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By C. Edwards

"The processes for rare earth (RE) extraction include the decomposition of RE ore concentrate minerals, and the concurrent or subsequent leaching of the rare earth elements (REEs) from the decomposed minerals. Ore beneficiation concentrate can be decomposed by, for example, acid roasting, caustic cracking, and chlorination. The REEs can be selectively extracted. The nature of the REE extraction process depends on the concentrate mineralogy and the targeted products. Based on the experience of the Saskatchewan Research Council (SRC) in RE processing, this paper reviews REE extraction from the major RE minerals, including bastnaesite, monazite, xenotime, ion-adsorption clay, allanite, cerite, and eudialyte. An update on the development of RE extraction processes is also provided.INTRODUCTIONRE processing usually involves two operation stages, physical processing and chemical processing. Physical processing, also known as ore beneficiation, separates the RE minerals from gangue minerals to produce an RE mineral concentrate. Chemical processing, which includes extraction and separation processes, converts the RE mineral concentrate to an RE compound which is either an end product or an intermediate product for the subsequent production of individual REEs or other compounds. The RE extraction process uses one or more reagents to decompose the RE minerals and to leach the REEs into solution. The RE separation process uses solvent extraction, ion-exchange, or chemical precipitation to produce either rare earth oxides (REOs) or individual REEs. The authors have previously reviewed RE ore beneficiation processes (Zhang & Edwards, 2012). This paper focuses on extraction processes for a variety of RE minerals. Table 1 gives the chemical compositions of the RE minerals mentioned in this paper. The varieties of RE extraction methods use many different reagents. These reagents are mainly inorganic acids, alkalis, salts, and chlorine gas. The commonly used acids include sulfuric acid (H2SO4), hydrochloric acid (HCl), and nitric acid (HNO3). Sodium hydroxide (NaOH) and sodium carbonate (Na2CO3) are the most common alkalis. Salts include ammonium sulphate ((NH4)2SO4), ammonium chloride (NH4Cl), and sodium chloride (NaCl). HCl is normally used to extract RE from silicate ore minerals such as allanite and gadolinite. The alkalis and H2SO4 are mainly used to leach REs from phosphate ores minerals like monazite and xenotime. The carbonate ore RE minerals such as bastnaesite can be treated using either acids or alkalis. HNO3 is mainly used to leach eudialyte and apatite. The extraction of REs from ionadsorption clay deposits uses salt solutions. Chlorine gas (Cl2) is exclusively used in the RE chlorination process which can be used to treat any RE minerals."

Jan 1, 2012

By F. Habashi

"The rare earths industry started in Austria in 1887 by Carl Auer von Welsbach (1858-1929) Professor of Chemistry at the University of Vienna. The process was based on monazite sand transported from Brazil as shipping ballast free of charge. This made possible producing thorium, cerium, and other rare earths at a low cost, thus permitting the growth of the industry. However, once the Brazilian authorities realized the strategic importance of the sand, shipping was stopped. Brazil then started its own processing of the sand in 1949. The background for Auer’s work, the role of Robert Bunsen in Heidelberg, and the invention of the spectroscope will be presented. INTRODUCTIONHeidelberg on the Neckar (Figure 1) was the meeting place for chemistry students from all over Europe in the nineteenth century. Her university founded in 1386 had already a famous professor of chemistry and medecine in the Faculty of Medicine by the name Leopold Gmelin whose three - volume Handbuch der theoretischen Chemie appeared in 1817-1819, that became later a multi-volume monumental work. As successor to Gmelin came Robert Bunsen (Figure 2) in 1852 who made this university town the Mecca of chemistry students. One of his students, the English Henry Roscoe (1833-1915) who became later a distinguished professor in Manchester, described him as follows: ""As an investigator he was great, as a teacher he was greater, as a man and a friend he was greatest""."

