In the past, metallurgical testing involved a few large composite samples for lab and pilot plant testwork. As ore deposit becomes less homogeneous and more variable, a few large composite samples cannot represent the metallurgy of a large ore body. In addition, useful information about the deposit such as zones of “impurities” or floatable rock minerals would not be obtained. Different processing strategies could have been developed if the locations and sizes of these zones were known in advance. For proper metallurgical studies, a large number of samples reflecting variation in ore head grades and in ore mineralization types must be used. A relationship can be established between the recovery of valuable minerals and ore grade for each mineralization type. This relationship can be used to estimate values recoverable in the ore body that can include multiple pay metals. Ultimately, the recovery verses ore grade relationship will be used in business decision-making."

Jan 1, 2013

By Karina Forster

Open stope design depends on the ore body geometry, loading conditions and rock mass properties to estimate stope dilution and ground support requirements. Rock mass conditions for design primarily rely upon estimates of well established rock classification systems. Many sources of data exist for obtaining estimates for these rock mass classification values which include core logging, geotechnical mapping, geological mapping as well as linking one classification system to another through the use of empirically derived equations. The extent of mapping coverage can also vary significantly based on the data collection technique. This paper proposes an approach where individual components of rock mass classification systems are collected by the different available data collection techniques. Data from different rock types are also considered separately based on their alteration characteristics and general observation products. Data from the Cameco Corporation Eagle Point Mine is presented and an approach is outlined for obtaining average representative classification values for stope hanging wall characterization. The effectiveness of this approach is demonstrated through the analysis of a data base of hanging wall dilution information.

Jun 1, 2012

By R. Esteban, D. Runnels, J. Torrealba-Vargas, G. Couture

"Data handling is an important step in the development of a simulator of a mineral processing circuit. The model requires representative data of the scenario to be modeled. The model development involves protocols that must be followed very closely to complete a successful project.Data handling of large and diverse datasets (metallurgical test results, geological data, mining models, historical data, etc.) is a key element of the model. The information needs to be processed, reconciled, interpreted, modeled and presented to support the design or the optimization of a mineral processing plant.Best practice recommends that teams from different disciplines (such as mining, metallurgy, geology and environmental) interact to define the most important variables that could influence the simulator. For example by adopting a geometallurgical approach in the earlier stages of the project, it is possible to consolidate the number of main ore rock types in a testwork program (saving money and time) by involving geologists and metallurgists in the sample selection and data interpretation.Planning the development of a model involves an understanding of the software capabilities but also the limitations and the magnitude of the data required to calibrate the model in case of changes in the project.A successful model requires a deep understanding of the circuit to be modeled and thus plant personnel should be considered as members of the team.This paper describes the use of the "state of the art" tools for data analysis, simulation and optimization; and shows three practical examples of the use those tools in the design of mineral processing plants."

Jan 1, 2015

By O. Mejia, J. Drozdiak

"This paper summarizes a comprehensive energy and cost study comparing an existing SAG mill based circuit at Huckleberry Mine with two proposed circuits involving comminution technologies which are associated with energy efficiency: high pressure grinding rolls (HPGR) and high speed stirred mills. The specific energy requirements expressed as kWh/t for the proposed circuits were determined from pilotscale HPGR and stirred mill testing conducted at the University of British Columbia. Samples and operating data were collected from Huckleberry’s copper-molybdenum concentrator to evaluate current mill performance for comparison. To support the base case, the SABC circuit was modeled using JK SimMet® software. The main comparison focused on the complete energy requirements for each circuit, including materials handling equipment such as conveyors, screens, feeders and pumps. This paper also provides capital and operating cost estimates for each of the comminution circuits. The results showed that the HPGR - ball mill circuit achieved a 21% reduction in energy consumption over the existing SAG - ball mill circuit at the same P80 grind size of 160 µm. At a grind of 80% passing 75 µm, the HPGR - stirred mill circuit showed a 34% reduction in energy compared to the base case. It was concluded that the energy reduction for the new flowsheets significantly improved the economics of the Huckleberry comminution duty.INTRODUCTIONUp until now, tumbling mills such as AG/SAG mills and ball mills have had a dominant bearing on the design and economics of comminution circuits. However, it is commonly agreed that the majority of employed comminution processes are energy intensive and energy inefficient, accounting for up to 80% of overall process plant energy consumption and having an efficiency of as low as 1% (Abouzeid and Fuerstenau, 2009; Fuerstenau and Abouzeid, 2002). The U.S. department of energy reported that there is a potential to reduce energy consumption in the metals industry by up to 61% from current practice to bestestimated practical minimum energy consumption; suggestions included the implementation of best practices and the adoption of energy efficient mining and mineral processing technologies such as advanced blasting techniques, high pressure grinding rolls (HPGR) and stirred mills (U.S. DOE, 2007)."

