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By A. Sutherland Brown

"The ProblemMany science activities receive substantial funding from governments without much direct economic benefit accruing to state or individuals. In contrast, the search for knowledge has never been an acceptable so le justification of geoscience activity, perhaps because of its utility right from its inception. William Smith's geological activities were embraced because of their usefulness in building canals. Utility has been expected ever since.For decades it has been accepted at senior level s of government, without much understanding of the process, that geological surveys are necessary as a basis of resource evaluation and utilization. Recently, government treasury board s, staffed with economist s, have questioned these near axioms and in many cases the budget s of geological surveys have reflected their stone y-eyed appraisal s. Are government surveys necessary? Can their functions be reduced? Can some or all of their functions be privatized?Government geologists have been muted in trumpeting their successes outside their own ranks. Companies have been reluctant to give specific public feedback on the work of government surveys that have truly aided or guided them toward discovery. Lack of acknowledged linkages between survey work and discovery has dogged survey managers in budget reviews. Impoverished surveys cannot perform adequately so the circle is completed and the doubters' prophecy fulfilled. This is the genera l problem; British Columbia is the archetypical province."

Jan 1, 1986

"Coupon testing has been used to investigate stress corrosion cracking (SCC) of rockbolts in a laboratory based experimental program. This program has focused on the use of ASTM G39 three- and four-point bent beam coupon specimens, immersed in an acidified sodium chloride test solution containing hydrogen sulfide. The specimens were loaded to a range of stresses from zero, to just above the materials yield strength. It was found that only specimens above an applied stress of 580MPa failed by means of SCC, showing that rockbolts loaded to near their yield strength may be susceptible to SCC in-situ.INTRODUCTIONStress corrosion cracking (SCC) is a failure mechanism that affects material through the growth of hairline cracks when exposed to a corrosive medium while under stress (Jones and Ricker, 1999). SCC has been found to affect rockbolts in the Australian underground coal mining industry and has the capacity to cause the catastrophic failure of ground support systems, potentially leading to falls of ground in underground excavations, injury or death to mine personnel, damage or loss of equipment, and loss of productivity through the loss of roadway access (Crosky et al, 2002).Coupon testing utilises small scale samples that are intended to be indicative of the behaviour exhibited by a material in-situ (ASTM G39). The small scale, and usually high surface area to volume ratio of coupon specimens mean that they corrode at faster rate proportional to their mass, greatly reducing testing times. The small scale of the specimens allows them to be more easily prepared and handled, loaning them to mass manufacturing techniques.A previous study conducted by Vandermaat et al (2012b) into the use of three- and four-point coupon testing in-situ in an underground coal mine failed to result in SCC of the specimens. This paper serves as a follow up laboratory investigation in order to understand why these specimens did not fail. Previous studies into the SCC in rockbolts carried out by Gamboa and Atrens (2003) determined that rockbolt steel has a critical stress threshold of approximately 90% of the material ultimate tensile strength (800-900MPa). This study will focus on this critical stress threshold as a possible explanation for the lack of failure in the in-situ specimens (Vandermaat, 2012b)."

Jan 1, 2015

By Leonardo F. Trivino

Despite the significant economical and safety implications of poor blasting practice in mining and quarrying operations, the default practice in many large operations, including both design and control, is considerably below standard when compared to other engineering disciplines. Blast dynamics includes a number of complex phenomena, such as the generation, propagation and interaction of stress waves, the expansion of high pressure, high temperature gases from the explosive components, and their combined effects upon the rock mass, including fracturing, fragmentation and displacement. In order to tackle this non-trivial problem, a combined finite and discrete element software (Y-code) capable of accounting for the dynamic behaviour of stress waves, simulating fracturing processes and modeling the expansion of gases is under development. The constitutive models used in this particular software are fundamentally simple, however, non-linearity and chaotic behaviour result as natural consequences of the interaction of relatively simple processes and mechanisms, such as propagation of stress waves in the immediate vicinity of the exploding borehole, and the creation and propagation of fractures. Advances on its development and comparisons with experimental data show realistic propagation of stress waves and fracture networks.