Jan 1, 2012

By R. R. Culbert

Several thousand parts per billion of uranium are present in some alkaline lake and ground waters of the Okanagan region, British Columbia. To a major extent the uranium content of these highly anomalous waters is controlled by their levels of dissolved bicarbonate. In lakes, dissolved bicarbonate and the organic content of the sediment largely control the partitioning of uranium between sediment and water. This relationship is found to a lesser extent in alkaline creeks, and transported geochemical anomalies in soils appear where uranium-bearing alkaline ground waters have encountered organic materials. There is a possibility that young, near-surface deposits (with very low radioactivity) are forming from these uraniferous waters.

Jan 1, 1978

By J. F. Nie

Mechanical properties of precipitation hardenable magnesium alloys depend critically on the chemistry, structure, morphology, orientation and distribution of strengthening precipitates. It is therefore important to gain an improved understanding of these information and their correlations with mechanical properties. Our recent studies indicate that additions of 1-2 wt% of Zn to a Mg-6wt%Gd alloy result in a substantial enhancement in precipitation hardening and in creep resistance. If the strength and creep resistance of the resulting ternary alloy are to be further enhanced for commercial applications, then a detailed characterisation of the strengthening precipitates in these alloys is required. In the present study, the precipitates formed in a Mg-6Gd-1Zn-0.6Zr (wt%) alloy, peaked aged at 250°C, have been characterised in detail using transmission electron microscopy and 3-dimensional atom probe field-ion microscopy. It is found the peak-aged microstructure contains a dense and uniform distribution of precipitate plates that form on the basal plane of the matrix phase and are typically less than 1 nm in thickness. Detailed analyses of the structure and composition of these basal precipitate plates will be presented and discussed in the context of previous work on other Mg-RE¬Zn alloys of similar compositions.

Jan 1, 2006

By Yves Gagnon, Nicole Gauthier, Daniel Kelly, Michel Rocheleau

"The Larder Lake-Cadillac Tectonic Zone in Rouyn-Beauchastel area (a 20 km long segment) contains distinct lithotectonic units bounded by artastomosing or sub-parallel shear zones. The gold deposits in the area are located within highly strained portions of E-W striking shear zones. The ore-zones are structurally controlled disseminated and vein-type lodes. They are spatially related either to megascopic z-shaped folds which refold E-W shears, or to areas of intersection between E-W shear zones and late NE-striking faults. Several ore bodies are enclosed within ultramafic rock units or at their contacts with adjacent units. All the lenses are elongated down dip and distributed, both loterally and vertically, ""en echelon"" . The ore zones tend to decrease in size and number away from the hinge zone of the megascopic z-shaped folds.Two main styles of mineralization are recognized at the Astoria deposit and at for most of the deposits in the Rouyn-Beauchastel segments a discontinuous ""Carbonate Ore"" and a more continuous, albitic sulphide-bearing ""Flow Ore"" (terminology used at the Kerr Addison mine).The typical ""Carbonate Ore"" zones are found within strongly arbonatized blocks bounded by conjugate late NE or NNW-striking fralls. The carbonatized blocks display features characteristic of llrittle to brittle-ductile deformation developed in shear zone system. Vein systems in the ""Carbonate Ore"" occur within shear fractures(D R)tension fractures (T), or within brecciated rocks adjacent to NS llrilcing faults. The ""Carbonate Ore"" zones are displaced by numer IU lole E-W, NNE, NW and N-S faults.The ""Flow Ore"" zones are found within predominantly ductile portions of E-W shear zones. The sulphide mineralization is finely disseminated and regularly distributed within mylonitic foliation or associated with veins and veinlets sub-parallel or oblique to the mylonitic foliation, in which case the mineralization is coarser grained. The gold mineralization is a late Archean event postdating the formation of the penetrative fabric, and synchronous with the end of the dextral oblique-slip motion."