Jan 1, 2013

This growing dependence of Canada upon foreign mineral commodities, just referred to, applies particularly in the direction of the United States. There is, in fact, no more significant feature of Canada's mineral trade than the manner in which it affects the Dominion's commercial standing with that country. Our heavy adverse balance of trade with the United States is perhaps not a matter of such wide concern or frequent comment as was the case two or three years ago. It is, of course, a well-known fact that the Dominion each year buys from the States a volume of goods to a value enormously in excess of our sales to that country. And it has come to be accepted as a ?normal, though not altogether satisfactory, feature of our international commerce that a huge portion of the bill incurred by our American purchases must be met, not by our American sales, but by the proceeds of our sales to other countries, not-ably Great Britain. It is a three-cornered situation in which our trading deficit with the United States is covered largely by our trading surplus with the United Kingdom. In this situation the mineral trade plays a remarkable part. If one delves into the details of our transactions with the United States it will be found that, in one sense, the mineral trade is entirely responsible for the huge annual balance against the Dominion. In fact, Canada gets decidedly better than an even break on Canadian American trade, if one leaves out of account the three mineral groups, "iron and steel", "non- metallic minerals", and "non-ferrous metals".

Jan 1, 1924

By Chen Xia, G. Deschenes, Wan-Tai Yen

"Ammonium thiosulphate is a potential replacement for the cyanide in gold leaching. However, the high reagent consumption hinders its practical applications. In order to reduce the thiosulphate consumption, chemical additives were used. The gold leaching tests were conducted on a sulphide copper-bearing gold ore with 0.3M thiosulphate, 0.03M copper sulphate and 3M ammonium hydroxide solution at 44% solids and pH 10.2. Sulphate, sulphite, amino acid and chelating agents were initially used as additives. It was found that chelating agents (EDTA and NTA) could reduce the thiosulphate consumption from 30 kg/t to 17.8 kg/t with some increase of gold extraction. The improvement from other additives was not significant. Other approaches were also attempted to reduce thiosulphate consumption with some success. The thiosulphate consumption could be reduced to about 17 kg/t by reducing copper sulphate concentration fiom 0.03M to 0.0015M; adding 0.04M of EDTA; replacing copper sulphate with 0.001M of nickel sulphate. The increase of pulp density fkom 44% to 60% solids could reduce the thiosulphate consumption to 17 kg/t as well. Limiting the dissolved oxygen content by sparging nitrogen reduced the thiosulphate consumption further to 10 kg/t. It could be concluded that the regulations of copper and oxygen supply in the lixiviant were the keys to reduce the reagent consumption.INTRODUCTIONCyanidation, as the predominant gold leaching method, has been used in mining industry for more than a century. The low reagent requirement and the high performance are the reasons for its great success. However, cyanidation cannot deal with ores containing large amount of copper, nickel, arsenic and zinc minerals. This type of ore may consume more reagents and result in a poor gold extraction. On the other hand, the carbonaceous materials may preg-rob the gold from pregnant solution and make cyanidation a problem leaching method. Further more, the high toxicity of cyanide represents another challenge to modern gold mines. In the beginning of the year 2000, an environmental disaster caused by an accidental spill in Yugoslavia was broadcasted world-widely (Gurevitch 2000). Gold mine operators are facing higher social pressures and increasing costs on environmental protections. The usage of cyanide in mining industry has been banned in some countries and locations such as Czech Republic, Japan, Turkey, California, Colorado, Wisconsin and Montana States. Thus, a non-cyanide lixiviant is required."