May 1, 2013

By J. Lee, R. G. Rosehart

"The basic problem of arsenic contamination from mine water is discussed. Effective methods of removal involving chemical precipitation, activated carbon adsorption, ion exchange and reverse osmosis are discussed. As well as an economic analysis, detail is also paid to other ions in solution which are removed simultaneously.INTRODUCTIONThe object of this paper is to review arsenic and its removal from gold extraction plant effluents. The first method considered is chemical precipitation. A second method is sorption processes, such as ion exchange resins and activated carbon adsorption. A third method is the possible application of reverse osmosis for the treatment of mine waste waters containing arsenic.Arsenic pollution in the gold mining communities of Canada and Ghana have been extensively studies (l, 2). Lynch(3) Shabunin, Gutman and Kogan( 4), Hollo, Troth, Vennes and Illinigi (5) and Hau(6) have reported their removal methods of arsenic by chemical precipitation, ion exchange and biological methods. Their conclusions were that the precipitation with Fe2+ and Fe3+ ions was most effective.Scope of the ProblemInitial aspects of this research program involved a detailed analysis of the operation of a gold extraction plant located in Canada. The name and location of the mine is proprietary information. Figure 1 gives a basic process schematic with the main tailing streams identified.Table 1 gives information as to the various mine streams and their physical and chemical composition. In this study, primary attention is paid to the removal of dissolved arsenic from waste waters. Solids from this type of operation can always be back-filled. As could be anticipated, the dissolved As content of the primary flotation tailing stream is very low. The dissolved As level in the secondary processing stream and the roasting quench water is quite high. The reason being that at this stage of the process, the arsenic has been freed from the arsenopyrite forms."

Jan 1, 1972

By Fathi Habashi

"A process is proposed for the treatment of phosphate rock for the recovery of uranium and the lanthanides. The process assures the production of phosphatic fertilizers without polluting the environment with radioactive material.IntroductionWhile many processes for uranium recovery from phosphoric acid produced by the H2S04 route are known and utilised commercially, little is known about uranium recovery from phosphoric acid produced by the HN03 route1. Advantages of the latter route are both the elimination of the gypsum disposal problem, and the possibility of radium disposal in a controlled way2. Further, the lanthanides originally present in the rock can be recovered if the nitric acid route is used; they will be mostly lost in the gypsum produced by the sulphuric acid route3. In the present work a scheme for the recovery of uranium and the lanthanides from phosphate rock without interfering with the normal route for fertiliser production is proposed using HN03 as a leaching agent. Attention was also given to uranium decay products and their separation so that they might not contaminate the fertiliser4. Further, an attempt was made to defluorinate the leach solution in order to upgrade the fertiliser and at the same time recover the fluorine5. Rapid analytical methods for the determination of uranium, radium, and lanthanides in phosphate rock were developed6,7."

Jan 1, 1997

By Kazuhide Nakaniwa

In this research, we devised a measurement method using total stations (TSs) which have ?the Baum? which is a concentric circle reticle, as substitute for crosshairs. The Baum owes its name to the similarity between the concentric circles and trees (Baum in German). By setting one circle on both of edges of cylinders, operators can set their sights on points on the center line of the cylinders, and also can measure positional coordinates of the points. Also, by measuring two different points on the center line, operators can measure the position and tilt of the axes of the cylinders. Furthermore, we developed a pile driving navigation system. Foundation piles are used for various structures, and their forms are generally cylindrical. Especially, although it is difficult to drive tilted pile foundations, their usage are expected to expand due to their high earthquake resistance. Yet, a method to accurately measure the tilts of piles has not been established. However, we proved that operators can obtain adequate accuracy to control foundation piles through the measurement experiment using this system. Using this system, the information of the pile is measured using a TS, transferred to a PDA, and displayed from the operator?s view of the piling machine.