Jan 1, 1990

By G. Barbery, P. Dauphin

"In order to obtain reproducible and reproducible results in batch flotation, researchers have tried various approaches, from normalized testing, to modifying existing cells, and even designing new machines. The paper reviews the basic concepts that must be fulfilled in a laboratory flotation machine, and present the FLOTOMATEC design, which results from five years of testing and development. In addition to providing accurate measurements of air flowrate, power consumption, agitation speed, the cell eliminates most operator induced errors. Results of experiments comparing FLOTOMATEC to a conventional cell, as well as reproducibility tests are given. Introduction The use of batch flotation machines in mineral processing research and development is very common. These machines have been used for many years without almost any change in their design, instrumentation or automation. Various authors since Raffinot (1960) have criticized the available designs, especially with respect to the large errors that are introduced by the manual mode of operation. Barbery et al. (1986) have presented a review of the problems involved in laboratory testing in flotation research.Batch laboratory machines should have the following characteristics:"

Jan 1, 1989

By G. Langlands

"R. Tenbergen Is this flotation machine suitable in the flotation ofInco ball mill discharges where we have a coarse feed at 60% solids?Reply Experience has shown that there is not a significant increase in the wear life of these machines when handling coarse material (8 mesh) at 60% solids. A common practice in Europe is shut down on the week-ends.The material is allowed to settle and on start-up an injectic of air for 15 seconds is sufficient prior to start-up. At,mining we put our unit in the middle of a bank of 44 cells and in order to ensure severe sanding we shut the aker cell down while the remaining cells kept running. After 20-25 seconds of air the cell started without trouble.P. Mahant Is there a build-up inside the impellor shaft housing? Falconbrige Ltd.Reply There is no sand build-up but rather a scale build-up which due to a flexing action frees itself periodically. Part of the design of the machine permits a water injection into the shaft housing to free any build-up. This is done in Europe during the week-end shut down."

Jan 1, 1984

By X. Xu, J. K. -W. Wong, J. -Y. Delenne, K. Soga

Hydraulic fracturing (HF) is a mulit-scale and multi-physics process which makes numerical modelling challenging. Conventional numerical models focus on multi-physics nature of HF but the multiscale nature is compromised by idealization of reservoir to be continuous, homogeneous and isotropic. However, natural fractures take a significant role in the success of HF for exploration of unconventional resources like Shale gas. Advancement in microseismic monitoring provides useful data for simulation in a much greater details. There is an urgent need to develop a suitable numerical tool for multi-scale threedimensional simulation to better understand the roles of discontinuities and heterogeneity in reservoir and its interaction with HF, especially to address the environmental concerns such as induced seismicity. In this paper, a simple discontinuum numerical method – Lattice Element Method (LEM) is proposed to model HF in a large scale three-dimensional model. A reservoir is modelled as a lattice network composed of 1D Hookean’s spring. Fracturing is modelled simply by removing lattices that meet a specified threshold as determined by the critical energy release rate of the rock. By introducing disorder in the model, mesh dependency in modelling fracture growth is minimized. Fluid flow is simplified as flow in pipe network and the permeability of pipe is related to fracture aperture by cubic flow law. Therefore, fracture flow and rock deformation are fully coupled. In this paper, four simulations of the same configuration except with different degrees of reservoir heterogeneity are presented. Fractures formed are diffusive and two groups of fracture are identified – connected fractures and isolated fracture without clear spatial correlation. The former forms a ‘fracture cloud’ and contributes to fluid flow and modeled by pipe network. The flow of fluid is highly tortuous and pipe network is sparely connected. The degree of reservoir heterogeneity controls the growth of ‘fracture cloud’ and pipe network. Microseismic monitoring often shows diffusive fracturing during HF on site and hence the outcome of the proposed model can be compared to such monitoring results.

Jan 1, 2015

By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

By Jarek Jakubec

The new euphoria in diamond exploration brings with it a need to understand the challenges that new projects can face in different stages of the development and risks that the commercial outcomes from the new projects fall short of expectations. In many cases, the problems are related to a poor understanding of the technical risks and a failure to adequately address them during the course of investigation. Failure to evaluate all disciplines to the same level of certainty could lead to a situation where the important issues are only identified late in the project development, resulting in costly delays and financial difficulties. The diamond projects located in Canadian Arctic, with its challenging environmental, geographical, social, political and geological contexts are especially sensitive to the high variability of the outcome. This presentation highlights some of the technical aspects that could be the leading sources of risk in diamond projects and could ultimately result in inappropriate mine designs, reducing the economic outcome.