Jan 1, 2002

By P. C. Richards

"Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency.The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42% to 46% (LHV).In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N. V. Sep). The plant is scheduled to start up in 1993. IntroductionBasic ConceptShell's experience with gasification dates back to the 1950s, when the first Shell Gasification Process was commissioned with oil as feedstock. There are now over 140 SGP gasifiers licensed. The experience gained on oil gasification provided a firm theoretical and practical base for the start of coal gasification process development in 1972.At that time, there were serious concerns about the future availability and price of crude oil. Coal gasification (making carbon monoxide and hydrogen by the partial oxidation of coal) was considered to be an important option for refinery applications, because the synthesis gas (syngas) produced can be used as:• a chemical feedstock for making transportation fuels and chemicals;• a source of hydrogen (making use of the water gas shift reaction) for upgrading petroleum products; and• a fuel for heating process streams and/or generating electricity."

Jan 1, 1994

By Jing Li, Weiqiang Lai, Joe Zhou, Jiezhen Ma, Shuibo Chen, Ashele Copper Company, Feng Gao, Guofu Feng

"Copper-zinc ores often contain gold and silver, which can be recovered into copper concentrate by flotation as by-product. The challenges for operations that produce copper, zinc, gold and silver are the separation of copper and zinc and the low grade of precious metals. Ashele copper-zinc ore in north China contains 2.38% Cu, 0.69% Zn, 0.21 g/t Au and 18.10 g/t Ag and the plant produces copper and zinc concentrates, with gold and silver being recovered into copper concentrate. Copper occurs mainly as chalcopyrite and Zn occurs as sphalerite. Copper is well recovered with a recovery of over 94%. However, the recovery of Zn is substantially low (around 50%) due to fine grain size of sphalerite. In addition, gold recovery is much lower than expected and only 33% of gold in the flotation feed was recovered. The grade of gold in copper concentrate is also lower than the required payable grade (1.0 g/t). To determine the cause for lower Zn and Au recoveries, a plant survey program was conducted on the operation. The information acquired shows that the loss of Zn was mainly in the copper concentrates (accounting for approximately 38% of the head assay); of which, 24% was liberated, 8.5% was associated with chalcopyrite and 4.6% was associated with pyrite, indicating that the separation of copper and zinc was the main cause for the Zn loss, with liberation being the second cause for Zn loss. Future effort in improving Zn recovery should be focused on the separation of zinc from copper. Gold in the ore occurs as both microscopic gold and submicroscopic gold, accounting for 36% and 64% of the head assay, respectively. Microscopic gold occurs mainly as native gold and electrum; it is relatively coarse with a grain size of 10 to 240 µm and a large portion can be recovered by gravity. Submicroscopic gold was mainly carried by pyrite (accounting for 38%), and to a less extent, by tennantite (15%) and chalcopyrite (10%). Gold in sphalerite is nominal (1%). It is suggested that more coarse gold and tennantite be recovered and a gold recovery increase can then be achieved to obtain a copper concentrate with over 1.0 g/t Au through flowsheet optimization. Gravity concentration should be investigated and may be worth added into the existing flowsheet to maximum the gold recovery and grade.INTRODUCTIONCopper-zinc ores containing gold and silver is a subtype of polymetallic sulphide ores. Unlike porphyry copper sulphide ores and iron-oxide copper-gold ores, this type of ores often contains substantial amounts of zinc and lead. Polymetallic sulphide ores are mainly distributed in Canada, such as at the LaRonde and Horne deposits. Other examples include Mt. Morgan in Australia and Boliden in Sweden. Globally, production and reserves from gold-rich VMS deposits account for 1370 t gold. This is equivalent to 1% of the world production and reserves, whereas the Canadian total for gold-rich VMS deposits is 870 t, representing close to 10 % of Canadian production and reserves (Gosselin & Dube, 2005a, 2005b). Flotation is the principal process for processing the copper-zinc sulphides ores, for subsequent smelting, roasting, or hydrometallurgical treatment. Oxidized copper-zinc ores can also be processed using leaching technology. For example, at LaRonde operation (a Cu-Zn-Pb ore containing 3-4 g/t Au and 60-100 g/t Ag) the flowsheet consists mainly of a copper flotation circuit and a zinc flotation circuit followed by a cyanidation process of flotation tails. The precious metals are recovered with copper concentrate, zinc concentrate and cyanidation of zinc tails via Merrill Crowe precipitation (Zhou et al., 2005)."

Jan 1, 2016