Aug 1, 2013

By S. Kelebek, E. Yalcin

"Two composite samples of a gold-bearing ore from North Western Quebec (Barry Township) were tested to assess their grindability, recovery by flotation and Knelson concentrator as well as extraction using cyanidation.Work index values (BWi) for two composites were found to be 10.4 and 11.0 kWh/tonne, respectively. Flotation tests involved feed samples for which the particle size ranged from a P80 value of 205 ?m to 53 ?m, which resulted in gold recoveries of 91.8% to 95.8% (at gold grades of 130 to 140 g/tonne). Cyanidation tests indicated gold extraction levels ranging from 94.2 to 97.5%. Higher, recoveries were obtained at finer grind sizes and higher cyanide strengths. However, the grind size had a bigger impact on gold leaching. Gold grade and recoveries obtained with the Knelson concentrator device were lower than those obtained by flotation. Mass recoveries to concentrate products strongly depended on the fluidization pressure used. High gold recoveries can be obtained generally at low water pressures of 3 to 4 psi. Higher water pressures produced more selectivity at the expense of higher gold losses.It can be concluded that the gold ore samples tested have good characteristics due to moderate levels of energy requirement, high gold recoveries and extraction rates attainable.INTRODUCTIONBench scale testing of ore samples is an important step in the long series of metallurgical and economic studies involved in bringing new ore bodies into production (Coleman, 1980). Through a laboratory testing program, the behaviour of an ore in a particular process on a larger scale can be established. In an exploratory manner, this testing can be helpful for classification of ores in terms of “good ore” or “problematic ore” by providing preliminary information on recoverability of target minerals. Potential problems if any can be assessed by further investigation of products (e.g., middlings) obtained as a result of testing. A detailed bench scale experimental program in the metallurgical laboratory can also provide the background work for flowsheet development. Depending on the simplicity or complexity of the ore to be tested and type of details required from a testing program, the amount of samples required in the mineral processing laboratory can vary from several kg to more than one hundred kg depending on how detailed the metallurgical testing program is."

Jan 1, 2008

By B. Rivard, D. Francis

A layered Archean magma chamber is exposed at the base of the Yasinski segment of the La Grande greenstone belt. This intrusive complex lies beneath a sequence of mafic volcanics and is underlain by granitoid basement which is crosscut by a swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm of gabbroic dykes. The gabbros of both this complex and the dyke swarm define a pronounced Fe-enrichment trend. The volcanic patterns of the La Grande and Eas tmain greens tone belts, however, define a series of iron depletion trends which originate in the iron enrichment trend of the gabbroic intrusives. These patterns suggest that the gabbros produced in the intrusive complex may serve as parental liquids for some of the lava suites of the James Bay greens tone belts.

Jan 1, 1984

By R. S. Jones

"Fording Coal Ltd. is now in its fifth year of a 15-year contract to supply 3 million long tons of clean coal per annum to its Japanese steel-making customers. The mine employs both conventional truck-shovel and unconventional ""walking"" dragline coal mining techniques in multiple-seam pits. This paper describes the present and future application of the 60-cu.-yd dragline and truck-shovel pre-stripping fleet in 1•ecovering 5- to 40-footthick coal seams in mountainous terrain. Deep blastholes, coal flow demands, spring ""run-off"", seam and inter-seam thrust faulting, limited seam outcrop data and regional faulting are a few of the problems encountered in this application. The author discusses these problems and their solutions as applied at Fording Coal Ltd."

Jan 1, 1976

By M. R. Swaan, G. J. Stewart

"ABSTRACTThe application of failsafe techniques to ask the ""What if"" questions about any process has been well established in the chemical industry for many years. The unusual number of fatalities that occurred in Ontario during 1986-87, prompted Inco management to look at the Fail Safe techniques as a method of improving safety performance.INTRODUCTIONOne of the major areas at any time for potentially disastrous accidents is the shaft, where all men and materials must travel. In April 1987, Inco's Thompson Mine's first Fail Safe Team was established to look at its shaft operations. The initial group of eight people was made up of hourly equipment operators, mine foremen, engineering, maintenance and the superintendent. This group took the name of Shaft Risk Analysis Team or SRAT.The many tasks or jobs that are performed in a shaft prompted the team to divide the work under six major headings; slinging, moving men, skipping, dewatering, shaft inspections and moving materials. Each of these areas contained many different tasks which are interrelated. The only way to understand this interrelationship was to flow chart the steps that actually occur in getting any job done.The flow charting is done by the foreman and operators using existing standard manuals and their experience of what actually takes place. In many cases, it soon became apparent that they had been ""working around"" many problems created by their standards. Fine tuning of these flow charts takes place at the weekly meetings, where input from all involved leads to a better understanding of the actual job being analyzed and its potential hazards. Two major points need to be emphasized in getting good flow charting at a mine:I. It must never be blame oriented or you will never discover how the jobs are actually done and hence you won't know what to improve.2 . All team members must have equal voting rights in deciding how to put the charts together so that they have ownership of the finished product. It is far too easy to end up with amanagement view of the way it should be. Many different techniques or methods are being employed to improve the tasks and reduce the risks associated with any job once the basic flow chart is established. The ones found to be the most useful are highlighted."