May 1, 2006

By Y. Q. Li, X. H. Long

In this work, structural and electronic properties of smithsonite (ZnCO3) and cerussite (PbCO3) as the typical lead-zinc oxide minerals is simulated by means of DFT. The calculated results could be concluded as: (1) The density of states (DOS) of Zn atom in ZnCO3 is nearer to the Fermi level than that of Pb atom in PbCO3, suggesting that the Zn atom of ZnCO3 is more active and easier to interact with water molecules and hydroxyl ions. Smithsonite, therefore, could be more readily depressed in the flotation process. (2) The bond population value of Zn-O (0.23) and C-O (0.92) in ZnCO3 is obviously larger than that of Pb-O (-0.01) and C-O (0.85) in PbCO3, indicating that the covalent characteristic of ZnCO3 is stronger than that of PbCO3. (3) It is shown that the charge of Pb (+1.32e) in PbCO3 is more positive than that of Zn (+1.22e) in ZnCO3, suggesting that cerussite is easier to interacting with HS- compared with smithsonite in the flotation process. In summary, the structural and electronic property of smithsonite is completely different with cerussite, leading to the difference of their flotation behaviour.

Jan 1, 2015

By Zygmunt Kowalczyk

"A theory permitting the determination of expected surface deformations for planned underground exploitation is proposed and discussed in this paper. The relations between surface subsidence and various methods of mining are analyzed, and allowable horizontal .deformations for protected objects, according to the degree of their significance, are reviewed."

Jan 1, 1966

By A. H. A. Robinson

Until quite recently-practically up to the present time-all but an insignificant amount of the copper produced in Canada was shipped abroad in the form of ore, matte, blister, etc., there to undergo the further treatment necessary to bring it to the refined state in which it is required by fabricators of copper. Consequently, Canadian manufacturers were forced to import nearly all the copper required in their business; and a considerable portion of the ultimate value to be derived from a Canadian raw material was lost to the country of its origin. In the early days of Canadian copper mining, when both the production and consumption of copper in Canada were much smaller than now, such a condition of affairs was perhaps economically unavoidable, and, in any case, was not a matte~ of sufficient importance to attract general attention. Later on, however, when there had been large and rapid increases both in the production and consumption of copper in Canada, it formed the basis of much adverse criticism, deserved or not, of producers of Canadian copper-criticism that became intensified during the war and subsequent years. Happily, the chief grounds of complaint have now been removed, and there are today copper refineries in Canada, either operating or under construction, that are capable, in the aggregate, of turning out amounts of refined copper greatly in excess of any indicated Canadian consumption.

Jan 1, 1931

By D. Mu

A method is presented for evaluating the effective gas diffusion coefficient of porous media. A series of random-distributed porous solids with different porosity are generated, a solution of the gas diffusion equations inside the porous media is obtained using the finite element method (FEM), and then the effective gas diffusivities are computed. The results show that there is a percolation threshold sp, and this percolation threshold decreases with an increase in the connectivity of the pore network; the relationship between the effective diffusivity and the porosity is strongly nonlinear when the porosity £ is less than about 0.2; and is quasi linear for higher porosities. The threshold decreases with increasing the connectivity of the pore network. A formula relating the effective diffusion coefficient with porosity is proposed.

Jan 1, 2005

By R. Plassart, F. Laigle

"As a powerhouse, a transformer or a valve chamber, large underground caverns are a major element of hydropower plant. On the contrary to galleries and shafts which are linear and long underground structures, large caverns are designed with often complex geometries and large spans. Moreover, as these caverns are generally located on the foot of the hydraulic scheme, the high overburden is often responsible of a high stress state. Thanks to current experiences in France and around the world, the Hydro Engineering Centre (CIH) of EDF has defined great principles in the design of caverns leading to a more general methodology. The project of Tehri in India is an example of difficult ground, with in the same time a high overburden, a ductile material and an important schistosity. These physical realities are attempted to be approached in numerical modelling thanks to a constitutive law with softening behaviour and an oriented criterion integrated in the continuum model. As a result, a flexible support is advised, based on a high density bolt system and a thin lay of shotcrete. This methodology has been developed in the case of Gilboa in Israel, except the schistosity which has not been observed in situ. At last, the example of Gavet (France) illustrates a discontinuous case of numerical modelling for a good quality but fractured rock mass.PRINCIPES ET METHODES DE CONCEPTION DE GRANDES CAVERNESHYDROELECTRIQUES SOUTERRAINESRESUME Les grandes cavernes souterraines abritant les turbines, les transformateurs et certaines vannes sont des ouvrages majeurs dans les aménagements hydroélectriques. A la différence des galeries et des puits qui présentent de longs linéaires, les grandes cavernes sont des structures à la géométrie souvent complexe et avec des portées conséquentes. De plus, ces cavernes étant généralement situées en pied du circuit hydraulique, la grande couverture rocheuse peut se traduire par un état de contraintes important. Forte de ses expériences récentes en France et dans le monde, le Centre d’Ingénierie Hydraulique d’EDF a identifié de grands principes de conception des cavernes permettant l’élaboration d’une méthodologie plus générale. Le projet de Tehri en Inde est un exemple de terrain difficile, présentant à la fois une forte couverture, un matériau ductile et une schistosité marquée. Ces réalités physiques sont approchées au mieux grâce à la prise en compte dans les modélisations numériques d’une loi de comportement radoucissante avec un critère orienté intégré dans un modèle continu. Les résultats ont conduit à privilégier un soutènement souple basé sur un boulonnage systématique relativement dense associé à une fine couche de béton projeté. Cette méthodologie a ensuite été reprise pour le projet de Gilboa en Israël, exception faite de la schistosité puisque non observée sur site. L’exemple de Gavet (France) enfin permet d’illustrer un cas de modélisation numérique discontinue d’un massif rocheux de bonne qualité mais fracturé."

Jan 1, 2015

By Jose R. Hernandez-Aguilar, Jeet Basi

"The study evaluated the impact on overall circuit metallurgy of improving the performance of the two flotation columns that make up the final Mo cleaning stage in the Cu/Mo separation circuit at Highland Valley Copper mine. The results showed that a key factor to improve the overall circuit metallurgy was to control the size of the bubbles generated in the columns. When a large proportion of small (< 1 mm) bubbles were generated, the production rate of solids-in-concentrate increased by a factor of 4-5 compared to typical production figures without compromising concentrate quality. This increase in concentrate production rate reduced the circulating load in the circuit causing a significant increase of Mo recovery. A statistical analysis of historical production data showed a strong relationship between final concentrate production rate and overall Mo recovery. This relationship along with the results from this study indicated an opportunity to increase the recovery of Mo from 90% (typical) to 94% without downgrading concentrate grade. This 4% increase represents about 14,000 lbs or $500,000 worth of Mo each month at current metal prices.To provide a rational interpretation of the results, this study also examined whether the model of Gorain et al. (1997; 1998; 1999) could explain the increase of Mo recovery seemingly resulting from the decrease of bubble size. The data showed that the model predictions did not agree with the experimental data, i.e., for a given change (decrease) of bubble size, the predictions underestimated significantly the observed recovery increase. An interpretation based on the fundamental analysis of Finch and Dobby (1990) and Hernandez-Aguilar et al. (2005) is proposed to explain the discrepancy between measurements and predictions obtained from Gorain et al.’s model.INTRODUCTIONIt is generally accepted that the size of the bubbles generated in a flotation cell – a concept usually referred to as “bubble size” – has a significant effect on metallurgical performance. However, a significant number of mineral processing practitioners often question, with valid reasons, the practical benefits of implementing process improvement strategies based on controlling bubble size. “Small” bubbles are often considered to be “favourable”, but how small they need to be for a particular case, or how to adjust operating conditions to control a target bubble size, or whether the bubbles need to be smaller in the first place are questions that usually remain unanswered. Two reasons explain this situation."