Jan 1, 1989

By Alan S. Lock

Large scale feasibility studies for the establishment of oil-seed and cellulose producing crops on mine tailings have been successfully conducted over 1 growing season with the purpose of these crops to be used as feedstock to the biofuels industry. An acid sulphide tailings impoundment in Copper Cliff, Ontario and a near neutral pH goldmine tailings impoundment in Timmins, Ontario were both tested by amending half hectare plots to approximately 1 m thick with residual biosolids from the pulp and paper industry and growing canola and corn on these plots. Full scale agricultural equipment was used to cultivate seed and harvest the plots to prove the full scale feasibility of farming on these biosolids. The vegetation development, growth, yield, quality and composition were assessed to identify the best species that would maximize biomass development for feedstock to the biofuels industry and carbon credits for the mining industry. Groundwater, biosolids and tailings chemistries were investigated to identify potential deleterious impacts of degrading organic matter on tailings metal mobility. Preliminary hydrologic investigations using moisture sensor profiles elucidate potential conservation of water in amended plots. Tailings amended with biosolids have the potential to provide the mining industry with carbon credits and supply feedstock to this new industry while reclaiming brownfields to a new level, utilizing industrial and municipal organic waste material.

May 1, 2009

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

By Kremena Dedelyanova

The paper presents research of mechanism for the creation of air bubbles in vibratory a column flotation machine. Factors are discussed that influence the increase in the duration of the bubble in the area of contact with the mineral particles. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in a vibratory column flotation machine is determined.

Aug 1, 2013

By M. Ounpuu

"Gold, because of low head grade and recovery, is usually of minor importance in the economics of base metal flotation mills. Because of the above little metallurgical attention is usually provided to gold in these mills. But collectively, the gold losses can be significant. For instance, Noranda presently has interest in 13 base metal flotation mills with a collective gold recovery of only 50%. Gold losses are in the order of 150.000 oz per year!The Noranda Technology Centre, in cooperation with Noranda's milling operations, has been investigating the potential of gravity concentration of gold from base metal flotation mills. This paper outlines the pilot and plant testing conducted at three operations with distinctly different ore types; porphyry copper, complex massive sulphide and polymetallic semi-massive sulphide. Testing has been with the Knelson Concentrator which has proven to successfully recover fine gold in a simple, trouble free circuit. Discussion of issues which have risen from the testwork is included. INTRODUCTIONGold, because of low head grade and recovery, is usually of minor importance in the economics of poly-metallic base metal ores. TABLE I presents gold heads and recovery for some of Noranda's base metal mills. It should be noted that the stated recoveries are to payable concentrates, but does not reflect the actual payable gold recovery which in cases is significantly lower. Noranda's average gold recovery into a gold payable concentrates is about 45%. This equates to a collective loss in the order of $57 MM per year of gold"

Jan 1, 1992

By G. V. Poropat

Roughness of a discontinuity may be an important factor influencing shear strength of the discontinuity. Traditionally, determining the roughness of a discontinuity surface and providing a numerical measure of the roughness has required considerable effort or specialised equipment. The development of new 3D imaging tools that are easy to use has provided effective fast and accurate means of creating 3D surface models from which roughness measurements can be readily obtained. These new techniques are versatile enabling a user to measure roughness along any desired profile and at any resolution up to the limit of the spatial subtense of a measurement on the discontinuity surface. This paper primarily reviews extensions to the use of 3D imaging that enable the measurement of roughness. Additionally we provide some examples of the measurements and examine some of the issues associated with extracting measures from the spatial data that will support estimation of shear strength.