Jan 1, 2009

By A. McLean, A. Hue, K. Le, Y. D. Yang, P. Wu

While the treatment of relatively inexpensive ferrosilicon alloys is a potential refining route in order to generate solar grade silicon, phosphorus is one of the more difficult impurities to remove by conventional processing. In this project, the use of an electromagnetic levitation technique was used to investigate the dephosphorization of ferrosilicon alloy droplets exposed for various times and temperatures to a hydrogen-argon gas mixture. It was found that approximately 40% of the phosphorus was removed from an 85%Si-15%Fe alloy after 20 minutes exposure at approximately 1673K, to a gas mixture containing 48.5% hydrogen. Further dephosphorization is expected with longer reaction times. The effect of increasing temperature was found to be insignificant, although processing at lower temperatures is not only economically advantageous, it also decreases evaporative silicon losses, thus resulting in a more efficient process.

Jan 1, 2015

By A. A. de Gast, R. B. James

"The metal content of ore blocks can be calculated by the use of many different methods. These methods range in sophistication from manual calculation to computer. oriented techniques. In this case a cubic polynomial regression model is developed to depict the grade distribution of an orebody. Mine production, in stope dimensions, is then simulated on a computer to predict the output of metal content. The volume, grade and variance of the grade are estimated by triple integration and matrix algebra. A case study shows reasonable agreement between the results from the mathematical model and the mine geologists' estimate of production and ore reserve grade and tonnage."

Jan 1, 1972

By W. Hawker, A. M. Ivana

"Pressure oxidation is used to liberate gold from refractory sulphide ore and concentrates with over fifteen autoclaves in operation. Despite the importance of pressure oxidation, the autoclave chemistry and chemical thermodynamics are not well established. For example, there is no consensus on aqueous iron speciation or stability of jarosite phases. Additionally, there remains questions about basic ferric sulphate formation and stability. In addition to a review of the current state of knowledge, a methodology to study the ferric precipitation reaction and relate the results to chemical thermodynamic predictions is presented which will be used to accurately define the phase boundaries of the iron precipitates in the future (hematite, jarosite and basic ferric sulphate).INTRODUCTION With declining availability of orebodies that respond to simple leaching conditions, pressure oxidation has become a prevalent technology to liberate gold locked in sulphide mineral matrices. Gold pressure oxidation was established 32 years ago, with McLaughlin being the first facility in 1985 (Thomas & Pearson, 2016). Pressure oxidation is carried out at elevated temperatures ranging from 180 to 240°C as shown in the summary of operations in Table 1 (Ruonala et al., 2016; Fleming, 2010).A considerable amount of research has been done to study iron solubility and precipitation under autoclave conditions (Tozawa & Sasaki, 1986; Umetsu et al., 1977; Sasaki et al., 1993; Fleuriault, 2016; Cheng & Demopoulos, 2004; Papangelakis et al., 1994; Yue et al., 2003). These reports provide a description of the process chemistry and iron behaviour in the autoclave. However, there remain questions about the type and stability of aqueous species and solid phases. This detailed information is required to build a robust chemical thermodynamic model of the system, allowing for equilibrium and kinetic reaction limitations to be discerned."

Jan 1, 2017

By Alex Cormode, Carlos Perucca

"Sylvinite ore from the Saskatoon area typically contains about 5% insolubles, occurring as clays and carbonates. These insoluble slimes must be removed sufficiently well to permit an efficient subsequent potassium chloride flotation, due to their high adsorptive capacity for amines used as potash collectors. The insolubles are liberated from sylvinite by high attrition scrubbing in a slurry. The liberated slimes are separated by multistage cycloning or by a selective flocculation-flotation process.An outline of the potash processing operations at Agrium Vanscoy Potash Operations is given, emphasizing the insoluble slimes froth flotation separation process. This process was originally implemented at the Agrium plant in the mid- 1970's and replaced a hydrocyclone system.IntroductionAgrium Vanscoy Potash Operations is located 40 Km southwest of Saskatoon, almost midway between the communities of Vanscoy and Delisle. Processing operations started in 1969, and the annual production capability was subsequently increased to the current 1.8 MM tonnes per year of muriate of potash.The mining operation at Agrium Potash which was described in a paper by Jones and Pruggerl , is done underground using four large continuous double rotor boring machines for the main production with development done by heliminers. Annual ore production is 5.5 MM tonnedannum. Ore is hoisted 1,100 m to surface for processing."

Jan 1, 1999