May 1, 2009

By W. Standifird

"Cohesive fracture is a mechanical model widely used for modeling quasi-brittle fracture in rocklike materials. This work discusses use of this model to simulate quasi-brittle fractures generated by injection stimulation during the process of cuttings reinjection in West Africa. Cuttings reinjection is an engineering practice used for disposal of drilling waste. During this process, hydraulic fractures are created at the target formation and milled cuttings are injected with fluid. In practice, this process must remain in compliance with environmental regulations and zero-discharge policies. The purpose of this study is to determine the following factors of injection design for a field in West Africa: (1) pumping pressure capacity required to successfully perform the injection and (2) the injection rate for injection performance and the value of fracture width under injection.A simplified three-dimensional (3D) finite element model (FEM) was built. A poroelastic plastic damage model was used for simulation of the cohesive crack prorogation within the target formation. For simplicity, fracture development in both horizontal and vertical directions was simulated separately. In this way, the computational burden for one calculation was reduced to a reasonably low level, without losing accuracy of the model. Loads of the model include fluid injection and gravity, which balances the initial geostress field. Various values of injection rate were used in these calculations to determine the most reasonable value of injection pressure. The capacity of pressure of a pumping device was determined using this optimized value of injection pressure.Results in values of width and length of fractures created by the injection are presented. Injection pressures at bottom-hole (BHP) corresponding to each value of injection rate are also given. Numerical results for fracture generation and propagation in a horizontal direction were visualized. The pumping pressure capacity required to fulfill the cuttings reinjection work was determined based on the numerical results of optimized injection rates and pressure. The fracture width was determined using the given pumping pressure. The length and height of the fractures was determined using pumping pressure along with the required volume of cuttings waste to be disposed of into the formation.This work presents a case study of 3D finite element modeling of hydraulic fracturing generated by cuttings reinjection. The results of the optimized injection rate and pressure provide a best practice and a useful reference for cuttings reinjection analyses in this region."

Jan 1, 2015

By Marvin J. Udy

THE preparation of this paper is in response to many requests for in-formation on the mining and smelting developments which have been carried on for the past three years or more by the Chromium Mining and Smelting Corporation of Canada. By way of introduction, the following paragraphs, relating to the early history and present status of the chrome-mining industry in the United States, are of interest. They are quoted from Bulletin No. 76 of the California State Mining Bureau, published in August, 1918: 'Chromium was discovered about 1797 by a French chemist, Louis Nicolaus Vauquelin, in ore from Siberia. From that time until 1827, the Urals, in the region of Ekaterinburg, supplied the chromium used in . Europe. In the summer of 1827, as the historian advises us, Isaac Tyson, Jr., saw in a Baltimore market-place a cart containing a cider barrel, which was held from rolling about by some heavy black stones. He had made a study of such stones at the first-known American locality, the Bare hills near his father's home, six miles from Baltimore, and he recognized the black stones as chromite. On inquiry, he found the chromite came from the Reed farm in Harford county, 27 miles northeast of Baltimore. At this time, Tyson was one of the very few men in the country who knew the value of chromite, and in the next few years he took full advantage of this knowledge. He immediately bought the Reed farm. He found about 30 tons of float-ore on the surface, but there was no outcrop of ore in place. Never-theless, he sank a shaft, and at a depth of eight feet struck an ore-pocket which proved to be 80 ft. long, 25 ft. wide, and 8 ft. in maximum thickness. His next discovery was of placer chromite in the sands in the beds of brooks on an estate called Soldiers' Delight, 16 miles northwest of Baltimore. Thus far, Tyson's observations had shown him that chromite occurred apparently only in serpentine areas. His explorations were now leading him farther afield. In 1828, he found on the Wood Farm, in Lancaster county, Pennsylvania, a deposit of float chromite which led him to lease the ore-right of the farm, which he finally purChased in 1832. Here he developed the famous Wood mine, the largest single producer of chromite in the world.

Jan 1, 1938

By John W. Korczak

The use of geological and grade block models has been standard practice in mine design for many years now, with a wide range of software available for creation and analysis. Although geotechnical parameters are of vital importance to mine planning there is very little in the way of commercially available systems for integrating geotechnical data into the mine planning and design process. Sirovision is a new technology developed by the CSIRO (Commonwealth Scientific and Industrial Research Organization) in Australia for automated, safe and accurate 3D mapping of geological and geotechnical features. Datamine has integrated this capability into its product range so that Sirovision has become an integral part of the day-to-day mapping, mine geology and geological / geotechnical modeling in both open pit and underground mine environments. This is the first integrated underground application of Sirovision from Datamine collaboration with Xstrata Nickel at the Nickel Rim South Project. This paper discusses the role of Sirovision in collecting the raw data required for geological and geotechnical analysis and the interpretation in a quick, safe, auditable and reproducible manner.

May 1, 2009

By R. A. Bergman

"Process descriptions are provided for the following ten plants that treat high-magnesia lateritic nickel ores (saprolite) by pyrometallurgical means: PT Aneka Tambang; Cerro Matoso S.A.; Falconbridge Dominicana C. por A.; Hyuga Smelting Company Ltd.; Larco (Societé Minière & Métallurgique de Larymna); Loma de Niquel; Le Nickel, SLN-Eramet; Nippon Yakin Kogyo Company Ltd.; Pacific Metals Company Ltd.; and PT Inco Indonesia.Flowsheets, equipment information,chemistry and production data have been compiledfor plants based on both information providedby the companies and on calculated massand energy balances.IntroductionNickel is of vital importance to modern society. Without it, we would not be able to enjoy many of the things that we take for granted, such as computers, airplanes and stainless steel appliances in our homes and workplaces, to mention a few.Nickel occurs in nature both as sulphide and oxide ores. Approximately 36% of the nickel reserves in the Western World occur as sulphide and 64% as oxide ores. Sulphide ores respond to concentration processes, whereas, oxide ores do not. Sulphide ores mined at 1% nickel can be readily concentrated to 10% nickel, whereas, oxide ores cannot be concentrated and therefore have to be processed as mined.Laterite ores are normally classified intotwo groups:1. The high-magnesia ores, saprolites or serpentines, are, as a rule, processed by smelting. The main reason for this is that the nickel replaces magnesium in the magnesium-silicate lattice. To be able to recover nickel, the lattice has to be destroyed. This can be achieved by smelting under reducing conditions.Acid leaching is also possible, but in this case, large amounts of MgSO4 or MgCl2 will be produced making it costly to regenerate the acid.2. The high-iron, low-magnesia ores are known as limonite. The nickel is relatively loosely bonded to goethite and hence can be recovered by selective reduction followed by ammonium-ammonium carbonate leaching. In recently developed processes, these ores are also being extracted by acid pressure leaching, with high Ni and Co recoveries.This paper focusses on the production of ferronickel and nickel matte from the highmagnesia ores."

Jan 1, 2003

By A. Roca, V. A. Quezada, O. A. Benavente, M. Cruells

The leaching pretreatment of copper ores is widely used in the Chilean mining industry. Agglomeration and acid curing have been identified as the most useful pretreatments. Of these, acid curing was recognized as beneficial in the dissolution of copper minerals, even in sulphides such as chalcopyrite. Extensive acid curing times have an impact on copper extraction, generate a homogeneous acid distribution in the mineral bed and benefit the inhibition of aluminum-silicate minerals (acid consumers). This document describes some of the theoretical background and results regarding the effect of acid curing in a chalcopyrite sample with 74% purity according to Qemscan analysis and a 28.5% of total copper. Leaching tests are carried out at 25, 50 and 70°C, evaluating the effect of a pretreatment on the chalcopyrite dissolution. The original sample and products generated were characterized by X-ray diffraction analysis and Scanning Electron Microscopy (SEM). The performed experiments indicate a direct relation between the effect of curing time and temperature in copper extraction. 92% of copper can be extracted in a leaching at 70°C and with 15 days of curing. Elemental sulfur, jarosite and copper polysulfide (CuS2) have been detected in leaching products. INTRODUCTION The copper extraction from minerals is a technique that has been developed for hundreds of years in the world. In 2017, the largest copper producer was Chile, exported 5.5 million tons (COCHILCO, 2018). However, in order to preserve this production level means overcoming multiple challenges. In the case of the Chilean copper deposits, the average copper grade in 2016 was 0.65%, lower than the 1% declared in 2004 (Consejo Minero, 2018). This is mainly due to the deeper of the deposits reaching sulfide mineral zones, mainly chalcopyrite. Traditionally, these sulfurized zones ore are treated through concentration by flotation and subsequent pyrometallurgical treatments. However, for some copper companies it is complex to process by this alternative, due to the high costs and high rates of water consumption. The mineral resources of these companies are known as "low-grade sulfides" and do not allow, economically, the treatment of these minerals through concentration by flotation. This is how hydrometallurgy becomes an alternative for the treatment of this type of deposits. In addition, several companies have hydrometallurgical plants, which would allow the operational continuity of these plants.

Jan 1, 2019